CN102587130B - Processing method of durable nano water-and-stain-proofing woolen fabric - Google Patents
Processing method of durable nano water-and-stain-proofing woolen fabric Download PDFInfo
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- CN102587130B CN102587130B CN 201210056926 CN201210056926A CN102587130B CN 102587130 B CN102587130 B CN 102587130B CN 201210056926 CN201210056926 CN 201210056926 CN 201210056926 A CN201210056926 A CN 201210056926A CN 102587130 B CN102587130 B CN 102587130B
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- 239000004744 fabric Substances 0.000 title claims abstract description 62
- 238000003672 processing method Methods 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 25
- 238000012545 processing Methods 0.000 claims abstract description 15
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 59
- 239000002689 soil Substances 0.000 claims description 54
- 238000004043 dyeing Methods 0.000 claims description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 238000002203 pretreatment Methods 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 206010016825 Flushing Diseases 0.000 claims description 6
- 238000011010 flushing procedure Methods 0.000 claims description 6
- 238000006386 neutralization reaction Methods 0.000 claims description 6
- 238000009941 weaving Methods 0.000 claims description 6
- 238000003287 bathing Methods 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 12
- 239000000835 fiber Substances 0.000 abstract description 5
- 230000035699 permeability Effects 0.000 abstract description 3
- 238000005096 rolling process Methods 0.000 abstract description 2
- 238000007781 pre-processing Methods 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 239000012466 permeate Substances 0.000 abstract 1
- 238000005108 dry cleaning Methods 0.000 description 9
- 230000003373 anti-fouling effect Effects 0.000 description 3
- 210000000085 cashmere Anatomy 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- -1 fluoroalkyl acrylates Chemical class 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Treatment Of Fiber Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a processing method of a durable nano water-and-stain-proofing woolen fabric, aiming to provide the processing method of the durable nano water-and-stain-proofing woolen fabric, which has a simple processing process, less resource and energy consumption, short construction period and a durable water-and stain-proofing effect. The processing method comprises the following steps of: preprocessing to a fabric and water-and-stain-proofing finishing of co-bath padding of a nano water-and-stain-proofing finishing agent and a cross-linking agent. According to the invention, by the preprocessing process and using the corresponding additives, the permeability of the water-and-stain-proofing agent in the fabric in the following water-and-stain-proofing processing is greatly improved; and simultaneously, in water-and-stain-proofing processing, various corresponding water-and-stain-proofing processing agents and a twice-immersing twice-rolling process are adopted, so that the water-and-stain-proofing processing agent can be fully combined with the fabric, and can permeate into the insides of fibers, and further, the water-and-stain proofing effect is more durable.
Description
Technical field
The present invention relates to textile product, relate in particular to the processing method of the durable nano water-and-stain-proofing woolen fabric of cashmere, the rabbit hair, wool blended series products.
Background technology
Society, people are constantly improving the requirement of dressing fabric, except warming, comfortable, fashion are the target pursued of people, and specific function, textiles with high content of technology are arranged, and more and more are subject to consumer's favor.Because the technological progress of material is dyed in weaving, the research and development of specific function textiles have also been promoted to have.At present high-end market is larger to the demand of water proof anti-soil fabric, as cashmere fiber is tool affinity to skin, so cashmere product is subject to the welcome of high-end piece market most.Contrary these high-grade fabrics also preferably can be washed less, and therefore many fabrics just require the function of water proof anti-soil.
At present can be more for the auxiliary agent of water proof anti-soil fabric, but the auxiliary agent that through disposable processing processing, can reach water proof anti-soil is seldom.Although nano assistant is arranged, its molecular particle size is very thin, usually is less than 100nm, has good dispersiveness, permeability, can manyly be adsorbed onto more equably on fabric, therefore with the nano water-proof anti-soil agent, can obtain water proof anti-soil effect preferably.If, but, by after repeatedly dry-cleaning, its effect can obviously descend, as uses following 5 kinds of finishing agents to process through routine, effect is also unsatisfactory after testing:
As can be seen from the above table, the water proof anti-soil effect before dry-cleaning is relatively good after treatment, but classification of waterproof and all obviously reductions of antifouling grade after dry-cleaning generally descends more than 2 grades or 2 grades through 3-5 dry-cleaning.Although process and can suitably improve the water proof anti-soil performance as the auxiliary agent through repetitious water proof anti-soil, can bring damage to the quality of fabric, can bring the waste of more pollution and water resource and the energy in processing procedure, work consuming is consuming time large, less economical.If carry out after water proof anti-soil processes, can also keep water proof anti-soil performance preferably through dry-cleaning repeatedly, to the quality of water proof anti-soil fabric, will be great raising, also saved multiple resources.
Summary of the invention
The object of the present invention is to provide that a kind for the treatment of process is simple, resource and energy resource consumption few, the process-cycle is short, the processing method of the durable nano water-and-stain-proofing woolen fabric that the water proof anti-soil effect is lasting.
In order to reach above-mentioned requirements, the processing method of durable nano water-and-stain-proofing woolen fabric: it includes successively to the pre-treatment of fabric with nano water-proof anti-soil agent and crosslinking agent and arranges with bathing the water proof anti-soil padded, and the feature of its treatment process is:
(1) pre-treatment:
Use following auxiliary agent:
ECO-9 finishing agent 15-25%o.w.f (weight ratio of fabric and ECO-9 finishing agent)
NaHCO
3(every premium on currency is containing 15-25g NaHCO for 15-25g/l
3)
Na
2sO
4(every premium on currency is containing 10-20g Na for 10-20g/l
2sO
4)
Bath raio (weight ratio of fabric and water): 1: 10-1: 15
Fabric is through the rope dyeing machine pre-treatment in above-mentioned auxiliary agent, and specifically treatment process is successively:
When 25 ℃ ± 3 ℃ of temperature, 12-18 minute → rope dyeing machine of rope dyeing machine running running 20-30 minute, be warmed up to 70 ℃ ± 3 ℃, → insulation under the environment of 70 ℃ ± 3 ℃, rope dyeing machine running 35-45 minute → with 8-15 minute → draining of 40 ℃ ± 3 ℃ water temperatures flushings;
Neutralisation treatment technique: add the neutralization of 1% acetum in rope dyeing machine; bath raio (weight ratio of fabric and water): 1: 10-1: 15; heat 50 ℃ ± 3 ℃; fabric turns round in rope dyeing machine, and 12-18 minute → draining → with the clear water flushings of 25 ℃ ± 3 ℃, 8-15 minute → draining → detection pH value is between 6-6.5;
Dry: the fabric after processing is dried at 90 ℃ of-110 ℃ of temperature;
(2) water proof anti-soil arranges:
Water proof anti-soil finishing agent and consumption:
UEG-3 nano water-proof anti-soil agent: consumption is that every premium on currency is containing 50-70g;
The J2 crosslinking agent: consumption is that every premium on currency is containing 2.5-4.5g;
Propylene glycol: consumption is that every premium on currency is containing 15-25g;
The weaving nonionic penetrant: consumption is that every premium on currency is containing 0-3.5g;
Pick-up; 70%--75%;
Water proof anti-soil finishing technique: fabric is immersed in the above-mentioned mixed uniformly water proof anti-soil finishing agent of 25 ℃ of temperature, through twice roll-in of twice immersion of water calender roll, wherein the pressure of roll remains on 0.45-0.55MPa, the speed that fabric advances roll is 6-8 m/min, and during roll-in, fabric enters roll and will keep smooth;
(3) bake routinely: preliminary drying: 80 ℃--90 ℃; Bake: 175 ℃--180 ℃, the time: 1 minute;
(4) become the finished product with water proof anti-soil fancy yarn after arrangement afterwards routinely.
The not good reason of analytic routines water proof anti-soil treatment effect is that the nano water-proof anti-soil agent is not combined with fiber, just by self-crosslinking, cover fiber surface formation one deck and refuse the water film, perhaps too low with the crosslinked degree of fiber and cause adhesion little, so the durability of water proof anti-soil is poor.The permeability of water proof anti-soil agent in fabric when the present invention is follow-up water proof anti-soil processing by pre-treatment process and the corresponding auxiliary agent of use is greatly enhanced, simultaneously when water proof anti-soil is processed, adopt corresponding multiple water proof anti-soil finishing agent and two to soak two roll process and make water proof anti-soil finishing agent and the abundant combination of fabric, and be penetrated into fibrous inside, make water proof anti-soil more lasting.
The accompanying drawing explanation
Fig. 1 is the pre-treatment process curve map.
The specific embodiment
Below in conjunction with by embodiment and accompanying drawing, the invention will be further described.
The processing method of durable nano water-and-stain-proofing woolen fabric: it includes successively to the pre-treatment of fabric with nano water-proof anti-soil agent and crosslinking agent and arranges with bathing the water proof anti-soil padded, and the feature of its treatment process is:
(1) pre-treatment:
Use following auxiliary agent:
ECO-9 finishing agent 15-25%o.w.f (weight ratio of fabric and ECO-9 finishing agent)
NaHCO
3(every premium on currency is containing 15-25g NaHCO for 15-25g/1
3)
Na
2sO
4(every premium on currency is containing 10-20g Na for 10-20g/l
2sO
4)
Bath raio (weight ratio of fabric and water): 1: 10-1: 15
Fabric is through the rope dyeing machine pre-treatment in above-mentioned auxiliary agent, and specifically treatment process is successively:
When 25 ℃ ± 3 ℃ of temperature, 12-18 minute → rope dyeing machine of rope dyeing machine running running 20-30 minute, be warmed up to 70 ℃ ± 3 ℃, → insulation under the environment of 70 ℃ ± 3 ℃, rope dyeing machine running 35-45 minute → with 8-15 minute → draining of 40 ℃ ± 3 ℃ water temperatures flushings;
Neutralisation treatment technique: add the neutralization of 1% acetum in rope dyeing machine; bath raio (weight ratio of fabric and water): 1: 10-1: 15; heat 50 ℃ ± 3 ℃; fabric turns round in rope dyeing machine, and 12-18 minute → draining → with the clear water flushings of 25 ℃ ± 3 ℃, 8-15 minute → draining → detection pH value is between 6-6.5;
Dry: the fabric after processing is dried at 90 ℃ of-110 ℃ of temperature;
Above-mentioned pre-treatment process curve map as shown in Figure 1;
(2) water proof anti-soil arranges:
Water proof anti-soil finishing agent and consumption:
UEG-3 nano water-proof anti-soil agent: consumption is that every premium on currency is containing 50-70g;
The J2 crosslinking agent: consumption is that every premium on currency is containing 2.5-4.5g;
Propylene glycol: consumption is that every premium on currency is containing 15-25g;
Nonionic penetrant is used in weaving: use the SP-2 bleeding agent, consumption is that every premium on currency is containing 0-3.5g;
Pick-up; 70%--75%;
Water proof anti-soil finishing technique: fabric is immersed in the above-mentioned mixed uniformly water proof anti-soil finishing agent of 25 ℃ of temperature, through twice roll-in of twice immersion of water calender roll (two soak two rolls), wherein the pressure of roll remains on 0.45-0.55MPa, the speed that fabric advances roll is 6-8 m/min, and during roll-in, fabric enters roll and will keep smooth.Above-mentioned pick-up also is liquid carrying rate, be on fabric with liquid weight and the percentage of the weight of fabric own.Be fabric after solution on the stock tank band, through rolling rod roll on cloth cover later with solution weight and pad the percentage of front original fabric weight.Two soak two rolls and refers to fabric and contaminate dye liquor and rolled by roll, repeats twice.A pads front fabric weight; B pads rear fabric weight, pick-up=(B-A)/A*100%.As: fabric original weight 100 grams, after twice pads, weigh 170 grams, pick-up is 70%;
(3) bake routinely: preliminary drying: 80 ℃--90 ℃; Bake: 175 ℃--180 ℃, the time: 1 minute;
(4) become the finished product with water proof anti-soil fancy yarn after arrangement afterwards routinely.
General finishing agent consumption is different and different according to the kind of processing fabric, as shown according to the form below:
Wherein the main component of ECO-9 finishing agent is many hydroxys amino-compound, and effect is the durability that increases the water proof anti-soil effect; The main component of UEG-3 nano water-proof anti-soil agent is dihalo triazine cyclisation thing, and effect is to give the fabric waterproof anti-pollution function; J2 crosslinking agent main component is fluoroalkyl acrylates resin, makes between the molecular structure of each finishing agent and finishing agent to obtain stable cross-linked structure.The effect of propylene glycol is the solubility that improves other water proof anti-soil finishing agents; Weaving improves the osmosis of water proof anti-soil finishing agent to fabric with nonionic penetrant, fabric is played to wetting, emulsification simultaneously, above-mentioned ECO-9 finishing agent, UEG-3 nano water-proof anti-soil agent and J2 crosslinking agent are all on sale in market, are that Shanghai Mei Xue International Trading Company Ltd produces in the present embodiment; Propylene glycol, with nonionic penetrant, market is on sale at home in weaving, as bleeding agent SP-2 etc.
The water proof anti-soil fancy yarn finished product of processing according to said method, check that through Japanese woolen association (Tianjin) detects: the finished product waterproof reaches 5 grades, still can reach 4 grades after dry-cleaning 5 times; Finished product is antifouling is 5 grades, after dry-cleaning 5 times, still can reach 4 grades, and indices all is better than Nippon Standard.In addition, finished product detects through national wool spinning product quality supervision and test centers (Shanghai): 5 grades of finished product waterproof reach 4 grades after dry-cleaning 5 times; Antifouling 5 grades of finished product, reach 3.5 grades after dry-cleaning 3 times.From detecting data, its water proof anti-soil Performance Ratio conventional method of product after processing with the said method water proof anti-soil is significantly increased.
Claims (1)
1. the processing method of durable nano water-and-stain-proofing woolen fabric, it includes successively to the pre-treatment of fabric with nano water-proof anti-soil agent and crosslinking agent and arranges with bathing the water proof anti-soil padded, and the feature of its treatment process is:
(1) pre-treatment:
Use following auxiliary agent:
ECO-9 finishing agent 15-25%o.w.f.
NaHCO
315-25g/L
Na
2SO
410-20g/L
Bath raio: 1: 10-1: 15
Fabric is through the rope dyeing machine pre-treatment in above-mentioned auxiliary agent, and specifically treatment process is successively:
When 25 ℃ ± 3 ℃ of temperature, 12-18 minute → rope dyeing machine of rope dyeing machine running running 20-30 minute, be warmed up to 70 ℃ ± 3 ℃, → insulation under the environment of 70 ℃ ± 3 ℃, rope dyeing machine running 35-45 minute → with 8-15 minute → draining of 40 ℃ ± 3 ℃ water temperatures flushings;
Neutralisation treatment technique: add the neutralization of 1% acetum in rope dyeing machine; bath raio: 1: 10-1: 15; heat 50 ℃ ± 3 ℃; fabric turn round in rope dyeing machine, and 12-18 minute → draining → with the clear water flushings of 25 ℃ ± 3 ℃, 8-15 minute → draining → detection pH value is between 6-6.5;
Dry: the fabric after processing is dried at 90 ℃ of-110 ℃ of temperature;
(2) water proof anti-soil arranges:
Water proof anti-soil finishing agent and consumption:
UEG-3 nano water-proof anti-soil agent: consumption is that every premium on currency is containing 50-70g;
The J2 crosslinking agent: consumption is that every premium on currency is containing 2.5-4.5g;
Propylene glycol: consumption is that every premium on currency is containing 15-25g;
The weaving nonionic penetrant: consumption is that every premium on currency is containing 0-3.5g;
Pick-up: 70%--75%;
Water proof anti-soil finishing technique: fabric is immersed in the above-mentioned mixed uniformly water proof anti-soil finishing agent of 25 ℃ of temperature, through twice roll-in of twice immersion of water calender roll, wherein the pressure of roll remains on 0.45-0.55MPa, the speed that fabric advances roll is 6-8 m/min, and during roll-in, fabric enters roll and will keep smooth;
(3) bake routinely: preliminary drying: 80 ℃--90 ℃; Bake: 175 ℃--180 ℃, the time: 1 minute;
(4) become the finished product with water proof anti-soil fancy yarn after arrangement afterwards routinely.
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|---|---|---|---|
| CN 201210056926 CN102587130B (en) | 2012-03-05 | 2012-03-05 | Processing method of durable nano water-and-stain-proofing woolen fabric |
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| CN102965817A (en) * | 2012-11-26 | 2013-03-13 | 江苏申利实业股份有限公司 | Waterproof monomer-resisting fabric and production method thereof |
| CN110409183A (en) * | 2019-08-31 | 2019-11-05 | 三赢家居用品(河源)有限公司 | A kind of free-floride water-proof aagent and its methods for making and using same |
| CN110565379A (en) * | 2019-09-04 | 2019-12-13 | 世联汽车内饰（苏州）有限公司 | Healthy antifouling automobile fabric and preparation method thereof |
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| CN100535228C (en) * | 2007-09-18 | 2009-09-02 | 江苏联发纺织股份有限公司 | Antifouling, water-proof and non-ironing post finishing method for woven plus material |
| CN102051824A (en) * | 2009-10-28 | 2011-05-11 | 山东魏桥创业集团有限公司 | Method for preparing water, oil and stain repellent and easy-to-clean household fabric |
| CN101709545B (en) * | 2009-12-15 | 2012-05-23 | 宁波艾利特服饰有限公司 | Finishing method for textile fabrics |
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Effective date of registration: 20211227 Address after: 276200 No. 16, Wenhe Third Road, Mengyin County, Linyi City, Shandong Province Patentee after: Shandong Shenzhou Wool Textile Co.,Ltd. Address before: 314100 No. 66, Chengxi Avenue, Luoxing street, Jiashan County, Zhejiang Province Patentee before: Zhejiang Shenzhou Woollen Textile Co.,Ltd. |
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Effective date of registration: 20240520 Address after: 276000, No. 4 Wenhe 3rd Road, Mengyin County Economic Development Zone, Linyi City, Shandong Province Patentee after: Shandong Huaao Textile Technology Co.,Ltd. Country or region after: China Address before: 276200 No. 16, Wenhe Third Road, Mengyin County, Linyi City, Shandong Province Patentee before: Shandong Shenzhou Wool Textile Co.,Ltd. Country or region before: China |