CN107815136A - A kind of static-free glue band base-material and its calendering formation method - Google Patents

A kind of static-free glue band base-material and its calendering formation method Download PDF

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Publication number
CN107815136A
CN107815136A CN201711079542.2A CN201711079542A CN107815136A CN 107815136 A CN107815136 A CN 107815136A CN 201711079542 A CN201711079542 A CN 201711079542A CN 107815136 A CN107815136 A CN 107815136A
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parts
static
ldpe
density polyethylene
thermoplastic
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CN201711079542.2A
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张永宏
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Individual
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Priority to CN201711079542.2A priority Critical patent/CN107815136A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/22Presence of unspecified polymer
    • C09J2400/226Presence of unspecified polymer in the substrate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of static-free glue band base-material, it is made up of the component of following parts by weight:10~20 parts of 60~80 parts of alkali-free glass fibre, 10~20 parts of thermoplastic, 5~10 parts of low density polyethylene (LDPE), 3~10 parts of polyacrylamide, 2~4 parts of potassium zinc composite liquid stabilizing agent, 1~2 part of lubricant, 3~4 parts of adhesive and flexibilizing agent.Static-free glue band prepared by the present invention has wear-resisting and antistatic function concurrently, and antistatic performance is lasting, can be used under various Different climate damp conditions, and high financial profit, cost is low, service life length.

Description

A kind of static-free glue band base-material and its calendering formation method
Technical field:
The present invention relates to tape technology field, more particularly to a kind of static-free glue band base-material and its calendering formation method.
Background technology:
With the rapid development of electronic technology, integrated circuit physical size gradually reduces, the continuous improvement of integrated level, and More new high polymer material widely uses, and Electro-static Driven Comb increasingly becomes important, the problem of electrostatic protection also increasingly by More extensive concern.FPC so far is (referred to as:Flexible PCB) manufacturing process nearly all be using subtractive process (etching Method) processing, generally using copper coated foil plate as the material that sets out, using photoetching process formed resist layer, etching removing should not part copper Face forms circuit conductor, then HTHP pressing cover layer composition wiring board.Resistance to height is needed in this wiring board formation process Warm protection adhesive tape, is protected to its PI carrier layer, it was not pressed by the erosion of etching decoction and in cover layer Protect it from being destroyed in journey.Need to remove high temperature resistant protection adhesive tape after the laminating end of cover layer, shelled after high-temperature process It is easy to produce electrostatic from adhesive tape, caused accumulation of static electricity easily influences its performance being made after wiring board on PI faces;Therefore On the one hand require that High temperature-resistanadhesive adhesive tape has preferable heat-resisting quantity, i.e., peeled off after high temperature without cull;On the other hand, also require resistance to High temperature gummed tape has electrostatic-proof function.
At present, some high-temperature-resistant antistatic adhesive tapes on the market still have following problem:(1) to glue-line and the folder of base material Ionic additive is introduced in layer, its electrostatic conductive performance relies primarily on humidity in environment, in hot environment, will be unable to play just Normal anti-static electrification;(2) ionic additive is introduced into glue-line, because these ionic additives can directly connect with PI faces Touch, and the risk from migrate and being transferred on PI faces to film surface in glue-line be present, pollute PI faces;(3) into adhesive Conductive metal particles or high molecular particle are introduced, although its own can keep static conductive function, due to these conductive The introducing of grain, will have influence on some performances of adhesive in itself, such as reduce cohesive strength, adhesive tape transparency.
The content of the invention:
It is good that the technical problems to be solved by the invention are to provide a kind of feature of environmental protection, and elasticity is good, pliability is high, and toughness is strong Static-free glue band base-material.
In order to solve the above technical problems, the present invention uses following technical scheme:
A kind of static-free glue band base-material, is made up of the component of following parts by weight:60~80 parts of alkali-free glass fibre, thermoplastic 10~20 parts of plastics of property, 5~10 parts of low density polyethylene (LDPE), 3~10 parts of polyacrylamide, potassium zinc composite liquid stabilizing agent 2~4 Part, 1~2 part of lubricant, 3~4 parts of adhesive and 10~20 parts of flexibilizing agent.
The preferable weight of each component is:It is 80 parts of alkali-free glass fibre, 15 parts of thermoplastic, 5 parts of low density polyethylene (LDPE), poly- 15 parts of 5 parts of acrylamide, 3 parts of potassium zinc composite liquid stabilizing agent, 1 part of lubricant, 4 parts of adhesive and flexibilizing agent.
Described flexibilizing agent includes following components by weight:5~8 parts of atoleine, 3~4 parts of silicone oil, nanometer titanium dioxide 1~2 part of 1~2 part of titanium and N- methylols stearamide.
A kind of calendering formation method of static-free glue with base-material, it is characterised in that:Comprise the following steps,
(1) mixed after weighing alkali-free glass fibre, thermoplastic, low density polyethylene (LDPE) by proportioning, the order of addition First to add thermoplastic and low density polyethylene (LDPE), alkali-free glass fibre is added;
(2) by naphthalate, thermoplastic and low density polyethylene (LDPE) high-speed kneading into pasty state, in high-speed kneading While be uniformly added into polyacrylamide, potassium zinc composite liquid stabilizing agent, lubricant, adhesive and flexibilizing agent, mediate 60-80 points Clock;
(3) extrusion molding, extrusion temperature are 170~190 DEG C;
(4) calendering formation, the temperature of calendering is 190~200 DEG C;
(5) surface trimming.
The mixture that described high temperature mediates pasty state is filtered using 180 mesh copper mesh.
The beneficial effects of the invention are as follows:Static-free glue band prepared by the present invention has wear-resisting and antistatic function concurrently, prevents quiet Electrical property is lasting, can be used under various Different climate damp conditions, and high financial profit, cost is low, service life length.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of static-free glue band base-material, is made up of the component of following parts by weight:80 parts of alkali-free glass fibre, thermoplasticity modeling 15 parts of material, 5 parts of low density polyethylene (LDPE), 5 parts of polyacrylamide, 3 parts of potassium zinc composite liquid stabilizing agent, 1 part of lubricant, adhesive 4 15 parts of part and flexibilizing agent.
Described flexibilizing agent includes following components by weight:8 parts of atoleine, 4 parts of silicone oil, 2 parts of nano titanium oxide With 2 parts of N- methylols stearamide.
A kind of calendering formation method of static-free glue with base-material, it is characterised in that:Comprise the following steps,
(1) mixed after weighing alkali-free glass fibre, thermoplastic, low density polyethylene (LDPE) by proportioning, the order of addition First to add thermoplastic and low density polyethylene (LDPE), alkali-free glass fibre is added;
(2) naphthalate, thermoplastic and low density polyethylene (LDPE) high-speed kneading are mediated into paste into pasty state, high temperature The mixture of shape is filtered using 180 mesh copper mesh, and it is compound that polyacrylamide, potassium zinc are uniformly added into while high-speed kneading Liquid stabilisers, lubricant, adhesive and flexibilizing agent, mediate 60-80 minutes;
(3) extrusion molding, extrusion temperature are 170~190 DEG C;
(4) calendering formation, the temperature of calendering is 190~200 DEG C;
(5) surface trimming.
Embodiment 2
A kind of static-free glue band base-material, is made up of the component of following parts by weight:80 parts of alkali-free glass fibre, thermoplasticity modeling 20 parts of material, 10 parts of low density polyethylene (LDPE), 10 parts of polyacrylamide, 4 parts of potassium zinc composite liquid stabilizing agent, 2 parts of lubricant, adhesive 4 parts and 20 parts of flexibilizing agent.
Described flexibilizing agent includes following components by weight:5 parts of atoleine, 3 parts of silicone oil, 1 part of nano titanium oxide With 1 part of N- methylols stearamide.
A kind of calendering formation method of static-free glue with base-material, it is characterised in that:Comprise the following steps,
(1) mixed after weighing alkali-free glass fibre, thermoplastic, low density polyethylene (LDPE) by proportioning, the order of addition First to add thermoplastic and low density polyethylene (LDPE), alkali-free glass fibre is added;
(2) naphthalate, thermoplastic and low density polyethylene (LDPE) high-speed kneading are mediated into paste into pasty state, high temperature The mixture of shape is filtered using 180 mesh copper mesh, and it is compound that polyacrylamide, potassium zinc are uniformly added into while high-speed kneading Liquid stabilisers, lubricant, adhesive and flexibilizing agent, mediate 60-80 minutes;
(3) extrusion molding, extrusion temperature are 170~190 DEG C;
(4) calendering formation, the temperature of calendering is 190~200 DEG C;
(5) surface trimming.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention By appended claims and its equivalent thereof.

Claims (5)

1. a kind of static-free glue band base-material, it is characterised in that be made up of the component of following parts by weight:Alkali-free glass fibre 60~ 80 parts, 10~20 parts of thermoplastic, 5~10 parts of low density polyethylene (LDPE), 3~10 parts of polyacrylamide, potassium zinc composite liquid it is steady Determine 10~20 parts of 2~4 parts of agent, 1~2 part of lubricant, 3~4 parts of adhesive and flexibilizing agent.
2. a kind of static-free glue band base-material according to claim 1, it is characterised in that by the component system of following parts by weight Into:80 parts of alkali-free glass fibre, 15 parts of thermoplastic, 5 parts of low density polyethylene (LDPE), 5 parts of polyacrylamide, potassium zinc composite liquid 15 parts of 3 parts of stabilizer, 1 part of lubricant, 4 parts of adhesive and flexibilizing agent.
3. a kind of static-free glue band base-material according to claim 2, it is characterised in that described flexibilizing agent wraps by weight Include following components:5~8 parts of atoleine, 3~4 parts of silicone oil, 1~2 part of nano titanium oxide and N- methylols stearamide 1~2 Part.
A kind of 4. calendering formation method of static-free glue with base-material, it is characterised in that:Comprise the following steps:
(1) mixed after weighing alkali-free glass fibre, thermoplastic, low density polyethylene (LDPE) by proportioning, the order of addition is first Thermoplastic and low density polyethylene (LDPE) are added, adds alkali-free glass fibre;
(2) by naphthalate, thermoplastic and low density polyethylene (LDPE) high-speed kneading into pasty state, in the same of high-speed kneading When be uniformly added into polyacrylamide, potassium zinc composite liquid stabilizing agent, lubricant, adhesive and flexibilizing agent, mediate 60-80 minutes;
(3) extrusion molding, extrusion temperature are 170~190 DEG C;
(4) calendering formation, the temperature of calendering is 190~200 DEG C;
(5) surface trimming.
5. according to the method for claim 4, it is characterised in that the mixture that described high temperature mediates pasty state uses 180 mesh copper Silk screen is filtered.
CN201711079542.2A 2017-11-06 2017-11-06 A kind of static-free glue band base-material and its calendering formation method Pending CN107815136A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711079542.2A CN107815136A (en) 2017-11-06 2017-11-06 A kind of static-free glue band base-material and its calendering formation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711079542.2A CN107815136A (en) 2017-11-06 2017-11-06 A kind of static-free glue band base-material and its calendering formation method

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106398072A (en) * 2016-08-30 2017-02-15 安徽盛装电子科技有限公司 Base material of electrical adhesive tape and calendering molding method of base material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106398072A (en) * 2016-08-30 2017-02-15 安徽盛装电子科技有限公司 Base material of electrical adhesive tape and calendering molding method of base material

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