CN107793773A - A kind of high-performance anti-corrosion water-proof environmental protection new material - Google Patents

A kind of high-performance anti-corrosion water-proof environmental protection new material Download PDF

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Publication number
CN107793773A
CN107793773A CN201711082769.2A CN201711082769A CN107793773A CN 107793773 A CN107793773 A CN 107793773A CN 201711082769 A CN201711082769 A CN 201711082769A CN 107793773 A CN107793773 A CN 107793773A
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parts
new material
water
environmental protection
proof environmental
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温九江
袁松平
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Guangxi Xiaocao Information Industry Co Ltd
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Guangxi Xiaocao Information Industry Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/248Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
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  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
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Abstract

The present invention relates to a kind of high-performance anti-corrosion water-proof environmental protection new material, it is composed of the following raw materials by weight:35 45 parts of pitch, 15 25 parts of natural rubber powder, 25 35 parts of neoprene, 20 30 parts of Corvic, 79 parts of retinasphal, 57 parts of graphite, 69 parts of nano silicon, 46 parts of nanometer silicon carbide, 46 parts of metallocene PE, 46 parts of nano aluminium oxide, 0.4 0.6 parts of graphene, 6 10 parts of zinc oxide, 10 13 parts of light stabilizer, 10 14 parts of watery water-proofing agent.In the manner described above, several different materials are proportionally coordinated and is combined into a kind of new material, the new material composition is simple, and waterproof, antiseptic property are good, and tensile strength is high, has a good heat resistance, and market application foreground is extensive.

Description

A kind of high-performance anti-corrosion water-proof environmental protection new material
Technical field
The present invention relates to new material technology field, more particularly to a kind of high-performance anti-corrosion water-proof environmental protection new material.
Background technology
Pitch class or high score subclass waterproof material are immersed on carcass, the waterproof material product being fabricated to is with coiled material shape Formula provides, referred to as waterproof roll.It is different according to main composition material, it is divided into asphalt water-proof coiled material, high-polymer modified pitch waterproof Coiled material and synthetic polymeric waterproofing material;No carcass coiled material, paper tire coiled material, glass fibre tire volume are divided into according to the difference of carcass Material, glass cloth tire coiled material and polyethylene tire coiled material.It is mainly used for construction wall, roofing and tunnel, highway, garbage loading embeading Etc., play and resist extraneous rainwater, a kind of rollable flexible building material product into web-like of underground water seepage, as engineering Ne-leakage connects between basis and building, is first of barrier of whole engineering waterproofing, whole engineering is played heavy to closing The effect wanted.Product mainly has asphalt water-proof coiled material and polymer membranes.
At present, there is the shortcomings of non-refractory, antiseptic property difference and the scope of application is small in existing waterproof roll.Due to Present extreme weather protrudes, and the performance of existing waterproof roll has been unable to meet demand, therefore the performance for improving waterproof roll has turned into The technical problem of urgent need to resolve.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of high-performance anti-corrosion water-proof environmental protection new material, it is intended to solve The problem of existing waterproof roll poor performance.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:
A kind of high-performance anti-corrosion water-proof environmental protection new material, is composed of the following raw materials by weight:Pitch 35-45 parts, natural gum Powder 15-25 parts, neoprene 25-35 parts, Corvic 20-30 parts, retinasphal 7-9 parts, graphite 5-7 parts, nanometer two Silica 6-9 parts, nanometer silicon carbide 4-6 parts, metallocene PE 4-6 parts, nano aluminium oxide 4-6 parts, graphene 0.4-0.6 Part, zinc oxide 6-10 parts, light stabilizer 10-13 parts, watery water-proofing agent 10-14 parts.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the new material is composed of the following raw materials by weight:38 parts of pitch, 20 parts of natural rubber powder, neoprene 30 parts, 25 parts of Corvic, 8 parts of retinasphal, 6 parts of graphite, 8 parts of nano silicon, 5 parts of nanometer silicon carbide, cyclopentadienyl gold Belong to 5 parts of polyethylene, 5 parts of nano aluminium oxide, 0.5 part of graphene, 8 parts of zinc oxide, 12 parts of light stabilizer, 12 parts of watery water-proofing agent.
Further, the light stabilizer is titanium oxide.
Further, the waterborne preservative is PM-4700.
Further, the preparation method of described new material, comprises the following steps:Each component is mixed, mixed in kneader Refining, 2.5-4.5 hours are handled under the conditions of 145-165 DEG C, anti-refining plasticizing, is made into sizing material, dip-coating is in non-woven fabrics on twin-roll machine Wound, it is made after drying.
The beneficial effects of the invention are as follows:Present component is simple, and manufacture craft is simple, reduces the labor intensity of employee And production cost, meanwhile, the new material has good waterproof, antiseptic property, and tensile strength is high, high temperature resistant, has a wide range of application It is general.
Embodiment
The principle and feature of the present invention are described below in conjunction with specific embodiment, example is served only for explaining this Invention, is not intended to limit the scope of the present invention.
Embodiment 1
The present embodiment provides a kind of high-performance anti-corrosion water-proof environmental protection new material, is composed of the following raw materials by weight:Pitch 38 Part, 20 parts of natural rubber powder, 30 parts of neoprene, 25 parts of Corvic, 8 parts of retinasphal, 6 parts of graphite, nanometer titanium dioxide 8 parts of silicon, 5 parts of nanometer silicon carbide, 5 parts of metallocene PE, 5 parts of nano aluminium oxide, 0.5 part of graphene, 8 parts of zinc oxide, light are steady Determine 12 parts of agent, 12 parts of watery water-proofing agent.
The preparation method of above-mentioned new material is as follows:Each component is mixed, is kneaded in kneader, in 145-165 DEG C of condition Lower processing 2.5-4.5 hours, anti-refining plasticizing, is made into sizing material on twin-roll machine, and dip-coating is hindered in non-woven fabrics, is made after drying.
Embodiment 2
The present embodiment provides a kind of high-performance anti-corrosion water-proof environmental protection new material, is composed of the following raw materials by weight:Pitch 36 Part, 16 parts of natural rubber powder, 26 parts of neoprene, 20 parts of Corvic, 7 parts of retinasphal, 5 parts of graphite, nanometer titanium dioxide 6 parts of silicon, 4 parts of nanometer silicon carbide, 4 parts of metallocene PE, 4 parts of nano aluminium oxide, 0.4 part of graphene, 6 parts of zinc oxide, light are steady Determine 10 parts of agent, 11 parts of watery water-proofing agent.
The preparation method of above-mentioned new material is as follows:Each component is mixed, is kneaded in kneader, in 145-165 DEG C of condition Lower processing 2.5-4.5 hours, anti-refining plasticizing, is made into sizing material on twin-roll machine, and dip-coating is hindered in non-woven fabrics, is made after drying.
Embodiment 3
The present embodiment provides a kind of high-performance anti-corrosion water-proof environmental protection new material, is composed of the following raw materials by weight:Pitch 44 Part, 24 parts of natural rubber powder, 34 parts of neoprene, 30 parts of Corvic, 9 parts of retinasphal, 7 parts of graphite, nanometer titanium dioxide 9 parts of silicon, 6 parts of nanometer silicon carbide, 6 parts of metallocene PE, 6 parts of nano aluminium oxide, 0.6 part of graphene, 10 parts of zinc oxide, light 13 parts of stabilizer, 13 parts of watery water-proofing agent.
The preparation method of above-mentioned new material is as follows:Each component is mixed, is kneaded in kneader, in 145-165 DEG C of condition Lower processing 2.5-4.5 hours, anti-refining plasticizing, is made into sizing material on twin-roll machine, and dip-coating is hindered in non-woven fabrics, is made after drying.
Comparative example 1
This comparative example provides a kind of high-performance anti-corrosion water-proof environmental protection new material, is composed of the following raw materials by weight:Natural gum 24 parts of powder, 34 parts of neoprene, 30 parts of Corvic, 9 parts of retinasphal, 7 parts of graphite, 9 parts of nano silicon, receive 6 parts of carborundum of rice, 6 parts of metallocene PE, 6 parts of nano aluminium oxide, 0.6 part of graphene, 10 parts of zinc oxide, light stabilizer 13 Part, 13 parts of watery water-proofing agent.
The preparation method of above-mentioned new material is as follows:Each component is mixed, is kneaded in kneader, in 145-165 DEG C of condition Lower processing 2.5-4.5 hours, anti-refining plasticizing, is made into sizing material on twin-roll machine, and dip-coating is hindered in non-woven fabrics, is made after drying.
Comparative example 2
This comparative example provides a kind of high-performance anti-corrosion water-proof environmental protection new material, is composed of the following raw materials by weight:Pitch 44 Part, 24 parts of natural rubber powder, 30 parts of Corvic, 9 parts of retinasphal, 7 parts of graphite, 9 parts of nano silicon, nano-sized carbon 6 parts of SiClx, 6 parts of metallocene PE, 6 parts of nano aluminium oxide, 0.6 part of graphene, 10 parts of zinc oxide, 13 parts of light stabilizer, water 13 parts of waterproofing agent of property.
The preparation method of above-mentioned new material is as follows:Each component is mixed, is kneaded in kneader, in 145-165 DEG C of condition Lower processing 2.5-4.5 hours, anti-refining plasticizing, is made into sizing material on twin-roll machine, and dip-coating is hindered in non-woven fabrics, is made after drying.
It is that the anti-corrosion water-proof environmental protection material for preparing three groups of embodiments and two groups of comparative examples carries out performance test below As a result:
Example Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1 Comparative example 2
Seepage rate (%) 0.08 0.05 0.07 0.15 0.13
Rate of corrosion (mm/a) 0.07 0.05 0.06 0.11 0.14
Deform minimum temperature (DEG C) 298 303 296 285 279
Above-mentioned measurement result shows that green wood material formula provided by the invention is reasonable, hence it is evident that improves the material waterproofing, prevents The performances such as rotten and high temperature resistant so that the material is resistant to more dislike the weather condition of summary during use, extends The service life of material, cost reduce, economic results in society.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (5)

1. a kind of high-performance anti-corrosion water-proof environmental protection new material, it is characterised in that be composed of the following raw materials by weight:Pitch 35-45 Part, natural rubber powder 15-25 parts, neoprene 25-35 parts, Corvic 20-30 parts, retinasphal 7-9 parts, graphite 5-7 Part, nano silicon 6-9 parts, nanometer silicon carbide 4-6 parts, metallocene PE 4-6 parts, nano aluminium oxide 4-6 parts, graphene 0.4-0.6 parts, zinc oxide 6-10 parts, light stabilizer 10-13 parts, watery water-proofing agent 10-14 parts.
2. a kind of high-performance anti-corrosion water-proof environmental protection new material according to claim 1, it is characterised in that by following parts by weight Raw material forms:38 parts of pitch, 20 parts of natural rubber powder, 30 parts of neoprene, 25 parts of Corvic, 8 parts of retinasphal, graphite 6 parts, 8 parts of nano silicon, 5 parts of nanometer silicon carbide, 5 parts of metallocene PE, 5 parts of nano aluminium oxide, 0.5 part of graphene, 8 parts of zinc oxide, 12 parts of light stabilizer, 12 parts of watery water-proofing agent.
A kind of 3. high-performance anti-corrosion water-proof environmental protection new material according to claim 1, it is characterised in that:The light stabilizer For titanium oxide.
A kind of 4. high-performance anti-corrosion water-proof environmental protection new material according to claim 1, it is characterised in that:The water-repellent preservation Agent is PM-4700.
5. a kind of preparation method of new material as claimed in claim 1 or 2, it is characterised in that comprise the following steps:By each component Mixing, is kneaded in kneader, and 2.5-4.5 hours are handled under the conditions of 145-165 DEG C, and anti-refining plasticizing, is made on twin-roll machine Sizing material, dip-coating are hindered in non-woven fabrics, are made after drying.
CN201711082769.2A 2017-11-07 2017-11-07 A kind of high-performance anti-corrosion water-proof environmental protection new material Withdrawn CN107793773A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110872448A (en) * 2018-08-30 2020-03-10 中国石油化工股份有限公司 Ultraviolet aging resistant waste rubber powder modified asphalt and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104805692A (en) * 2015-04-08 2015-07-29 界首市华强防水防腐材料有限公司 High-performance anticorrosive waterproof environment-friendly novel material
CN106317528A (en) * 2016-09-04 2017-01-11 淄博夸克医药技术有限公司 Novel high-performance anticorrosion waterproof environment-friendly material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104805692A (en) * 2015-04-08 2015-07-29 界首市华强防水防腐材料有限公司 High-performance anticorrosive waterproof environment-friendly novel material
CN106317528A (en) * 2016-09-04 2017-01-11 淄博夸克医药技术有限公司 Novel high-performance anticorrosion waterproof environment-friendly material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110872448A (en) * 2018-08-30 2020-03-10 中国石油化工股份有限公司 Ultraviolet aging resistant waste rubber powder modified asphalt and preparation method thereof

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