CN107771812A - A kind of bactericidal composition and its application containing Boscalid and cyazofamid - Google Patents
A kind of bactericidal composition and its application containing Boscalid and cyazofamid Download PDFInfo
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- CN107771812A CN107771812A CN201610757790.7A CN201610757790A CN107771812A CN 107771812 A CN107771812 A CN 107771812A CN 201610757790 A CN201610757790 A CN 201610757790A CN 107771812 A CN107771812 A CN 107771812A
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- cyazofamid
- boscalid
- bactericidal composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing Boscalid and cyazofamid and its application.The bactericidal composition is using Boscalid and cyazofamid as principle active component, and wherein the mass ratio of Boscalid and cyazofamid is 1:50~70:1.The bactericidal composition can be applied to prevent and treat Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and prevention effect is substantially better than the use of its single dose.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as powdery mildew, gray mold, sclerotiniose, rot, downy mildew, epidemic disease, effect is better than single dose use.
Description
Technical field:
It is especially a kind of using Boscalid and cyazofamid to be main living the present invention relates to a kind of bactericidal composition and application thereof
The bactericidal composition of property composition and its application.
Background technology
Boscalid (Boscalid), be BASF Aktiengesellschaft exploitation new nicotine acid amide fungicides, chemical name
Claim:The chloro- N- of 2- (4'- chlordiphenyl -2- bases) niacinamide, molecular formula:C18H12Cl2N2O.Structural formula is as follows:
The bactericide fungicidal spectrum is wider, almost all active to all types of fungal diseases, to preventing and treating powdery mildew, grey mold
Disease, sclerotiniose and various rots etc. are highly effective and also effective to the resistance bacterium of other medicaments, for rape, beans, ball
Stem vegetables, leaf mustard, carrot, apple, lettuce, peanut, potato, drupe, strawberry, nut, wild cabbage, cucumber, peppermint, pea, root
The preventing and treating of the disease such as class vegetables, sunflower, grape, lawn, other fruit trees, vegetables, field crop;Due to its distinctive effect machine
Reason is not likely to produce cross resistance, is the new of significant in addition to crop safety and favourable toxicity data and ecological effect
Nicotinamide bactericide.
Cyazofamid (Cyazofamidc), molecular formula:C13H13ClN4O2S, chemical name:Chloro- 2- cyano group-N, the N- diformazans of 4-
Base -5- p-methylphenyl imidazoles -1- sulfonamide.Structural formula:
Cyazofamid is the sulphaguanidine azoles fungicide of Japanese Ishihara Sangyo Kaisha, Ltd.'s production, and mechanism of action is to block oomycetes
The electron transmission of mitochondrial cytochrome b c1 complexs carrys out the supply of interfering energy in guiding principle germ body, and its binding site is enzyme
Q1 centers, with other bactericide without cross tolerance.Its high selection activity to pathogen is probably because target enzymes are to medicament
Caused by sensitivity difference.To Oomycete fungal such as downy mildew, Pseudo peronospara, phytophthora, pythium spp and Plasmodiophoromycetes
Plasmodiophora brassica bacteria has very high bioactivity.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity increase, and difficulty increases in preventing and treating;Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
The content of the invention:
The purpose of the present invention be for above-mentioned technical problem provide it is a kind of it is applied widely, cost is low, effect is good contains pyridine
The plant bactericidal composition of acyl bacterium amine and cyazofamid.
It is a still further object of the present invention to provide the bactericidal composition to prevent and treat caused by plant epiphyte on fungal disease
Using the especially purposes on preventing and treating powdery mildew, gray mold, sclerotiniose, rot, downy mildew, the fungal disease such as epidemic disease.
The purpose of the present invention is to be achieved through the following technical solutions:
A kind of bactericidal composition containing Boscalid and cyazofamid, the bactericidal composition is based on Boscalid and cyazofamid
Active ingredient is wanted, the wherein mass ratio of Boscalid and cyazofamid is 1:50~70:1, wherein effective ingredient in bactericidal composition
It is present in enhancing effective amount in composition.
Described bactericidal composition, wherein Boscalid and cyazofamid mass ratio are preferably 1:50~1:6、1:2~70:1,
More preferably 1:30~1:20、1:1~10:1 and 50:1~70:1, still more preferably for:1:30~1:20、2.5:1
~10:1、50:1, further elect as:1:30~1:20、5:1~10:1、50:1.
In bactericidal composition of the present invention, the weight/mass percentage composition that both Boscalid and cyazofamid account for composition is 2%
~80%.It is preferred that 10%~40%.
Described bactericidal composition, wherein using Boscalid and cyazofamid as principle active component and known auxiliary agent and tax
Shape agent is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, defoaming
Agent, wetting agent, disintegrant etc., calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy can be used
Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combine, and excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other
Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation are that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the described bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared.Especially in preventing and treating cereal
Class, fruit tree, the application in vegetable crop disease.
Above-mentioned fungal diseases of plants be powdery mildew, gray mold, sclerotiniose, rot, downy mildew and epidemic disease at least
It is a kind of.
Beneficial effects of the present invention:
1st, the Boscalid used in the present invention is pyridine series bactericidal agent, and cyazofamid is sulphaguanidine azoles fungicide, acts on machine
Reason is different, mutual mixture will not produce it is low touch, can Synergistic, reduce dosage, reduce cost.
2nd, the present composition scope of application increase, suitable for preventing and treating Cereal, fruit tree, vegetables refractory fungal disease,
Particularly preventing and treating powdery mildew, gray mold, sclerotiniose, rot, downy mildew, epidemic disease has significant effect.Sterilization group of the present invention
Compound has good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete refractory fungal disease;And suppress insect or
Drug-fast generation of the fungi to unitary agent (Boscalid and cyazofamid are any).Bactericidal composition of the present invention can produce higher
Synergistic function, and the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e. the work of mixture
Property be more than independent component activity.
Beneficial effects of the present invention compared with prior art:(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as powdery mildew, gray mold, sclerotiniose, rot, downy mildew, epidemic disease have obvious synergistic function, overcome and prolong
Delay the resistance to the action of a drug, expand preventing and treating spectrum, hence it is evident that improve prevention effect;(2) preventing and treating recruitment, drug cost are reduced;(3) it is alternative normal
Advise and be also easy to produce the agricultural chemicals of resistance;(4) compared with single dose, production and use cost reduce;(5) the drug-fast production of fungi is suppressed
Raw, its positive effect uses higher than its single dose.
Embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested:
Mycelial growth rate method, EC of the measure different agents to bacterial strain are used indoors50Value, using co-toxicity coefficient calculating side
Method, the co-toxicity coefficient (CTC) of mixture is calculated, determines the building performance of mixture, circular is as follows:
EC (is generally selected as standard agent using a certain single dose in mixture50Junior), calculated:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified:Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, CTC exists
It is summation action between 80-120.
According to active ingredient Boscalid (A):Cyazofamid (B) quality proportioning is:70:1、50:1、30:1、20:
1、10:1、5:1、2.5:1、1:1、1:2、1:4、1:6、1:10、1:20、1:30、1:50 are tested, and it is right to determine its
The co-toxicity coefficient of Phytophthora infestans germ (Phytophthora infestans (Mont.) de Bary).
Table 1:Indoor biometricses result of the Boscalid+cyazofamid different ratio to Phytophthora infestans germ
Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
25% Boscalid SC | Y=2.046X+4.339 | 2.103 | - |
10% cyazofamid SC | Y=1.324X+4.202 | 4.004 | - |
A:B=70:1 | Y=2.041X+4.200 | 2.465 | 163.52 |
A:B=50:1 | Y=1.263X+4.609 | 2.041 | 198.01 |
A:B=30:1 | Y=1.452X+4.397 | 2.601 | 156.32 |
A:B=20:1 | Y=2.358X+3.995 | 2.667 | 153.62 |
A:B=10:1 | Y=2.314X+4.308 | 1.990 | 210.23 |
A:B=5:1 | Y=1.324X+4.501 | 2.382 | 182.56 |
A:B=2.5:1 | Y=2.225X+4.071 | 2.615 | 177.14 |
A:B=1:1 | Y=1.936X+4.046 | 3.111 | 168.79 |
A:B=1:2 | Y=2.332X+3.636 | 3.845 | 152.36 |
A:B=1:4 | Y=1.245X+4.182 | 4.539 | 142.25 |
A:B=1:6 | Y=2.014X+3.745 | 4.199 | 160.78 |
A:B=1:10 | Y=1.245X+4.191 | 4.463 | 157.84 |
A:B=1:20 | Y=2.547X+3.567 | 3.654 | 200.01 |
A:B=1:30 | Y=1.525X+4.087 | 3.971 | 186.53 |
A:B=1:50 | Y=1.965X+3.672 | 4.740 | 158.02 |
Field control effectiveness test:
The pesticidal preparations preventing and treating tomato late blight experiment made from following examples.
1st, test process:This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is the cyazofamid SC of agricultural chemicals single dose 10% and 25% Boscalid SC and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times;Investigation drug effect side after investigating and prevent and treat before dispenser
Method is:5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2:
The field test results of table 2
Shown by indoor biometricses and field efficacy result, Boscalid has with cyazofamid composition significantly cooperates with increasing
Effect acts on, and the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application value in agricultural is applied.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1:15% Boscalid cyazofamid wettable powder (1:2)
By Boscalid 5g, cyazofamid 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusant
NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures carry out air-flow crushing, be made effectively into
It is 15% Boscalid cyazofamid wettable powder to divide mass percent.
Embodiment 2:15% Boscalid cyazofamid wettable powder (1:4)
By Boscalid 3g, cyazofamid 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 15% Boscalid cyazofamid wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 3:14% Boscalid cyazofamid wettable powder (1:6)
By Boscalid 2g, cyazofamid 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 14% Boscalid cyazofamid wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 4:20% Boscalid cyazofamid suspending agent (1:1)
10g Boscalids, 10g cyazofamids, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
It is 20% Boscalid cyazofamid suspending agent that effective ingredient percent, which is made,.
Embodiment 5:55% Boscalid cyazofamid aqueous emulsion (1:10)
Weigh 5g Boscalids, 50g cyazofamids, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared to aqueous emulsion puts into mixing kettle
High speed mixes, and it is 55% Boscalid cyazofamid aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 6:42% Boscalid cyazofamid missible oil (1:20)
Weigh 2g Boscalids, 40g cyazofamids, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 42% Boscalid cyazofamid missible oil.
Embodiment 7:70% Boscalid cyazofamid missible oil (2.5:1)
Weigh 50g Boscalids, 20g cyazofamids, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Sesame oil APEO 2g, solvent naphtha to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil,
It is 70% Boscalid cyazofamid missible oil that effective ingredient percent, which is made,.
Embodiment 8:18% Boscalid cyazofamid water dispersion granule (5:1)
Weigh 15g Boscalids, 3g cyazofamids, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, diatomite 28g complement to 100g, and above raw material is formed with into effect into sub-prime by water dispersible granular agent method
Amount percentage is 17% Boscalid cyazofamid water dispersion granule.
Embodiment 9:11% Boscalid cyazofamid missible oil (10:1)
Weigh 10g Boscalids, 1g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 11% Boscalid cyazofamid missible oil.
Embodiment 10:31.5% Boscalid cyazofamid microemulsion (20:1)
Weigh 30g Boscalids, 1.5g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared micro-
Mixed in the method input mixing kettle of emulsion, it is 32% Boscalid cyazofamid micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 11:31% Boscalid cyazofamid missible oil (30:1)
Weigh 30g Boscalids, 1g cyazofamids, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 31% Boscalid cyazofamid missible oil.
Embodiment 12:51% Boscalid cyazofamid suspending agent (50:1)
Weigh 50g Boscalids, 1g cyazofamids, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill
It is 51% Boscalid cyazofamid suspending agent into active ingredient mass percent.
Embodiment 13:32% Boscalid cyazofamid microemulsion (1:15)
Weigh 2g Boscalids, 30g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, it is 32% Boscalid cyazofamid microemulsion that effective ingredient percent, which is made,.
Embodiment 14:6% Boscalid cyazofamid aqueous emulsion (1:5)
1g Boscalids, 5g cyazofamids, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol is weighed to gather
Oxygen vinethene 1g, solvent naphtha 13g, adds water to 100g.In the method input mixing kettle that above raw material is routinely prepared to aqueous emulsion
Mixed at high speed, it is 6% Boscalid cyazofamid aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 15:62% Boscalid cyazofamid microemulsion (1:30)
Weigh 2g Boscalids, 60g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, it is 62% Boscalid cyazofamid microemulsion that effective ingredient percent, which is made,.
Embodiment 16:51% Boscalid cyazofamid suspending agent (1:50)
Weigh 1g Boscalids, 50g cyazofamids, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill
It is 51% Boscalid cyazofamid suspending agent into active ingredient mass percent.
Embodiment 17:7% Boscalid cyazofamid water dispersion granule (1:2.5)
Weigh 2g Boscalids, 5g cyazofamids, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyethylene
Alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, by above raw material by water dispersible granular agent method be formed with effect into
It is 7% Boscalid cyazofamid water dispersion granule to divide mass percent.
Claims (9)
1. a kind of bactericidal composition containing Boscalid and cyazofamid, it is characterised in that the bactericidal composition is with Boscalid and cyanogen
White azoles is principle active component, and wherein the mass ratio of Boscalid and cyazofamid is 1:50~70:1.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the Boscalid and cyazofamid is
1:50~1:6、1:2~70:1.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the Boscalid and cyazofamid is
1:30~1:20、1:1~10:1 and 50:1~70:1.
4. bactericidal composition according to claim 1, it is characterised in that both described Boscalids and cyazofamid account for group
The weight/mass percentage composition of compound is 2%~80%.
5. bactericidal composition according to claim 4, it is characterised in that both described Boscalids and cyazofamid account for group
The weight/mass percentage composition of compound is 10%~40%.
6. bactericidal composition according to claim 1, it is characterised in that using Boscalid and cyazofamid as it is main effectively into
Point and insecticides adjuvant, excipients be configured to any one formulation for allowing on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared described in claim 1.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is powdery mildew, gray mold, bacterium
At least one of core disease, rot, downy mildew and epidemic disease.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1481215A (en) * | 2000-12-18 | 2004-03-10 | �����ɷ� | Fungicide mixtures based on amide compounds |
CN1484492A (en) * | 2001-01-16 | 2004-03-24 | �����ɷ� | Fungicidal mixture |
CN103719090A (en) * | 2013-12-09 | 2014-04-16 | 江阴苏利化学股份有限公司 | Sterilization composition containing cyazofamid and cyprosulfamide as well as use of sterilization composition |
-
2016
- 2016-08-29 CN CN201610757790.7A patent/CN107771812A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1481215A (en) * | 2000-12-18 | 2004-03-10 | �����ɷ� | Fungicide mixtures based on amide compounds |
CN1484492A (en) * | 2001-01-16 | 2004-03-24 | �����ɷ� | Fungicidal mixture |
CN103719090A (en) * | 2013-12-09 | 2014-04-16 | 江阴苏利化学股份有限公司 | Sterilization composition containing cyazofamid and cyprosulfamide as well as use of sterilization composition |
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