CN105475342B - A kind of bactericidal composition and its application containing Silthiopham and fluazinam - Google Patents
A kind of bactericidal composition and its application containing Silthiopham and fluazinam Download PDFInfo
- Publication number
- CN105475342B CN105475342B CN201511008594.1A CN201511008594A CN105475342B CN 105475342 B CN105475342 B CN 105475342B CN 201511008594 A CN201511008594 A CN 201511008594A CN 105475342 B CN105475342 B CN 105475342B
- Authority
- CN
- China
- Prior art keywords
- fluazinam
- silthiopham
- bactericidal composition
- composition according
- silthiophams
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing Silthiopham and fluazinam and its application.The bactericidal composition is using Silthiopham and fluazinam as principle active component, and wherein the mass ratio of Silthiopham and fluazinam is 1~70：1~50.The bactericidal composition can be applied to prevent and treat Cereal, fruit tree, vegetable disease, it is particularly useful for preventing and treating the fungal diseases such as take-all, downy mildew, late blight, with higher synergistic function, overcome and delayed the resistance to the action of a drug of germ, sterilization speed is fast, the lasting period is long, reduces application cost, and prevention effect is substantially better than the use of its single dose.
Description
Technical field：
It is especially a kind of using Silthiopham and fluazinam to be main living the present invention relates to a kind of bactericidal composition and application thereof
The bactericidal composition of property composition and its application.
Background technology
Silthiopham (Silthiopham), chemical name：N- pi-allyl -4,5- dimethyl -2- (trimethylsilyl) thiophene
Fen -3- formamides.Silthiopham has good protection activity, longevity of residure length, crop, mammal and environment is all relatively pacified
Entirely, there is special efficacy to take-all.
Fluazinam (Metalaxyl), molecular formula：C15H21NO4, chemical name：N- (2- Methoxyacetyls)-N- (2,6-
3,5-dimethylphenyl)-DL-alpha- aminopropanoates.Structural formula：
Fluazinam is new and effective systemic fungicide.Can in inspiration enter in plant, it is water-soluble higher than general bactericide
It is more.There is selective special efficacy to the downy mildew in Oomycete and phytophthora, to the late blight of potato, downy mildew of garpe, hops
Downy mildew, beet epidemic disease, white rust of colza, tobacco black shank etc. have good prevention effect.Can also be used for cotton samping off,
The downy mildew of millet, prevention effect are good.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity increase, and difficulty increases in preventing and treating；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
The content of the invention：
The purpose of the present invention be for above-mentioned technical problem provide it is a kind of it is applied widely, that cost is low, effect is good is siliceous
The plant bactericidal composition of metsulfovax and fluazinam.
Cause answering on fungal disease in preventing and treating plant epiphyte it is a still further object of the present invention to provide the bactericidal composition
With the especially purposes on preventing and treating take-all, downy mildew, the fungal disease such as late blight.
The purpose of the present invention is to be achieved through the following technical solutions：
A kind of bactericidal composition containing Silthiopham and fluazinam, the bactericidal composition is based on Silthiopham and fluazinam
Active ingredient is wanted, the wherein mass ratio of Silthiopham and fluazinam is 1~70：1~50, wherein effective ingredient in bactericidal composition
It is present in enhancing effective amount in composition.
The mass ratio of described bactericidal composition, wherein Silthiopham and fluazinam is preferably 1~70：1~30, further
Preferably 1~30：1~20.
The preferred mass of Silthiopham and fluazinam matches：70：1、50：1、30：1、20：1、10：1、5：1、
2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50.
In the compositions of the present invention, the weight/mass percentage composition that composition is accounted for both Silthiopham and fluazinam is 2~80%.
It is preferred that 5~70%.
Described bactericidal composition, wherein using Silthiopham and fluazinam as principle active component and known auxiliary agent and tax
Shape agent is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, defoaming
Agent, wetting agent, disintegrant etc., calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy can be used
Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combine, and excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other
Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation are missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared.Especially in preventing and treating cereal
Application has remarkable result in terms of class, fruit tree, vegetable crop disease.
Above-mentioned application, described fungal diseases of plants are at least one of take-all, downy mildew, late blight.
The characteristics of bactericidal composition of the present invention：
1st, the Silthiopham and fluazinam used in the present invention, mutual mixture will not produce conflicts, can Synergistic, reduce use
Dose, reduce cost.
2nd, the present composition scope of application increase, suitable for preventing and treating Cereal, fruit tree, vegetables refractory fungal disease,
Particularly preventing and treating take-all, downy mildew, late blight etc. has significant effect.Bactericidal composition of the present invention to sac fungus,
Basidiomycetes, Fungi Imperfecti and Oomycete fungal disease have good prevention effect；And suppress insect or fungi to unitary agent (silicon
Metsulfovax and fluazinam are any) drug-fast generation.Bactericidal composition of the present invention can produce higher synergistic function, and
And the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e., the activity of mixture is more than the work of independent component
Property.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as take-all, downy mildew, late blight have obvious synergistic function, overcome and have delayed the resistance to the action of a drug, expand
Preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and it is also easy to produce resistance
Agricultural chemicals；(4) compared with single dose, production and use cost reduce；(5) the drug-fast generation of fungi is suppressed, its positive effect is high
Used in its single dose.
Embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method, EC of the measure different agents to bacterial strain are used indoors50Value, using co-toxicity coefficient calculating side
Method, the co-toxicity coefficient (CTC) of mixture is calculated, determines the building performance of mixture, circular is as follows：
EC (is generally selected as standard agent using a certain single dose in mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, CTC exists
It is summation action between 80-120.
According to active ingredient Silthiopham (A)：Fluazinam (B) quality proportioning is：80：1、70：1、50：1、30：1、20：1、
10：1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50、1：60 are tested, and determine it to tomato
The co-toxicity coefficient of late disease bacteria (Phytophthora infestans (Mont.) de Bary).
Table 1：Indoor biometricses result of the Silthiopham+fluazinam different ratio to Phytophthora infestans germ
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 12.5% Silthiopham SC | Y=2.409+3.598X | 5.248 | - |
| 25% fluazinam WP | Y=2.472+4.520X | 3.625 | - |
| A:B=80:1 | Y=3.658+2.088X | 4.394 | 118.78 |
| A:B=70:1 | Y=4.164+1.875X | 2.790 | 186.95 |
| A:B=50:1 | Y=3.777+2.265X | 3.468 | 150.02 |
| A:B=30:1 | Y=2.967+3.630X | 3.632 | 142.44 |
| A:B=20:1 | Y=4.473+1.147X | 2.879 | 178.48 |
| A:B=10:1 | Y=3.494+3.601X | 2.619 | 192.53 |
| A:B=5:1 | Y=3.910+2.187X | 3.149 | 155.06 |
| A:B=2.5:1 | Y=2.563+4.589X | 3.397 | 136.95 |
| A:B=1:1 | Y=4.259+2.063X | 2.287 | 187.48 |
| A:B=1:2 | Y=4.357+1.963X | 2.127 | 190.02 |
| A:B=1:4 | Y=4.007+2.597X | 2.411 | 160.25 |
| A:B=1:6 | Y=4.333+2.003X | 2.154 | 177.45 |
| A:B=1:10 | Y=2.989+4.572X | 2.753 | 135.49 |
| A:B=1:20 | Y=3.043+5.032X | 2.449 | 150.25 |
| A:B=1:30 | Y=4.128+2.587X | 2.173 | 168.49 |
| A:B=1:50 | Y=3.625+3.002X | 2.872 | 127.01 |
| A:B=1:60 | Y=3.840+1.949X | 3.938 | 92.53 |
Field control effectiveness test：
The pesticidal preparations preventing and treating tomato late blight experiment made from above-described embodiment.
1st, test process：This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is the Silthiopham SC of agricultural chemicals single dose 12.5% and 25% fluazinam WP and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2：
The field test effect of table 2
Shown by indoor biometricses and field efficacy result, Silthiopham has with fluazinam composition significantly cooperates with increasing
Effect acts on, and the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application value in agricultural is applied.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% Silthiopham fluazinam wettable powder (1:2)
By Silthiopham 5g, fluazinam 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusant
NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures carry out air-flow crushing, be made effectively into
It is 15% Silthiopham fluazinam wettable powder to divide mass percent.
Embodiment 2：15% Silthiopham fluazinam wettable powder (1:4)
By Silthiopham 3g, fluazinam 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 15% Silthiopham fluazinam wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 3：14% Silthiopham fluazinam wettable powder (1:6)
By Silthiopham 2g, fluazinam 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 14% Silthiopham fluazinam wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 4：20% Silthiopham fluazinam suspending agent (1:1)
10g Silthiophams, 10g fluazinams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
It is 20% Silthiopham fluazinam suspending agent that effective ingredient percent, which is made,.
Embodiment 5：55% Silthiopham fluazinam aqueous emulsion (1:10)
Weigh 5g Silthiophams, 50g fluazinams, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared to aqueous emulsion puts into mixing kettle
High speed mixes, and it is 55% Silthiopham fluazinam aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 6：42% Silthiopham fluazinam missible oil (1:20)
Weigh 2g Silthiophams, 40g fluazinams, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 42% Silthiopham fluazinam missible oil.
Embodiment 7：70% Silthiopham fluazinam missible oil (2.5:1)
Weigh 50g Silthiophams, 20g fluazinams, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Sesame oil APEO 2g, solvent naphtha to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil,
It is 70% Silthiopham fluazinam missible oil that effective ingredient percent, which is made,.
Embodiment 8：18% Silthiopham fluazinam water dispersion granule (5：1)
Weigh 15g Silthiophams, 3g fluazinams, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, diatomite 28g complement to 100g, and above raw material is formed with into effect into sub-prime by water dispersible granular agent method
Amount percentage is 17% Silthiopham fluazinam water dispersion granule.
Embodiment 9：11% Silthiopham fluazinam missible oil (10:1)
Weigh 10g Silthiophams, 1g fluazinams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 11% Silthiopham fluazinam missible oil.
Embodiment 10：31.5% Silthiopham fluazinam microemulsion (20:1)
Weigh 30g Silthiophams, 1.5g fluazinams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared micro-
Mixed in the method input mixing kettle of emulsion, it is 32% Silthiopham fluazinam micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 11：31% Silthiopham fluazinam missible oil (30:1)
Weigh 30g Silthiophams, 1g fluazinams, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 31% Silthiopham fluazinam missible oil.
Embodiment 12：51% Silthiopham fluazinam suspending agent (50:1)
Weigh 50g Silthiophams, 1g fluazinams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill
It is 51% Silthiopham fluazinam suspending agent into active ingredient mass percent.
Embodiment 13：32% Silthiopham fluazinam microemulsion (1:15)
Weigh 2g Silthiophams, 30g fluazinams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, it is 32% Silthiopham fluazinam microemulsion that effective ingredient percent, which is made,.
Embodiment 14：6% Silthiopham fluazinam aqueous emulsion (1:5)
1g Silthiophams, 5g fluazinams, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol is weighed to gather
Oxygen vinethene 1g, solvent naphtha 13g, adds water to 100g.In the method input mixing kettle that above raw material is routinely prepared to aqueous emulsion
Mixed at high speed, it is 6% Silthiopham fluazinam aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 15：62% Silthiopham fluazinam microemulsion (1:30)
Weigh 2g Silthiophams, 60g fluazinams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, it is 62% Silthiopham fluazinam microemulsion that effective ingredient percent, which is made,.
Embodiment 16：51% Silthiopham fluazinam suspending agent (1:50)
Weigh 1g Silthiophams, 50g fluazinams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill
It is 51% Silthiopham fluazinam suspending agent into active ingredient mass percent.
Embodiment 17：7% Silthiopham fluazinam water dispersion granule (1：2.5)
Weigh 2g Silthiophams, 5g fluazinams, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyethylene
Alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, by above raw material by water dispersible granular agent method be formed with effect into
It is 7% Silthiopham fluazinam water dispersion granule to divide mass percent.
Claims (9)
1. a kind of bactericidal composition containing Silthiopham and fluazinam, it is characterised in that the bactericidal composition is with Silthiopham and fluorine
Pyridine amine is principle active component, and wherein the mass ratio of Silthiopham and fluazinam is 1~70：1~50.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the Silthiopham and fluazinam is 1
~70：1~30.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the Silthiopham and fluazinam is 1
~30：1~20.
4. bactericidal composition according to claim 1, it is characterised in that both described Silthiophams and fluazinam account for group
The weight/mass percentage composition of compound is 2-80%.
5. bactericidal composition according to claim 4, it is characterised in that both described Silthiophams and fluazinam account for group
The weight/mass percentage composition of compound is 5-70%.
6. bactericidal composition according to claim 1, it is characterised in that using Silthiopham and fluazinam as it is main effectively into
Point and insecticides adjuvant, excipients be configured to any one formulation for allowing on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder or water dispersion granule.
8. application of the bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared described in claim 1.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is take-all, downy mildew
At least one of disease, late blight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511008594.1A CN105475342B (en) | 2015-12-28 | 2015-12-28 | A kind of bactericidal composition and its application containing Silthiopham and fluazinam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511008594.1A CN105475342B (en) | 2015-12-28 | 2015-12-28 | A kind of bactericidal composition and its application containing Silthiopham and fluazinam |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105475342A CN105475342A (en) | 2016-04-13 |
| CN105475342B true CN105475342B (en) | 2017-12-05 |
Family
ID=55662923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511008594.1A Active CN105475342B (en) | 2015-12-28 | 2015-12-28 | A kind of bactericidal composition and its application containing Silthiopham and fluazinam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105475342B (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU664392B2 (en) * | 1991-10-18 | 1995-11-16 | Monsanto Technology Llc | Fungicides for the control of take-all disease of plants |
| CN103070189A (en) * | 2013-01-25 | 2013-05-01 | 海利尔药业集团股份有限公司 | Sterilization composition comprising fluopicolide and silthiopham |
-
2015
- 2015-12-28 CN CN201511008594.1A patent/CN105475342B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105475342A (en) | 2016-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105766952B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet | |
| CN105941416B (en) | A kind of bactericidal composition and its application of the bacterium amine of pyrrole containing biphenyl and Tebuconazole | |
| CN107027778A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole | |
| CN105794794A (en) | Bactericidal composition containing isopyrazam and tiadinil and application of bactericidal composition | |
| CN106212474A (en) | A kind of Fluxapyroxad-containsterilization and the bactericidal composition of cycloheximide triazole and application thereof | |
| CN105475342B (en) | A kind of bactericidal composition and its application containing Silthiopham and fluazinam | |
| CN105475340B (en) | A kind of bactericidal composition and its application containing Silthiopham and metalaxyl | |
| CN105941438B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium amide and folpet | |
| CN105994281B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium amide and bupirimate | |
| CN106889079A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine | |
| CN105746545A (en) | Fungicidal composition containing isopyrazam and thifluzamide and application thereof | |
| CN105746534A (en) | Fungicidal composition containing isopyrazam and isotianil and application thereof | |
| CN105918335B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and Propamocarb | |
| CN105379725B (en) | A kind of bactericidal composition and its application containing mepanipyrim and metalaxyl | |
| CN105794792B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil | |
| CN105941403B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and coumoxystrobin | |
| CN105994280B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and mepanipyrim | |
| CN105831140B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and thiram | |
| CN105360128B (en) | A kind of bactericidal composition and its application containing mepanipyrim and Boscalid | |
| CN105766926A (en) | Bactericidal composition containing bixafen and coumoxystrobin and application thereof | |
| CN105379731B (en) | It is a kind of containing mepanipyrim He the bactericidal composition of famoxadone and its application | |
| CN107306957A (en) | A kind of bactericidal composition and its application containing isopyrazam and metalaxyl | |
| CN107771833A (en) | A kind of bactericidal composition and its application containing Boscalid and Propamocarb | |
| CN107027777A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and cyflufenamid | |
| CN107047576A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and kresoxim-methyl |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180515 Address after: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Co-patentee after: Nanjing Redsun Co., Ltd. Patentee after: Nanjing Huazhou Pharmaceutical Co., Ltd. Address before: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Patentee before: Nanjing Huazhou Pharmaceutical Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200903 Address after: 705 Xingye building, 15 Hubu street, Qinhuai District, Nanjing City, Jiangsu Province Patentee after: Jiangsu Ouyue Biotechnology Co., Ltd Address before: Dongfeng Road, Xi Zhen Gaochun County of Nanjing City, Jiangsu province 211318, No. 8 Co-patentee before: NANJING RED SUN Co.,Ltd. Patentee before: Nanjing Huazhou Parmaceutical Co.,Ltd. |