CN107746248A - A kind of Environment-friendlyceramic ceramic material and preparation method thereof - Google Patents
A kind of Environment-friendlyceramic ceramic material and preparation method thereof Download PDFInfo
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- CN107746248A CN107746248A CN201711166487.0A CN201711166487A CN107746248A CN 107746248 A CN107746248 A CN 107746248A CN 201711166487 A CN201711166487 A CN 201711166487A CN 107746248 A CN107746248 A CN 107746248A
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Abstract
The present invention provides a kind of Environment-friendlyceramic ceramic material and preparation method thereof, is related to technical field of ceramic material, is prepared from the following raw materials in parts by weight：35 40 parts of industrial solid castoff,10 15 parts of agricultural crop straw,Discarded 20 30 parts of shredded paper,25 50 parts of scrap glass,40 60 parts of clay,15 20 parts of quartz,6 10 parts of feldspar,10 20 parts of alkali stone,0.5 1.5 parts of aluminum oxide,5 10 parts of silica,8 10 parts of mullite,8 12 parts of Corvic,25 parts of aluminium block,8 12 parts of calcium carbonate,35 parts of dioctyl ester,5 10 parts of bamboo charcoal,10 15 parts of diatomite,37 parts of plant purification liquid etc.,The preparation method of the Environment-friendlyceramic ceramic material,Including ball milling,Slurrying,Base,Five steps of body drying and sinter molding,A kind of Environment-friendlyceramic ceramic material provided by the invention,There is antibacterial simultaneously and purify the function of air,And raw material is industrial solid castoff,Agricultural crop straw,Discarded shredded paper and scrap glass etc.,Not only there is good performance,Also reduce the cost for making ceramics,Discarded object is rationally utilized,Energy-conserving and environment-protective.
Description
Technical field
The present invention relates to technical field of ceramic material, and in particular to a kind of Environment-friendlyceramic ceramic material and preparation method thereof.
Background technology
With the continuous improvement of people's living standards, environment and the consciousness of health are progressively strengthening, green material and ring
Protecting product will be increasingly of interest by people.Health, long-lived, the comfortable highest goal for having become modern and pursuing, antibacterial, guarantor
Strong, environment-protecting product arises at the historic moment, and developed rapidly.And no matter ceramic is as domestic ceramics or as household, dress
The building ceramics such as decorations, it is all closely bound up with daily life, so health care work(of the people to all kinds of ceramics
Higher requirement can be it is also proposed.
At present, traditional ceramics due to thermal coefficient of expansion it is big, poor toughness, wear no resistance, be easily broken in high temperature environments,
Therefore its application field is very restricted, it is impossible to be used in high temperature position, the frequently position that colds and heat succeed each other especially is cannot be used for,
And the firing temperature of traditional wear-resistant ceramic is high, so as to add the energy consumption of wear-resistant ceramic, improves ceramic sintering mistake
Waste discharge in journey.Further, since the selection relation of existing ceramic material, its raw material is all more or less that there is poisonous
Harmful material, and it is that can discharge some toxic gases or solid particle that ornament materials in existing life staying idle at home etc. is mostly,
In living now, the pollution of air and water resource is also inevitable.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of Environment-friendlyceramic ceramic material and preparation method thereof so that ceramics
Material is not only environmentally friendly, while has antibacterial and purify the function of air.
To realize object above, the present invention is achieved by the following technical programs：
A kind of Environment-friendlyceramic ceramic material, is prepared from the following raw materials in parts by weight：
Industrial solid castoff 35-40 parts, agricultural crop straw 10-15 parts, discarded shredded paper 20-30 parts, scrap glass 25-50 parts,
Clay 40-60 parts, quartzy 15-20 parts, feldspar 6-10 parts, alkali stone 10-20 parts, aluminum oxide 0.5-1.5 parts, silica 5-10
Part, mullite 8-10 parts, Corvic 8-12 parts, aluminium block 2-5 parts, calcium carbonate 8-12 parts, dioctyl ester 3-5 parts, bamboo charcoal 5-
10 parts, diatomite 10-15 parts, plant purification liquid 3-7 parts, inorganic antiseptic 5-8 parts, polycarboxylate 2-3 parts, ammonium dichromate 0.5-
1 part, chlorination hydroxyl aluminium 0.4-0.6 parts, cobaltous octadecanate 3-9 parts, plasticizer 6-8 parts, appropriate amount of water.
Preferably, the inorganic antiseptic is silver-loaded zirconium phosphate or silver-carrying active aluminum oxide.
Preferably, the mass ratio of the Corvic and calcium carbonate is 1：1.
Preferably, the plasticizer is prepared from the following raw materials in parts by weight：Diethylene glycol dibenzoate 10-12 parts, third
Acrylamide 10-15 parts, polyethylene glycol 20-25 parts, glycerine 12-15 parts, hydroxymethyl cellulose 12-16 parts, carborundum 4-7 parts, go
Ionized water 70-90 parts.
Preferably, the plant purification liquid is mixed by the effective ingredient after bracketplant, epipremnum aureum, black poplar, the refined extraction of mountain locust tree
Conjunction forms.
The preparation method of above-mentioned Environment-friendlyceramic ceramic material, comprises the following steps：
（1）Ball milling：Other raw materials for removing dioctyl ester, plant purification liquid, plasticizer and water are put into ball mill and grind 40-
100 mesh sieves are crossed after 60min, obtain mixed-powder；
（2）Slurrying：Mixed-powder and dioctyl ester, plant purification liquid, plasticizer are mixed, and be stirred continuously 20-30min, is obtained mixed
Compound, water is added, until water did not had mixture, stir 1-2h, slurry is made；
（3）Base：Slurry is vacuumized into 10-20min under 750-800mmHg, blank is made；
（4）Body drying：Blank is subjected to microwave drying 30-40min at 45-60 DEG C；
（5）Sinter molding：5-8h then is sintered at 1250-1300 DEG C, Environment-friendlyceramic ceramic material is made.
Beneficial effect：
The invention provides a kind of Environment-friendlyceramic ceramic material, clay and quartz can be dissolved among feldspar during high temperature, aluminum oxide and
Silica interacts, and promotes the formation of mullite crystal and grows up, and imparts the mechanical strength and chemically stable of base substrate
Property；Inorganic antiseptic is silver-loaded zirconium phosphate or silver-carrying active aluminum oxide, after heated, can generate the chemical combination with antibacterial action
Thing；From bracketplant, epipremnum aureum, black poplar, mountain locust tree plant in refining extract its more esters of effective ingredient sequiterpene and alcohol compound,
So that ceramic material bactericidal effect is significantly, persistently, it is not only various to Escherichia coli, human influenza virus, avian influenza virus etc. common
Bacterium, fungi have good bactericidal action, and the toxic gas such as energy effectively decomposing formaldehyde, benzene；Meanwhile bamboo charcoal and diatomite
With suction-operated, the pernicious gases such as ammonia nitrogen and oxysulfide can be adsorbed.
The invention provides a kind of Environment-friendlyceramic ceramic material, while there is antibacterial and purify the function of air, and raw material is work
Industry solid waste, agricultural crop straw, discarded shredded paper and scrap glass etc., not only with good performance, also reduce making
The cost of ceramics, discarded object is rationally utilized, energy-conserving and environment-protective.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, belongs to the scope of protection of the invention.
Embodiment 1：
A kind of Environment-friendlyceramic ceramic material, is prepared from the following raw materials in parts by weight：
35 parts of industrial solid castoff, 15 parts of agricultural crop straw, discarded 20 parts of shredded paper, 50 parts of scrap glass, 40 parts of clay, quartz
20 parts, 6 parts of feldspar, 20 parts of alkali stone, 0.5 part of aluminum oxide, 5 parts of silica, 10 parts of mullite, 12 parts of Corvic, aluminium
It is 2 parts of block, 12 parts of calcium carbonate, 3 parts of dioctyl ester, 5 parts of bamboo charcoal, 15 parts of diatomite, 3 parts of plant purification liquid, 5 parts of silver-loaded zirconium phosphate, poly-
3 parts of carboxylate, 0.5 part of ammonium dichromate, 0.6 part of chlorination hydroxyl aluminium, 3 parts of cobaltous octadecanate, 8 parts of plasticizer, appropriate amount of water.
Wherein, plasticizer is prepared from the following raw materials in parts by weight：10 parts of diethylene glycol dibenzoate, acrylamide 15
Part, 20 parts of polyethylene glycol, 15 parts of glycerine, 12 parts of hydroxymethyl cellulose, 7 parts of carborundum, 70 parts of deionized water；Plant purification liquid by
Effective ingredient after bracketplant, epipremnum aureum, black poplar, the refined extraction of mountain locust tree mixes.
Embodiment 2：
A kind of Environment-friendlyceramic ceramic material, is prepared from the following raw materials in parts by weight：
40 parts of industrial solid castoff, 10 parts of agricultural crop straw, discarded 30 parts of shredded paper, 25 parts of scrap glass, 60 parts of clay, quartz
15 parts, 10 parts of feldspar, 10 parts of alkali stone, 1.5 parts of aluminum oxide, 0 part of silica 1,10 parts of mullite, 8 parts of Corvic, aluminium
5 parts of block, 8 parts of calcium carbonate, 5 parts of dioctyl ester, 10 parts of bamboo charcoal, 10 parts of diatomite, 7 parts of plant purification liquid, silver-carrying active aluminum oxide 8
Part, 2 parts of polycarboxylate, 1 part of ammonium dichromate, 0.4 part of chlorination hydroxyl aluminium, 9 parts of cobaltous octadecanate, 6 parts of plasticizer, appropriate amount of water.
Wherein, plasticizer is prepared from the following raw materials in parts by weight：12 parts of diethylene glycol dibenzoate, acrylamide 10
Part, 25 parts of polyethylene glycol, 12 parts of glycerine, 16 parts of hydroxymethyl cellulose, 4 parts of carborundum, 90 parts of deionized water；Plant purification liquid by
Effective ingredient after bracketplant, epipremnum aureum, black poplar, the refined extraction of mountain locust tree mixes.
Embodiment 3：
A kind of Environment-friendlyceramic ceramic material, is prepared from the following raw materials in parts by weight：
38 parts of industrial solid castoff, 12 parts of agricultural crop straw, discarded 25 parts of shredded paper, 30 parts of scrap glass, 50 parts of clay, quartz
17 parts, 8 parts of feldspar, 15 parts of alkali stone, 1 part of aluminum oxide, 6 parts of silica, 9 parts of mullite, 10 parts of Corvic, aluminium block 3
Part, 10 parts of calcium carbonate, 4 parts of dioctyl ester, 7 parts of bamboo charcoal, 14 parts of diatomite, 5 parts of plant purification liquid, 6 parts of silver-loaded zirconium phosphate, polycarboxylic acids
2.5 parts of salt, 0.6 part of ammonium dichromate, 0.5 part of chlorination hydroxyl aluminium, 5 parts of cobaltous octadecanate, 7 parts of plasticizer, appropriate amount of water.
Wherein, plasticizer is prepared from the following raw materials in parts by weight：11 parts of diethylene glycol dibenzoate, acrylamide 12
Part, 22 parts of polyethylene glycol, 13 parts of glycerine, 15 parts of hydroxymethyl cellulose, 6 parts of carborundum, 80 parts of deionized water；Plant purification liquid by
Effective ingredient after bracketplant, epipremnum aureum, black poplar, the refined extraction of mountain locust tree mixes.
Embodiment 4：
A kind of Environment-friendlyceramic ceramic material, is prepared from the following raw materials in parts by weight：
36 parts of industrial solid castoff, 14 parts of agricultural crop straw, discarded 27 parts of shredded paper, 40 parts of scrap glass, 50 parts of clay, quartz
18 parts, 7 parts of feldspar, 11 parts of alkali stone, 0.5 part of aluminum oxide, 6 parts of silica, 9 parts of mullite, 11 parts of Corvic, aluminium block
3 parts, 11 parts of calcium carbonate, 4.5 parts of dioctyl ester, 6 parts of bamboo charcoal, 12 parts of diatomite, 4 parts of plant purification liquid, silver-carrying active aluminum oxide 6
Part, 3 parts of polycarboxylate, 0.7 part of ammonium dichromate, 0.5 part of chlorination hydroxyl aluminium, 8 parts of cobaltous octadecanate, 6 parts of plasticizer, appropriate amount of water.
Wherein, plasticizer is prepared from the following raw materials in parts by weight：12 parts of diethylene glycol dibenzoate, acrylamide 13
Part, 21 parts of polyethylene glycol, 14 parts of glycerine, 15 parts of hydroxymethyl cellulose, 6 parts of carborundum, 85 parts of deionized water；Plant purification liquid by
Effective ingredient after bracketplant, epipremnum aureum, black poplar, the refined extraction of mountain locust tree mixes.
The preparation method of Environment-friendlyceramic ceramic material described in above-described embodiment 1-4, comprises the following steps：
（1）Ball milling：Other raw materials for removing dioctyl ester, plant purification liquid, plasticizer and water are put into ball mill and grind 40-
After 60min, cross 100 mesh sieves and obtain mixed-powder；
（2）Slurrying：Mixed-powder and dioctyl ester, plant purification liquid, plasticizer are mixed, and be stirred continuously 20-30min, is obtained mixed
Compound, water is added, until water did not had mixture, stir 1-2h, slurry is made；
（3）Base：Slurry is vacuumized into 10-20min under 750-800mmHg, blank is made；
（4）Body drying：Blank is subjected to microwave drying 30-40min at 45-60 DEG C；
（5）Sinter molding：5-8h then is sintered at 1250-1300 DEG C, Environment-friendlyceramic ceramic material is made.
Performance detection：Performance detection is carried out to the ceramic tile as made from embodiment 1-4 according to national standard, testing result is such as
Under：
1st, natural radionuclide radium-226, thorium -232, the specific radioactivity of kalium-40 meet 1Ra≤1.0 simultaneously in material,
1r≤1.3。
2nd, there is no the difference of shade, brick edge lengths one corresponding with brick made from the same embodiment between brick and brick
Cause, side directly not warpage.
3rd, water absorption rate is low, and ceramic tile surface is not cracked, and whole tile does not peel off.
4th, ceramic tile is tapped, clear, quality density is high, and hardness is good.
5th, after a period of time, the toxic and harmful gas amount such as indoor bacteria, fungi number and formaldehyde, benzene is decreased obviously.
To sum up, the embodiment of the present invention has the advantages that：According to test result as can be seen that by above-described embodiment 1-
Ceramic tile made from 4 has antibacterial and purifies the function of air, and with the characteristics of density is high, hardness is good, surface is not cracked.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality
Body or operation make a distinction with another entity or operation, and not necessarily require or imply and deposited between these entities or operation
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Nonexcludability includes, so that process, method, article or equipment including a series of elements not only will including those
Element, but also the other element including being not expressly set out, or it is this process, method, article or equipment also to include
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Other identical element also be present in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic；And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. a kind of Environment-friendlyceramic ceramic material, it is characterised in that be prepared from the following raw materials in parts by weight：Industrial solid castoff 35-
40 parts, agricultural crop straw 10-15 parts, discarded shredded paper 20-30 parts, scrap glass 25-50 parts, clay 40-60 parts, quartzy 15-20
Part, feldspar 6-10 parts, alkali stone 10-20 parts, aluminum oxide 0.5-1.5 parts, silica 5-10 parts, mullite 8-10 parts, polychlorostyrene second
Olefine resin 8-12 parts, aluminium block 2-5 parts, calcium carbonate 8-12 parts, dioctyl ester 3-5 parts, bamboo charcoal 5-10 parts, diatomite 10-15 parts, plant
Scavenging solution 3-7 parts, inorganic antiseptic 5-8 parts, polycarboxylate 2-3 parts, ammonium dichromate 0.5-1 parts, chlorination hydroxyl aluminium 0.4-0.6 parts,
Cobaltous octadecanate 3-9 parts, plasticizer 6-8 parts, appropriate amount of water.
2. Environment-friendlyceramic ceramic material as claimed in claim 1, it is characterised in that the inorganic antiseptic is silver-loaded zirconium phosphate or load
Silver-colored activated alumina.
3. Environment-friendlyceramic ceramic material as claimed in claim 1, it is characterised in that the quality of the Corvic and calcium carbonate
Than for 1：1.
4. Environment-friendlyceramic ceramic material as claimed in claim 1, it is characterised in that the plasticizer by following parts by weight raw material
It is made：Diethylene glycol dibenzoate 10-12 parts, acrylamide 10-15 parts, polyethylene glycol 20-25 parts, glycerine 12-15 parts, hydroxyl first
Base cellulose 12-16 parts, carborundum 4-7 parts, deionized water 70-90 parts.
5. Environment-friendlyceramic ceramic material as claimed in claim 1, it is characterised in that the plant purification liquid is by bracketplant, epipremnum aureum, black
Effective ingredient after poplar, the refined extraction of mountain locust tree mixes.
6. the preparation method of Environment-friendlyceramic ceramic material as claimed in claim 1, it is characterised in that comprise the following steps：
（1）Ball milling：Other raw materials for removing dioctyl ester, plant purification liquid, plasticizer and water are put into ball mill and grind 40-
100 mesh sieves are crossed after 60min, obtain mixed-powder；
（2）Slurrying：Mixed-powder and dioctyl ester, plant purification liquid, plasticizer are mixed, and be stirred continuously 20-30min, is obtained mixed
Compound, water is added, until water did not had mixture, stir 1-2h, slurry is made；
（3）Base：Slurry is vacuumized into 10-20min under 750-800mmHg, blank is made；
（4）Body drying：Blank is subjected to microwave drying 30-40min at 45-60 DEG C；
（5）Sinter molding：5-8h then is sintered at 1250-1300 DEG C, Environment-friendlyceramic ceramic material is made.
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Application publication date: 20180302 |