CN107735178B - 铯选择性树脂 - Google Patents

铯选择性树脂 Download PDF

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Publication number
CN107735178B
CN107735178B CN201680040119.9A CN201680040119A CN107735178B CN 107735178 B CN107735178 B CN 107735178B CN 201680040119 A CN201680040119 A CN 201680040119A CN 107735178 B CN107735178 B CN 107735178B
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CN
China
Prior art keywords
cobalt
ion exchanger
hexacyanoferrate
polymer
process step
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201680040119.9A
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English (en)
Chinese (zh)
Other versions
CN107735178A (zh
Inventor
贝恩德·科普
赖因霍尔德·克利佩尔
斯特凡·诺伊曼
皮埃尔·万霍尔内
珍妮·巴比尔
杨天雷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Deutschland GmbH
Original Assignee
Lanxess Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Deutschland GmbH filed Critical Lanxess Deutschland GmbH
Publication of CN107735178A publication Critical patent/CN107735178A/zh
Application granted granted Critical
Publication of CN107735178B publication Critical patent/CN107735178B/zh
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/12—Macromolecular compounds
    • B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/07—Processes using organic exchangers in the weakly basic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/016—Modification or after-treatment of ion-exchangers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/422—Treatment of water, waste water, or sewage by ion-exchange using anionic exchangers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02—Non-contaminated water, e.g. for industrial water supply
    • C02F2103/023—Water in cooling circuits

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
CN201680040119.9A 2015-07-06 2016-07-05 铯选择性树脂 Active CN107735178B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15175385 2015-07-06
EP15175385.2 2015-07-06
PCT/EP2016/065841 WO2017005741A1 (de) 2015-07-06 2016-07-05 Caesium selektive harze

Publications (2)

Publication Number Publication Date
CN107735178A CN107735178A (zh) 2018-02-23
CN107735178B true CN107735178B (zh) 2020-11-03

Family

ID=53773203

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680040119.9A Active CN107735178B (zh) 2015-07-06 2016-07-05 铯选择性树脂

Country Status (7)

Country Link
US (1) US10478814B2 (ru)
EP (1) EP3319726B1 (ru)
JP (1) JP6714684B2 (ru)
CN (1) CN107735178B (ru)
EA (1) EA035628B1 (ru)
ES (1) ES2752459T3 (ru)
WO (1) WO2017005741A1 (ru)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117160404A (zh) * 2023-10-31 2023-12-05 江苏海普功能材料有限公司 多孔复合材料及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2560253B2 (ja) * 1994-05-18 1996-12-04 工業技術院長 セシウム分離用イオン交換体の製造および再生方法
CN1184004A (zh) * 1996-11-26 1998-06-10 罗姆和哈斯公司 混合床离子交换树脂体系和其制备方法
CN1835803A (zh) * 2003-06-13 2006-09-20 兰爱克谢斯德国有限责任公司 吸附砷的离子交换剂
DE102006011316A1 (de) * 2006-03-09 2007-09-13 Lanxess Deutschland Gmbh Radionuklidharze
CN102015107A (zh) * 2008-03-03 2011-04-13 朗盛德国有限责任公司 氨甲基吡啶树脂

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4382124B1 (en) 1958-07-18 1994-10-04 Rohm & Haas Process for preparing macroreticular resins, copolymers and products of said process
DE3031737A1 (de) 1980-08-22 1982-04-01 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von perlpolymerisaten einheitlicher teilchengroesse
CA1166413A (en) 1980-10-30 1984-05-01 Edward E. Timm Process and apparatus for preparing uniform size polymer beads
US4419245A (en) 1982-06-30 1983-12-06 Rohm And Haas Company Copolymer process and product therefrom consisting of crosslinked seed bead swollen by styrene monomer
EP0481603A1 (en) 1990-10-15 1992-04-22 The Dow Chemical Company Separation of weak organic acids from liquid mixtures
US5231115A (en) 1991-12-19 1993-07-27 The Dow Chemical Company Seeded porous copolymers and ion-exchange resins prepared therefrom
IT1262180B (it) * 1993-08-12 1996-06-19 Plastic Legno Giocattoli Di Co Procedimento per la produzione di bocce in materiale plastico e bocce cosi' ottenute
FI111765B (fi) 1996-06-26 2003-09-15 Fortum Nuclear Services Oy Menetelmä cesiumin erottamiseksi ydinjäteliuoksista sekä menetelmä heksasyanoferraattien valmistamiseksi
EP1568660B1 (en) 2004-02-24 2010-12-15 Rohm And Haas Company Method for removal of arsenic from water
DE102009047847A1 (de) * 2009-09-30 2011-03-31 Lanxess Deutschland Gmbh Verfahren zur verbesserten Entfernung von Kationen mittels Chelatharzen
JP6156832B2 (ja) * 2011-06-02 2017-07-05 株式会社 環境浄化研究所 放射性物質捕集材料の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2560253B2 (ja) * 1994-05-18 1996-12-04 工業技術院長 セシウム分離用イオン交換体の製造および再生方法
CN1184004A (zh) * 1996-11-26 1998-06-10 罗姆和哈斯公司 混合床离子交换树脂体系和其制备方法
CN1835803A (zh) * 2003-06-13 2006-09-20 兰爱克谢斯德国有限责任公司 吸附砷的离子交换剂
DE102006011316A1 (de) * 2006-03-09 2007-09-13 Lanxess Deutschland Gmbh Radionuklidharze
CN102015107A (zh) * 2008-03-03 2011-04-13 朗盛德国有限责任公司 氨甲基吡啶树脂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Preparation of Insoluble Hexacyanoferrate(II)-Macroporous Ion Exchange Resin Composites and Comparison of Their Performance as a Regenerable Ion Exchanger for Cesium;Koichi TANIHARA;《NIPPON KAGAKU KAISHI》;19960930(第9期);第835页摘要、第385页第2.1节、第837页表1、第836页第2.2.1-2.2.2节 *

Also Published As

Publication number Publication date
JP6714684B2 (ja) 2020-06-24
US10478814B2 (en) 2019-11-19
ES2752459T3 (es) 2020-04-06
JP2018525471A (ja) 2018-09-06
US20180193828A1 (en) 2018-07-12
WO2017005741A1 (de) 2017-01-12
CN107735178A (zh) 2018-02-23
EP3319726A1 (de) 2018-05-16
EP3319726B1 (de) 2019-09-11
EA035628B1 (ru) 2020-07-17
EA201890230A1 (ru) 2018-08-31

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