CN107725912A - A kind of anti-electrostatic fire retardant shaped steel plastic composite - Google Patents

A kind of anti-electrostatic fire retardant shaped steel plastic composite Download PDF

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Publication number
CN107725912A
CN107725912A CN201710917947.2A CN201710917947A CN107725912A CN 107725912 A CN107725912 A CN 107725912A CN 201710917947 A CN201710917947 A CN 201710917947A CN 107725912 A CN107725912 A CN 107725912A
Authority
CN
China
Prior art keywords
parts
layer
fire retardant
steel pipe
shaped steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710917947.2A
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Chinese (zh)
Inventor
余忠琪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU RUITENG PAINTING TECHNOLOGY CO LTD
Original Assignee
JIANGSU RUITENG PAINTING TECHNOLOGY CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by JIANGSU RUITENG PAINTING TECHNOLOGY CO LTD filed Critical JIANGSU RUITENG PAINTING TECHNOLOGY CO LTD
Priority to CN201710917947.2A priority Critical patent/CN107725912A/en
Publication of CN107725912A publication Critical patent/CN107725912A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • F16L9/147Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups comprising only layers of metal and plastics with or without reinforcement
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of anti-electrostatic fire retardant shaped steel plastic composite, including inner liner, intermediate layer and outermost layer;The inner liner is the lining plastic bed of material, and intermediate layer is middle steel pipe layer, and outermost layer is outer layer plastic layer;Incised groove or meshed grooves are equipped with the inner surface of the steel pipe layer and outer surface, inner liner is by adhesive bond on the inner surface of steel pipe layer, and outermost layer is by adhesive bond on the outer surface of middle steel pipe layer.The anti-electrostatic fire retardant shaped steel plastic composite of the present invention is by making antistatic, wearability and flame retardant type have large increase the raw material proportioning of the lining plastic bed of material.In addition, the present invention makes to be mutually twisted connection between steel pipe and inside and outside layer plastics by the incised groove structure or meshed grooves structure of steel pipe surfaces externally and internally, seal very much firmly with reference to integral, the situation that stress, which can be avoided, to be caused to separate, slip between steel pipe and plastics occurs, service life length.

Description

A kind of anti-electrostatic fire retardant shaped steel plastic composite
Technical field
The present invention relates to inflammable gas, liquid or fluidized solids transfer tube, more particularly to a kind of anti-electrostatic fire retardant Shaped steel plastic composite.
Background technology
Many inflammable, explosive occasion needs large-scale Pipeline transport gas, even liquid, fluidized solids.Many pipelines The gas conveyed, liquid or liquefied solid, inherently explosives, inflammable items, such as the various transfer pipelines under mine, such as The high underground air of firedamp drainage content, blast furnace gas, flyash.Under this occasion, there is higher requirement to transfer conduit, such as Fire-resistant, prevent electrostatic phenomenon, wear-resisting, anti-leakage etc..So traditional engineering discipline can only use cast iron pipe, or large-diameter steel Pipe.Its weight is big, and corrosion is too fast, if it is considered that to be directed at use cost too high for friction loss.So needing what is constructed Occasion is often invested greatly.
In the last few years with material technology, the raising of technique, due to being solved well in pvc pipe road and composite glass steel pipe Fire-retardant and antistatic problem.The plastic composite pipe of PVC and fiberglass etc has been also widely used under mine and similar Occasion.By fiber or fabric it is base-material in composite plastic pipe manufacture craft, using thermosetting resin adhesive as adhesive, adds and match somebody with somebody Fire retardant, antistatic additive, curing agent and inserts composition adhering and solidifying agent, in the coating bonding of tubular mould top winding base-material side Curing agent, forms the pipeline with prefabricated ring flange fitment combination after final solidification, the structure of pipeline includes three layers:In tubular mould Even application has the tool that conductive and flame-retarding characteristic thermosetting resin adhesive is formed simultaneously for upper winding fiber or its fabric There is impervious and anti-wear performance inner liner, wind enhanced fiber on the basis of ring flange mold and inner liner are formed or it is knitted Even application has the strength layer that conductive and flame-retarding characteristic thermosetting resin adhesive is formed to thing simultaneously, in the table of strength layer The thermosetting resin adhesive of fiber or its fabric while even application with strong conduction and flame-retarding characteristic of densification is wound on face Formed surface conductive layer.Due to its low cost, corrosion resistance is strong, service life received the welcome of pole up to 50 years.
But with application, the shortcomings that inner obvious is exposed, as flexural strength is too low, difficulty of construction is larger.Then remove Also capacity of resisting impact load is poor outside above weakness, and quality is crisp, poor toughness easily causes comminuted breakage in the presence of a harsh environment, Easily without possessing excellent security, its anti-wear performance is also poor for leakage, for the big gas of dustiness and fluidized solids Conveying then shows hidden danger clearly disadvantageous and for security.In addition, existing steel-plastics composite pipe, its steel pipe is moulded with inside and outside layer Material pass through PUR adhering and sealing, easily causes steel pipe and is combined with plastics not firm enough, the particularly time one is grown and cold and hot caused Under stress, it may occur that separate, slip between steel pipe and plastics, cause steel pipe by corrosion, reduction of service life.
The content of the invention
Goal of the invention:To solve the deficiencies in the prior art, there is provided a kind of anti-electrostatic fire retardant shaped steel plastic composite.
Technical scheme:A kind of anti-electrostatic fire retardant shaped steel plastic composite, including inner liner, intermediate layer and outermost layer;In described Lining is the lining plastic bed of material, and intermediate layer is middle steel pipe layer, and outermost layer is outer layer plastic layer;The inner surface of the steel pipe layer and outer Be equipped with incised groove or meshed grooves on surface, inner liner by adhesive bond on the inner surface of steel pipe layer, outermost Layer is by adhesive bond on the outer surface of middle steel pipe layer.
Preferably, the lining plastic bed of material is counted including the following raw material in parts by weight:100 parts of acrylic resin, fire retardant 3 parts of 90 parts, 1 part of gypsum, 0.5 part of curing agent, 5 parts of accelerator and silica flour.
Preferably, the lining plastic bed of material is counted including the following raw material in parts by weight:100 parts of acrylic resin, fire retardant 10 parts of 30 parts, 1.5 parts of gypsum, 1 part of curing agent, 4 parts of accelerator and silica flour.
Preferably, the lining plastic bed of material is counted including the following raw material in parts by weight:100 parts of acrylic resin, fire retardant 15 parts of 40 parts, 2 parts of gypsum, 2 parts of curing agent, 3 parts of accelerator and silica flour.
Preferably, the lining plastic bed of material is counted including the following raw material in parts by weight:100 parts of acrylic resin, fire retardant 30 parts of 20 parts, 3 parts of gypsum, 4 parts of curing agent, 1 part of accelerator and silica flour.
Preferably, the outer layer plastic layer is counted including the following raw material in parts by weight:100 parts of epoxy resin, fire retardant 20 10 parts of part, 0.5 part of gypsum, 0.5 part of curing agent, 4 parts of accelerator and silica flour.
Preferably, the outer layer plastic layer is counted including the following raw material in parts by weight:100 parts of epoxy resin, fire retardant 10 20 parts of part, 1 part of gypsum, 1.5 parts of curing agent, 3 parts of accelerator and silica flour.
Preferably, the outer layer plastic layer is counted including the following raw material in parts by weight:100 parts of epoxy resin, fire retardant 40 30 parts of part, 2 parts of gypsum, 3.5 parts of curing agent, 1 part of accelerator and silica flour.
Beneficial effect:Compared with prior art, anti-electrostatic fire retardant shaped steel plastic composite of the invention passes through to plastic lining The raw material proportioning of layer makes antistatic, wearability and flame retardant type have large increase.In addition, the present invention passes through steel pipe surfaces externally and internally Incised groove structure or meshed grooves structure make to be mutually twisted connection between steel pipe and inside and outside layer plastics, and very sealing is firm Combination it is integral, the situation for stress can be avoided to cause to separate between steel pipe and plastics, slipping occurs, service life It is long.
Brief description of the drawings
Fig. 1 is the cross-sectional structure schematic diagram of the present invention.
Embodiment
Technical scheme is elaborated with reference to the accompanying drawings and examples.
As shown in figure 1, the steel-plastics composite pipe of the present invention includes inner liner 1, intermediate layer 2 and outermost layer 3, wherein, inner liner For plastic layer, intermediate layer is steel pipe layer, and outermost layer is plastic layer.Sawtooth is equipped with the inner surface of middle steel pipe layer and outer surface Connected in star or meshed grooves, by adhesive bond on the inner surface of middle steel pipe layer, outer layer plastic layer leads to the lining plastic bed of material Adhesive bond is crossed on the outer surface of middle steel pipe layer, groove is more, more beneficial to the lining plastic bed of material and outer layer plastic layer with Between combination between steel pipe layer, enhance cohesive, more firmly, prevent from coming off.
There is the conductive thermosetting with flame-retarding characteristic used in each structure sheaf of steel-plastics composite pipe of the present invention is specific when processing Resin binder embodiment is by following composition by weight than being formulated:
(1) the lining plastic bed of material 1 is used
Embodiment Acrylic resin Fire retardant Gypsum Curing agent Accelerator Silica flour
1 100 90 1 0.5 5 3
2 100 30 1.5 1 4 10
3 100 40 2 2 3 15
4 100 50 2.5 3 2 20
5 100 20 3 4 1 30
(2) outer layer plastic layer 3 is used
Embodiment Epoxy resin Fire retardant Gypsum Curing agent Accelerator Silica flour
6 100 20 0.5 0.5 4 10
7 100 10 1 1.5 3 20
8 100 30 1.5 2.5 2 20
9 100 40 2 3.5 1 30
10 100 25 2.5 4.5 0.5 30
Selected epoxy resin is food-grade epoxy resin in above example, is a kind of polar material, with steel pipe Adhesion is extremely strong, and for a long time using being not in separation, obscission, aspect of particularly expanding with heat and contract with cold, which has, more preferably to be showed, Weatherability is more preferable.Accelerator, it can specifically use cobalt naphthenate or methylaniline.Curing agent, it can specifically use methyl ketone peroxide, second Any of ketone, potassium peroxide acyl, cycloethanone peroxide.

Claims (8)

1. a kind of anti-electrostatic fire retardant shaped steel plastic composite, it is characterised in that including inner liner, intermediate layer and outermost layer;In described Lining is the lining plastic bed of material, and intermediate layer is middle steel pipe layer, and outermost layer is outer layer plastic layer;The inner surface of the steel pipe layer and outer Be equipped with incised groove or meshed grooves on surface, inner liner by adhesive bond on the inner surface of steel pipe layer, outermost Layer is by adhesive bond on the outer surface of middle steel pipe layer.
A kind of 2. anti-electrostatic fire retardant shaped steel plastic composite according to claim 1, it is characterised in that the lining plastic bed of material Meter includes the following raw material in parts by weight:100 parts of acrylic resin, 90 parts of fire retardant, 1 part of gypsum, 0.5 part of curing agent, promotion 3 parts of 5 parts of agent and silica flour.
A kind of 3. anti-electrostatic fire retardant shaped steel plastic composite according to claim 1, it is characterised in that the lining plastic bed of material Meter includes the following raw material in parts by weight:100 parts of acrylic resin, 30 parts of fire retardant, 1.5 parts of gypsum, 1 part of curing agent, promotion 10 parts of 4 parts of agent and silica flour.
A kind of 4. anti-electrostatic fire retardant shaped steel plastic composite according to claim 1, it is characterised in that the lining plastic bed of material Meter includes the following raw material in parts by weight:100 parts of acrylic resin, 40 parts of fire retardant, 2 parts of gypsum, 2 parts of curing agent, accelerator 3 15 parts of part and silica flour.
A kind of 5. anti-electrostatic fire retardant shaped steel plastic composite according to claim 1, it is characterised in that the lining plastic bed of material Meter includes the following raw material in parts by weight:100 parts of acrylic resin, 20 parts of fire retardant, 3 parts of gypsum, 4 parts of curing agent, accelerator 1 30 parts of part and silica flour.
A kind of 6. anti-electrostatic fire retardant shaped steel plastic composite according to claim 1, it is characterised in that the outer layer plastic layer Meter includes the following raw material in parts by weight:100 parts of epoxy resin, 20 parts of fire retardant, 0.5 part of gypsum, 0.5 part of curing agent, promotion 10 parts of 4 parts of agent and silica flour.
A kind of 7. anti-electrostatic fire retardant shaped steel plastic composite according to claim 1, it is characterised in that the outer layer plastic layer Meter includes the following raw material in parts by weight:100 parts of epoxy resin, 10 parts of fire retardant, 1 part of gypsum, 1.5 parts of curing agent, accelerator 3 20 parts of part and silica flour.
A kind of 8. anti-electrostatic fire retardant shaped steel plastic composite according to claim 1, it is characterised in that the outer layer plastic layer Meter includes the following raw material in parts by weight:100 parts of epoxy resin, 40 parts of fire retardant, 2 parts of gypsum, 3.5 parts of curing agent, accelerator 1 30 parts of part and silica flour.
CN201710917947.2A 2017-09-27 2017-09-27 A kind of anti-electrostatic fire retardant shaped steel plastic composite Pending CN107725912A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710917947.2A CN107725912A (en) 2017-09-27 2017-09-27 A kind of anti-electrostatic fire retardant shaped steel plastic composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710917947.2A CN107725912A (en) 2017-09-27 2017-09-27 A kind of anti-electrostatic fire retardant shaped steel plastic composite

Publications (1)

Publication Number Publication Date
CN107725912A true CN107725912A (en) 2018-02-23

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19531708A1 (en) * 1994-08-30 1996-03-07 Usui Kokusai Sangyo K Ltd Corrosion resistant resin coating assembly on a metal tube
CN201568654U (en) * 2010-02-03 2010-09-01 山西俪通复合材料有限公司 Steel plastic composite pipe
CN102506240A (en) * 2011-10-21 2012-06-20 浙江师范大学 High-strength flame-retardant anti-static pipeline
CN103772789A (en) * 2014-01-10 2014-05-07 公安部四川消防研究所 Flame-retardant polyolefin resin composition and preparation method thereof, and flame-retardant tubular product
CN203686388U (en) * 2014-01-24 2014-07-02 新兴铸管股份有限公司 Steel and plastic composite pressure pipe
CN105670109A (en) * 2014-11-21 2016-06-15 神华集团有限责任公司 Polypropylene composition, preparation method thereof, and polypropylene material prepared therethrough

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19531708A1 (en) * 1994-08-30 1996-03-07 Usui Kokusai Sangyo K Ltd Corrosion resistant resin coating assembly on a metal tube
CN201568654U (en) * 2010-02-03 2010-09-01 山西俪通复合材料有限公司 Steel plastic composite pipe
CN102506240A (en) * 2011-10-21 2012-06-20 浙江师范大学 High-strength flame-retardant anti-static pipeline
CN103772789A (en) * 2014-01-10 2014-05-07 公安部四川消防研究所 Flame-retardant polyolefin resin composition and preparation method thereof, and flame-retardant tubular product
CN203686388U (en) * 2014-01-24 2014-07-02 新兴铸管股份有限公司 Steel and plastic composite pressure pipe
CN105670109A (en) * 2014-11-21 2016-06-15 神华集团有限责任公司 Polypropylene composition, preparation method thereof, and polypropylene material prepared therethrough

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
罗河胜: "《塑料工艺与实用配方》", 31 January 2005, 广东科技出版社 *

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Application publication date: 20180223