CN107676132A - A kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide - Google Patents

A kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide Download PDF

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Publication number
CN107676132A
CN107676132A CN201710830974.6A CN201710830974A CN107676132A CN 107676132 A CN107676132 A CN 107676132A CN 201710830974 A CN201710830974 A CN 201710830974A CN 107676132 A CN107676132 A CN 107676132A
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China
Prior art keywords
discarded concrete
pipeline
carbon dioxide
goaf
valve
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CN201710830974.6A
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CN107676132B (en
Inventor
王圣程
姜慧
禄利刚
殷惠光
张朕
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State Power Investment Group Carbon Assets Management Co ltd
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Xuzhou University of Technology
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F15/00Methods or devices for placing filling-up materials in underground workings
    • E21F15/08Filling-up hydraulically or pneumatically
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F17/00Methods or devices for use in mines or tunnels, not covered elsewhere
    • E21F17/16Modification of mine passages or chambers for storage purposes, especially for liquids or gases

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  • Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide, A, the pulsation injection saturated limewater into old abandoned mine coal bed gas drainage tube;B, the pulsation injection saturated limewater into mine goaf;C~D, discarded concrete is transported in hopper and by the vibration of vibrator so that the particle diameter that hopper carries out discarded concrete sieves;E~G and then being transported in mine goaf in batches by the discarded concrete after screening, while saturated limewater makes distribution of the discarded concrete in goaf wider, then controls the injection rate of discarded concrete;H~I, into mine goaf, injection carbon dioxide seals ground drilling after being stored.Discarded concrete is filled in abandoned mine goaf by the present invention, while carbon dioxide is filled with mine goaf, so as to solve the problems, such as that discarded concrete is placed, abandoned mine is filled and carbon dioxide sequestration, reduces land pollution and atmospheric warming effect.

Description

A kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide
Technical field
The present invention relates to a kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide.
Background technology
Construction material of the concrete as human maximum dosage, its theory have reached its maturity with technology.It is but a large amount of at present Negative effect is brought to human settlement and the ecosystem while concrete is employed.The average life span of Chinese architecture is shorter only For 35 years, far below the Europe service life of 70 years, Urban House Demolition and it is engineered also discarded substantial amounts of concrete, according to existing There are data to calculate and draw the year two thousand twenty, China's discarded concrete amount is up to 6.28 hundred million tons, due to the discarded coagulation of current China Soil 97% is all direct landfill and outdoor accumulation, can thus waste substantial amounts of land resource, and pollute environment.Therefore How to handle discarded concrete both will not land occupation resource, the problem of pollution that can also be reduced to environment is urgent need to resolve.
Other China is maximum in the world coal production and country of consumption.The coal mining of long-term extensive high intensity produces Plurality of abandoned mine and area huge goaf, extraction coal bed gas can be carried out to goaf after mined out;For useless Barrow well can be divided into new abandoned mine and old abandoned mine, and new abandoned mine refers to stop producing, but in mine Transporting equipment is not removed also;And old abandoned mine refers to that the transporting equipment that mine has stopped production in certain time and mine is complete Remove, and mine is blocked, but this closure is only closure extraction well head at present, the goaf of underground is still empty Lack, so that the ground in goaf such as easily settles, collapsed at the disaster scenarios it, therefore how the goaf of old abandoned mine is entered Reduced after row filling and the problem of disaster scenarios it is urgent need to resolve such as settle, collapse.
Because the mistake of global carbon converges, i.e., mankind's activity it is for example fossil-fuel-fired discharge into the atmosphere with deforestation etc. two Carbonoxide exceedes the increment of carbon dioxide and the phenomenon of ocean uptake amount in same period earth atmosphere, so may result in air Carbon dioxide is more and more, and so as to cause the aggravation of global greenhouse effect, it is big to ultimately result in the global situation for extreme weather occur Big increase, although some in known material have absorption, such as concrete to carbon dioxide, due to concrete The construction of building is contributed to, therefore does not also have and seals required confined space up for safekeeping so as to which the envelope of carbon dioxide can not be carried out Deposit, therefore how caused carbon dioxide after mankind's activity seal up for safekeeping and it is not discharged into air and need solution badly Certainly the problem of.
The content of the invention
In view of the above-mentioned problems of the prior art, the present invention, which provides a kind of old abandoned mine, places discarded concrete and envelope The method for depositing carbon dioxide, discarded concrete is filled in abandoned mine goaf, while carbon dioxide is filled with ore deposit In well goaf, so as to solve the problems, such as that discarded concrete is placed, abandoned mine is filled and carbon dioxide sequestration, it is dirty to reduce soil Dye and atmospheric warming effect.
To achieve these goals, the technical solution adopted by the present invention is:A kind of old abandoned mine places discarded concrete And the method for sequestration of carbon dioxide, concretely comprise the following steps:
A, saturated limewater is injected into storage tank, opens the first valve, the second valve and the 3rd valve, starts jerk pump Conveying, saturated limewater enter coal bed gas through the first pipeline, the second pipeline, the 3rd pipeline, the 5th pipeline and the 6th pipeline successively Drainage tube, coal bed gas drainage tube is cleaned, the pressure limit for controlling saturated limewater after pulsation is 5MPa~40MPa, arteries and veins The change of dynamic frequency turns to 0.01Hz~0.1Hz, and pulsation injection length is 15min~25min;
B, using drilling well video-unit detection of coal seam gas drainage tube, it is ensured that after coal bed gas drainage tube is unobstructed, close the 3rd valve Door, while the 4th valve is opened, now saturated limewater bores through the first pipeline, the second pipeline and the 4th pipeline into ground successively In the mine goaf of downhole;
C, load discarded concrete into hopper, and record into discarded concrete volume in material bin, the discarded coagulation 0~10mm of particle size range of soil;
D, vibrator is controlled to start working by controller, now hopper is with vibrator sustained vibration;
E, discarded concrete is under vibrational state, and by the screening of large aperture sieve and small-bore sieve, 0~5mm particle diameters give up Abandon concrete and enter mine goaf after the 5th pipeline, the 6th pipeline and coal bed gas drainage tube, while saturated limewater passes through The pulsation of 4th pipeline sprays saturated limewater and breaks up the discarded concrete of accumulation, makes water of the discarded concrete with saturated limewater The distribution area flowed in goaf is wider;
F, by observing in hopper large aperture sieve and when upper discarded concrete volume stability is sieved in small-bore, opening small-bore Sieve, the discarded concrete for making particle diameter be 5mm~10mm enter mine goaf by coal bed gas drainage tube;
G, repeat step D~F, laser range finder it is per minute measurement ground in goaf discarded concrete away from From, and controller is passed to, when the distance value of measurement is equal to coal bed gas extraction length of tube, signal is fed back to vibration by controller Device and jerk pump, vibrator and jerk pump is set to be stopped;
H, the 4th valve and the 5th valve are closed, opens the 6th valve, the carbon dioxide in carbon dioxide storing apparatus leads to Cross carbon dioxide transport pipeline and the 6th pipeline injection mine goaf, the injection pressure of the carbon dioxide for 1MPa~ 1.5MPa, the injection rate of carbon dioxide are 100~120 times of discarded concrete volume;
I, to the end of carbon dioxide injection, all valves is closed and remove device, seal ground drilling.
Further, the controller is programmable logic controller (PLC).
Compared with prior art, the present invention is first injected saturated limewater in coal bed gas drainage tube by jerk pump, so as to Coal bed gas drainage tube can preferably be cleared up, it is ensured that drainage tube it is unobstructed, be advantageous to the conveying unobstructed subsequently into goaf and discard Concrete;When discarded concrete is transported in goaf, ground is measured in real time using laser range finder to mine goaf The distance of interior discarded concrete, contribute to the accurate transport progress for grasping discarded concrete, prevent discarded concrete from blocking coal seam The bottom nozzle of gas drainage tube, it is ensured that the patency of follow-up carbon dioxide injection;The joint sieved by large aperture sieve and small-bore Effect, the discarded concrete that its large pore sieve is played in hopper are uniformly transported on the sieve of small-bore, are easy to what small-bore was sieved Particle diameter sieving actoion, progressively transporting from small to large for discarded concrete particle diameter is realized, is favorably improved goaf discarded concrete Amount of storage;The dynamic injection saturated limewater of process middle arteries is transported in discarded concrete in addition, will can be accumulated in time in goaf Discarded concrete break up, make distribution area of the discarded concrete with the current of saturated limewater in goaf wider, favorably In the more discarded concretes of storage, and the calcium hydroxide composition in limewash can further strengthen the absorption to carbon dioxide With seal up for safekeeping, mitigate carbon dioxide caused by greenhouse effects;Because the density of carbon dioxide is heavier than air, the carbon dioxide being injected into Under self gravitation effect, to discarded concrete accumulation bottom diffusion, and discarded concrete and the calcium hydroxide reaction of limewash, Complete sealing up for safekeeping for carbon dioxide.In summary, discarded concrete is filled in abandoned mine goaf by the present invention, while by two Carbon oxide gas are filled with mine goaf, are placed so as to solve discarded concrete, abandoned mine filling and carbon dioxide are sealed The problem of depositing, and then realize the effect for reducing land pollution, preventing goaf sedimentation, collapsing and administer atmospheric warming effect.
Brief description of the drawings
Fig. 1 is the structural representation of induction system of the present invention.
In figure:1st, storage tank;2nd, the first valve;3rd, the first pipeline;4th, jerk pump;5th, controller;6th, hopper;7th, large aperture Sieve;8th, small-bore is sieved;9th, transparent plastic cover;10th, vibrator;11st, the second pipeline;12nd, the second valve;13rd, the first triple valve; 14th, the 3rd pipeline;15th, the 3rd valve;16th, the 4th pipeline;17th, the 4th valve;18th, four the mouth of a river is separated;19th, the 5th pipeline;20、 5th valve;21st, the second triple valve;22nd, high pressure sealing lid;23rd, carbon dioxide storing apparatus;24th, carbon dioxide delivery pipe; 25th, the 6th valve;26th, the 3rd triple valve;27th, the 6th pipeline;28th, laser range finder;29th, ground drilling;30th, coal bed gas extraction Pipe;31st, mine goaf;32nd, it is caving thing.
Embodiment
The invention will be further described below.
As shown in figure 1, the present invention includes storage tank 1, the first pipeline 3, jerk pump 4, controller 5, hopper 6, large aperture sieve 7th, small-bore sieve 8, vibrator 10, the second pipeline 11, the first triple valve 13, the 3rd pipeline 14, the 4th pipeline 16, the 5th pipeline 19th, the second triple valve 21, high pressure sealing lid 22, carbon dioxide storing apparatus 23, carbon dioxide delivery pipe 24, the 3rd triple valve 26th, the 6th pipeline 27 and laser range finder 28, storage tank 1 by the inlet communication of the first pipeline 3 and jerk pump 4, jerk pump 4 Outlet is connected by the second pipeline 11 with 13 one of port of the first triple valve, first two other port of triple valve 13 difference Connected with one end of the 3rd pipeline 14 and one end of the 4th pipeline 16, the other end of the 3rd pipeline 14 and the second triple valve 21 are wherein A port connects, and second two other port of triple valve 21 connects with the discharging opening of hopper 6 and one end of the 5th pipeline 19 respectively Logical, hopper 6 is arranged on the top of the second triple valve 21, the large aperture sieve 7 and small-bore sieve 8 be horizontally set in hopper 6 and Large aperture sieve 7 is fixed on the outer surface of hopper 6 in the top of small-bore sieve 8, vibrator 10;The other end and the 3rd of 5th pipeline 19 26 one of port of triple valve connects, the 3rd two other port of triple valve 26 one end with the 6th pipeline 27 and dioxy respectively Change one end connection of carbon delivery pipe 24, the other end of carbon dioxide delivery pipe 24 connects with carbon dioxide storing apparatus 23;High pressure Closure 22 seals the port for being fixed on coal bed gas drainage tube 30, and the other end of the 4th pipeline 16 stretches into through high pressure sealing lid 22 Into mine goaf 31, the other end of the 6th pipeline 27 is extend into coal bed gas drainage tube 30 through high pressure sealing lid 22, institute Laser range finder 28 is stated to be fixedly connected with high pressure sealing lid 22;
First pipeline 3 is provided with the first valve 2, and the second pipeline 11 is provided with the second valve 12, the 3rd pipeline 14 The 4th valve 17 is provided with provided with the 3rd valve 15, the 4th pipeline 16, the 5th valve is provided between the triple valve 21 of hopper 6 and second 20, carbon dioxide delivery pipe 24 is provided with the 6th valve 25;
The controller 5 is connected with jerk pump 4, vibrator 10 and laser range finder 28.
Further, the other end of the 4th pipeline 16 is in and is caving the top 0.1m~0.2m of thing 32.In this distance The ejection of saturated limewater can be easy to.
Further, the other end of the 4th pipeline 16 separates the mouth of a river 18 provided with four.4th pipe can be made using this structure The saturated limewater that road 16 exports uniformly sprays to surrounding, bigger so as to increase distribution of the saturated limewater in goaf And evenly.
Further, the charging aperture of the hopper 6 is provided with transparent plastic cover 9.Transparent plastic cover 9 is set to prevent hopper 6 from existing Discarded concrete particle can splash away from the charging aperture of hopper 6 during motion, can be easy to staff using transparent setting in addition The delivery situation of discarded concrete in Real Time Observation hopper 6.
Further, the controller 5 is programmable logic controller (PLC).This not only Stability Analysis of Structures, and being easy to of controller 5 The control program performed needed for setting.
Further, the sieve diameter of the large aperture sieve 7 is 10mm, and the sieve diameter of small-bore sieve 8 is 5mm.Using this Kind sieve diameter, can make discarded concrete reduce mutual gap, be stored in so as to as much as possible in goaf.
The present invention's concretely comprises the following steps:
A, saturated limewater is injected into storage tank 1, opens the first valve 2, the second valve 12 and the 3rd valve 15, is started Jerk pump 4 conveys, and saturated limewater is successively through the first pipeline 3, the second pipeline 11, the 3rd pipeline 14, the 5th pipeline 19 and the 6th Pipeline 27 enters coal bed gas drainage tube 30, and coal bed gas drainage tube 30 is cleaned, the pressure of saturated limewater after control pulsation Scope is 5MPa~40MPa, and the change of ripple frequency turns to 0.01Hz~0.1Hz, and pulsation injection length is 15min~25min;
B, using drilling well video-unit detection of coal seam gas drainage tube 30, it is ensured that after coal bed gas drainage tube 30 is unobstructed, close the Three valves 15, while the 4th valve 17 is opened, now saturated limewater is successively through the first pipeline 3, the second pipeline 11 and the 4th pipe Road 16 enters in the mine goaf 31 of the lower section of ground drilling 29;
C, load discarded concrete into hopper 6, and record into discarded concrete volume in material bin 6, it is described discarded mixed Coagulate 0~10mm of particle size range of soil;
D, vibrator 10 is controlled to start working by controller 5, now hopper 6 is with the sustained vibration of vibrator 10;It is so that useless Abandoning concrete motion in hopper 6 is easy to the discarded concrete of different-grain diameter to pass through large aperture sieve 7 and small-bore sieve 8;
E, discarded concrete sieves 8 screening by large aperture sieve 7 and small-bore under vibrational state, 0~5mm particle diameters Discarded concrete enters mine goaf 31 after the 5th pipeline 19, the 6th pipeline 27 and coal bed gas drainage tube 30, in jerk pump 4 Under effect, saturated limewater is pulsed by the 4th pipeline 16 and sprays saturated limewater, in time can be rushed the discarded concrete of accumulation Dissipate, make distribution area of the discarded concrete with the current of saturated limewater in goaf wider;
When F, sieving discarded concrete volume stability on 7 and small-bore sieve 8 by observing large aperture in hopper 6, aperture is opened Footpath sieve 8, the discarded concrete that particle diameter is 5mm~10mm is set to enter mine goaf 31 by coal bed gas drainage tube 30;
G, repeat step D~F, laser range finder 28 it is per minute measurement ground in goaf discarded concrete away from From, and controller 5 is passed to, when the distance value of measurement is equal to coal bed gas 30 length of drainage tube, controller 5 feeds back to signal Vibrator 10 and jerk pump 4, vibrator 10 and jerk pump 4 is set to be stopped;
H, the 4th valve 17 and the 5th valve 20 are closed, opens the 6th valve 25, two in carbon dioxide storing apparatus 23 Carbonoxide injects mine goaf 31, the injection pressure of the carbon dioxide by the pipeline 27 of carbon dioxide delivery tube 24 and the 6th For 1MPa~1.5MPa, the injection rate of carbon dioxide is 100~120 times of discarded concrete volume;
I, to the end of carbon dioxide injection, all valves is closed and remove device, seal ground drilling.
Further, the controller 5 is programmable logic controller (PLC).This not only Stability Analysis of Structures, and being easy to of controller 5 The control program performed needed for setting.

Claims (2)

1. a kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide, it is characterised in that concretely comprise the following steps:
A, the injection saturated limewater into storage tank (1), opens the first valve (2), the second valve (12) and the 3rd valve (15), Start jerk pump (4) conveying, saturated limewater is successively through the first pipeline (3), the second pipeline (11), the 3rd pipeline (14), the 5th Pipeline (19) and the 6th pipeline (27) enter coal bed gas drainage tube (30), and coal bed gas drainage tube (30) is cleaned, and control arteries and veins The pressure limit of saturated limewater is 5MPa~40MPa after dynamic, and the change of ripple frequency turns to 0.01Hz~0.1Hz, pulsation injection Time is 15min~25min;
B, using drilling well video-unit detection of coal seam gas drainage tube (30), it is ensured that after coal bed gas drainage tube (30) is unobstructed, close the Three valves (15), while the 4th valve (17) is opened, now saturated limewater is successively through the first pipeline (3), the second pipeline (11) Enter with the 4th pipeline (16) in the mine goaf (31) below ground drilling (29);
C, load discarded concrete into hopper (6), and record into the interior discarded concrete volume of material bin (6), it is described discarded mixed Coagulate 0~10mm of particle size range of soil;
D, vibrator (10) is controlled to start working by controller (5), now hopper (6) is with vibrator (10) sustained vibration;
E, discarded concrete sieves (7) by large aperture and the screening of (8) is sieved in small-bore under vibrational state, 0~5mm particle diameters Discarded concrete enters mine goaf (31) after the 5th pipeline (19), the 6th pipeline (27) and coal bed gas drainage tube (30), Under jerk pump (4) effect, saturated limewater is pulsed by the 4th pipeline (16) and sprays saturated limewater;
When F, by observing discarded concrete volume stability on the interior large aperture sieve (7) of hopper (6) and small-bore sieve (8), open small Aperture sieve (8), the discarded concrete for making particle diameter be 5mm~10mm enter mine goaf by coal bed gas drainage tube (30) (31);
G, repeat step D~F, laser range finder (28) it is per minute measurement ground in goaf discarded concrete away from From and passing to controller (5), when the distance value of measurement is equal to coal bed gas drainage tube (30) length, controller (5) is by signal Vibrator (10) and jerk pump (4) are fed back to, vibrator (10) and jerk pump (4) is stopped;
H, the 4th valve (17) and the 5th valve (20) are closed, opens the 6th valve (25), carbon dioxide storing apparatus (23) is interior Carbon dioxide pass through carbon dioxide delivery tube (24) and the 6th pipeline (27) injection mine goaf (31), the carbon dioxide Injection pressure be 1MPa~1.5MPa, the injection rate of carbon dioxide is 100~120 times of discarded concrete volume;
I, to the end of carbon dioxide injection, all valves is closed and remove device, sealing ground drilling (29).
2. the method that a kind of old abandoned mine according to claim 1 places discarded concrete and sequestration of carbon dioxide, its It is characterised by, the controller (5) is programmable logic controller (PLC).
CN201710830974.6A 2017-09-15 2017-09-15 A kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide Active CN107676132B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109812293A (en) * 2019-02-18 2019-05-28 河南理工大学 It is a kind of to seal CO up for safekeeping using coal mine waste mine goaf2Method
CN110526245A (en) * 2019-09-16 2019-12-03 中建商品混凝土有限公司 A kind of method of sequestration of carbon dioxide and cooperative disposal radioactive waste
CN110652847A (en) * 2019-11-14 2020-01-07 河南理工大学 Device and method for treating carbon dioxide in industrial waste gas based on coal mine goaf
CN115095387A (en) * 2022-07-25 2022-09-23 中南大学 Utilize filling material to seal up and deposit return airway CO in pit 2 Method (2)
CN115306479A (en) * 2022-08-23 2022-11-08 中国矿业大学 CO based on abandoned mine goaf 2 Block sealing method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU976111A1 (en) * 1981-05-05 1982-11-23 За витель „976111 (I Device for cleaning filling-up concrete conduit
SU1134496A1 (en) * 1983-04-14 1985-01-15 Пермский политехнический институт Method for conveying filling mix
CN104338605A (en) * 2014-07-23 2015-02-11 湖南鑫生矿冶废弃物综合利用科技有限公司 Method for recycling inorganic filler from iron tailings, obtained inorganic filler and inorganic filler modification method
CN204783111U (en) * 2015-06-24 2015-11-18 辽宁有色基础工程公司 Structure is backfilled to abandonment colliery shaft

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU976111A1 (en) * 1981-05-05 1982-11-23 За витель „976111 (I Device for cleaning filling-up concrete conduit
SU1134496A1 (en) * 1983-04-14 1985-01-15 Пермский политехнический институт Method for conveying filling mix
CN104338605A (en) * 2014-07-23 2015-02-11 湖南鑫生矿冶废弃物综合利用科技有限公司 Method for recycling inorganic filler from iron tailings, obtained inorganic filler and inorganic filler modification method
CN204783111U (en) * 2015-06-24 2015-11-18 辽宁有色基础工程公司 Structure is backfilled to abandonment colliery shaft

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109812293A (en) * 2019-02-18 2019-05-28 河南理工大学 It is a kind of to seal CO up for safekeeping using coal mine waste mine goaf2Method
CN110526245A (en) * 2019-09-16 2019-12-03 中建商品混凝土有限公司 A kind of method of sequestration of carbon dioxide and cooperative disposal radioactive waste
CN110652847A (en) * 2019-11-14 2020-01-07 河南理工大学 Device and method for treating carbon dioxide in industrial waste gas based on coal mine goaf
CN110652847B (en) * 2019-11-14 2024-01-19 河南理工大学 Device and method for disposing carbon dioxide in industrial waste gas based on coal mine goaf
CN115095387A (en) * 2022-07-25 2022-09-23 中南大学 Utilize filling material to seal up and deposit return airway CO in pit 2 Method (2)
CN115306479A (en) * 2022-08-23 2022-11-08 中国矿业大学 CO based on abandoned mine goaf 2 Block sealing method
CN115306479B (en) * 2022-08-23 2023-06-09 中国矿业大学 CO based on abandoned mine goaf 2 Block type sealing method

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