A kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide
Technical field
The present invention relates to a kind of method that old abandoned mine places discarded concrete and sequestration of carbon dioxide.
Background technology
Construction material of the concrete as human maximum dosage, its theory have reached its maturity with technology.It is but a large amount of at present
Negative effect is brought to human settlement and the ecosystem while concrete is employed.The average life span of Chinese architecture is shorter only
For 35 years, far below the Europe service life of 70 years, Urban House Demolition and it is engineered also discarded substantial amounts of concrete, according to existing
There are data to calculate and draw the year two thousand twenty, China's discarded concrete amount is up to 6.28 hundred million tons, due to the discarded coagulation of current China
Soil 97% is all direct landfill and outdoor accumulation, can thus waste substantial amounts of land resource, and pollute environment.Therefore
How to handle discarded concrete both will not land occupation resource, the problem of pollution that can also be reduced to environment is urgent need to resolve.
Other China is maximum in the world coal production and country of consumption.The coal mining of long-term extensive high intensity produces
Plurality of abandoned mine and area huge goaf, extraction coal bed gas can be carried out to goaf after mined out;For useless
Barrow well can be divided into new abandoned mine and old abandoned mine, and new abandoned mine refers to stop producing, but in mine
Transporting equipment is not removed also;And old abandoned mine refers to that the transporting equipment that mine has stopped production in certain time and mine is complete
Remove, and mine is blocked, but this closure is only closure extraction well head at present, the goaf of underground is still empty
Lack, so that the ground in goaf such as easily settles, collapsed at the disaster scenarios it, therefore how the goaf of old abandoned mine is entered
Reduced after row filling and the problem of disaster scenarios it is urgent need to resolve such as settle, collapse.
Because the mistake of global carbon converges, i.e., mankind's activity it is for example fossil-fuel-fired discharge into the atmosphere with deforestation etc. two
Carbonoxide exceedes the increment of carbon dioxide and the phenomenon of ocean uptake amount in same period earth atmosphere, so may result in air
Carbon dioxide is more and more, and so as to cause the aggravation of global greenhouse effect, it is big to ultimately result in the global situation for extreme weather occur
Big increase, although some in known material have absorption, such as concrete to carbon dioxide, due to concrete
The construction of building is contributed to, therefore does not also have and seals required confined space up for safekeeping so as to which the envelope of carbon dioxide can not be carried out
Deposit, therefore how caused carbon dioxide after mankind's activity seal up for safekeeping and it is not discharged into air and need solution badly
Certainly the problem of.
The content of the invention
In view of the above-mentioned problems of the prior art, the present invention, which provides a kind of old abandoned mine, places discarded concrete and envelope
The method for depositing carbon dioxide, discarded concrete is filled in abandoned mine goaf, while carbon dioxide is filled with ore deposit
In well goaf, so as to solve the problems, such as that discarded concrete is placed, abandoned mine is filled and carbon dioxide sequestration, it is dirty to reduce soil
Dye and atmospheric warming effect.
To achieve these goals, the technical solution adopted by the present invention is:A kind of old abandoned mine places discarded concrete
And the method for sequestration of carbon dioxide, concretely comprise the following steps:
A, saturated limewater is injected into storage tank, opens the first valve, the second valve and the 3rd valve, starts jerk pump
Conveying, saturated limewater enter coal bed gas through the first pipeline, the second pipeline, the 3rd pipeline, the 5th pipeline and the 6th pipeline successively
Drainage tube, coal bed gas drainage tube is cleaned, the pressure limit for controlling saturated limewater after pulsation is 5MPa~40MPa, arteries and veins
The change of dynamic frequency turns to 0.01Hz~0.1Hz, and pulsation injection length is 15min~25min;
B, using drilling well video-unit detection of coal seam gas drainage tube, it is ensured that after coal bed gas drainage tube is unobstructed, close the 3rd valve
Door, while the 4th valve is opened, now saturated limewater bores through the first pipeline, the second pipeline and the 4th pipeline into ground successively
In the mine goaf of downhole;
C, load discarded concrete into hopper, and record into discarded concrete volume in material bin, the discarded coagulation
0~10mm of particle size range of soil;
D, vibrator is controlled to start working by controller, now hopper is with vibrator sustained vibration;
E, discarded concrete is under vibrational state, and by the screening of large aperture sieve and small-bore sieve, 0~5mm particle diameters give up
Abandon concrete and enter mine goaf after the 5th pipeline, the 6th pipeline and coal bed gas drainage tube, while saturated limewater passes through
The pulsation of 4th pipeline sprays saturated limewater and breaks up the discarded concrete of accumulation, makes water of the discarded concrete with saturated limewater
The distribution area flowed in goaf is wider;
F, by observing in hopper large aperture sieve and when upper discarded concrete volume stability is sieved in small-bore, opening small-bore
Sieve, the discarded concrete for making particle diameter be 5mm~10mm enter mine goaf by coal bed gas drainage tube;
G, repeat step D~F, laser range finder it is per minute measurement ground in goaf discarded concrete away from
From, and controller is passed to, when the distance value of measurement is equal to coal bed gas extraction length of tube, signal is fed back to vibration by controller
Device and jerk pump, vibrator and jerk pump is set to be stopped;
H, the 4th valve and the 5th valve are closed, opens the 6th valve, the carbon dioxide in carbon dioxide storing apparatus leads to
Cross carbon dioxide transport pipeline and the 6th pipeline injection mine goaf, the injection pressure of the carbon dioxide for 1MPa~
1.5MPa, the injection rate of carbon dioxide are 100~120 times of discarded concrete volume;
I, to the end of carbon dioxide injection, all valves is closed and remove device, seal ground drilling.
Further, the controller is programmable logic controller (PLC).
Compared with prior art, the present invention is first injected saturated limewater in coal bed gas drainage tube by jerk pump, so as to
Coal bed gas drainage tube can preferably be cleared up, it is ensured that drainage tube it is unobstructed, be advantageous to the conveying unobstructed subsequently into goaf and discard
Concrete;When discarded concrete is transported in goaf, ground is measured in real time using laser range finder to mine goaf
The distance of interior discarded concrete, contribute to the accurate transport progress for grasping discarded concrete, prevent discarded concrete from blocking coal seam
The bottom nozzle of gas drainage tube, it is ensured that the patency of follow-up carbon dioxide injection;The joint sieved by large aperture sieve and small-bore
Effect, the discarded concrete that its large pore sieve is played in hopper are uniformly transported on the sieve of small-bore, are easy to what small-bore was sieved
Particle diameter sieving actoion, progressively transporting from small to large for discarded concrete particle diameter is realized, is favorably improved goaf discarded concrete
Amount of storage;The dynamic injection saturated limewater of process middle arteries is transported in discarded concrete in addition, will can be accumulated in time in goaf
Discarded concrete break up, make distribution area of the discarded concrete with the current of saturated limewater in goaf wider, favorably
In the more discarded concretes of storage, and the calcium hydroxide composition in limewash can further strengthen the absorption to carbon dioxide
With seal up for safekeeping, mitigate carbon dioxide caused by greenhouse effects;Because the density of carbon dioxide is heavier than air, the carbon dioxide being injected into
Under self gravitation effect, to discarded concrete accumulation bottom diffusion, and discarded concrete and the calcium hydroxide reaction of limewash,
Complete sealing up for safekeeping for carbon dioxide.In summary, discarded concrete is filled in abandoned mine goaf by the present invention, while by two
Carbon oxide gas are filled with mine goaf, are placed so as to solve discarded concrete, abandoned mine filling and carbon dioxide are sealed
The problem of depositing, and then realize the effect for reducing land pollution, preventing goaf sedimentation, collapsing and administer atmospheric warming effect.
Brief description of the drawings
Fig. 1 is the structural representation of induction system of the present invention.
In figure:1st, storage tank;2nd, the first valve;3rd, the first pipeline;4th, jerk pump;5th, controller;6th, hopper;7th, large aperture
Sieve;8th, small-bore is sieved;9th, transparent plastic cover;10th, vibrator;11st, the second pipeline;12nd, the second valve;13rd, the first triple valve;
14th, the 3rd pipeline;15th, the 3rd valve;16th, the 4th pipeline;17th, the 4th valve;18th, four the mouth of a river is separated;19th, the 5th pipeline;20、
5th valve;21st, the second triple valve;22nd, high pressure sealing lid;23rd, carbon dioxide storing apparatus;24th, carbon dioxide delivery pipe;
25th, the 6th valve;26th, the 3rd triple valve;27th, the 6th pipeline;28th, laser range finder;29th, ground drilling;30th, coal bed gas extraction
Pipe;31st, mine goaf;32nd, it is caving thing.
Embodiment
The invention will be further described below.
As shown in figure 1, the present invention includes storage tank 1, the first pipeline 3, jerk pump 4, controller 5, hopper 6, large aperture sieve
7th, small-bore sieve 8, vibrator 10, the second pipeline 11, the first triple valve 13, the 3rd pipeline 14, the 4th pipeline 16, the 5th pipeline
19th, the second triple valve 21, high pressure sealing lid 22, carbon dioxide storing apparatus 23, carbon dioxide delivery pipe 24, the 3rd triple valve
26th, the 6th pipeline 27 and laser range finder 28, storage tank 1 by the inlet communication of the first pipeline 3 and jerk pump 4, jerk pump 4
Outlet is connected by the second pipeline 11 with 13 one of port of the first triple valve, first two other port of triple valve 13 difference
Connected with one end of the 3rd pipeline 14 and one end of the 4th pipeline 16, the other end of the 3rd pipeline 14 and the second triple valve 21 are wherein
A port connects, and second two other port of triple valve 21 connects with the discharging opening of hopper 6 and one end of the 5th pipeline 19 respectively
Logical, hopper 6 is arranged on the top of the second triple valve 21, the large aperture sieve 7 and small-bore sieve 8 be horizontally set in hopper 6 and
Large aperture sieve 7 is fixed on the outer surface of hopper 6 in the top of small-bore sieve 8, vibrator 10;The other end and the 3rd of 5th pipeline 19
26 one of port of triple valve connects, the 3rd two other port of triple valve 26 one end with the 6th pipeline 27 and dioxy respectively
Change one end connection of carbon delivery pipe 24, the other end of carbon dioxide delivery pipe 24 connects with carbon dioxide storing apparatus 23;High pressure
Closure 22 seals the port for being fixed on coal bed gas drainage tube 30, and the other end of the 4th pipeline 16 stretches into through high pressure sealing lid 22
Into mine goaf 31, the other end of the 6th pipeline 27 is extend into coal bed gas drainage tube 30 through high pressure sealing lid 22, institute
Laser range finder 28 is stated to be fixedly connected with high pressure sealing lid 22;
First pipeline 3 is provided with the first valve 2, and the second pipeline 11 is provided with the second valve 12, the 3rd pipeline 14
The 4th valve 17 is provided with provided with the 3rd valve 15, the 4th pipeline 16, the 5th valve is provided between the triple valve 21 of hopper 6 and second
20, carbon dioxide delivery pipe 24 is provided with the 6th valve 25;
The controller 5 is connected with jerk pump 4, vibrator 10 and laser range finder 28.
Further, the other end of the 4th pipeline 16 is in and is caving the top 0.1m~0.2m of thing 32.In this distance
The ejection of saturated limewater can be easy to.
Further, the other end of the 4th pipeline 16 separates the mouth of a river 18 provided with four.4th pipe can be made using this structure
The saturated limewater that road 16 exports uniformly sprays to surrounding, bigger so as to increase distribution of the saturated limewater in goaf
And evenly.
Further, the charging aperture of the hopper 6 is provided with transparent plastic cover 9.Transparent plastic cover 9 is set to prevent hopper 6 from existing
Discarded concrete particle can splash away from the charging aperture of hopper 6 during motion, can be easy to staff using transparent setting in addition
The delivery situation of discarded concrete in Real Time Observation hopper 6.
Further, the controller 5 is programmable logic controller (PLC).This not only Stability Analysis of Structures, and being easy to of controller 5
The control program performed needed for setting.
Further, the sieve diameter of the large aperture sieve 7 is 10mm, and the sieve diameter of small-bore sieve 8 is 5mm.Using this
Kind sieve diameter, can make discarded concrete reduce mutual gap, be stored in so as to as much as possible in goaf.
The present invention's concretely comprises the following steps:
A, saturated limewater is injected into storage tank 1, opens the first valve 2, the second valve 12 and the 3rd valve 15, is started
Jerk pump 4 conveys, and saturated limewater is successively through the first pipeline 3, the second pipeline 11, the 3rd pipeline 14, the 5th pipeline 19 and the 6th
Pipeline 27 enters coal bed gas drainage tube 30, and coal bed gas drainage tube 30 is cleaned, the pressure of saturated limewater after control pulsation
Scope is 5MPa~40MPa, and the change of ripple frequency turns to 0.01Hz~0.1Hz, and pulsation injection length is 15min~25min;
B, using drilling well video-unit detection of coal seam gas drainage tube 30, it is ensured that after coal bed gas drainage tube 30 is unobstructed, close the
Three valves 15, while the 4th valve 17 is opened, now saturated limewater is successively through the first pipeline 3, the second pipeline 11 and the 4th pipe
Road 16 enters in the mine goaf 31 of the lower section of ground drilling 29;
C, load discarded concrete into hopper 6, and record into discarded concrete volume in material bin 6, it is described discarded mixed
Coagulate 0~10mm of particle size range of soil;
D, vibrator 10 is controlled to start working by controller 5, now hopper 6 is with the sustained vibration of vibrator 10;It is so that useless
Abandoning concrete motion in hopper 6 is easy to the discarded concrete of different-grain diameter to pass through large aperture sieve 7 and small-bore sieve 8;
E, discarded concrete sieves 8 screening by large aperture sieve 7 and small-bore under vibrational state, 0~5mm particle diameters
Discarded concrete enters mine goaf 31 after the 5th pipeline 19, the 6th pipeline 27 and coal bed gas drainage tube 30, in jerk pump 4
Under effect, saturated limewater is pulsed by the 4th pipeline 16 and sprays saturated limewater, in time can be rushed the discarded concrete of accumulation
Dissipate, make distribution area of the discarded concrete with the current of saturated limewater in goaf wider;
When F, sieving discarded concrete volume stability on 7 and small-bore sieve 8 by observing large aperture in hopper 6, aperture is opened
Footpath sieve 8, the discarded concrete that particle diameter is 5mm~10mm is set to enter mine goaf 31 by coal bed gas drainage tube 30;
G, repeat step D~F, laser range finder 28 it is per minute measurement ground in goaf discarded concrete away from
From, and controller 5 is passed to, when the distance value of measurement is equal to coal bed gas 30 length of drainage tube, controller 5 feeds back to signal
Vibrator 10 and jerk pump 4, vibrator 10 and jerk pump 4 is set to be stopped;
H, the 4th valve 17 and the 5th valve 20 are closed, opens the 6th valve 25, two in carbon dioxide storing apparatus 23
Carbonoxide injects mine goaf 31, the injection pressure of the carbon dioxide by the pipeline 27 of carbon dioxide delivery tube 24 and the 6th
For 1MPa~1.5MPa, the injection rate of carbon dioxide is 100~120 times of discarded concrete volume;
I, to the end of carbon dioxide injection, all valves is closed and remove device, seal ground drilling.
Further, the controller 5 is programmable logic controller (PLC).This not only Stability Analysis of Structures, and being easy to of controller 5
The control program performed needed for setting.