CN107674481A - The heat-insulated sterilization paint of compound ion bactericide, graphene and the composition for emulsion paint - Google Patents
The heat-insulated sterilization paint of compound ion bactericide, graphene and the composition for emulsion paint Download PDFInfo
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- CN107674481A CN107674481A CN201710845565.3A CN201710845565A CN107674481A CN 107674481 A CN107674481 A CN 107674481A CN 201710845565 A CN201710845565 A CN 201710845565A CN 107674481 A CN107674481 A CN 107674481A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
Painted the invention discloses a kind of compound ion bactericide, the heat-insulated sterilization of graphene and the composition for emulsion paint, the compound ion bactericide include the raw material of following percentage by weight：Acrylic resin 30~80%, nano-silver powder 0.1~0.3%, dispersant 0.2~2%, bactericide Vink KTL 0.2~0.5%, bactericide Vink CDO 0.3~0.7%, photocatalyst 1~3% and water 10~60%.The heat-insulated sterilization paint of bactericide and graphene of the present invention has stronger cohesive force, can kill germ, fungi and algal control longer, can effectively subtract haze, reduce PM2.5, and then reduce atmosphere pollution.
Description
Technical field
The present invention relates to emulsion paint production technical field, in particular to a kind of compound ion bactericide, graphene every
Thermal sterilization paint and the composition for emulsion paint.
Background technology
Emulsion paint is using synthetic resin emulsion as film forming matter, using water as solvent, pigment and auxiliary agent is added, by certain work
Coating made of skill process.Emulsion paint is dispersion of synthetic resin (latex) solia particle in water and color stuffing particle in water
In dispersion formed mixture.
But existing emulsion paint is very different, because technological means is not high, formula is simple, and easily production, causes market
It is chaotic.Emulsion paint on the market has the following disadvantages when being applied on building wall at present：
1st, most emulsion paint cohesive force is poor, easily comes off；
2nd, it is easily mouldy in a humidity environment；
3rd, function is single；
4th, it is most of to need to use priming paint, and most of priming paint contains the higher toxic solvent of volatility.
The content of the invention
In view of this, the heat-insulated sterilization of a kind of compound ion bactericide provided by the invention, graphene is painted and for emulsion paint
Composition, preferably overcome the above-mentioned problems of the prior art and defect, the bactericide and graphene it is heat-insulated sterilization paint
With stronger cohesive force, germ, fungi and algal control can be killed longer, can effectively subtract haze, reduce PM2.5, and then drop
Low atmosphere pollution；And during applied to building wall decoration and the emulsion paint protected, there is good sterilization to subtract haze and insulation
Performance, and effectively increase the wash-resistant property of emulsion paint.
A kind of compound ion bactericide, include the raw material of following percentage by weight：Acrylic resin 30~80%, Nano Silver
Powder 0.1~0.3%, dispersant 0.2~2%, bactericide Vink KTL 0.2~0.5%, bactericide Vink CDO 0.3~
0.7%th, photocatalyst 1~3% and water 10~60%.
In some embodiments, the compound ion bactericide also includes the raw material of following percentage by weight：Nano oxygen
Change zinc powder 0.2~1%.
In some embodiments, the compound ion bactericide also includes the raw material of following percentage by weight：Defoamer
0.1~0.3%.
Present invention also offers a kind of heat-insulated sterilization paint of graphene, comprising above-mentioned compound ion bactericide, with described multiple
The weight for closing ion sterilizing agent is 100 parts of meters, also includes the raw material of following parts by weight：0.1~0.5 part of graphene.
Present invention also offers a kind of composition for emulsion paint, comprising the above-mentioned heat-insulated sterilization paint of graphene, with institute
The weight for stating the heat-insulated sterilization paint of graphene is 100 parts of meters, also includes the raw material of following parts by weight：5~15 parts of insulation agent, plant
20~60 parts of 3~8 parts of fiber, 0.1~3 part of nanometer titanium dioxide titanium valve, 0.2~1 part of levelling agent and filler.
In some embodiments, the composition also includes the raw material of following parts by weight：Infrared reflection pigment 2~
10 parts.
In some embodiments, the composition also includes the raw material of following parts by weight：10~15 parts of fire retardant.
In some embodiments, the filler is one or both of barium sulfate, silica flour and talcum powder.
In some embodiments, the insulation agent is perlite or perlite ceramic microballoon.
In some embodiments, the perlite ceramic microballoon reburns after putting pottery slurry stirring into using perlite raw material
Knot obtains；The particle diameter of the perlite raw material is 80~120 mesh, and the sintering temperature is 1000~1500 DEG C.
Compared with prior art, the heat-insulated sterilization of a kind of compound ion bactericide of the invention, graphene is painted and for latex
The beneficial effect of the composition of paint is：
The bactericide of the present invention is by the way that metal, mineral and chemical sterilization material are fixed on medium acrylic resin, both
It can mutually play a role, metal and chemical sterilization material etc. will not again be lost in, the effect of so as to reach lasting sterilization, and bond
Power is strong；The heat-insulated sterilization paint of graphene that graphene can just obtain having heat insulation and preservation effect is added on the basis of the bactericide,
And during applied to building wall decoration and the emulsion paint protected, make emulsion paint that there is good insulation, antifouling mould proof, waterproof
Fire prevention, sterilization algal control performance, and effectively increase the wash-resistant property of emulsion paint；Further, since it is added with photocatalyst and nanometer
It titanium dioxide powder, can effectively subtract haze, reduce PM2.5, and then reduce atmosphere pollution.
To enable the above objects, features and advantages of the present invention to become apparent, preferred embodiment cited below particularly, make detailed
It is described as follows.
Embodiment
For the ease of understanding the present invention, technical scheme is elaborated with reference to the mode of embodiment,
Many details are elaborated in the following description in order to fully understand the present invention.
But the invention can be embodied in many other ways as described herein, those skilled in the art can be with
Similar improvement is done in the case of without prejudice to intension of the present invention, therefore the present invention is not limited to the specific embodiments disclosed below.
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention
The identical implication that art personnel are generally understood that.When contradiction be present, the definition in this specification is defined.
Term as used herein：
Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that covering
Non-exclusionism includes.Wanted for example, composition, step, method, product or device comprising listed elements are not necessarily limited to those
Element, but can include not expressly listed other key elements or such a composition, step, method, product or device it is intrinsic
Key element.
Conjunction " by ... form " exclude any key element do not pointed out, step or component.If be used in claim,
This phrase will make claim be closed, it is not included the material in addition to the material of those descriptions, but relative
Except customary impurities.When phrase " by ... form " be rather than immediately following theme in the clause that appears in claim main body after
When, it is only limited to the key element described in the clause；Other key elements be not excluded as entirety the claim it
Outside.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit
During the Range Representation that choosing value limits, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope
All scopes that any pairing of lower limit or preferred value is formed, regardless of whether the scope separately discloses.For example, when open
Scope " when 1~5 ", described scope should be interpreted as including scope " 1~4 ", " 1~3 ", " 1~2 ", " 1~2 and 4~
5 ", " 1~3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end
Value and all integers and fraction within the range.
"and/or" is used to represent that one of illustrated situation or both may to occur, for example, A and/or B includes (A
And B) and (A or B).
A kind of compound ion bactericide, include the raw material of following percentage by weight：
Acrylic resin 30~80% such as 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%
Or 80% etc.；
Nano-silver powder 0.1~0.3% such as 0.1%, 0.15%, 0.2%, 0.25% or 0.3%；
Dispersant 0.2~2% such as 0.2%, 0.5%, 0.8%, 1%, 1.2%, 1.5%, 1.8% or 2%；
Bactericide Vink KTL 0.2~0.5% such as 0.2%, 0.25%, 0.3%, 0.35%, 0.4%, 0.45% or
0.5% etc.；
Bactericide Vink CDO 0.3~0.7% such as 0.3%, 0.4%, 0.5%, 0.6% or 0.7%；
Photocatalyst 1~3% such as 1%, 1.2%, 1.5%, 1.8%, 2.0%, 2.5%, 2.8% or 3%；
Water 10~60% such as 10%, 20%, 30%, 40%, 50% or 60%.
It should be noted that Nano Silver has, antibacterial, strong bactericidal, permeability are strong, reparative regeneration, antibacterial are lasting, safety
Characteristic and effect nontoxic, have no drug resistance.It is that the best one kind of antibacterial is generally acknowledged in natural material that silver, which can be said, can kill 650 kinds
Bacterium above, and silver material is not toxic.Nano Silver can attract the sulfydryl (- SH) on zymoprotein in bacterial body, fast
Speed is combined together, and the ferment containing sulfydryl is lost activity, and so as to destroy the normal ingestion of bacterium nutrient, and then is made
Bacterial death.In addition, the effect of Nano Silver is to belong to long-acting type bactericide, it is however generally that, its effectiveness can at least be kept 5 years.
Photocatalyst is a kind of semipermanent scavenging material, toxic and harmful gas in the air that can effectively degrade, reaches and subtracts haze
Effect；It can also effectively kill various bacteria, and antibiotic rate is up to 99.99%, and the toxin that can discharge bacterium or fungi point
Solution and harmless treatment；It is also equipped with the functions such as deodorization, anti-soil simultaneously.Affiliated photocatalyst is preferably photocatalyst of titanium dioxide.
In some embodiments, the compound ion bactericide also includes the raw material of following percentage by weight：Nano oxygen
Change zinc powder 0.2~1% such as 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9% or 1%, by
Zinc oxide is added in bactericide of the present invention and on the one hand further strengthens bactericidal property, on the other hand can effective shielding ultraviolet rays.
In some embodiments, the compound ion bactericide also includes the raw material of following percentage by weight：Defoamer
0.1~0.3% such as 0.1%, 0.15%, 0.2%, 0.25% or 0.3%.It is understood that the defoamer is used to disappear
Except caused foam in bactericide preparation process, the defoamer can be that silicone emulsion, the higher alcohols commonly used are fatty acid ester compounded
Thing, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxypropylene gather
One or more in oxygen Ethylene Glycol ether and dimethyl silicone polymer.
It is to be appreciated that the compound ion bactericide of the present invention by by metal and chemical sterilization material (nano-silver powder,
Bactericide Vink KTL and bactericide Vink CDO) it is fixed on medium acrylic resin, it both can mutually play a role, again will not
Be lost in metal and chemical sterilization material, the effect of so as to reach persistently sterilization algal control, and cohesive force is strong, additionally, due to added with
It photocatalyst, can effectively subtract haze, reduce PM2.5, and then reduce atmosphere pollution.
It should be noted that silver nanoparticle silver and nano zine oxide have potent antibacterial under conditions of no light source, killed
The ability for virus of going out；Photocatalyst can sterilize under visible ray and ultraviolet light conditions, antiviral, bacterium for degrading and purification of air, rise
To the effect for subtracting haze；Bactericide Vink KTL's and bactericide Vink CDO is compound, to hepatitis B, Staphylococcus aureus, big
The suppression of the bacterial viruses such as enterobacteria, fungi, aftosa, anthrax kills rate up to 99.9%, and without any toxicity, has no side effect.
The compound ion bactericide of the present invention has effectively bactericidal action to following microorganism, as shown in table 1 below：
Table 1
Present invention also offers a kind of heat-insulated sterilization paint of graphene, comprising above-mentioned compound ion bactericide, with described multiple
The weight for closing ion sterilizing agent is 100 parts of meters, also includes the raw material of following parts by weight：Such as 0.1 part of 0.1~0.5 part of graphene,
0.15 part, 0.2 part, 0.25 part, 0.3 part, 0.35 part, 0.4 part, 0.45 part or 0.5 part etc..
Bidimensional (2D) cycle honeycomb lattice structure that graphene (Graphene) is made up of carbon hexatomic ring.Graphene was both
It is most thin material, and most tough material, 200 times more taller than best steel of fracture strength；It has very well again simultaneously
Elasticity, high temperature resistant, stretch range can reach 20 parts of own dimensions, and it is that current nature is most thin, intensity highest material.
The heat-insulated sterilization paint of graphene of the present invention, fills the performance that part make use of graphene, improvement and enhancing acrylic resin
Self-crosslinking and the effect emulsified by force, it will not polymerize in compatible other materials after making graphene dispersion, energy rapid curing after use,
Avoid dissociating.It is above-mentioned added on the basis of compound ion bactericide the heat-insulated sterilization paint of the obtained graphene of graphene remove have compared with
Outside strong cohesive property and the effect for subtracting haze, also with excellent heat insulation and preservation effect, and bactericidal effect is more preferable.
The above-mentioned heat-insulated sterilization paint of compound ion bactericide and graphene can be used in any place, such as hospital, school, old man
Institute, market, subway, compartment, cabin etc., it is significant in terms of public health.
Present invention also offers a kind of composition for emulsion paint, comprising the above-mentioned heat-insulated sterilization paint of graphene, with institute
The weight for stating the heat-insulated sterilization paint of graphene is 100 parts of meters, also includes the raw material of following parts by weight：
Such as 5 parts, 8 parts, 10 parts, 12 parts or 15 parts of 5~15 parts of insulation agent；
Such as 3 parts, 4 parts, 5 parts, 6 parts, 7 parts or 8 parts of 3~8 parts of string；
0.1~3 part of nanometer titanium dioxide titanium valve as 0.1 part, 0.5 part, 0.8 part, 1 part, 1.2 parts, 1.5 parts, 1.8 parts, 2 parts,
2.5 parts, 2.8 parts or 3 parts etc.；
0.2~1 part of levelling agent is such as 0.2 part, 0.3 part, 0.4 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part or 1 part
Deng
With 20~60 parts such as 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts or 60 parts of filler.
It it should be noted that above-mentioned string can play good insulation effect, while can turn waste into wealth, avoid burning
Burn pollution environment.Preferably, the string is nanometer rice straw fiber, and it is by the way that the rice straw dried fiber is blended, then
By nanometer, children grinding machine children wears into nm regime.Certainly, the string can also use the strings such as cornstalk or bamboo.
Above-mentioned Nano titanium dioxide, also known as titanium dioxide, product appearance are fluffy white powder；It has uvioresistant,
Antibacterial, self-cleaning, ageing resistace, it can play a part of antibacterial algal control in the emulsion paint of the present invention and subtract haze.
When emulsion paint is applied to building exterior wall face, the composition also includes the raw material of following percentage by weight：
Such as 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts of 2~10 parts of infrared reflection pigment.
It should be noted that the infrared reflection pigment effectively increases the infrared reflection performance of emulsion paint, Neng Gouyou
Effect reflects at least 20 parts of illumination.The infrared reflection pigment can be enumerated as：The cruel cold systems of the ARCTIC of Xue Te pigment company of the U.S.
It is row infrared reflection inorganic pigment, such as yellow Yellow10C112 pigment, brown Brown157, blue Blue424, green Green187B, black
Black411A etc., the infrared reflection pigment of other companies also can be selected certainly, such as titanium nickel merimee's yellow, titanium yellow or green glow titan yellow
Deng.
In some embodiments, the composition also includes the raw material of following parts by weight：10~15 parts of fire retardant is such as
10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts etc..The fire retardant of the present invention is preferably fire retardant AP422, certainly described fire-retardant
Agent can also be enumerated as other flame retardant materials.
Preferably, the filler is one or both of barium sulfate, silica flour and talcum powder.
Preferably, the insulation agent is perlite or perlite ceramic microballoon, and it can completely cut off at least 20% heat leak.
Preferably, the perlite ceramic microballoon re-sinters to obtain after putting pottery slurry stirring into using perlite；The treasure
Zhu Yan particle diameter is 80~120 mesh such as 80 mesh, 90 mesh, 100 mesh, 110 mesh or 120 mesh etc., the sintering temperature for 1000~
1500 DEG C such as 1000 DEG C, 1200 DEG C, 1300 DEG C, 1400 DEG C or 1500 DEG C.
It should be noted that levelling agent is a kind of conventional coating additive, it can promote coating during drying and forming-film
A smooth, smooth, uniform film is formed, can effectively reduce and cover with paint, lacquer, colour wash, etc. liquid surface tension, improves its levelability and uniformity
A kind of material.The permeability for covering with paint, lacquer, colour wash, etc. liquid can be improved, the possibility that spot and spot are produced when brushing can be reduced, increase spreadability,
Make film forming uniformly, naturally, levelling agent is mainly the surfactant or other organic solvents etc. commonly used in coating.
It is that can obtain the emulsion paint of graphene-containing by above-mentioned composition hybrid reaction.
Present invention also offers application of the above-mentioned composition for emulsion paint in building wall is decorated and is protected.
Specially：By the emulsion paint being mixed with by above-mentioned composition directly spray, brush or roller coating by way of coated in building
On metope, then solidification obtains emulsioni paint layer, without using priming paint.
For the ease of understanding the present invention, technical scheme is further illustrated with reference to embodiment.Applicant
Statement, the present invention are illustrated by the following examples detailed process equipment and the technological process of the present invention, but not office of the invention
It is limited to following detailed process equipments and technological process, that is, does not mean that the present invention should rely on above-mentioned detailed process equipment and technique stream
Cheng Caineng is implemented.Person of ordinary skill in the field is it will be clearly understood that any improvement in the present invention, to each original of product of the present invention
The equivalence replacement of material and the addition of auxiliary element, the selection of concrete mode etc., all fall within protection scope of the present invention and open model
Within enclosing.
Embodiment 1
(1) by 0.1 part of nano-silver powder, 0.2 part of bactericide Vink KTL, 0.3 part of bactericide Vink CDO and 1 part of photocatalyst
It is added sequentially in 10 parts of water, and is uniformly mixing to obtain Nano Silver mixed liquor；Then side is stirred successively in 30 parts of acrylic resins
Mix side and add 0.2 part of dispersant, Nano Silver mixed liquor, 0.1 part of defoamer, to being well mixed, obtain compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.01 part of graphene and be stirred
It is even, obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 0.5 part of pearl while stirring
Rock ceramic microballoon, 0.3 part of nanometer rice straw fiber, 0.01 part of nanometer titanium dioxide titanium valve, 0.02 part of levelling agent, 2 parts of barium sulfate, are obtained
Emulsion paint.
Embodiment 2
(1) by 0.2 part of nano-silver powder, 1 part of bactericide Vink KTL, 0.5 part of bactericide Vink CDO and 2 parts of photocatalysts according to
It is secondary to be added in 40 parts of water, and it is uniformly mixing to obtain Nano Silver mixed liquor；Then side is stirred successively in 50 parts of acrylic resins
Side adds 1 part of dispersant, Nano Silver mixed liquor, 0.2 part of defoamer, to being well mixed, obtains compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.03 part of graphene and be stirred
It is even, obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 1 part of perlite while stirring
Ceramic microballoon, 0.5 part of nanometer rice straw fiber, 0.15 part of nanometer titanium dioxide titanium valve, 0.05 part of levelling agent, 4 parts of barium sulfate, obtain breast
Shellac varnish.
Embodiment 3
(1) by 0.3 part of nano-silver powder, 0.5 part of bactericide Vink KTL, 0.7 part of bactericide Vink CDO and 3 parts of photocatalysts
It is added sequentially in 60 parts of water, and is uniformly mixing to obtain Nano Silver mixed liquor；Then side is stirred successively in 80 parts of acrylic resins
Mix side and add 2 parts of dispersants, Nano Silver mixed liquor, 0.3 part of defoamer, to being well mixed, obtain compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.05 part of graphene and be stirred
It is even, obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 1.5 parts of pearls while stirring
Rock ceramic microballoon, 0.8 part of nanometer rice straw fiber, 0.3 part of nanometer titanium dioxide titanium valve, 0.1 part of levelling agent, 6 parts of barium sulfate, obtain breast
Shellac varnish.
Embodiment 4
(1) 0.15 part of nano-silver powder, 0.3 part of bactericide Vink KTL, 0.4 part of bactericide VinkCDO and 1.5 parts of light are touched
Matchmaker is added sequentially in 20 parts of water, and is uniformly mixing to obtain Nano Silver mixed liquor；Then the side successively in 40 parts of acrylic resins
Stir side and add 0.2 dispersant, Nano Silver mixed liquor, 0.2 part of nano zinc oxide powder, 0.15 part of defoamer, to being well mixed, obtain
To compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.15 part of graphene and be stirred
It is even, obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 0.8 part of pearl while stirring
Rock ceramic microballoon, 0.4 part of nanometer rice straw fiber, 0.05 part of nanometer titanium dioxide titanium valve, 0.05 part of levelling agent, 3 parts of barium sulfate and 1 part
Fire retardant, obtain emulsion paint.
Embodiment 5
(1) by 0.25 part of nano-silver powder, 0.35 part of bactericide Vink KTL, 0.5 part of bactericide VinkCDO and 1.8 parts of light
Catalyst is added sequentially in 30 parts of water, and is uniformly mixing to obtain Nano Silver mixed liquor；Then in 45 parts of acrylic resins successively
1.2 dispersants, Nano Silver mixed liquor, 0.4 part of nano zinc oxide powder, 0.2 part of defoamer are added while stirring, it is extremely well mixed,
Obtain compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.2 part of graphene and be uniformly mixed,
Obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 1 part of perlite while stirring
Ceramic microballoon, 0.5 part of nanometer rice straw fiber, 0.12 part of nanometer titanium dioxide titanium valve, 0.06 part of levelling agent, 4 parts of barium sulfate and 1.2 parts
Fire retardant, obtain emulsion paint.
Embodiment 6
(1) 0.2 part of nano-silver powder, 0.4 part of bactericide Vink KTL, 0.5 part of bactericide Vink CDO and 2.5 parts of light are touched
Matchmaker is added sequentially in 50 parts of water, and is uniformly mixing to obtain Nano Silver mixed liquor；Then the side successively in 55 parts of acrylic resins
Stir side and add 1.5 parts of dispersants, Nano Silver mixed liquor, 0.6 part of nano zinc oxide powder, 0.2 part of defoamer, it is extremely well mixed,
Obtain compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.35 part of graphene and be stirred
It is even, obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 1.2 parts of pearls while stirring
Rock ceramic microballoon, 0.2 part of infrared reflection pigment, 0.6 part of nanometer rice straw fiber, 0.18 part of nanometer titanium dioxide titanium valve, 0.07 part
Levelling agent, 4.5 parts of barium sulfate and 1.3 parts of fire retardants, obtain emulsion paint.
Embodiment 7
(1) by 0.25 part of nano-silver powder, 0.45 part of bactericide Vink KTL, 0.6 part of bactericide VinkCDO and 2.8 parts of light
Catalyst is added sequentially in 60 parts of water, and is uniformly mixing to obtain Nano Silver mixed liquor；Then in 65 parts of acrylic resins successively
1.8 parts of dispersants, Nano Silver mixed liquor, 0.6 part of nano zinc oxide powder, 0.25 part of defoamer are added while stirring, it is equal to mixing
It is even, obtain compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.45 part of graphene and be stirred
It is even, obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 1.5 parts of pearls while stirring
Rock ceramic microballoon, 0.5 part of infrared reflection pigment, 0.7 part of nanometer rice straw fiber, 0.25 part of nanometer titanium dioxide titanium valve, 0.08 part
Levelling agent, 5.5 parts of barium sulfate and 1.4 parts of fire retardants, obtain emulsion paint.
Embodiment 8
(1) by 0.3 part of nano-silver powder, 0.5 part of bactericide Vink KTL, 0.7 part of bactericide Vink CDO and 3 parts of photocatalysts
It is added sequentially in 60 parts of water, and is uniformly mixing to obtain Nano Silver mixed liquor；Then side is stirred successively in 75 parts of acrylic resins
Mix side and add 1.8 parts of dispersants, Nano Silver mixed liquor, 1 part of nano zinc oxide powder, 0.3 part of defoamer, to being well mixed, obtain
Compound ion bactericide.
(2) the compound ion bactericide for taking 10 parts of steps (1) to be prepared, add 0.5 part of graphene and be uniformly mixed,
Obtain the heat-insulated sterilization paint of graphene.
(3) the heat-insulated sterilization paint of graphene for taking 10 parts of steps (2) to be prepared, sequentially adds 1.5 parts of pearls while stirring
Rock ceramic microballoon, 1 part of infrared reflection pigment, 0.8 part of nanometer rice straw fiber, 0.3 part of nanometer titanium dioxide titanium valve, 0.1 part of levelling
Agent, 6 parts of barium sulfate and 1.5 parts of fire retardants, obtain emulsion paint.
The preferred embodiments of the present invention are above are only, are not intended to limit the invention, for those skilled in the art
For member, inventive formulation and preparation technology can have various modifications and variations.Within the spirit and principles of the invention, institute
Any modification, equivalent substitution and improvements of work etc., should be included in the scope of the protection.
Claims (10)
- A kind of 1. compound ion bactericide, it is characterised in that：Include the raw material of following percentage by weight：Acrylic resin 30~ 80%th, nano-silver powder 0.1~0.3%, dispersant 0.2~2%, bactericide Vink KTL 0.2~0.5%, bactericide Vink CDO 0.3~0.7%, photocatalyst 1~3% and water 10~60%.
- 2. compound ion bactericide according to claim 1, it is characterised in that：Also include the original of following percentage by weight Material：Nano zinc oxide powder 0.2~1%.
- 3. compound ion bactericide according to claim 1, it is characterised in that：Also include the original of following percentage by weight Material：Defoamer 0.1~0.3%.
- A kind of 4. heat-insulated sterilization paint of graphene, it is characterised in that：Include the compound ion as described in any one of claims 1 to 3 Bactericide, counted using the weight of the compound ion bactericide as 100 parts, also include the raw material of following parts by weight：Graphene 0.1 ~0.5 part.
- A kind of 5. composition for emulsion paint, it is characterised in that：Include the heat-insulated sterilization of graphene as claimed in claim 4 Paint, counted using the weight of the heat-insulated sterilization paint of the graphene as 100 parts, also include the raw material of following parts by weight：Insulation agent 5~15 Part, 3~8 parts of string, 0.1~3 part of nanometer titanium dioxide titanium valve, 0.2~1 part of levelling agent and 20~60 parts of filler.
- 6. the composition according to claim 5 for emulsion paint, it is characterised in that：Also include the original of following parts by weight Material：2~10 parts of infrared reflection pigment.
- 7. the composition according to claim 5 for emulsion paint, it is characterised in that：Also include the original of following parts by weight Material：10~15 parts of fire retardant.
- 8. the composition according to claim 5 for emulsion paint, it is characterised in that：The filler is barium sulfate and talcum One or both of powder.
- 9. the composition according to claim 5 for emulsion paint, it is characterised in that：The insulation agent is perlite or treasure Pearl rock ceramic microballoon.
- 10. the composition according to claim 9 for emulsion paint, it is characterised in that：The perlite ceramic microballoon is adopted Re-sinter to obtain after putting pottery slurry stirring into perlite raw material；The particle diameter of the perlite raw material is 80~120 mesh, the burning Junction temperature is 1000~1500 DEG C.
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| CN201710845565.3A CN107674481A (en) | 2017-09-19 | 2017-09-19 | The heat-insulated sterilization paint of compound ion bactericide, graphene and the composition for emulsion paint |
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| CN201710845565.3A CN107674481A (en) | 2017-09-19 | 2017-09-19 | The heat-insulated sterilization paint of compound ion bactericide, graphene and the composition for emulsion paint |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109762434A (en) * | 2019-02-19 | 2019-05-17 | 安徽企服工程技术有限公司 | A kind of environmental protection photocatalytic degradation type coating for wall surface and its application |
| CN113512328A (en) * | 2020-04-10 | 2021-10-19 | 北京石墨烯研究院有限公司 | Exterior wall coating composition, exterior wall coating and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101698769A (en) * | 2009-10-19 | 2010-04-28 | 佛山夫田涂料化工有限公司 | Paint for preventing influenza viruses and preparation method thereof |
-
2017
- 2017-09-19 CN CN201710845565.3A patent/CN107674481A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101698769A (en) * | 2009-10-19 | 2010-04-28 | 佛山夫田涂料化工有限公司 | Paint for preventing influenza viruses and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109762434A (en) * | 2019-02-19 | 2019-05-17 | 安徽企服工程技术有限公司 | A kind of environmental protection photocatalytic degradation type coating for wall surface and its application |
| CN113512328A (en) * | 2020-04-10 | 2021-10-19 | 北京石墨烯研究院有限公司 | Exterior wall coating composition, exterior wall coating and preparation method thereof |
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