CN104046156B - Nano colorful green inner wall paint - Google Patents
Nano colorful green inner wall paint Download PDFInfo
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- CN104046156B CN104046156B CN201410320326.2A CN201410320326A CN104046156B CN 104046156 B CN104046156 B CN 104046156B CN 201410320326 A CN201410320326 A CN 201410320326A CN 104046156 B CN104046156 B CN 104046156B
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- nano
- wall paint
- green inner
- wall
- colorful green
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- 239000003973 paint Substances 0.000 title claims abstract description 91
- 238000000576 coating method Methods 0.000 claims abstract description 61
- 239000011248 coating agent Substances 0.000 claims abstract description 59
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 15
- 239000010445 mica Substances 0.000 claims abstract description 13
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000011521 glass Substances 0.000 claims abstract description 12
- 230000001699 photocatalysis Effects 0.000 claims abstract description 12
- 238000007146 photocatalysis Methods 0.000 claims abstract description 12
- 230000001954 sterilising effect Effects 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 11
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 11
- 239000000440 bentonite Substances 0.000 claims abstract description 11
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000001913 cellulose Substances 0.000 claims abstract description 11
- 229920002678 cellulose Polymers 0.000 claims abstract description 11
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 11
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 11
- 239000003205 fragrance Substances 0.000 claims abstract description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000000361 pesticidal effect Effects 0.000 claims abstract description 11
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 11
- 238000005496 tempering Methods 0.000 claims abstract description 11
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 11
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 10
- 229920002101 Chitin Polymers 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 abstract description 26
- 230000007613 environmental effect Effects 0.000 abstract description 16
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 12
- 238000005516 engineering process Methods 0.000 abstract description 8
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 239000007789 gas Substances 0.000 abstract description 6
- 230000006870 function Effects 0.000 abstract description 5
- 239000002114 nanocomposite Substances 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000000505 pernicious effect Effects 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- 229910001868 water Inorganic materials 0.000 description 26
- 238000003756 stirring Methods 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 16
- 239000000047 product Substances 0.000 description 16
- 239000007788 liquid Substances 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000009931 harmful effect Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 239000013530 defoamer Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002086 nanomaterial Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- -1 hydroxyl group anion Chemical class 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 230000007096 poisonous effect Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 125000005626 carbonium group Chemical group 0.000 description 1
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 1
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- 229910021641 deionized water Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
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- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
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- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
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- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 description 1
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Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of nano colorful green inner wall paint, be bentonite colorful luminous, chitin glass porcelain glaze fragrance multi-color decorative pattern, oyster shell whiting SiO2, environmental protection multi-color decorative pattern, Pesticidal and sterilizing multi-color decorative pattern tempering environmental protection, mica powder environment-friendly type stereo multi-colour look glisten, cellulose light is colorful, kaolin photocatalysis TiO2Golden silk coloured silk nano inner wall coating forms.Present invention application nano composite material technology and paint field.Give coating specific function, antibacterial, antibacterial, desinsection, sterilizing, elimination peculiar smell, particularly to formaldehyde produced after room finish, Benzene Chloride and containing heavy metal pernicious gas, there is good effect of dispelling, launch the hydrogen-oxygen anion far infrared rays being of value to human body.Color light enriches, and chromatogram is wide, wide in variety, nontoxic, harmless, pollution-free, without the three wastes, a kind of nano colorful green inner wall paint safe to the human body.
Description
Technical field:
The invention discloses a kind of nano colorful green inner wall paint, be belonging to high-tech coating material production preparation technique neck
Territory.
Background technology:
Nano composite material technology is applied to paint field can improve many performances of coating, as physical and mechanical properties,
Antiseptic property, electric property, optical property, anti-flammability, mildewproof sterilized property, anti-wear performance, weather resistance etc..As far back as 20th century eight
The nineties, the state such as the U.S., Japan, West Europe just actively develops nano material in building coating, industrial coating, special functional painting
The research of the field application such as material, has the product of many nanocomposite coatings to achieve industrialization, commercialization the most successively.
Nano material or nanostructured component are introduced in organic coating, it is achieved compound (hydridization) of organic/inorganic phase, combine
The advantage closing both organic polymer and inorganic structure component, makes coating property be significantly improved, nano-TiO2Compound ferrotianium
Powder replaces that rustless property is excellent but red lead (Pb that toxicity is the biggest3O4) pigment, widely apply in anticorrosive paint, meet environmental protection and want
Ask, and cost performance is better than red lead, be worth further genralrlization.
Nano metal and oxide thereof introduce coating can give coating specific function, nanometer material in modified function coating
Expect the ground of more useful force.Nano-indium stannum oxide (ITO) etc. has the ability of the highest shielding infra-red radiation and good visible ray
Transmitance, introduces in coating the contradiction solving " transparent and heat insulation ", makes nano transparent insulating coating at building large area window
Mouth and transparent ceiling, automotive window etc. use the occasion of glass to be applied in a large number, promote the most in China.
Nano titanium oxide and argent had both had an antibacterial action, again can shield ultraviolet radiation, improve the resistance to of coating
Hou Xing, expands the range of application of anti-biotic material, makes this coating reach the level of industrial applications.Nano-metal-oxide draws
Enter fireproof coating can make that ultra-thin steel structure is fire-retardant greatly extends with the fireproof time, reach the degree of industrial applications.
Rectorite is obvious with the performance of corrosion-resistant epoxy paint with the nano composite material modified building coating of montmorillonite intercalation
Improve.The former is close to industrial applications, though the latter is laboratory result, also provides useful inspiration effect for intercalation modifying.
Sol-gel method is a kind of to prepare the technology that hybrid nano composite dope is best, at film forming procedure
In, carry out in situ the compound of inorganic nano phase and organic polymer matrix, its easy control of structure system, develop abroad quickly.
Summary of the invention:
It is an object of the invention to provide a kind of nano colorful green inner wall paint.
The scheme that the technology of the present invention solves is:
A kind of nano colorful green inner wall paint, is characterized in that: formed % by following masses proportioning
(1) a kind of nano colorful green inner wall paint, is characterized in that: be coated with by bentonite flash of light nano colorful green inner wall
Material, forms % by following masses proportioning
Preparation method:
First diamante being shown, shape and color determine.Then other are raw materials used equal by ratio requirement mix and blend
Even, then will select out and the CL diamante of color is added thereto and stirs,.
This coating does not use any solvent and nitrocotton, all uses poisonous material, and raw material sources are extensive, cheap,
Manufacturing process is simple, be used conveniently and safely, and facing is multicoloured, elegant style, create an aesthetic feeling, different viewing angle has sudden strain of a muscle not
Light color and luster, facing resistant is washable, ageing resistance good.
The concentration of polyvinyl alcohol water solution is 3.2%.Air cleanser fineness is 4000 mesh, and 10% is nano level with electricity
The multiple natural mineral matter of energy, is produced by the refined moist scientific & technical corporation in Beijing, the most commercially sells, and it is by with electric energy
Multiple natural mineral matter mixes, owing to it has permanent through advanced superfine communication technique and advanced calendering process
Electrode, can produce instantaneous high pressure electrostatic field about, when contacting with the hydrone in air, water be ionized to hydrogen ion and
Hydroxide ion, hydrogen ion quickly moves to the negative pole of permanent electrode, becomes hydrogen and distributes in atmosphere, hydroxide ion then and
One water molecules generates hydrogen-oxygen anion emission in air.In addition to launching hydrogen-oxygen anion, moreover it is possible to launch and human body is had
Benefit, the far infrared easily absorbed, so, be there is electricity by carbonium cladding in air with hydroxyl group anion in harmful poisonous gas
Property precipitates with formation neutral ion；Additionally, by chemical reaction, toxic and harmful is carried out chemical breakdown；By absorption
Can by foul smell Molecular Adsorption to the surrounding such as wall, ceiling, so, this product can antibacterial, be sterilized, eliminate peculiar smell, particularly to room
After room finishing, the pernicious gas such as the formaldehyde of generation, chlorine and benzene has good effect of dispelling, and can effectively purify Interior Space
Gas.
This product is building coating, be a kind of capable of purifying air in color inner wall fluorescent paint.This coating is coated with common
Material is compared and is had the following advantages.Energy is antibacterial, be sterilized, eliminate peculiar smell, particularly to formaldehyde, chlorine and the benzene etc. produced after house decoration
Pernicious gas has good dispels effect, the colorful environmental protection coating material of nanometer internal wall that can effectively purify the air of a room.
(2) a kind of nano colorful green inner wall paint, is characterized in that: by chitin glass porcelain glaze fragrance multi-color decorative pattern nanometer
Colourful interior wall environmental protection coating material, forms % by following masses proportioning
Preparation method:
The preparation of decentralized medium: add the desired amount of water in reactor, then put into methylcellulose, open mixer,
While heating up, stirring, then lower the temperature, dispersion liquid butyl glycol ether is put in reactor, then plasticizer O-phthalic
Dibutyl phthalate, adds tween in putting into reactor, adds preservative sodium benzoate and (can be selected for 0.1% proportional quantities to add in right amount
Enter), then remaining each component is mixed, finely ground with colloid mill.Stirring can be prepared by this product.
The preparation of dispersion phase: the multiple color color separation ratio consumption on request such as green to sand base varnish and cadmium red, cadmium yellow, cadmium is divided
It is not in harmonious proportion standby.
The preparation of multicolor finish: the zapon of the band required color of the modulated sum of dispersion phase is put into the water of decentralized medium
Property coating high speed stirring 5-10min, it is desirable to mixing speed at 150-300r/min, forms the most color grain to stirring blade, then adds
Entering appropriate amount of deionized water makes its density reach unanimity the suspension degree of the color grain of regulation, can be prepared by riotous with colour multi-color decorative pattern and is coated with
Material, packed for standby use.
This product is suitable for use as strong body and ceiling ceiling decoration coating.This technology has reduced investment, low cost, technique letter
Single, coating coloured silk grain is uniformly dispersed that not colour contamination, not sagging, brightness be good, third dimension by force, once spray, there is obvious weatherability
And ageing resistance, the advantages such as facing is luxurious, elegant, this coating in process of production without dangerous material such as inflammable and explosive, poisonous and harmfuls,
Its raw material uses the most cheap domestic chitin material.After this spray painting bonding firmly, do not lack to fall, not dry linting, colour-fast,
As wall and ceiling ceiling decoration coating.
(3) a kind of nano colorful green inner wall paint, is characterized in that: by oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer
Colourful interior wall environmental protection coating material, forms % by following masses proportioning
Preparation method:
First, by hydroxyethyl cellulose: the water proportions equal to 1: 40 becomes hydroxyethyl cellulose aqueous solution, is gathered by solid
PAA and water are configured to solution by 1: 20.Certain water is injected, then according to proportioning depends in the reactor of belt stirrer
Secondary addition hydroxyethyl cellulose solution, sodium polyacrylate solution, dispersant, rheological agent, ethylene glycol, Antisepticize and mildew preventive, iris pearl
Delustering pigment, styrene-acrylic emulsion, mill base, then filter this preparation solution, after filtration, adds thickener, tributyl phosphate, three ethanol
Amine, obtains this environmental protection decorative pattern paint.
Nano-meter SiO_22, nano-TiO2Particle diameter about 50nm, the effect of scattering shielded to ultraviolet, can effectively absorb purple
Outside line, makes the life of coating to more than 10 years.Under natural light action, nano particle can produce photocatalysis oxidation reaction and produce
Liveliness proof oxygen and OH free radical, have the highest reactivity, when pollutant be adsorbed in show time, just tie with free electron or hole
Close, redox reaction occurs, thus reaches to eliminate pollution, purify air, to material tools such as nitrogen oxides, grease, formaldehyde
There is obvious catalytic degradation effect.
This product, for making floral designs on metope, makees building inside and outside wall coating.This decorative pattern paint be one have waterproof,
The environmental protection decorative pattern paint nontoxic, free of contamination of the feature such as moistureproof, antifouling, alkaline-resisting, washability and life-span.This product is the most thorough
Improve to the end every technical performances such as the water proofing property of original coating, anti-pollution, ageing-resistant, uvioresistant, antibiotic property, after tinning
Not precipitating, the resting period is long, non-scale layer, adopts water as solvent, without the harmful substance such as benzene, formaldehyde.Coating is through nanometer technology
After improvement, its surface is hard, and fineness reaches higher standard, and the metope of decoration has the hydrophobicity as lotus leaf, and pollutant is difficult to mix
Enter, resistance to cleaning, scrub up to more than 11000 times.Due to highly polished in painting process, without lump obstacle, have anti-aging,
Non-scale, do not fall off, nondiscolouring, superpower alkali resistance, washability, freexing tolerance, bacterium, germ cannot penetrate into exquisiteness metope
In, microorganism cannot show survival, have suitable air cleaning absorption function, the exterior coating life-span up to more than 10 years, interior wall
More than 15 years.Construction is simple simultaneously, and drying time is fast, about 1-2h.
(4) a kind of nano colorful green inner wall paint, is characterized in that: by Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful
Wall environmental protection paint, forms % by following masses proportioning
Preparation method:
1. part water is injected in reaction pot and is warming up to 60-85 DEG C, add polyvinyl alcohol, stop after being completely dissolved heating up,
It is subsequently adding dibutyl phthalate or ethylene glycol, and makes it after fully reacting, be cooled to normal temperature；
2. calgon is added appropriate hot water dissolves standby；
3. brightening agent is added appropriate hot water dissolves standby；
4. by step the most 3. in obtain liquid and remaining water be mixed and stirred for uniformly, addition lithopone, titanium dioxide,
Calcium hydroxide or calcium oxide also stir, and dispersion carries out sand milling with sand mill the most again, then adds thickener thickening, finally
Add insecticide, bactericidal agent is uniformly mixed the environmental protection type insecticide coating i.e. obtaining this technology.
(5) a kind of nano colorful green inner wall paint, is characterized in that: by mica powder environment-friendly type stereo flash nano colorful
Wall environmental protection paint, forms % by following masses proportioning
Preparation method:
First in carboxymethylcellulose calcium and borax and water addition reactor, start mixer, be allowed to stir
After, obtain A slurry and pour out standby.
2. appropriate water is added reactor, after starting mixer, add titanium dioxide and be stirred all poly-with rear addition vinegar
Acid vac emulsion stirs, and adds ethylene glycol, adds polyvinyl acetate emulsion and stirs, then add after stirring
Enter ethylene glycol, i.e. obtain B slurry after stirring and pour out standby.
3. by hydroxypropyl cellulose and sodium sulphate, sodium chloride solution mix C liquid.
4. mica powder, metal powder, pigment and ethylene glycol are mixed and i.e. obtain D liquid.
5. the A of above-mentioned preparation is starched and B starches and remaining raw material is sequentially added into and is stirring evenly and then adding into C liquid to reactor,
Add precipitated calcium carbonate to stir and then filter, remove its moisture, get product.
6. add the water of equal in quality by the quality of above-mentioned finished product, and mix D liquid and can pack warehouse-in.
This product can be used for coating for internal and external wall, subbing, anticorrosive paint, coatings for furniture, floor coating, decorative paint.Also
Can be widely applied to public place building and the wall fitting of luxurious hotels house.Owing to adding nanoscale material in coating
Material, the performance such as obtained coating its ageing-resistant, antiseep, washability is all greatly improved, thus improves the shelves of coating
Secondary, extend the service life of film.After adding surface coupling agent in formula especially, the coating of formation is big with the adhesive force of substrate
Big raising.It is emphasized that water paint characteristic after such modification, its film forming can meet or exceed universal oiliness and be coated with
Performance after material film forming.Various coating products outward appearances after nano-material modified seem fuller, well-balanced, and film is bright and clean carefully
Greasy, sense of touch is excellent, and water resistance is good, is greatly improved with the cohesion of base material.Particularly evident is that modified coating resists
Ultraviolet, wash-resistant property are the most superior.
This product does not use the harmful substances such as organic solvent, nontoxic, tasteless, "dead", without any environmental pollution, makes for a long time
With harmless, producing " without the three wastes ", raw material sources is extensively sent out, convenient transportation, low cost, a kind of nano colorful green inner wall
Coating.
(6) a kind of nano colorful green inner wall paint, is characterized in that: be coated with by cellulose light nano colorful green inner wall
Material, forms % by following masses proportioning
Preparation method:
Weighing material (except pigment printing paste) the most according to the above ratio, device in a reservoir, and is stirred, is then stirred for
While add water, stir.To nano-component pre-process: take be equivalent to nano-component quality 3%-7% point
Powder, disperses dosage 1 to be diluted to the water of 3 times again with being equivalent to, then is sprayed at equably on nano-component, uniform mixing,
Stand 5-24h, standby.
2. prepare acidic liquid, weigh the aluminum sulfate of liquid gross mass 5%, join in stirred tank, and add water and carry out
Stirring, is adjusted to the pH ＜ 4 of above-mentioned solution, then under stress the mill base preparing to pelletize is sprayed into the acid in stirred tank by shower nozzle
In property solution, and it is stirred simultaneously.Scattered Kettle with high speed shear dispersant or homogenizer adds appropriate water,
Add and the uniform nano-component of dispersant and sodium hexametaphosphate and dispersant, then high speed shear or high-speed stirred 10-
30min；
3. the speed of high speed shear dispersion machine or homogenizer is turned down, add color stuffing, thickener part, defoamer
Part and preservative, then high speed dispersion, survey granularity；
4. emulsion, coalescents, defoamer part, levelling agent, antifreezing agent, low rate mixing dispersion 20-it are sequentially added into
30min, adds thickener part regulation viscosity, is uniformly dispersed, filling.
Product performance: this product can guarantee that the fully dispersed of nano-component, is allowed to and emulsion, auxiliary agent and pigment component have relatively
Good compatible, stability, uses multiple nano-component simultaneously, is greatly improved coating combination property, particularly have superpower
The functions such as abrasion resistance, weatherability and antibiosis and self-cleaning.
This product has that low cost, product be nonpoisonous and tasteless, easy construction and to have that decorative pattern is good, wide in variety, chromatogram is wide etc. excellent
Point, the most also has preferable antiseptic property and fire resistance, and firmness is good, it is easy to the advantage of production in enormous quantities.
(7) a kind of nano colorful green inner wall paint, is characterized in that: by kaolin photocatalysis TiO2In golden silk coloured silk nanometer
Wall coating, forms % by following masses proportioning
Preparation method:
1. the preparation of photochemical catalyst titanium oxide dispersion: first particulate titanium dioxide is added a certain amount of polycarboxylate high
In dispersal agent molecule and water, and pass through sand milling so that it is become dispersant；The solid content of photocatalyst dispersion liquid is 10%-40%,
Most preferably 30%；Sand milling jitter time is preferably 6-8h；
2. the preparation of graining paste: pigment, filler, coalescents, functional additive such as defoamer, wetting agent is incorporated in
Water 1. in, and add a certain amount of polycarboxylate salt dispersant, stir 1h by homogenizer, be eventually adding photochemical catalyst titanium dioxide
Titanium dispersion liquid, then high-speed stirred 30min, make graining paste；Add water in a reservoir, under stirring, add transparent silicon the third breast
Liquid, nano titanium oxide, mica titanium, after stirring, sequentially add hydrochloric acid, NaOH, and making pH value is 7-8, adds
Penta sodium pentachlorophenate, ethylene glycol, tributyl phosphate and organic silicon defoamer, stir；
3. the preparation of coating: by above-mentioned titanium dioxide optical catalyst dispersion liquid, graining paste and film forming matter macromolecule silicon third
In emulsion and acrylic emulsion one or both, Ludox and water 2. dispersion mixing under vulgar shearing, stirring 1h
This coating, this coating has that hot strength and compression strength is high, resistance to elevated temperatures by force, do not ftracture, length in service life, environmental protection with become
This low, rich color, the advantage using good visual effect.And polluter in surrounding air of can effectively degrading, purify Interior Space
Gas, particularly degrades to the organic substances such as indoor formaldehyde, toluene and heavy metal, and has the merits such as antibacterial, self-cleaning, fog dispersal
Energy.
Below in conjunction with embodiment, the present invention is further described
Specific implementation method:
(1) a kind of nano colorful green inner wall paint, is characterized in that: be coated with by bentonite flash of light nano colorful green inner wall
Material, forms % by following masses proportioning
(2) a kind of nano colorful green inner wall paint, is characterized in that: by chitin glass porcelain glaze fragrance multi-color decorative pattern nanometer
Colourful interior wall environmental protection coating material, forms % by following masses proportioning
(3) a kind of nano colorful green inner wall paint, is characterized in that: by oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer
Colourful interior wall environmental protection coating material, forms % by following masses proportioning
(4) a kind of nano colorful green inner wall paint, is characterized in that: by Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful
Wall environmental protection paint, forms % by following masses proportioning
(5) a kind of nano colorful green inner wall paint, is characterized in that: by mica powder environment-friendly type stereo flash nano colorful
Wall environmental protection paint, forms % by following masses proportioning
(6) a kind of nano colorful green inner wall paint, is characterized in that: be coated with by cellulose light nano colorful green inner wall
Material, forms % by following masses proportioning
(7) a kind of nano colorful green inner wall paint, is characterized in that: by kaolin photocatalysis TiO2In golden silk coloured silk nanometer
Wall coating, forms % by following masses proportioning
A kind of nano colorful green inner wall paint, by bentonite flash of light nano colorful green inner wall paint, chitin glass
Enamel fragrance multi-color decorative pattern nano colorful green inner wall paint, oyster shell whiting SiO2Environmental protection multi-color decorative pattern nano colorful interior wall ring
Friendly coating, Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, mica powder environment-friendly type stereo flash nano colorful
Green inner wall paint, cellulose light nano colorful green inner wall paint, kaolin photocatalysis TiO2Golden silk coloured silk nanometer internal wall
Coating forms, and it is characterized in that: formed % by following masses proportioning
Embodiment 2: a kind of nano colorful green inner wall paint, by bentonite flash of light nano colorful green inner wall paint, first
Shell element glass porcelain glaze fragrance multi-color decorative pattern nano colorful green inner wall paint, oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer is many
Color green inner wall paint, Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, mica powder environment-friendly type stereo flash
Nano colorful green inner wall paint, cellulose light nano colorful green inner wall paint, kaolin photocatalysis TiO2Golden silk coloured silk
Nano inner wall coating forms, and it is characterized in that: formed % by following masses proportioning
Embodiment 3: a kind of nano colorful green inner wall paint, by bentonite flash of light nano colorful green inner wall paint, first
Shell element glass porcelain glaze fragrance multi-color decorative pattern nano colorful green inner wall paint, oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer is many
Color green inner wall paint, Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, mica powder environment-friendly type stereo flash
Nano colorful green inner wall paint, cellulose light nano colorful green inner wall paint, kaolin photocatalysis TiO2Golden silk coloured silk
Nano inner wall coating forms, and it is characterized in that: formed % by following masses proportioning
Embodiment 4: a kind of nano colorful green inner wall paint, by bentonite flash of light nano colorful green inner wall paint, first
Shell element glass porcelain glaze fragrance multi-color decorative pattern nano colorful green inner wall paint, oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer is many
Color green inner wall paint, Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, mica powder environment-friendly type stereo flash
Nano colorful green inner wall paint, cellulose light nano colorful green inner wall paint, kaolin photocatalysis TiO2Golden silk coloured silk
Nano inner wall coating forms, and it is characterized in that: formed % by following masses proportioning
Embodiment 5: a kind of nano colorful green inner wall paint, by bentonite flash of light nano colorful green inner wall paint, first
Shell element glass porcelain glaze fragrance multi-color decorative pattern nano colorful green inner wall paint, oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer is many
Color green inner wall paint, Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, mica powder environment-friendly type stereo flash
Nano colorful green inner wall paint, cellulose light nano colorful green inner wall paint, kaolin photocatalysis TiO2Golden silk coloured silk
Nano inner wall coating forms, and it is characterized in that: formed % by following masses proportioning
Embodiment 6: a kind of nano colorful green inner wall paint, by bentonite flash of light nano colorful green inner wall paint, first
Shell element glass porcelain glaze fragrance multi-color decorative pattern nano colorful green inner wall paint, oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer is many
Color green inner wall paint, Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, mica powder environment-friendly type stereo flash
Nano colorful green inner wall paint, cellulose light nano colorful green inner wall paint, kaolin photocatalysis TiO2Golden silk coloured silk
Nano inner wall coating forms, and it is characterized in that: formed % by following masses proportioning
Embodiment 7: a kind of nano colorful green inner wall paint, by bentonite flash of light nano colorful green inner wall paint, first
Shell element glass porcelain glaze fragrance multi-color decorative pattern nano colorful green inner wall paint, oyster shell whiting SiO2Environmental protection multi-color decorative pattern nanometer is many
Color green inner wall paint, Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, mica powder environment-friendly type stereo flash
Nano colorful green inner wall paint, cellulose light nano colorful green inner wall paint, kaolin photocatalysis TiO2Golden silk coloured silk
Nano inner wall coating forms, and it is characterized in that: formed % by following masses proportioning
Claims (1)
1. a nano colorful green inner wall paint, is characterized in that: formed % by following masses proportioning
Wherein, (1) bentonite flash of light nano colorful green inner wall paint, form % by following masses proportioning
(2) chitin glass porcelain glaze fragrance multi-color decorative pattern nano colorful green inner wall paint, forms % by following masses proportioning
(3) oyster shell whiting SiO2Environmental protection multi-color decorative pattern nano colorful green inner wall paint, forms % by following masses proportioning
(4) Pesticidal and sterilizing multi-color decorative pattern tempering nano colorful green inner wall paint, forms % by following masses proportioning
(5) mica powder environment-friendly type stereo flash nano colorful green inner wall paint, forms % by following masses proportioning
(6) cellulose light nano colorful green inner wall paint, forms % by following masses proportioning
(7) kaolin photocatalysis TiO2Golden silk coloured silk nano inner wall coating, forms % by following masses proportioning
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| CN105776961A (en) * | 2016-02-18 | 2016-07-20 | 吉林省珍贝壳环保新材料有限公司 | Comprehensive environment-friendly shell powder coating |
| WO2018202830A1 (en) * | 2017-05-05 | 2018-11-08 | Basf Se | Fluidically applicable vapor retarder |
| CN109233474A (en) * | 2018-09-14 | 2019-01-18 | 深圳市博原实业有限公司 | A kind of inner wall decorative coating and its preparation process |
| CN111268996B (en) * | 2020-03-16 | 2021-09-21 | 绍兴蓝竹新材料科技有限公司 | Preparation method of photocatalytic air purification decorative plate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1766017A (en) * | 2004-07-14 | 2006-05-03 | 武汉金刚高丽建材有限公司 | Aqueous colorful pattern coating composition for building |
| CN101974263A (en) * | 2010-10-19 | 2011-02-16 | 王秀宝 | Coating for removing formaldehyde in indoor air |
| CN102816493A (en) * | 2012-07-05 | 2012-12-12 | 成钢 | Multi-element multifunctional healthy longevity-promoting nanometer environment-friendly interior-wall paint rich in silver, selenium and germanium |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6147766A (en) * | 1984-08-15 | 1986-03-08 | Tamio Yamane | Additive for indoor wall material |
| JPH03124777A (en) * | 1989-10-07 | 1991-05-28 | Yoshiyuki Ogushi | Surface coating agent |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1766017A (en) * | 2004-07-14 | 2006-05-03 | 武汉金刚高丽建材有限公司 | Aqueous colorful pattern coating composition for building |
| CN101974263A (en) * | 2010-10-19 | 2011-02-16 | 王秀宝 | Coating for removing formaldehyde in indoor air |
| CN102816493A (en) * | 2012-07-05 | 2012-12-12 | 成钢 | Multi-element multifunctional healthy longevity-promoting nanometer environment-friendly interior-wall paint rich in silver, selenium and germanium |
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Inventor after: Liu Shanjiang Inventor after: Liu Zhanchuan Inventor after: Hu Zhongyuan Inventor after: Ding Shuai Inventor after: Liu Hongliang Inventor after: Chu Huilai Inventor before: Cheng Jinxue Inventor before: Cheng Gang |
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Effective date of registration: 20170411 Address after: 072550 Hebei city of Baoding province Xushui Chenyang Street No. 1 Co-patentee after: Hebei Chenyang water paint Co. Ltd. Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: 226000 Nantong City, Gangzha District, Qin Qin street, the village of the four groups of the temple of the group of eight in the District of Jiangsu Patentee before: Nantong Snakes Treating Inst. |
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