CN107668043A - A kind of desinsection ointment containing left-handed α terpinols and tridemorph - Google Patents
A kind of desinsection ointment containing left-handed α terpinols and tridemorph Download PDFInfo
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- CN107668043A CN107668043A CN201711207168.XA CN201711207168A CN107668043A CN 107668043 A CN107668043 A CN 107668043A CN 201711207168 A CN201711207168 A CN 201711207168A CN 107668043 A CN107668043 A CN 107668043A
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- tridemorph
- terpineol
- desinsection ointment
- desinsection
- ointment
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of ointment for preventing and treating insect pest longicorn of poplar, and in particular to a kind of desinsection ointment containing left-handed α terpinols and tridemorph, belongs to agricultural chemicals and its formulation art.A kind of desinsection ointment containing left-handed α terpinols and tridemorph, it is characterized in that, the desinsection ointment is formed by left-handed α terpinols, tridemorph and additive mixture, the percentage by weight that wherein left-handed α terpinols account for the desinsection ointment gross weight is 0.1~55%, the percentage by weight that tridemorph accounts for the desinsection ointment gross weight is 0.1~55%, and remaining is auxiliary agent.Ointment lasting period length of the present invention, environmental pollution is small, and dispenser is easy.
Description
Technical field
The present invention relates to a kind of ointment for preventing and treating insect pest longicorn of poplar, belong to agricultural chemicals and its formulation art.
Background technology
Poplar longicorn is the important trunk borer of the seeds such as China poplar, willow, elm, maple, the poplar longicorn reported in China
Up to kind more than 100.Because poplar longicorn is lived, hidden, Natural Enemies are few, the history of life is complicated, and willow is China's afforestation, prevented
Wind one of fixes the sand with the preferred seeds of afforestation such as fast growing, causes poplar longicorn food resource sufficient, in China's poplar longicorn
Harm is serious, and year, occurring area was in 600,000 hm2Left and right.Over 10 years, yellow spotted star longicorn beetle, anoplophora glabripennis spread rapidly, and harm is tight
Weight, is extremely restricted the development of willow, has had a strong impact on forestry sound development.Because the life of poplar longicorn larva is hidden,
Very big difficulty is brought to preventing and controlling, therefore the preventing and treating of poplar longicorn is a very urgent task.Poplar longicorn at present
Preventing and treating using integrated control strategy.Concrete condition is as follows:
(1)Silvicultural Measures:The improved seeds afforestation such as middle forest 46, the middle forest No. 108 of selection with pest-resistant performance, strict nursery stock inspection
Epidemic disease, avoid band worm nursery stock afforestation.New poplar forest of making is away from insects sources, or plant isolation strip, Mixed Forests;With longicorn apocleisis
Seeds and willow collocation Mixed forestation, are typically advisable, shelter belt can use section gap is mixed to hand over Mixed in blocks.Using big
Cave, seedlings, flood, diligent fertilising, the diligent measure such as loosen the soil, promote forest health fast-growth, strengthen insect resistance capacity.
(2)Biological control measure:Prevented and treated using longicorn natural enemy insect, longicorn causal organism etc., can use in conditional region and peck wood
Bird controls longicorn insect population;New afforestation can use moraceae plants of longicorn addiction etc., trap and kill Cerambycid beetles.Also have for longicorn
The bio-control method of body mainly applies longicorn defecation using the biological agents such as muscardine, green muscardine fungus, Dipel are directly stifled
Hole.
(3)Physical measure:Mulberry borer nocturnalism, there is stronger phototaxis, black light lamps can be used.Anoplophora glabripennis daytime
Night is movable, and phototaxis is not strong, can artificial capture method adult.Applied from deterrent Cerambycid beetles and laid eggs with trunk, winter can combine young growth
Foster and repair except worm branch, cut generation serious aggrieved trees, eradicate hidden danger.
(4)Chemical measure:1. malicious label can be made of organophosphorus insecticides such as zinc phosphides, worm channel, smoked kill larva, effect are inserted
Up to 90%.2. injecting worm channel with 50~300 times of organophosphorus pesticide dilutions, larva is killed.3. with Azodrin, flolimat etc.
Systemics agricultural chemicals is injected in butt or root punching, is sealed after perfusion with wet soil, can be prevented and treated tall and big trees larva.4. into
Worm phase and ovum phase, large area sprinkling 1000 ~ 2000 times of glue suspensions of d ichlorbenzuron, adult and ovum can be killed.It is 5. " green with new contact insecticide
Se Weilei " prevents and treats Cerambycid beetles.
The problem that above each method is faced is that biological control effect is unstable, and prevention effect is by factors such as weather
Influence, and poplar longicorn, as a kind of borer pest, biological control medicament is difficult the adult and larva for reaching longicorn;In mesh
It is preceding still to use chemical prevention and control method in large area, the methods of such as using poison label, drilling injection, bury medicine, spray, but these
Method runs into very hang-up in prevention effect or specific implementation operation.Malicious label method needs to find the hole of roundheaded borer and adult
Mouthful, during large area control, workload is too big;Workload is too big when drilling is injected at large area control, and injures poplar after boring sky
The xylem of tree, the self-healing ability of willow is limited, and the situation of rotten unrest occurs in significant portion, and peasant has one on the method is received
Fixed difficulty;Dosage is big during spraying, and droplet can be with wind drift, it is necessary to employ high pressure spraying mechanical, and medicament also has been difficult to
Effect reaches polypide, and medicament utilization rate is too low.
The content of the invention
It is an object of the invention to provide a kind of desinsection ointment containing levogyrate alpha-terpineol and tridemorph, the ointment holding effect
Phase is grown, and environmental pollution is small, and dispenser is easy.
The purpose of the present invention is achieved through the following technical solutions, a kind of containing levogyrate alpha-terpineol and tridemorph
Desinsection ointment, it is characterised in that the desinsection ointment is formed by levogyrate alpha-terpineol, tridemorph and additive mixture, wherein left
The percentage by weight that rotation alpha-terpineol accounts for the desinsection ointment gross weight is 0.1~55%, and it is total that tridemorph accounts for the desinsection ointment
The percentage by weight of weight is 0.1~55%, and remaining is auxiliary agent.
Preferably, the desinsection ointment is 5 by the weight proportion of levogyrate alpha-terpineol and tridemorph:1、4:1、3:1、1:
3、1:4、1:5。
Preferably, the auxiliary agent includes solvent, sticker and filler;It is total that solvent, sticker, filler account for the desinsection ointment
The percentage by weight of weight is respectively 0.1~80.0%, 0.1~80.0%, 0.1~80.0%.
Preferably, the solvent be selected from benzene,toluene,xylene, methanol, ethanol, propyl alcohol, butanol, isobutanol, cyclohexanone,
Appoint in MEK, isophorone, pyrrolidones, 1-METHYLPYRROLIDONE, dimethylformamide, dimethyl sulfoxide, 2-Pyrrolidone
Anticipate two or more a kind of or any composition.
Preferably, the sticker is selected from polyvinyl acetate, gelatin, polyvinyl alcohol, styrene-butadiene latex, Arabic gum, marine alga
Sour sodium, xanthans, sodium carboxymethylcellulose, carboxy-propyl cellulose sodium, polyethylene glycol, polyethylene glycol oxide, polyvinylpyrrolidone,
Appoint in polyacrylamide, soluble starch, dextrin, polyvinyl acetate, coumarone resin, Petropols, naphthalene resinox
Anticipate two or more a kind of or any composition.
Preferably, the filler is selected from diatomite, Concave-convex clay rod, bentonite, sepiolite, kaolin, clay, lightweight
Any one in calcium carbonate, sawdust powder, rice husk, tobacco powder, walnut parting, lignin or two or more any combination
Thing.
Compared with prior art, the invention has the advantages that:
First, the tridemorph selected by the present invention has good systemic action, and levogyrate alpha-terpineol has photoactivation poisoning
Effect.Tridemorph and synergistic effect after levogyrate alpha-terpineol mixture are obvious;
Second, ointment of the present invention has good adhesion strength, lasting effect, and dispenser is easy, improves the utilization rate of medicament, reduces
Environmental pollution, medicament can be by being inhaled in plant, and ointment of the present invention has certain action of contace poison, and insect can be prevented to set
Dry creeping back and forth up and down, causes harm so as to can also mitigate significantly to plant.
Embodiment
The following examples are that technical solution of the present invention is further illustrated, but present disclosure is not limited thereto
(All compositions of following examples are by weight percentage).
Embodiment 1,40.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 30.0, tridemorph 10.0, propyl alcohol 8.0, cyclohexanone 6.0, polyvinyl acetate 5.0, gelatin 5.0, pottery
Soil 8.0, diatomite 28.0;Pesticide active ingredient is added under stirring at normal temperature after binding agent, filler, solvent are mixed, into paste
Liquid and tinning.
Embodiment 2,30.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 20.0, tridemorph 10.0, isobutanol 6.0, dimethylformamide 8.0,2-Pyrrolidone 2.0, gather
Ethylene glycol 10.0, precipitated calcium carbonate 30.0, sawdust powder 14.0;Added after binding agent, filler, solvent are mixed under stirring at normal temperature
Pesticide active ingredient, into cream liquid and tinning.
Embodiment 3,20.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 10.0, tridemorph 10.0,2-Pyrrolidone 4.0, butanol 4.0, MEK 6.0, dextrin 0.2, gather
Vinyl acetate 5.0, coumarone resin 5.0, kaolin 55.8;Add after binding agent, filler, solvent are mixed under stirring at normal temperature
Enter pesticide active ingredient, into cream liquid and tinning.
Embodiment 4,30.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 10.0, tridemorph 20.0, toluene 10.0, ethanol 4.0,2-Pyrrolidone 4.0, sodium alginate 8.0,
Xanthans 4.0, precipitated calcium carbonate 40.0;Will binding agent, filler, solvent mix after under stirring at normal temperature add agricultural chemicals effectively into
Point, into cream liquid and tinning.
Embodiment 5,40.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 10.0, tridemorph 30.0, isophorone 12.0, MEK 4.0, sodium carboxymethylcellulose 0.5, sea
Algae element sodium 9.5, rice husk 5.0, tobacco powder 5.0, diatomite 24.0;Add after binding agent, filler, solvent are mixed under stirring at normal temperature
Enter pesticide active ingredient, into cream liquid and tinning.
Embodiment 6,30.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 6.0, tridemorph 24.0,1-METHYLPYRROLIDONE 0.5, isobutanol 7.5, ethanol 0.5, gelatin 0.5,
Dextrin 0.5, coumarone resin 9.0, diatomite 0.5, kaolin 51.0;In stirring at normal temperature after binding agent, filler, solvent are mixed
Lower addition pesticide active ingredient, into cream liquid and tinning.
Embodiment 7,30.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 24.0, tridemorph 6.0, propyl alcohol 2.0, dimethylformamide 0.5, cyclohexanone 7.5, Arabic gum
0.5, polyvinyl lactam 0.5, butadiene-styrene latex 8.0, clay 0.5, bentonite 50.5;Normal after binding agent, filler, solvent are mixed
Temperature stirring is lower to add pesticide active ingredient, into cream liquid and tinning.
Embodiment 8,30.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 5.0, tridemorph 25.0,1-METHYLPYRROLIDONE 0.5, isobutanol 7.5, ethanol 0.5, gelatin 0.5,
Dextrin 0.5, coumarone resin 9.0, diatomite 0.5, kaolin 51.0;In stirring at normal temperature after binding agent, filler, solvent are mixed
Lower addition pesticide active ingredient, into cream liquid and tinning.
Embodiment 9,30.0% levogyrate alpha-terpineol tridemorph ointment
Levogyrate alpha-terpineol 25.0, tridemorph 5.0, propyl alcohol 2.0, dimethylformamide 0.5, cyclohexanone 7.5, Arabic gum
0.5, polyvinyl lactam 0.5, butadiene-styrene latex 8.0, clay 0.5, bentonite 50.5;Normal after binding agent, filler, solvent are mixed
Temperature stirring is lower to add pesticide active ingredient, into cream liquid and tinning.
Embodiment 10, indoor mixture synergism toxicity test
Each reagent agent is made into respective concentration respectively, draws the agricultural chemicals prepared from low concentration to high concentration with microsyringe,
Drip and rinse microsyringe with acetone between the pronotary of the instar larvae of anoplophora glabripennis 3, different agents, every drips 1 μ L,
Per concentration 30, while 5% acetone solution is set to do control treatment, 24h observation dead larvae numbers.Calculate LC50Value and toxicity regression side
Journey and co-toxicity coefficient.Co-toxicity coefficient is calculated using the abundant methods of Sun Yun.
The toxicity index that mixed toxicity index/theory in co-toxicity coefficient CTC=100 × actually is used with
When co-toxicity coefficient is significantly greater than 100, show there is synergistic effect;Close to 100, summation action is indicated;It is significantly less than
100, show there is antagonism.It is dense during each proportioning mixture of levogyrate alpha-terpineol and tridemorph is effectively lethal to anoplophora glabripennis
Spend LC50Value is sequentially(5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5)Respectively 20.78,23.47,26.30,
57.26th, 54.67,52.98,27.54,28.21 and 23.89 mg/mL;Levogyrate alpha-terpineol and each proportioning mixture of tridemorph
Co-toxicity coefficient sequentially(5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5)Respectively 134.56,137.89,
139.20th, 108.24,105.24,101.98,128.47,130.47 and 130.22.Levogyrate alpha-terpineol matches with tridemorph
For 5:1、4:1、3:1、1:3、1:4、1:5 have synergistic effect, wherein proportioning is 1:Synergistic effect is most obvious when 2.
Claims (6)
1. a kind of desinsection ointment containing levogyrate alpha-terpineol and tridemorph, it is characterised in that the desinsection ointment is by left-handed
Alpha-terpineol, tridemorph and additive mixture form, and wherein levogyrate alpha-terpineol accounts for the weight hundred of the desinsection ointment gross weight
Divide than being 0.1~55%, the percentage by weight that tridemorph accounts for the desinsection ointment gross weight is 0.1~55%, and remaining is auxiliary agent.
2. a kind of desinsection ointment containing levogyrate alpha-terpineol and tridemorph, it is characterised in that the desinsection ointment is by left-handed
The weight proportion of alpha-terpineol and tridemorph is 5:1、4:1、3:1、1:3、1:4、1:5.
3. the desinsection ointment according to claim 1 containing levogyrate alpha-terpineol and tridemorph, it is characterised in that described
Auxiliary agent includes solvent, sticker and filler;Solvent, sticker, filler account for the weight percent score of the desinsection ointment gross weight
Wei 0.1~80.0%, 0.1~80.0%, 0.1~80.0%.
4. the desinsection ointment according to claim 2 containing levogyrate alpha-terpineol and tridemorph, it is characterised in that described
Solvent is selected from benzene,toluene,xylene, methanol, ethanol, propyl alcohol, butanol, isobutanol, cyclohexanone, MEK, isophorone, pyrroles
Any one in alkanone, 1-METHYLPYRROLIDONE, dimethylformamide, dimethyl sulfoxide, 2-Pyrrolidone is any two kinds or two
The composition of the kind above.
5. the desinsection ointment according to claim 2 containing levogyrate alpha-terpineol and tridemorph, it is characterised in that described
It is fine that sticker is selected from polyvinyl acetate, gelatin, polyvinyl alcohol, styrene-butadiene latex, Arabic gum, sodium alginate, xanthans, carboxymethyl
Tie up plain sodium, carboxy-propyl cellulose sodium, polyethylene glycol, polyethylene glycol oxide, polyvinylpyrrolidone, polyacrylamide, soluble shallow lake
Any one in powder, dextrin, polyvinyl acetate, coumarone resin, Petropols, naphthalene resinox or it is any two kinds or
Two or more compositions.
6. the desinsection ointment according to claim 2 containing levogyrate alpha-terpineol and tridemorph, it is characterised in that described
Filler be selected from diatomite, Concave-convex clay rod, bentonite, sepiolite, kaolin, clay, precipitated calcium carbonate, sawdust powder, rice husk,
Any one in tobacco powder, walnut parting, lignin or two or more any composition.
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Cited By (1)
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CN109874810A (en) * | 2019-01-30 | 2019-06-14 | 广东省农业科学院植物保护研究所 | A kind of Conopomorpha sinensis Bradley adult stage cooperates with preventing control method with the ovum phase |
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CN104126605A (en) * | 2014-07-07 | 2014-11-05 | 广西三晶化工科技有限公司 | Compound pesticide |
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CN104126605A (en) * | 2014-07-07 | 2014-11-05 | 广西三晶化工科技有限公司 | Compound pesticide |
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Title |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109874810A (en) * | 2019-01-30 | 2019-06-14 | 广东省农业科学院植物保护研究所 | A kind of Conopomorpha sinensis Bradley adult stage cooperates with preventing control method with the ovum phase |
CN109874810B (en) * | 2019-01-30 | 2021-01-05 | 广东省农业科学院植物保护研究所 | Litchi fruit borer adult stage and egg stage cooperative prevention and control method |
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