CN107662958A - A kind of eutrophied water treatment method - Google Patents
A kind of eutrophied water treatment method Download PDFInfo
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- CN107662958A CN107662958A CN201710963562.XA CN201710963562A CN107662958A CN 107662958 A CN107662958 A CN 107662958A CN 201710963562 A CN201710963562 A CN 201710963562A CN 107662958 A CN107662958 A CN 107662958A
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- Prior art keywords
- tabacco straw
- conditions
- mass concentration
- drying
- bed mud
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
- B01J2220/4825—Polysaccharides or cellulose materials, e.g. starch, chitin, sawdust, wood, straw, cotton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4875—Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
- B01J2220/4887—Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure; fly-ashes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
Abstract
A kind of eutrophied water treatment method, first gathers in tabacco straw, dries, crushes, sieves, is pyrolyzed；It is in 50~70% dimethyl diallyl ammonium chloride mixed solutions to be immersed in the aluminum sulfate of mass concentration 10~40% and mass concentration again, adds the ceric ammonium nitrate solution of mass concentration 10~40%, is stirred 5 minutes under the conditions of 30~60 DEG C；Washing, drying, sieving obtain being modified tabacco straw charcoal；The bed mud of eutrophication water is taken, through being dehydrated, drying, crushing, sieving；The bed mud after screening and modified tabacco straw charcoal by volume 1:3 ratio mixing, obtains new adsorbent；The uniform cloth of new adsorbent is spread in eutrophication water；Sediments are excavated in the dry season, a part of bed mud makes new adsorbent, largely transports landfill yard landfill, or burning disposal to.
Description
Technical field
The present invention relates to technical field of sewage, especially a kind of eutrophied water treatment method.
Background technology
The generation of body eutrophication phenomenon is mostly derived from the excess accumulation of water body nitrogen and phosphorous nutrient material, shows as algae
Amount reproduction, fish mortality, water body is smelly, occurs being referred to as " red tide " in ocean, " water is referred to as in rivers and lakes
China ".It is physico that traditional nutritive water administration way includes wastewater treatment, Sediment Dredging, aeration cycle, algicide add etc.
Method and biological control method, but all presence investment and technical difficulty are larger, destroy lake, river natural ecosystems etc.
Problem.
With the development of modern agriculture, straw quantity is significantly increased, the t of China's agricultural crop straw annual production about 700,000,000 marks
Coal.Meanwhile with the continuous adjustment of Industry Structure, it is greatly reduced in life using stalk, causes a large amount of agricultural straws
It is remaining and burned or abandoned everywhere by field.At present, the conventional utilization ways of China's stalk include：Straw-returning, using energy source,
Feed conversion, industrial utilization etc..Therefore, new technology is developed, the effective rate of utilization of agricultural stalk is improved, realizes changing rejected material to useful resource
Utilize, have far-reaching significance to improving resource scarcity problem and preserving the ecological environment.
By taking tabacco straw as an example, national cigarette district about produces tabacco straw 4500kt every year, and overall utilization is very low, most quilts
Open incineration, not only waste of resource but also environment was polluted.
The content of the invention
The technical problem to be solved in the present invention is：Present invention proposition one kind is raw material using tabacco straw, is prepared new
Adsorbent, by the use of the new adsorbent as the sorbing material of eutrophication water, solves the eutrophy of the water bodys such as lake, river
The problems such as change is low with tabacco straw utilization rate, pollution environment.
The technical solution adopted for the present invention to solve the technical problems is：The present invention is implemented as follows；
(1) tabacco straw is gathered in, dried；
(2) tabacco straw after drying crushed, cross 60~100 mesh sieves；
(3) will be put into after the tabacco straw washing after screening, drying in box atmosphere furnace, it is 10~20 to set heating rate
DEG C/min, be passed through nitrogen protection, mould anaerobic environment, it is 500~700 DEG C to set pyrolysis temperature, set pyrolysis time be 2~
4h, room temperature is cooled to afterwards, obtain tabacco straw charcoal；
(4) tabacco straw powdered carbon it is broken, cross 60~100 mesh sieves, wash to neutrality；
(5) the tabacco straw charcoal after washing be immersed in mass concentration 10~40% aluminum sulfate and mass concentration be 50~
In 70% dimethyl diallyl ammonium chloride mixed solution, stirred 20 minutes under the conditions of 30~60 DEG C；
(6) ceric ammonium nitrate solution of mass concentration 10~40% is added into the mixed solution of step (5), at 30~60 DEG C
Under the conditions of stir 5 minutes；
(7) mixed solution of step (6) is in N2Stirred 20~40 minutes under environment and under the conditions of 30~60 DEG C；
(8) mixed solution of step (7) stands 30~60 minutes under the conditions of 20~25 DEG C；
(9) the tabacco straw charcoal of step (8) is filtered；
(10) the tabacco straw charcoal ethanol after filtering and distillation water washing；
(11) the tabacco straw charcoal after washing under the conditions of 60~80 DEG C of temperature drying, cross 60~80 mesh sieves, changed
Property tabacco straw charcoal；
(12) bed mud of eutrophication water is taken, through being dehydrated, drying, crushing, crosses 60~80 mesh sieves；
(13) the bed mud after screening and modified tabacco straw charcoal by volume 1:3 ratio mixing, obtains novel adsorption
Agent；
(13) the uniform cloth of new adsorbent is spread in eutrophication water；
(14) Sediments are excavated in the dry season, a part of bed mud gives over to making new adsorbent, largely transports to and fill out
Bury field landfill, or burning disposal.
It is raw material the beneficial effects of the invention are as follows the bed mud using tabacco straw and eutrophication water, prepares new suction
Attached dose, the new adsorbent has good absorption, exchange and settling property to nitrogen, phosphonium ion, can using the new adsorbent
Eutrophication water is administered, while can also solve the problems, such as the recycling of tabacco straw.
Embodiment
The present invention prepares new adsorbent using the bed mud of tabacco straw and eutrophication water for raw material, both administers
Polluted-water, also seeks to effective utilization of tabacco straw, while can reduce the pollution for burning tabacco straw to environment body.
Embodiment 1
(1) tabacco straw is gathered in, dried；
(2) tabacco straw after drying crushed, cross 60 mesh sieves；
(3) will be put into after the tabacco straw washing after screening, drying in box atmosphere furnace, it is 10 DEG C to set heating rate
min-1, it is passed through nitrogen and moulds anaerobic environment, it is 550 DEG C to set pyrolysis temperature, and setting pyrolysis time is 3h, is cooled to room afterwards
Temperature, obtain tabacco straw charcoal；
(4) tabacco straw powdered carbon it is broken, cross 60 mesh sieves, wash to neutrality；
(5) it is 50% diformazan the tabacco straw charcoal after washing to be immersed in the aluminum sulfate of mass concentration 10% and mass concentration
In base diallyl ammonium chloride mixed solution, stirred 20 minutes under the conditions of 30 DEG C；
(6) ceric ammonium nitrate solution of mass concentration 10% is added into the mixed solution of step (5), is stirred under the conditions of 30 DEG C
Mix 5 minutes；
(7) mixed solution of step (6) is in N2Stirred 20 minutes under environment and under the conditions of 30 DEG C；
(8) mixed solution of step (7) stands 30 minutes under the conditions of 20 DEG C；
(9) the tabacco straw charcoal of step (8) is filtered；
(10) the tabacco straw charcoal ethanol after filtering and distillation water washing；
(11) the tabacco straw charcoal after washing dried under the conditions of temperature 60 C, cross 60 mesh sieves, obtain being modified tobacco straw
Stalk charcoal；
(12) bed mud of eutrophication water is taken, through being dehydrated, drying, crushing, crosses 60 mesh sieves；
(13) the bed mud after screening and modified tabacco straw charcoal by volume 1:3 ratio mixing, obtains novel adsorption
Agent；
(13) the uniform cloth of new adsorbent is spread in eutrophication water；
(14) Sediments are excavated in the dry season, a part of bed mud gives over to making new adsorbent, largely transports to and fill out
Bury field landfill, or burning disposal.
Embodiment 2
(1) tabacco straw is gathered in, dried；
(2) tabacco straw after drying crushed, cross 80 mesh sieves；
(3) will be put into after the tabacco straw washing after screening, drying in box atmosphere furnace, it is 15 DEG C to set heating rate
min-1, it is passed through nitrogen protection and moulds anaerobic environment, it is 600 DEG C to set pyrolysis temperature, and setting pyrolysis time is 3h, is cooled to afterwards
Room temperature, obtain tabacco straw charcoal；
(4) tabacco straw powdered carbon it is broken, cross 80 mesh sieves, wash to neutrality；
(5) it is 60% diformazan the tabacco straw charcoal after washing to be immersed in the aluminum sulfate of mass concentration 30% and mass concentration
In base diallyl ammonium chloride mixed solution, stirred 20 minutes under the conditions of 50 DEG C；
(6) ceric ammonium nitrate solution of mass concentration 30% is added into the mixed solution of step (5), is stirred under the conditions of 50 DEG C
Mix 5 minutes；
(7) mixed solution of step (6) is in N2Stirred 30 minutes under environment and under the conditions of 50 DEG C；
(8) mixed solution of step (7) stands 50 minutes under the conditions of 25 DEG C；
(9) the tabacco straw charcoal of step (8) is filtered；
(10) the tabacco straw charcoal ethanol after filtering and distillation water washing；
(11) the tabacco straw charcoal after washing dried under the conditions of temperature 70 C, cross 80 mesh sieves, obtain being modified tobacco straw
Stalk charcoal；
(12) bed mud of eutrophication water is taken, through being dehydrated, drying, crushing, crosses 80 mesh sieves；
(13) the bed mud after screening and modified tabacco straw charcoal by volume 1:3 ratio mixing, obtains novel adsorption
Agent；
(13) the uniform cloth of new adsorbent is spread in eutrophication water；
(14) Sediments are excavated in the dry season, a part of bed mud gives over to making new adsorbent, largely transports to and fill out
Bury field landfill, or burning disposal.
Embodiment 3
(1) tabacco straw is gathered in, dried；
(2) tabacco straw after drying crushed, cross 80 mesh sieves；
(3) will be put into after the tabacco straw washing after screening, drying in box atmosphere furnace, it is 20 DEG C to set heating rate
min-1, it is passed through nitrogen protection and moulds anaerobic environment, it is 700 DEG C to set pyrolysis temperature, and setting pyrolysis time is 2h, is cooled to afterwards
Room temperature, obtain tabacco straw charcoal；
(4) tabacco straw powdered carbon it is broken, cross 80 mesh sieves, wash to neutrality；
(5) it is 60% diformazan the tabacco straw charcoal after washing to be immersed in the aluminum sulfate of mass concentration 40% and mass concentration
In base diallyl ammonium chloride mixed solution, stirred 20 minutes under the conditions of 60 DEG C；
(6) ceric ammonium nitrate solution of mass concentration 40% is added into the mixed solution of step (5), is stirred under the conditions of 30 DEG C
Mix 5 minutes；
(7) mixed solution of step (6) is in N2Stirred 40 minutes under environment and under the conditions of 60 DEG C；
(8) mixed solution of step (7) stands 60 minutes under the conditions of 25 DEG C；
(9) the tabacco straw charcoal of step (8) is filtered；
(10) the tabacco straw charcoal ethanol after filtering and distillation water washing；
(11) the tabacco straw charcoal after washing dried under the conditions of temperature 60 C, cross 80 mesh sieves, obtain being modified tobacco straw
Stalk charcoal；
(12) bed mud of eutrophication water is taken, through being dehydrated, drying, crushing, crosses 80 mesh sieves；
(13) the bed mud after screening and modified tabacco straw charcoal by volume 1:3 ratio mixing, obtains novel adsorption
Agent；
(13) the uniform cloth of new adsorbent is spread in eutrophication water；
(14) Sediments are excavated in the dry season, a part of bed mud gives over to making new adsorbent, largely transports to and fill out
Bury field landfill, or burning disposal.
It is complete by above-mentioned description, relevant staff using the above-mentioned desirable embodiment according to the present invention as enlightenment
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to determines its technical scope according to right.
Claims (1)
- A kind of 1. eutrophied water treatment method, it is characterised in that：Implement as follows；(1) tabacco straw is gathered in, dried；(2) tabacco straw after drying crushed, cross 60~100 mesh sieves；(3) will be put into after the tabacco straw washing after screening, drying in box atmosphere furnace, it is 10~20 DEG C to set heating rate min-1, it is passed through nitrogen and moulds anaerobic environment, it is 500~700 DEG C to set pyrolysis temperature, and setting pyrolysis time is 2~4h, Zhi Houleng But to room temperature, tabacco straw charcoal is obtained；(4) tabacco straw powdered carbon it is broken, cross 60~100 mesh sieves, wash to neutrality；(5) it is 50~70% the tabacco straw charcoal after washing to be immersed in the aluminum sulfate of mass concentration 10~40% and mass concentration In dimethyl diallyl ammonium chloride mixed solution, stirred 20 minutes under the conditions of 30~60 DEG C；(6) ceric ammonium nitrate solution of mass concentration 10~40% is added into the mixed solution of step (5), in 30~60 DEG C of conditions Lower stirring 5 minutes；(7) mixed solution of step (6) is in N2Stirred 20~40 minutes under environment and under the conditions of 30~60 DEG C；(8) mixed solution of step (7) stands 30~60 minutes under the conditions of 20~25 DEG C；(9) the tabacco straw charcoal of step (8) is filtered；(10) the tabacco straw charcoal ethanol after filtering and distillation water washing；(11) the tabacco straw charcoal after washing under the conditions of 60~80 DEG C of temperature drying, cross 60~80 mesh sieves, obtain being modified cigarette Careless straw charcoal；(12) bed mud of eutrophication water is taken, through being dehydrated, drying, crushing, crosses 60~80 mesh sieves；(13) the bed mud after screening and modified tabacco straw charcoal by volume 1:3 ratio mixing, obtains new adsorbent；(13) the uniform cloth of new adsorbent is spread in eutrophication water；(14) Sediments are excavated in the dry season, a part of bed mud gives over to making new adsorbent, largely transports landfill yard to Landfill, or burning disposal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710963562.XA CN107662958A (en) | 2017-10-17 | 2017-10-17 | A kind of eutrophied water treatment method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710963562.XA CN107662958A (en) | 2017-10-17 | 2017-10-17 | A kind of eutrophied water treatment method |
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Family
ID=61098587
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109464984A (en) * | 2018-10-23 | 2019-03-15 | 常州大学 | A kind of oriental plant branch processing method |
| CN111018035A (en) * | 2019-12-10 | 2020-04-17 | 常州大学 | Dehydration method of water body bottom mud |
| CN111807449A (en) * | 2020-07-17 | 2020-10-23 | 长沙理工大学 | Device and method for in-situ treatment of natural water pollution |
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| JP2931775B2 (en) * | 1995-06-27 | 1999-08-09 | 株式会社環研 | Meat fish processing wastewater treatment agent and treatment method |
| CN101780952A (en) * | 2010-03-26 | 2010-07-21 | 上海交通大学 | Method for preparing loading functional oxide porous carbon |
| CN102583618A (en) * | 2012-01-16 | 2012-07-18 | 浙江工业大学 | Technique for adsorbing organics in biomass wastewater by biomass carbon |
| CN103223330A (en) * | 2013-05-13 | 2013-07-31 | 中国林业科学研究院林产化学工业研究所 | Preparation method of special modified active carbon for removing mercury |
| CN105060579A (en) * | 2015-08-11 | 2015-11-18 | 安徽锦洋氟化学有限公司 | Advanced treatment method of fluoride-containing wastewater |
| CN105056902A (en) * | 2015-08-03 | 2015-11-18 | 四川农业大学 | Method for treatment of anionic pollutant containing wastewater with modified tobacco straw |
| CN106116071A (en) * | 2016-07-29 | 2016-11-16 | 张倩 | A kind of Methyl Benzene-o-dicarboxylate Contaminated Sewage Sludge inorganic agent and preparation method thereof |
| CN106477699A (en) * | 2016-12-23 | 2017-03-08 | 张伟荃 | A kind of Industrial Wastewater Treatment coagulant and preparation method thereof |
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2017
- 2017-10-17 CN CN201710963562.XA patent/CN107662958A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2931775B2 (en) * | 1995-06-27 | 1999-08-09 | 株式会社環研 | Meat fish processing wastewater treatment agent and treatment method |
| CN101780952A (en) * | 2010-03-26 | 2010-07-21 | 上海交通大学 | Method for preparing loading functional oxide porous carbon |
| CN102583618A (en) * | 2012-01-16 | 2012-07-18 | 浙江工业大学 | Technique for adsorbing organics in biomass wastewater by biomass carbon |
| CN103223330A (en) * | 2013-05-13 | 2013-07-31 | 中国林业科学研究院林产化学工业研究所 | Preparation method of special modified active carbon for removing mercury |
| CN105056902A (en) * | 2015-08-03 | 2015-11-18 | 四川农业大学 | Method for treatment of anionic pollutant containing wastewater with modified tobacco straw |
| CN105060579A (en) * | 2015-08-11 | 2015-11-18 | 安徽锦洋氟化学有限公司 | Advanced treatment method of fluoride-containing wastewater |
| CN106116071A (en) * | 2016-07-29 | 2016-11-16 | 张倩 | A kind of Methyl Benzene-o-dicarboxylate Contaminated Sewage Sludge inorganic agent and preparation method thereof |
| CN106477699A (en) * | 2016-12-23 | 2017-03-08 | 张伟荃 | A kind of Industrial Wastewater Treatment coagulant and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109464984A (en) * | 2018-10-23 | 2019-03-15 | 常州大学 | A kind of oriental plant branch processing method |
| CN111018035A (en) * | 2019-12-10 | 2020-04-17 | 常州大学 | Dehydration method of water body bottom mud |
| CN111807449A (en) * | 2020-07-17 | 2020-10-23 | 长沙理工大学 | Device and method for in-situ treatment of natural water pollution |
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Application publication date: 20180206 |