CN103215591B - Preparation method of imitated-metal enameled steel sheet - Google Patents
Preparation method of imitated-metal enameled steel sheet Download PDFInfo
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- CN103215591B CN103215591B CN201310045067.2A CN201310045067A CN103215591B CN 103215591 B CN103215591 B CN 103215591B CN 201310045067 A CN201310045067 A CN 201310045067A CN 103215591 B CN103215591 B CN 103215591B
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- imitative
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- steel plate
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 53
- 239000010959 steel Substances 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 22
- 239000002184 metal Substances 0.000 title claims abstract description 22
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 87
- 239000000375 suspending agent Substances 0.000 claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 20
- -1 sodium fluoroborate Chemical compound 0.000 claims abstract description 17
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004202 carbamide Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000498 ball milling Methods 0.000 claims abstract description 7
- 235000015895 biscuits Nutrition 0.000 claims abstract description 7
- 239000007921 spray Substances 0.000 claims abstract description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 15
- 229910052700 potassium Inorganic materials 0.000 claims description 15
- 239000011591 potassium Substances 0.000 claims description 15
- 229910001495 sodium tetrafluoroborate Inorganic materials 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 238000005034 decoration Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 abstract 2
- 238000005202 decontamination Methods 0.000 abstract 1
- 230000003588 decontaminative effect Effects 0.000 abstract 1
- 238000004534 enameling Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 6
- 229910052573 porcelain Inorganic materials 0.000 description 4
- 230000003670 easy-to-clean Effects 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
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Abstract
The invention relates to a preparation method of an imitated-metal enameled steel sheet. The prepared enameled steel sheet has the advantages of good mechanical properties, good heat resistance, excellent chemical stability, clean and gorgeous appearance, and easy cleaning and decontamination. The enameled steel sheet is suitable to be used in decorative enamel of building interior and exterior wall decorations and decorative enamel of public places such as tunnels and subways. The enameled steel sheet has good imitated metal effect. A production process of the enameled steel sheet comprises the steps that: a suspending agent, water, sodium fluoroborate, urea, and potassium fluorosilicate are added into a transparent base glaze; ball milling is carried out, such that a glaze slurry is obtained; imitated-metal powder is added into the glaze slurry, and the mixture is well mixed, such that an imitated-metal enamel glaze is obtained; the imitated-metal enamel glaze is sprayed on a biscuit by using a spray gun; and the material is fired under a temperature of 800-860 DEG C, such that the imitated-metal enameled steel sheet is obtained.
Description
Technical field
The present invention relates to a kind of preparation method of imitative metallic enamel steel plate, the imitative metallic enamel steel plate prepared has good mechanical property, good heat resistance, and chemical stability is excellent, and outward appearance is clean, magnificent, is easy to clean scrubbing.Be applicable to buildings decorating inner and external walls and the public place such as tunnel, subway decoration enamel.
Background technology
Enamel porcelain product and is also rear coated article, and it is a kind ofly given the functions such as its preservative property, resistance to chemical reagents and weather proofing by forming enamel layer on the surface at substrate steel sheet and improve the goods in steel plate life-span.Enamel porcelain product compared with precoating goods, though have the shortcomings such as manufacturing cost is expensive, it is all possessed of good qualities in hardness, weather proofing, detergency, thermotolerance and uninflammability etc.; Meanwhile, enamel porcelain products itself and is also had and highly suppress to pollute, can excellent chemical-resistant effect of restoring by cleaning.At present, be widely used in enameling sheet building curtain wall abroad and various upholstery work, also having nearly ten years in China is applicating history.
The thickness of enameling sheet is generally not more than 0.3mm, easily deforms in sintering process, causes its surface finish poor, during finishing material in addition as skin, can affect attractive in appearance.Meanwhile, the tension force unit elongation that enamel surfaces stands during bending machining is not less than 10%, and enamel layer is the glassiness that a kind of unit elongation is low, in any case the cracking of then unavoidable enamel layer.So enameling sheet only when meeting some basic demands, just stands bending machining, these requirements are exactly that enamel layer will stick on steel plate securely, even if this layer of cracking part can not cause at all get rusty.
Traditional enameling sheet has excellent bendability, enamel adherence, glossiness and erosion resistance, also has good stability, the advantages such as resistance to stripping simultaneously.But traditional enameling sheet outward appearance is graceful not, is not suitable for the application of some special occasions.
For this reason, have color and luster in the urgent need to developing a kind of surface, outward appearance is clean, magnificent, is applicable to the imitative metallic enamel steel plate of various applications.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of imitative metallic enamel steel plate, and enameling sheet prepared by the method has good mechanical property, good heat resistance, chemical stability is excellent, outward appearance is clean, magnificent, is easy to clean scrubbing, also has well imitative metal effect.
Above-mentioned technical problem of the present invention is implemented by the following technical programs: a kind of preparation method of imitative metallic enamel steel plate, is characterized in that: comprise the following steps:
(1) in transparent base glaze, add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride carry out ball milling and obtain glaze slip, control the fineness degree of glaze slip at 0.2g/100ml/150 order ~ 0.3g/100ml/150 order, glaze slip unit weight is at 165g/100ml ~ 170gml;
In glaze slip, add imitative metal powder mix, obtain imitative metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant spray gun is sprayed at biscuit, obtains imitative metallic enamel steel plate;
Under above-mentioned imitative metallic enamel steel plate is placed in 100 ~ 250 DEG C of temperature, dry 20 ~ 60min;
Again the imitative metallic enamel steel plate of drying is put into firing furnace, at 800 ~ 860 DEG C, fire 4 ~ 6min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 90 ~ 110 parts, transparent base glaze, suspension agent 6 ~ 8 parts, 40 ~ 50 parts, water, Sodium tetrafluoroborate 0.1 ~ 0.3 part, 0.3 ~ 0.7 part, urea, potassium silicofluoride 0.1 ~ 0.3 part, imitative metal powder 8 ~ 12 parts.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 95 ~ 105 parts, transparent base glaze, suspension agent 6.5 ~ 7.5 parts, 42 ~ 48 parts, water, Sodium tetrafluoroborate 0.15 ~ 0.25 part, 0.45 ~ 0.55 part, urea, potassium silicofluoride 0.15 ~ 0.25 part, imitative metal powder 9 ~ 11 parts.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 100 parts, transparent base glaze, suspension agent 7 parts, 45 parts, water, Sodium tetrafluoroborate 0.2 part, 0.5 part, urea, potassium silicofluoride 0.2 part, imitative metal powder 10 parts.
The preparation method of described imitative metallic enamel steel plate, described suspension agent is clay.
The preparation method of described imitative metallic enamel steel plate, the imitative metallic enamel frit particles thickness in described step (2) is 80 ~ 110 μm.
The preparation method of described imitative metallic enamel steel plate, the imitative metal powder stated has simulating golden colour powder, imitative silver color powder, imitation copper powder and artificial stainless steel toner.
In sum, the present invention compared with prior art tool have the following advantages and beneficial effect:
The present invention makes enameling sheet porcelain facing effect have metallic color, as gold, silver color, coppery, stainless steel etc.Have good mechanical property, good heat resistance, chemical stability is excellent, and outward appearance is clean, magnificent, is easy to clean scrubbing.
Embodiment
Below by embodiment, be described in further detail the technical scheme of invention, in these embodiments, unless otherwise indicated, all percentage compositions are all in mass parts:
Embodiment 1:
A preparation method for imitative metallic enamel steel plate, is characterized in that: comprise the following steps:
(1) in transparent base glaze, add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride carry out ball milling and obtain glaze slip, control the fineness degree of glaze slip at 0.2g/100ml/150 order, glaze slip unit weight is at 165g/100ml;
(2) in glaze slip, add imitative metal powder to mix, obtain imitative metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant spray gun is sprayed at biscuit, obtains imitative metallic enamel steel plate;
Under above-mentioned imitative metallic enamel steel plate is placed in 100 DEG C of temperature, dry 20min;
(3) the more imitative metallic enamel steel plate of drying is put into firing furnace, at 800 DEG C, fire 4min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 100 parts, transparent base glaze, suspension agent 7 parts, 45 parts, water, Sodium tetrafluoroborate 0.2 part, 0.5 part, urea, potassium silicofluoride 0.2 part, 10 parts, simulating golden colour powder.
Described suspension agent is clay.
Imitative metallic enamel frit particles thickness in described step (2) is 80 μm.
Simulating golden colour enameling sheet is obtained by aforesaid method.
Embodiment 2:
A preparation method for imitative metallic enamel steel plate, is characterized in that: comprise the following steps:
(1) in transparent base glaze, add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride carry out ball milling and obtain glaze slip, control the fineness degree of glaze slip at 0.3g/100ml/150 order, glaze slip unit weight is at 170g/ml;
(2) in glaze slip, add imitative metal powder to mix, obtain imitative metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant spray gun is sprayed at biscuit, obtains imitative metallic enamel steel plate;
Under above-mentioned imitative metallic enamel steel plate is placed in 250 DEG C of temperature, dry 60min;
(3) the more imitative metallic enamel steel plate of drying is put into firing furnace, at 860 DEG C, fire 4.5min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 110 parts, transparent base glaze, suspension agent 8 parts, 50 parts, water, Sodium tetrafluoroborate 0.3 part, 0.7 part, urea, potassium silicofluoride 0.3 part, imitative 12 parts, silver color powder.
Described suspension agent is clay.
Imitative metallic enamel frit particles thickness in described step (2) is 110 μm.
Imitative silver color enameling sheet is obtained by aforesaid method.
Embodiment 3:
A preparation method for imitative metallic enamel steel plate, is characterized in that: comprise the following steps:
(1) in transparent base glaze, add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride carry out ball milling and obtain glaze slip, control the fineness degree of glaze slip at 0.25g/100ml/150 order, glaze slip unit weight is at 168g/100ml;
(2) in glaze slip, add imitative metal powder to mix, obtain imitative metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant spray gun is sprayed at biscuit, obtains imitative metallic enamel steel plate;
Under above-mentioned imitative metallic enamel steel plate is placed in 200 DEG C of temperature, dry 40min;
(3) the more imitative metallic enamel steel plate of drying is put into firing furnace, at 820 DEG C, fire 5min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 90 parts, transparent base glaze, suspension agent 6 parts, 40 parts, water, Sodium tetrafluoroborate 0.1 part, 0.3 part, urea, potassium silicofluoride 0.1 part, 8 parts, imitation copper powder.
Described suspension agent is clay.
Imitative metallic enamel frit particles thickness in described step (2) is 80 μm.
Imitation copper enameling sheet is obtained by aforesaid method.
Embodiment 4:
A preparation method for imitative metallic enamel steel plate, is characterized in that: comprise the following steps:
(1) in transparent base glaze, add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride carry out ball milling and obtain glaze slip, control the fineness degree of glaze slip at 0.2g/100ml/150 order, glaze slip unit weight is at 165g/100ml;
(2) in glaze slip, add imitative metal powder to mix, obtain imitative metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant spray gun is sprayed at biscuit, obtains imitative metallic enamel steel plate;
Under above-mentioned imitative metallic enamel steel plate is placed in 150 DEG C of temperature, dry 50min;
(3) the more imitative metallic enamel steel plate of drying is put into firing furnace, at 840 DEG C, fire 4.5min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 95 parts, transparent base glaze, suspension agent 6.5 parts, 42 parts, water, Sodium tetrafluoroborate 0.15 part, 0.45 part, urea, potassium silicofluoride 0.15 part, artificial stainless steel toner 9 parts.
Described suspension agent is clay.
Imitative metallic enamel frit particles thickness in described step (2) is 90 μm.
Artificial stainless steel colour enameling sheet is obtained by aforesaid method.
To producing the simulating golden colour enameling sheet obtained, imitative silver color enameling sheet, imitation copper enameling sheet, artificial stainless steel colour enameling sheet carry out testing performance index: under the four kinds of enameling sheets above-mentioned production obtained are placed on 540 DEG C of temperature, thermostatically heating 30 minutes, is cooled to room temperature; Above-mentioned steps carries out 5 times repeatedly.
Testing performance index contrast table is as follows:
Through performance is tested us and is found, imitative metallic enamel does not weaken in performance relative to common enamel, and partial properties also promotes to some extent, and has imitative metal effect, more attractive in appearance in appearance, magnificent, be applicable to buildings decorating inner and external walls and the public place such as tunnel, subway decoration enamel.
Claims (5)
1. a preparation method for imitative metallic enamel steel plate, is characterized in that: comprise the following steps:
(1) in transparent base glaze, add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride carry out ball milling and obtain glaze slip, control the fineness degree of glaze slip at 0.2g/100ml/150 order ~ 0.3 g/100ml/150 order, glaze slip unit weight is at 165g/100ml ~ 170g/ml;
(2) in glaze slip, add imitative metal powder to mix, obtain imitative metallic enamel glaze;
(3) above-mentioned imitative metallic enamel glaze spray gun is sprayed at biscuit, obtain imitative metallic enamel steel plate;
(4), under above-mentioned imitative metallic enamel steel plate being placed in 100 ~ 250 DEG C of temperature, 20 ~ 60min is dried;
(5) the more imitative metallic enamel steel plate of drying is put into firing furnace, at 800 ~ 860 DEG C, fire 4 ~ 6min;
Described imitative metallic enamel glaze is made up of the compound of following mass parts:
95 ~ 105 parts, transparent base glaze, suspension agent 6.5 ~ 7.5 parts, 42 ~ 48 parts, water, Sodium tetrafluoroborate 0.15 ~ 0.25 part, 0.45 ~ 0.55 part, urea, potassium silicofluoride 0.15 ~ 0.25 part, imitative metal powder 9 ~ 11 parts.
2. the preparation method of imitative metallic enamel steel plate according to claim 1, is characterized in that, described imitative metallic enamel glaze is made up of the compound of following mass parts:
100 parts, transparent base glaze, suspension agent 7 parts, 45 parts, water, Sodium tetrafluoroborate 0.2 part, 0.5 part, urea, potassium silicofluoride 0.2 part, imitative metal powder 10 parts.
3. the preparation method of imitative metallic enamel steel plate according to claim 1 and 2, is characterized in that, described suspension agent is clay.
4. the preparation method of imitative metallic enamel steel plate according to claim 1, is characterized in that, the imitative metallic enamel frit particles thickness in described step (2) is 80 ~ 110 μm.
5. the preparation method of imitative metallic enamel steel plate according to claim 1 and 2, is characterized in that, described imitative metal powder has simulating golden colour powder, imitative silver color powder, imitation copper powder and artificial stainless steel toner.
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| CN201310045067.2A CN103215591B (en) | 2013-02-01 | 2013-02-01 | Preparation method of imitated-metal enameled steel sheet |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105271751B (en) * | 2015-10-16 | 2017-10-17 | 湖南天欣科技股份有限公司 | A kind of Antiskid ceramic tile high temperature glaze and its production method and methods for using them |
| CN105271752B (en) * | 2015-10-16 | 2018-11-09 | 浙江开尔新材料股份有限公司 | A kind of preparation method of low gloss colour enamel glaze |
| CN105695994A (en) * | 2016-03-01 | 2016-06-22 | 吴申龙 | Nano-ceramic technology for inner wall of stainless steel |
| CN108423992B (en) * | 2018-05-28 | 2021-01-15 | 浙江开尔新材料股份有限公司 | Process for producing enameled steel plate with cobblestone-imitated concave-convex surface |
| CN110372208B (en) * | 2019-07-02 | 2021-12-31 | 浙江开尔新材料股份有限公司 | Enamel glaze slip capable of releasing negative ions and method for preparing negative ion enamel plate by using enamel glaze slip |
| CN112062469B (en) * | 2020-08-28 | 2022-06-03 | 浙江开尔新材料股份有限公司 | Bottom glaze material of stainless steel enamel plate and preparation method and application thereof |
| CN112573825A (en) * | 2020-11-24 | 2021-03-30 | 杭州方泰搪瓷制品有限公司 | Enamel cover glaze slip and preparation method thereof |
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| CN102086091A (en) * | 2010-07-08 | 2011-06-08 | 石家庄正中科技有限公司 | Surface glaze, white enamel and preparation method thereof |
| CN102181862A (en) * | 2011-04-12 | 2011-09-14 | 浙江开尔新材料股份有限公司 | Preparation method of enameled steel sheet |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6716490B2 (en) * | 2002-01-30 | 2004-04-06 | Kawasaki Steel Metal Products & Engineering Inc. | Method for making enameled steel sheet |
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- 2013-02-01 CN CN201310045067.2A patent/CN103215591B/en active Active
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|---|---|---|---|---|
| CN101255067A (en) * | 2007-12-28 | 2008-09-03 | 冼金源 | Preparation method of metal-imitation glaze |
| CN102086091A (en) * | 2010-07-08 | 2011-06-08 | 石家庄正中科技有限公司 | Surface glaze, white enamel and preparation method thereof |
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Denomination of invention: A Preparation Method of Imitation Metal Enamel Steel Plate Effective date of registration: 20230901 Granted publication date: 20150527 Pledgee: China Co. truction Bank Corp Jinhua branch Pledgor: ZHEJIANG KAIER NEW MATERIALS Co.,Ltd. Registration number: Y2023980054829 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20150527 Pledgee: China Co. truction Bank Corp Jinhua branch Pledgor: ZHEJIANG KAIER NEW MATERIALS Co.,Ltd. Registration number: Y2023980054829 |