CN107603199A - A kind of good wear-resisting type bubble wrap box of compressive property and its production technology - Google Patents
A kind of good wear-resisting type bubble wrap box of compressive property and its production technology Download PDFInfo
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- CN107603199A CN107603199A CN201710903441.6A CN201710903441A CN107603199A CN 107603199 A CN107603199 A CN 107603199A CN 201710903441 A CN201710903441 A CN 201710903441A CN 107603199 A CN107603199 A CN 107603199A
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- good wear
- resisting type
- compressive property
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Abstract
A kind of good wear-resisting type bubble wrap box of compressive property and its production technology, including each component of following parts by weight are prepared:50 90 parts of poly methylene poly phenyl poly isocyanate, 10 60 parts of PPG, 5 15 parts of triacetin, 3 17 parts of blanc fixe, 5 19 parts of chlorosulfonated polyethylene, 5 10 parts of coconut palm chaff, 3 13 parts of modified montmorillonoid, 10 18 parts of polyacrylamide, 28 parts of sodium carboxymethyl starch, 58 parts of ethoxylated dodecyl alcohol, 15 parts of paraffin etc..The present invention is light, intensity is high, absorbable impact loads property is good, heat-insulated, sound insulation value is good, ventilative, can be in the field extensive use such as industry, agricultural, building, communications and transportation.
Description
Technical field
The present invention relates to a kind of good wear-resisting type bubble wrap box of compressive property and its production technology, belong to foamed plastics
Packing box technical field.
Background technology
Foamed plastics is a kind of high polymer material formed by a large amount of gas micropore dispersions in solid plastic, has matter
The characteristics such as gently, heat-insulated, sound-absorbing, damping, and dielectric properties are better than matrix resin, have many uses;Almost various plastics can be made
Foamed plastics, foaming turn into a key areas in plastic processing.
Foamed plastics is integrally covered with countless interconnect or mutually disconnected micropore and the modeling that makes apparent density substantially reduce
Material, there is light, adiabatic, sound-absorbing, shockproof, moisture resistance, corrosion-resistant.Foamed plastics is using plastics as solvent and contained
The polymeric material of a large amount of bubbles, therefore could also say that the composite plastic using gas as filler.
In the market there is hardness height in the foamed plastics for electric equipment products packaging, flexibility is poor, matter is heavy, adiabatic effect
The defects of fruit is poor, air permeable effect is bad, anti-seismic performance is short of, anticorrosion effect is bad.
The content of the invention
The purpose of the present invention is to be directed to above-mentioned the deficiencies in the prior art, there is provided a kind of good wear-resisting type foamed plastics of compressive property
Packing box and its production technology.
Technical scheme is as follows:A kind of good wear-resisting type bubble wrap box of compressive property, it is characterized in that, including
The each component of following parts by weight is prepared:Poly methylene poly phenyl poly isocyanate 50-90 parts, PPG 10-60 parts,
Triacetin 5-15 parts, blanc fixe 3-17 parts, chlorosulfonated polyethylene 5-19 parts, coconut palm chaff 5-10 parts, modified montmorillonoid 3-
13 parts, polyacrylamide 10-18 parts, sodium carboxymethyl starch 2-8 parts, ethoxylated dodecyl alcohol 5-8 parts, paraffin 1-5 parts, tristearin
Sour calcium 5-8 parts, soya bean protein powder 10-20 parts, initiator 15-25 parts, glass fibre 3-8 parts, maleic anhydride 3-8 parts, isopentane
1-5 parts, stabilizer 1-5 parts, foaming agent 15-25 parts, age resister 1-8 parts, boric acid 5-12 parts, crosslinking agent 1-3 parts.
The stabilizer is organic tin stabilizer.
The initiator is dibenzoyl peroxide.
The crosslinking agent is Methacrylamide.
The foaming agent is azodicarbonamide.
A kind of production technology of the good wear-resisting type bubble wrap box of compressive property, it is characterized in that, plastics materials are heated
Into molten condition, by strong agitation, large quantity of air or other gases are introduced into liquid plastic, produce micropore;Make micropore
Rise to certain volume;Leftover materials are put into, continues to stir and heats 30-300 minutes;Then all materials are put into injection moulding
In machine, foaming agent decomposes in machine barrel, and when material leaves head, pressure drops to normal pressure, and it is i.e. expanded foamed to dissolve in gas, finally
To the foamed product.
PPG(Abbreviation polyethers)It is by initiator(Compound containing active hydrogen group)With oxirane(EO), ring
Ethylene Oxide(PO), epoxy butane(BO)Deng being made in the presence of a catalyst through sudden reaction.Polyethers yield the maximum is with glycerine
(Glycerine)Make initiator and epoxides(Usually PO and EO is used in combination), by the feed way for changing PO and EO(Mixing adds
Or separately add), dosage ratio, the charging condition such as order, produce various general PPGs.
Polyphenyl polymethylene polyisocyanates, light yellow to brown viscous liquid, irritant smell, it can send out during heating
Poly- effect is born from, is dissolved in chlorobenzene, o-dichlorohenzene, toluene etc..PAPI's is active low, and steam forces down, simply 1 the percent of TDI,
Therefore toxicity is very low.It for manufacturing polyurethane glue stick, can also be directly added into rubber based adhesives, improve rubber and nylon or polyester
The adhesive property of line.In the storehouse for be stored in shady and cool, ventilation, drying, away from kindling material, thermal source.
Chlorosulfonated polyethylene is made by low density polyethylene (LDPE) or high density polyethylene (HDPE) through superchlorination and chlorosulfonation.To be white
Color or yellow elastic body, aromatic hydrocarbon and chlorohydrocarbon can be dissolved in insoluble in fat and alcohol, can only be swelled in ketone and ether can not
Dissolving, there is excellent ozone resistance, resistance to weathering, chemical resistance etc., preferable physical and mechanical properties, resistance to ag(e)ing
Energy, heat-resisting and lower temperature resistance, oil resistivity, flame resistance, wearability and resistance to electrical insulating property.
Compared with the foamed plastics of existing electrical package, the present invention has many excellent performances:It is light, intensity is high,
Absorbable impact loads property is good, heat-insulated, sound insulation value is good, ventilative, also can be in the field such as industry, agricultural, building, communications and transportation
Extensive use.
Embodiment
A kind of good wear-resisting type bubble wrap box of compressive property, including each component of following parts by weight are prepared:It is more
Polymethylene polyphenyl polyisocyanates 50-90 parts, PPG 10-60 parts, triacetin 5-15 parts, blanc fixe 3-
17 parts, chlorosulfonated polyethylene 5-19 parts, coconut palm chaff 5-10 parts, modified montmorillonoid 3-13 parts, polyacrylamide 10-18 parts, carboxymethyl
Sodium starch 2-8 parts, ethoxylated dodecyl alcohol 5-8 parts, paraffin 1-5 parts, calcium stearate 5-8 parts, soya bean protein powder 10-20 parts,
Initiator 15-25 parts, glass fibre 3-8 parts, maleic anhydride 3-8 parts, isopentane 1-5 parts, stabilizer 1-5 parts, foaming agent 15-25
Part, age resister 1-8 parts, boric acid 5-12 parts, crosslinking agent 1-3 parts.
Stabilizer is organic tin stabilizer, and initiator is dibenzoyl peroxide, and crosslinking agent is Methacrylamide, foaming
Agent is azodicarbonamide.
Plastics materials are heated to molten condition by a kind of production technology of the good wear-resisting type bubble wrap box of compressive property
In, by strong agitation, large quantity of air or other gases are introduced into liquid plastic, produce micropore;Micropore is set to rise to necessarily
Volume;Leftover materials are put into, continues to stir and heats 30-300 minutes;Then all materials are put into injection (mo(u)lding) machine, foaming
Agent is decomposed in machine barrel, and when material leaves head, pressure drops to normal pressure, and it is i.e. expanded foamed to dissolve in gas, finally obtains the foam
Product.
Claims (6)
1. a kind of good wear-resisting type bubble wrap box of compressive property, it is characterized in that, include each component preparation of following parts by weight
Form:Poly methylene poly phenyl poly isocyanate 50-90 parts, PPG 10-60 parts, triacetin 5-15 parts, sulphur
Sour barium powder 3-17 parts, chlorosulfonated polyethylene 5-19 parts, coconut palm chaff 5-10 parts, modified montmorillonoid 3-13 parts, polyacrylamide 10-18
Part, sodium carboxymethyl starch 2-8 parts, ethoxylated dodecyl alcohol 5-8 parts, paraffin 1-5 parts, calcium stearate 5-8 parts, soya bean protein powder
10-20 parts, initiator 15-25 parts, glass fibre 3-8 parts, maleic anhydride 3-8 parts, isopentane 1-5 parts, stabilizer 1-5 parts, hair
Infusion 15-25 parts, age resister 1-8 parts, boric acid 5-12 parts, crosslinking agent 1-3 parts.
2. the good wear-resisting type bubble wrap box of a kind of compressive property according to claim 1, it is characterized in that, the stabilization
Agent is organic tin stabilizer.
3. the good wear-resisting type bubble wrap box of a kind of compressive property according to claim 1, it is characterized in that, the initiation
Agent is dibenzoyl peroxide.
4. the good wear-resisting type bubble wrap box of a kind of compressive property according to claim 1, it is characterized in that, the crosslinking
Agent is Methacrylamide.
5. the good wear-resisting type bubble wrap box of a kind of compressive property according to claim 1, it is characterized in that, the foaming
Agent is azodicarbonamide.
A kind of 6. production of the good wear-resisting type bubble wrap box of compressive property according to any one of claim 1-5
Technique, it is characterized in that, plastics materials are heated in molten condition, by strong agitation, large quantity of air or other gases drawn
Enter in liquid plastic, produce micropore;Micropore is set to rise to certain volume;Leftover materials are put into, continue to stir and heat 30-300
Minute;Then all materials are put into injection (mo(u)lding) machine, and foaming agent decomposes in machine barrel, and when material leaves head, pressure drops to
Normal pressure, it is i.e. expanded foamed to dissolve in gas, finally obtains the foamed product.
Priority Applications (1)
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CN201710903441.6A CN107603199A (en) | 2017-09-29 | 2017-09-29 | A kind of good wear-resisting type bubble wrap box of compressive property and its production technology |
Applications Claiming Priority (1)
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CN201710903441.6A CN107603199A (en) | 2017-09-29 | 2017-09-29 | A kind of good wear-resisting type bubble wrap box of compressive property and its production technology |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104341573A (en) * | 2013-08-07 | 2015-02-11 | 上海抚佳精细化工有限公司 | Polyurethane foam plastic and preparation method thereof |
CN106279634A (en) * | 2016-09-06 | 2017-01-04 | 南京大学 | A kind of high-strength anti-flaming hard polyaminoester insulation material for building and preparation method thereof |
CN106317364A (en) * | 2015-07-02 | 2017-01-11 | 青岛农业大学 | Peanut-shell filled polyurethane foamed plastic and preparation method thereof |
CN106366614A (en) * | 2016-09-08 | 2017-02-01 | 广西南宁桂尔创环保科技有限公司 | Novel environment-friendly foam plastic |
CN106832209A (en) * | 2017-01-23 | 2017-06-13 | 山东诺威新材料有限公司 | VHD high-strength polyurethane sprayed on material and its preparation method and application |
-
2017
- 2017-09-29 CN CN201710903441.6A patent/CN107603199A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104341573A (en) * | 2013-08-07 | 2015-02-11 | 上海抚佳精细化工有限公司 | Polyurethane foam plastic and preparation method thereof |
CN106317364A (en) * | 2015-07-02 | 2017-01-11 | 青岛农业大学 | Peanut-shell filled polyurethane foamed plastic and preparation method thereof |
CN106279634A (en) * | 2016-09-06 | 2017-01-04 | 南京大学 | A kind of high-strength anti-flaming hard polyaminoester insulation material for building and preparation method thereof |
CN106366614A (en) * | 2016-09-08 | 2017-02-01 | 广西南宁桂尔创环保科技有限公司 | Novel environment-friendly foam plastic |
CN106832209A (en) * | 2017-01-23 | 2017-06-13 | 山东诺威新材料有限公司 | VHD high-strength polyurethane sprayed on material and its preparation method and application |
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Application publication date: 20180119 |