CN107603101A - A kind of damage resistant bloom exempts from mould proof ABS/PMMA materials of spray antimicrobial and preparation method thereof - Google Patents
A kind of damage resistant bloom exempts from mould proof ABS/PMMA materials of spray antimicrobial and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of damage resistant bloom to exempt from mould proof ABS/PMMA materials of spray antimicrobial and preparation method thereof.The ABS/PMMA materials are made up of the raw material of following mass percent：ABS resin 34~60%, PMMA resins 30~50%, toughener 4~10%, organic-inorganic nanocomposite antibacterial and mouldproof master batch 0.5~2%, dispersant 0.5~2%, stabilizer 0.5~2%.Also disclose that a kind of damage resistant bloom exempts from the preparation method of the mould proof ABS/PMMA materials of spray antimicrobial simultaneously.Present invention uses organic-inorganic nanocomposite antibacterial and mouldproof master batch, ABS/PMMA materials is had the characteristics such as organic antibacterial mildew inhibitor wide spectrum, efficient bactericidal property and safe, the long-acting and heatproof of inorganic antimicrobial mildew preventive agent concurrently, while antibacterial and mouldproof composition is supported on the time that can effectively extend antibacterial and mouldproof is slowly discharged on the shimmering powders such as pearl essence.The material can be a kind of safe and healthy, good appearance, long-lived functional material extensively using fields such as the household electrical appliance, Household sanitary, telecommunications with direct body contact.
Description
Technical field
The present invention relates to a kind of damage resistant bloom to exempt from mould proof ABS/PMMA materials of spray antimicrobial and preparation method thereof.
Background technology
Harmful microorganism is widely distributed in nature, and species is various and substantial amounts, the health of serious threat people.With
The development and the improvement of people's living standards of social and economic level, requirement of the people to the understanding and daily necessities of living environment
More and more higher.The product category with direct body contact such as household electrical appliance used in everyday, sanitaryware, communication apparatus, automobile
Various, people inevitably touch the pathogenic bacteria for being attached to these product surfaces, so as to cause various health problems.Cause
This antibacterial and mouldproof material is arisen at the historic moment, and antibacterial and mouldproof material is to add antibacterial mildew inhibitor in the plastic, is caused so as to kill or suppress
Its route of transmission is propagated in growth, breeding and the cut-out of germ.
People do not only have the requirement of security to products such as household electrical appliance, sanitaryware, communication apparatus, to the outward appearance of material
And durability it is also proposed higher and higher requirement.Because ABS material lustrous surface is preferable, rigidity height, dimensionally stable, easy processing
The features such as, widely apply in many products.But nowadays Washing Machine Panel, television enclosure, air-conditioning panel and toilet lid etc. are permitted
Multi-product not only proposes higher requirement to the outer light gloss of ABS material, damage resistant, Anti- tarnishing, environmental protection, exempt from spraying etc. side
Face it is also proposed the process such as new requirement, the spray painting during common ABS uses and not only pollute environment, the recycling to material
Also there is detrimental effect.
The content of the invention
It is an object of the invention to provide a kind of damage resistant bloom to exempt from the mould proof ABS/PMMA materials of spray antimicrobial and its preparation
Method.
The technical solution used in the present invention is：
A kind of damage resistant bloom exempts from the mould proof ABS/PMMA materials of spray antimicrobial, is made up of the raw material of following mass percent：
ABS resin 34~60%, PMMA resins 30~50%, toughener 4~10%, organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch
0.5~2%, dispersant 0.5~2%, stabilizer 0.5~2%.
Melt index of the ABS resin under 220 DEG C, 10kg is more than 20g/10min；Butadiene content is in ABS resin
10wt%~40wt%.
The surface pencil hardness of PMMA resins is more than 2H, and Rockwell hardness R levels are more than 108.
Toughener is at least one of high glue powder, MBS, ACR, EVA, SEBS, SBS, POE.
In organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch, the mould proof composition of organic anti-bacterial is in quaternary ammonium salt or quaternary alkylphosphonium salt
At least one, and its backbone c atoms number is between 10-16；Inorganic anti-bacterium mildewproof composition is nano-silver ionic or nanometer zinc ion
At least one of antiseptic；The diameter of carrier of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is 10~150 μm.
The preparation method of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is：First by carrier, inorganic antimicrobial mildew preventive agent, have
Machine antibacterial mildew inhibitor, hyper-dispersant and coupling agent in mass ratio 70：20：10：(0.3~0.5)：0.1 premix, then by the pre- of gained
Mixed thing, antioxidant and ABS resin in mass ratio 25：(0.1~0.3)：75 mixing, it is extruded, it is granulated, it is mould proof obtains composite antibacterial
Master batch.
Carrier is pearl essence or aluminium powder, and hyper-dispersant TAS-2A, coupling agent is silane coupler.
Dispersant is at least one of PETS, TAF, silicone powder.
Stabilizer is the mixture that antioxidant and light stabilizer form.
A kind of damage resistant bloom exempts from the preparation method of the mould proof ABS/PMMA materials of spray antimicrobial, and original is weighed by above-mentioned composition
Material, first ABS resin, PMMA resins and toughener are premixed, add organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch, disperse
Agent and stabilizer continue to mix, and then by extrusion, granulation, obtain damage resistant bloom and exempt from the mould proof ABS/PMMA materials of spray antimicrobial
Material.
The beneficial effects of the invention are as follows：
Present invention uses organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch, ABS/PMMA materials are made to have organic anti-bacterial concurrently
The characteristics such as mould inhibitor wide spectrum, efficient bactericidal property and safe, the long-acting and heatproof of inorganic antimicrobial mildew preventive agent, while by antibacterial and mouldproof
Composition is supported on the time for slowly being discharged on the shimmering powders such as pearl essence and can effectively extending antibacterial and mouldproof.The material can extensively using with people
The fields such as household electrical appliance that body directly contacts, Household sanitary, telecommunications, it is a kind of safe and healthy, good appearance, durable in use
Functional material.
Specifically：
1st, the present invention selects organic-inorganic hybrid nanocomposite antibacterial mildew inhibitor, and this antibacterial mildew inhibitor has wide spectrum, height simultaneously
Effect, ageing length, it is heat-resist the features such as, small scale addition i.e. reach other antibacterial mildew inhibitors antibacterial and mouldproof effect, property
Valency is higher.The mould proof composition of complex antimicrobials is loaded to by the shimmering powder class pearly-lustre face such as pearl essence or aluminium powder using coupling agent simultaneously
Material, slowly release antibacterial and mouldproof composition, effectively extension antibacterial and mouldproof are ageing again during product use.Pearlescent pigment passes through pre-
Master batch is made in processing, can improve the dispersiveness of pearlescent material, the defects of reducing the current mark in injection molding, improves material appearance effect
Fruit, the pollution of spraying process is reduced, reduce the integrated cost of material production.
2nd, this antibacterial and mouldproof bloom damage resistant ABS/PMMA alloy material, glossiness, scratch resistant performance are excellent, are suitable as
The higher home electric appliance material of appearance requirement, household bathroom accessories, telecommunications etc., it can especially be washed with direct body contact
The products such as clothing machine side plate, housing of TV set, toilet backrests, suppress the growth and breeding of its surface microorganism, protect people from disease
Bacterium is infected.Because its case hardness is high, scratch resistance is good, will not also surface tear be caused to influence during daily cleaning wipes
Product is attractive in appearance and image product.
Embodiment
A kind of damage resistant bloom exempts from the mould proof ABS/PMMA materials of spray antimicrobial, is made up of the raw material of following mass percent：
ABS resin 34~60%, PMMA resins 30~50%, toughener 4~10%, organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch
0.5~2%, dispersant 0.5~2%, stabilizer 0.5~2%.
Preferably, melt index of the ABS resin under 220 DEG C, 10kg is more than 20g/10min；Butadiene contains in ABS resin
Measure as 10wt%~40wt%.
Preferably, the surface pencil hardness of PMMA resins is more than 2H, and Rockwell hardness R levels are more than 108.
Preferably, toughener is at least one of high glue powder, MBS, ACR, EVA, SEBS, SBS, POE.
In organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch, the mould proof composition of organic anti-bacterial is in quaternary ammonium salt or quaternary alkylphosphonium salt
At least one, and its backbone c atoms number is between 10-16；Inorganic anti-bacterium mildewproof composition is nano-silver ionic or nanometer zinc ion
At least one of antiseptic；The diameter of carrier of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is 10~150 μm.
The preparation method of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is：First by carrier, inorganic antimicrobial mildew preventive agent, have
Machine antibacterial mildew inhibitor, hyper-dispersant and coupling agent in mass ratio 70：20：10：(0.3~0.5)：0.1 premix, then by the pre- of gained
Mixed thing, antioxidant and ABS resin in mass ratio 25：(0.1~0.3)：75 mixing, it is extruded, it is granulated, it is mould proof obtains composite antibacterial
Master batch.
Preferably, carrier is pearl essence or aluminium powder, and hyper-dispersant TAS-2A, coupling agent is silane coupler.Described
Silane coupler can be selected from least one of KH550, KH560, KH570, KH792, DL602, DL171.
Preferably, at least one of dispersant PETS, TAF, silicone powder.
Preferably, stabilizer is the mixture that antioxidant and light stabilizer form；It is further preferred that stabilizer is to be obstructed
The mixing of phenolic antioxidant, phosphite ester kind antioxidant, Benzotriazole Ultraviolet Stabilizer, hindered amine light stabilizer composition
Thing；Still further preferably, stabilizer is antioxidant 1076, irgasfos 168, ultraviolet absorber UV-P, HALS light stabilizer amine
Mass ratio 1：(0.4~0.6)：(0.8~1.2)：(0.4~0.6) mixture of composition.
A kind of damage resistant bloom exempts from the preparation method of the mould proof ABS/PMMA materials of spray antimicrobial, and original is weighed by above-mentioned composition
Material, first ABS resin, PMMA resins and toughener are premixed, add organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch, disperse
Agent and stabilizer continue to mix, and then by extrusion, granulation, obtain damage resistant bloom and exempt from the mould proof ABS/PMMA materials of spray antimicrobial
Material.
Further, in preparation method, extrude and extruded in double screw extruder；Preferably, the main frame of double screw extruder
Rotating speed is 250r/min~500r/min, and the processing temperature of double screw extruder is 220 DEG C~250 DEG C.
It is slow bactericidal action to be present in the inorganic antimicrobial mildew preventive agent that ABS and its alloy material mainly use at present, expensive
And the shortcomings of acting on fungi unrestraint；Organic anti-bacterial mould inhibitor poor heat resistance, antimicrobial lifetime is short, and exists and ooze out risk.This
The pearlescent materials such as pearl essence or aluminium powder are used to prevent the inorganic antibacterials such as nano-silver ionic, nanometer zinc ion as carrier in invention
The organic anti-bacterial mould inhibitors such as mould composition and quaternary ammonium salt or quaternary alkylphosphonium salt load to the pearlescent materials such as pearl essence or aluminium powder by coupling agent
Surface, by double-screw extruding pelletizing, obtain compound pearly-lustre antibacterial and mouldproof master batch.
Organic anti-bacterial mould inhibitor quaternary ammonium salt or quaternary alkylphosphonium salt have wide spectrum, bactericidal effect efficiently, less toxic, its Antibacterial Mechanism master
If the cell membrane surface anion binding with thalline, or reacted with sulfydryl, the synthesis system of protein or cell membrane is destroyed, from
And suppress the breeding of bacterium and mould.Its antibacterial and mouldproof activity acceptor's alkyl group carbon number has a great influence, and research shows carbon
Atomicity is weaker higher than 16 antibacterial and mouldproof effects less than 10, therefore, the present invention preferably backbone c atoms number season between 10-16
Ammonium salt or quaternary alkylphosphonium salt, preferable phosphorus atoms radius is bigger, and polarization is stronger, and quaternary alkylphosphonium salt is easier to adsorb negatively charged bacterium
Body.Nano inorganic antibacterial mildew inhibitor has the advantages that heat-resist, the term of validity is long, and its antibacterial and mouldproof mechanism such as silver-ion antibiotic is prevented
Mould dose, mainly by discharging Ag+Contacted with thalline, the latter carries negative electrical charge meeting and Ag+Mutually adsorb, silver ion and sulfydryl in cell
Deng radical reaction, the protein synthesis of ring thalline is broken, destroys the energetic supersession activity of bacterium so as to reach fungistatic effect.It is although silver-colored
Ion antibacterial mould inhibitor positive effect, but its is expensive, and zinc ion antibacterial mildew inhibitor is cheap, mould proof with silver-ion antibiotic
Agent compounding reduces the cost of antibacterial mildew inhibitor while can reaching lifting antibacterial effect.The ABS/PMMA alloy materials of the present invention
After organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is added, antibacterial and mouldproof composition is slowly discharged in use, can be effective
The extension antibacterial and mouldproof life-span.This antibacterial mildew inhibitor have organic anti-bacterial mould inhibitor wide spectrum, it is efficient the advantages of, while also have
Inorganic antimicrobial mildew preventive agent is heat-resisting, long lifespan and it is safe the advantages that, can reach permanently effective antibacterial and mouldproof effect.Pearl essence passes through
The dispersiveness of pearl essence can be improved in use by pre-processing the master batch being prepared into, and can effectively reduce current mark phenomenon, enhancing production
Product outward appearance, improve product texture.
Present disclosure is described in further detail below by way of specific embodiment.
Embodiment：
Antibacterial and mouldproof effect proposed by the present invention according to《Antibiotic plastic-Anti-microbial Performance Tests method and antibacterial effect》Regulation
Method tested, the strain that uses of antibiotic rate test is staphylococcus aureus and Escherichia coli.Antibiotic rate is according to formula
(1) calculate：
R=(B-C)/B × 100 ... ... ... ... ... ... ... ... (1)
R：Antibiotic rate (%)；
B：The average bacterial count recovered (cfu/ pieces) of blank control sample；
C：Antibiotic plastic sample average bacterial count recovered (cfu/ pieces).
The mold species that mould proof level estimate uses are aspergillus niger, paecilomyces varioti, Chaetomium globosum, Aureobasidium pullulans, fly
One or more in shape mould and Aspergillus terreus.
Sample fungi-growth grade：
0 grade：Do not grow, i.e., observed under microscope (50 times) and have no growth；
1 grade：Vestige grows, i.e. naked eyes visible growth, but grows area coverage and be less than 10%；
2 grades：Grow area and be not less than 10%.
Table 1 show the raw material composition and test result of embodiment 1~4 and comparative example 1~2.
Melt index of the ABS resin that the present invention uses under 220 DEG C, 10kg is more than 20g/10min；Fourth in ABS resin
Diene content is more than one or both of 10wt%~40wt%, such as ABS 8391, ABS HP181, ABS MG94 ABS
Mixture.
The surface pencil hardness for the PMMA resins that the present invention uses is more than 2H, and Rockwell hardness R levels are more than 108, such as PMMA
More than one or both of PMMA such as LG2, PMMA CM-211, PMMA VH001 mixture.
One kind or two in the toughener such as toughener high glue powder HR181 that the present invention uses, MBS EM500, MBS M-701
The mixture of the kind above.
The organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch that the present invention uses, the mould proof composition of organic anti-bacterial be quaternary ammonium salt or
At least one of quaternary alkylphosphonium salt, and its backbone c atoms number is between 10-16；Inorganic anti-bacterium mildewproof composition be nano-silver ionic or
At least one of Nano-Zinc ion antibacterial agent；The carrier of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is pearl essence or aluminium
Powder, diameter of carrier are 10~150 μm；The preparation method of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is：First by carrier, nothing
Machine antibacterial mildew inhibitor, organic anti-bacterial mould inhibitor, hyper-dispersant and coupling agent in mass ratio 70：20：10：(0.3~0.5)：0.1 is pre-
It is mixed, then the pre-composition, antioxidant and ABS resin in mass ratio 25 by gained：(0.1~0.3)：75 mixing, it is extruded, it is granulated,
The mould proof master batch of composite antibacterial is obtained, wherein hyper-dispersant is TAS-2A, and coupling agent is silane coupler.
The dispersant that the present invention uses is at least one of PETS, TAF, silicone powder.
The mixture that the stabilizer that the present invention uses forms for antioxidant and light stabilizer, preferably antioxidant 1076,
Irgasfos 168, ultraviolet absorber UV-P, HALS light stabilizer amine mass ratio 1：(0.4~0.6)：(0.8~1.2)：(0.4~
0.6) mixture of composition.
According to table 1 formula by above-mentioned ABS resin, PMMA resins and toughener be proportionally added into batch mixer premix 5~
10min；Add organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch, dispersant, stabilizer and continue 5~10min of mixing to mixing
Uniformly, put into double screw extruder, the engine speed of double screw extruder is 250~500r/min, processing temperature 220
DEG C~250 DEG C, by extruding, cool down, air-dry, ABS/PMMA alloy materials being obtained after pelletizing.
The component (mass parts) and test result of the embodiment 1~4 of table 1 and comparative example 1~2
The damage resistant bloom that as can be seen from Table 1 prepared by the present invention is exempted from the mould proof ABS/PMMA alloys antibiotic rate of spray antimicrobial and reached
More than 99%, mould proof grade reaches 0 grade of highest ranking；ABS material glossiness and surface can be improved by adding appropriate PMMA resins
Hardness, glossiness of the common ABS material as appearance material is improved, while improve its case hardness to reduce materials'use process
In the possibility that is scratched；This ABS/PMMA alloy material can also keep the good toughness of ABS material simultaneously, expand it and apply model
Enclose.
The material of the present invention can be widely applied to various electric with the household electrical appliance of direct body contact, Household sanitary, communication
The fields such as son, such as television enclosure, toilet backrests, air conditioner housing etc., its excellent antibacterial and mouldproof performance effectively can be killed or suppressed
Growth, breeding and the propagation of germ, the health of people can be effectively protected, comfortable to pursue health, attractive and durable people carry
For a kind of cost-effective material solution.
Claims (10)
1. a kind of damage resistant bloom exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：By following mass percent
Raw material forms：ABS resin 34~60%, PMMA resins 30~50%, toughener 4~10%, organic-inorganic hybrid nanocomposite antibacterial
Mould proof master batch 0.5~2%, dispersant 0.5~2%, stabilizer 0.5~2%.
2. a kind of damage resistant bloom according to claim 1 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
Melt index of the ABS resin under 220 DEG C, 10kg is more than 20g/10min；In ABS resin butadiene content be 10wt%~
40wt%.
3. a kind of damage resistant bloom according to claim 1 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
The surface pencil hardness of PMMA resins is more than 2H, and Rockwell hardness R levels are more than 108.
4. a kind of damage resistant bloom according to claim 1 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
Toughener is at least one of high glue powder, MBS, ACR, EVA, SEBS, SBS, POE.
5. a kind of damage resistant bloom according to claim 1 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
In organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch, the mould proof composition of organic anti-bacterial is at least one of quaternary ammonium salt or quaternary alkylphosphonium salt,
And its backbone c atoms number is between 10-16；Inorganic anti-bacterium mildewproof composition is in nano-silver ionic or Nano-Zinc ion antibacterial agent
At least one；The diameter of carrier of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is 10~150 μm.
6. a kind of damage resistant bloom according to claim 5 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
The preparation method of organic-inorganic hybrid nanocomposite antibacterial and mouldproof master batch is：First carrier, inorganic antimicrobial mildew preventive agent, organic anti-bacterial are prevented
Mould dose, hyper-dispersant and coupling agent in mass ratio 70：20：10：(0.3~0.5)：0.1 premix, then by the pre-composition of gained, anti-
Oxygen agent and ABS resin in mass ratio 25：(0.1~0.3)：75 mixing, it is extruded, it is granulated, obtains the mould proof master batch of composite antibacterial.
7. a kind of damage resistant bloom according to claim 6 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
Carrier is pearl essence or aluminium powder, and hyper-dispersant TAS-2A, coupling agent is silane coupler.
8. a kind of damage resistant bloom according to claim 1 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
Dispersant is at least one of PETS, TAF, silicone powder.
9. a kind of damage resistant bloom according to claim 1 exempts from the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：
Stabilizer is the mixture that antioxidant and light stabilizer form.
10. a kind of damage resistant bloom exempts from the preparation method of the mould proof ABS/PMMA materials of spray antimicrobial, it is characterised in that：Will by right
Ask the composition described in 1~9 any one to weigh raw material, first ABS resin, PMMA resins and toughener are premixed, add organic-nothing
The mould proof master batch of machine nano composite antibacterial, dispersant and stabilizer continue to mix, and then by extrusion, granulation, obtain damage resistant height
Light exempts from the mould proof ABS/PMMA materials of spray antimicrobial.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111100417A (en) * | 2018-10-29 | 2020-05-05 | 合肥杰事杰新材料股份有限公司 | Impact-resistant reinforced mildew-proof acrylonitrile-butadiene-styrene copolymer material and preparation method thereof |
| EP3964550A4 (en) * | 2019-04-30 | 2023-01-25 | Lotte Chemical Corporation | Thermoplastic resin composition and molded product manufactured therefrom |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687200A (en) * | 2005-04-29 | 2005-10-26 | 宁波华实纳米材料有限公司 | Method of applying inorganic carrier nano silver powder in preparing antibiosis plastic |
| CN103435958A (en) * | 2013-07-26 | 2013-12-11 | 上海盈致橡塑制品有限公司 | ABS and PMMA composite antibacterial plastic alloy |
| CN106947209A (en) * | 2017-03-28 | 2017-07-14 | 昕亮科技（深圳）有限公司 | High-light no-trace ABS/PMMA materials and preparation method thereof |
-
2017
- 2017-08-29 CN CN201710756905.5A patent/CN107603101A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687200A (en) * | 2005-04-29 | 2005-10-26 | 宁波华实纳米材料有限公司 | Method of applying inorganic carrier nano silver powder in preparing antibiosis plastic |
| CN103435958A (en) * | 2013-07-26 | 2013-12-11 | 上海盈致橡塑制品有限公司 | ABS and PMMA composite antibacterial plastic alloy |
| CN106947209A (en) * | 2017-03-28 | 2017-07-14 | 昕亮科技（深圳）有限公司 | High-light no-trace ABS/PMMA materials and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111100417A (en) * | 2018-10-29 | 2020-05-05 | 合肥杰事杰新材料股份有限公司 | Impact-resistant reinforced mildew-proof acrylonitrile-butadiene-styrene copolymer material and preparation method thereof |
| EP3964550A4 (en) * | 2019-04-30 | 2023-01-25 | Lotte Chemical Corporation | Thermoplastic resin composition and molded product manufactured therefrom |
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Application publication date: 20180119 |