CN107573883A - A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof - Google Patents
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof Download PDFInfo
- Publication number
- CN107573883A CN107573883A CN201710859132.3A CN201710859132A CN107573883A CN 107573883 A CN107573883 A CN 107573883A CN 201710859132 A CN201710859132 A CN 201710859132A CN 107573883 A CN107573883 A CN 107573883A
- Authority
- CN
- China
- Prior art keywords
- component
- parts
- agent
- joint trimming
- aqueous double
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Sealing Material Composition (AREA)
Abstract
The invention discloses a kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof, the epoxy joint trimming agent is 1 by mass ratio：Component A and the B component composition of (0.8~1.2), wherein：Component A is made up of the raw material of following mass parts：Epoxy resin latex：100~150 parts；Pigment：5~20 parts；Thixotropic agent：1~5 part；Defoamer：0.1~0.5 part；Levelling agent：0.1~0.5 part；B component is made up of the raw material of following mass parts：Epoxy resin：15~25 parts；Polyetheramine：10~20 parts；Aminated compounds：15~40 parts；The antifouling auxiliary agent of antibacterial：10~20 parts；Thixotropic agent：1~5 part；Water：60~100 parts.Its preparation method is simple, first carries out material and is mixed to get A and B component, is again well mixed A and B component during use.The epoxy joint trimming agent intensity of the present invention is high, shrinkage factor is low, caking property is strong, brightness is high, attractive in appearance, antibacterial and mouldproof effect is lasting, hydrophobic good antifouling effect, easy to clean, and VOC content is extremely low, safety and environmental protection.
Description
Technical field
The present invention relates to a kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof.
Background technology
The gap of ceramic tile is filled using white cement, to reach the purpose of waterproof, attractive in appearance, antifouling, this be at present most
Conventional method.However, white cement gap filler rough surface, as the extension of usage time can become intensely dark, and easily
Go mouldy nigrescence, it is difficult to clean, have a strong impact on finishing aesthetic.In recent years, there is a kind of new joint filling material in the market
Material --- joint trimming agent, in addition to being acted on joint filling, it is excellent to be also equipped with mould proof waterproof, easy to clean, not blackening, glossiness height etc.
Point, is becoming increasingly popular.
At present, joint trimming agent on the market mainly includes two kinds of one-component joint trimming agent and two-component oiliness joint trimming agent.One-component
Joint trimming agent generally existing shrinkage factor is big, the shortcomings of easily coming off.Two-component oiliness joint trimming agent have shrinkage factor is low, caking property is good,
The advantages that intensity is high, brightness is high, is expected to gradually replace one-component joint trimming agent, turns into the market mainstream.However, existing two-component oil
There is also following shortcoming and defect for property joint trimming agent：1) volatile organic matter (VOC) is contained in two-component oiliness joint trimming agent, it is not only dirty
Environment is contaminated, but also health can be damaged；2) T-me line paper is needed before constructing, avoids the contaminated difficult cleaning of ceramic tile, work of constructing
Sequence is cumbersome；3) commercially available two-component oiliness joint trimming agent can not keep attractive in appearance for a long time, and easily grow germ in a humidity environment,
Easy nigrescence of going mouldy, it is difficult to clean, influence overall appearance effect.
Therefore, need badly exploitation it is a kind of it is environmentally friendly, antibiotic property is good, be not easy to go mouldy nigrescence, soil resistance are good, easy to clean, intensity
Joint trimming agent high, shrinkage factor is low.
The content of the invention
It is an object of the invention to provide a kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof.
The technical solution used in the present invention is：
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, it is 1 by mass ratio：The component A and B component of (0.8~1.2)
Composition, wherein：
Component A is made up of the raw material of following mass parts：
Epoxy resin latex：100~150 parts；
Pigment：5~20 parts；
Thixotropic agent：1~5 part；
Defoamer：0.1~0.5 part；
Levelling agent：0.1~0.5 part；
B component is made up of the raw material of following mass parts：
Epoxy resin：15~25 parts；
Polyetheramine：10~20 parts；
Aminated compounds：15~40 parts；
The antifouling auxiliary agent of antibacterial：10~20 parts；
Thixotropic agent：1~5 part；
Water：60~100 parts.
Described epoxy resin is at least one of epoxy resin E-51, epoxy resin E-44.
Described pigment is at least one of pearl essence, titanium dioxide, glitter powder.
Described thixotropic agent is at least one of aerosil, bentonite.
Described defoamer is at least one of TEGO Foamex 810, TEGO Foamex 825.
Described levelling agent is at least one of BYK-333, BYK-378.
The amine value of described polyetheramine is 1.05~3.20mmol/g.
Described aminated compounds be diethylenetriamine, triethylene tetramine, TEPA, 1,3- hexamethylenes dimethylamine, 4,
At least one of 4'- diamino-dicyclohexyl methanes, IPD.
The antifouling auxiliary agent of described antibacterial is quaternary ammonium salt-modified amido silicon oil, and amine value is 0.2~0.5mmol/g, quaternary ammonium group
Content is 0.1~1.0mmol/g.
The preparation method of above-mentioned aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, comprises the following steps：
1) pigment, thixotropic agent, defoamer, levelling agent are added in epoxy resin latex, is well mixed, obtains component A；
2) epoxy resin, polyetheramine, aminated compounds, the antifouling auxiliary agent of antibacterial are well mixed, 50~100 DEG C of reactions 1~
3h,
Add moisture to dissipate, add thixotropic agent and be well mixed, obtain B component；
3) when using construction, component A and B component are well mixed.
The beneficial effects of the invention are as follows：The intensity of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of the present invention is high, shrinks
Rate is low, caking property is strong, brightness is high, aesthetic is good, antibacterial and mouldproof effect is lasting, hydrophobic good antifouling effect, easy to clean, and VOC
Content is extremely low, safety and environmental protection, construction is simple.
1) aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of the invention is water-based system, and VOC content is extremely low, and can use water
Required working viscosity, safety and environmental protection are diluted to as diluent；
2) the antifouling auxiliary agent of antibacterial can be connected by covalent bond with crosslinked polymer network, quaternary ammonium group firmly embedded crosslinking
Network, it is not easy to elute so that aqueous double-component antibacterial anti-fouling epoxy joint trimming agent has more longlasting antibacterial and mouldproof effect；
3) the polysiloxanes segment in the antifouling auxiliary agent of antibacterial can be migrated to material surface, reduce material surface energy, not only
The hydrophobic anti-fouling effect of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent can be improved, aqueous double-component antibacterial can also be improved and prevented
Dirty epoxy joint trimming agent property easy to clean；
4) aqueous double-component antibacterial anti-fouling epoxy joint trimming agent intensity of the invention is high, shrinkage factor is low, caking property is strong, brightness
Height, aesthetic are good；
5) aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of the invention can design different colours according to the actual requirements, Gu
It can be wiped before change with water, not pollute ceramic tile, construction is flexibly simple.
Embodiment
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, it is 1 by mass ratio：The component A and B component of (0.8~1.2)
Composition, wherein：
Component A is made up of the raw material of following mass parts：
Epoxy resin latex：100~150 parts；
Pigment：5~20 parts；
Thixotropic agent：1~5 part；
Defoamer：0.1~0.5 part；
Levelling agent：0.1~0.5 part；
B component is made up of the raw material of following mass parts：
Epoxy resin：15~25 parts；
Polyetheramine：10~20 parts；
Aminated compounds：15~40 parts；
The antifouling auxiliary agent of antibacterial：10~20 parts；
Thixotropic agent：1~5 part；
Water：60~100 parts.
Preferably, described epoxy resin is at least one of epoxy resin E-51, epoxy resin E-44.
Preferably, described pigment is at least one of pearl essence, titanium dioxide, glitter powder.
Preferably, described thixotropic agent is at least one of aerosil, bentonite.
Preferably, described defoamer is at least one of TEGO Foamex 810, TEGO Foamex 825.
Preferably, described levelling agent is at least one of BYK-333, BYK-378.
Preferably, the amine value of described polyetheramine is 1.05~3.20mmol/g.
Preferably, described aminated compounds is diethylenetriamine, triethylene tetramine, TEPA, 1,3- hexamethylenes two
At least one of methylamine, 4,4'- diamino-dicyclohexyl methanes, IPD.
Preferably, the antifouling auxiliary agent of described antibacterial is quaternary ammonium salt-modified amido silicon oil, and amine value is 0.2~0.5mmol/g, season
Ammonium mass contg is 0.1~1.0mmol/g.
The preparation method of above-mentioned aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, comprises the following steps：
1) pigment, thixotropic agent, defoamer, levelling agent are added in epoxy resin latex, is well mixed, obtains component A；
2) epoxy resin, polyetheramine, aminated compounds, the antifouling auxiliary agent of antibacterial are well mixed, 50~100 DEG C of reactions 1~
3h, add moisture to dissipate, add thixotropic agent and be well mixed, obtain B component；
3) when using construction, component A and B component are well mixed.
The present invention is made further explanation and description with reference to specific embodiment.
Embodiment 1：
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, its raw material composition are as shown in the table：
A kind of raw material composition table of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of table 1
Wherein, the mass ratio of component A and B component is 1:1.
Embodiment 2：
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, its raw material composition are as shown in the table：
A kind of raw material composition table of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of table 2
Wherein, the mass ratio of component A and B component is 1:1.
Embodiment 3：
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, its raw material composition are as shown in the table：
A kind of raw material composition table of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of table 3
Wherein, the mass ratio of component A and B component is 1:0.8.
Embodiment 4：
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, its raw material composition are as shown in the table：
A kind of raw material composition table of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of table 4
Wherein, the mass ratio of component A and B component is 1:1.2.
Embodiment 5：
A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, its raw material composition are as shown in the table：
A kind of raw material composition table of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of table 5
Wherein, the mass ratio of component A and B component is 1:1.
Test case：
Component A and B component in aqueous double-component antibacterial anti-fouling epoxy joint trimming agent prepared by embodiment 1~5, which mix, to be applied
Work, carries out performance test, and test result is as shown in the table：
The performance test results of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent of the embodiment 1~5 of table 6
Note：
1) antibiotic rate test bacterial strain used is gold-coloured staphylococci and Escherichia coli；
2) test of going mouldy is carried out according to GB/T 24128-2009 standards.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
- A kind of 1. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent, it is characterised in that：It is 1 by mass ratio：The A groups of (0.8~1.2) Part and B component composition, wherein：Component A is made up of the raw material of following mass parts：Epoxy resin latex：100~150 parts；Pigment：5~20 parts；Thixotropic agent：1~5 part；Defoamer：0.1~0.5 part；Levelling agent：0.1~0.5 part；B component is made up of the raw material of following mass parts：Epoxy resin：15~25 parts；Polyetheramine：10~20 parts；Aminated compounds：15~40 parts；The antifouling auxiliary agent of antibacterial：10~20 parts；Thixotropic agent：1~5 part；Water：60~100 parts.
- 2. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described asphalt mixtures modified by epoxy resin Fat is at least one of epoxy resin E-51, epoxy resin E-44.
- 3. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described pigment is At least one of pearl essence, titanium dioxide, glitter powder.
- 4. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described thixotropic agent For at least one of aerosil, bentonite.
- 5. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described defoamer For at least one of TEGO Foamex 810, TEGO Foamex 825.
- 6. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described levelling agent For at least one of BYK-333, BYK-378.
- 7. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described polyetheramine Amine value be 1.05~3.20mmol/g.
- 8. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described amine Compound is diethylenetriamine, triethylene tetramine, TEPA, 1,3- hexamethylenes dimethylamine, 4,4'- diaminocyclohexyl first At least one of alkane, IPD.
- 9. aqueous double-component antibacterial anti-fouling epoxy joint trimming agent according to claim 1, it is characterised in that：Described antibacterial is prevented Dirty auxiliary agent is quaternary ammonium salt-modified amido silicon oil, and amine value is 0.2~0.5mmol/g, and quaternary ammonium group content is 0.1~1.0mmol/g.
- 10. the preparation method of the aqueous double-component antibacterial anti-fouling epoxy joint trimming agent in claim 1~9 described in any one, its It is characterised by：Comprise the following steps：1) pigment, thixotropic agent, defoamer, levelling agent are added in epoxy resin latex, is well mixed, obtains component A；2) epoxy resin, polyetheramine, aminated compounds, the antifouling auxiliary agent of antibacterial are well mixed, 50~100 DEG C of 1~3h of reaction, added Moisture dissipates, and adds thixotropic agent and is well mixed, obtains B component；3) when using construction, component A and B component are well mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710859132.3A CN107573883B (en) | 2017-09-21 | 2017-09-21 | Water-based two-component antibacterial antifouling epoxy crack sealer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710859132.3A CN107573883B (en) | 2017-09-21 | 2017-09-21 | Water-based two-component antibacterial antifouling epoxy crack sealer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107573883A true CN107573883A (en) | 2018-01-12 |
| CN107573883B CN107573883B (en) | 2020-06-16 |
Family
ID=61033855
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710859132.3A Active CN107573883B (en) | 2017-09-21 | 2017-09-21 | Water-based two-component antibacterial antifouling epoxy crack sealer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107573883B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841288A (en) * | 2018-05-24 | 2018-11-20 | 厦门东顺涂料有限公司 | Aqueous U.S. seam cream |
| CN109401535A (en) * | 2018-09-25 | 2019-03-01 | 江苏理工学院 | A kind of nano silver joint trimming agent and preparation method thereof |
| CN109735278A (en) * | 2019-02-01 | 2019-05-10 | 北京同益中新材料科技股份有限公司 | A kind of water-base epoxy adhesive and its application in high-performance fiber bulletproof plate bonding |
| CN109796920A (en) * | 2019-01-30 | 2019-05-24 | 派丽(上海)管理有限公司 | A kind of detection method of water-whitening resistance U.S. porcelain cement and its performance |
| CN110229584A (en) * | 2019-05-29 | 2019-09-13 | 胡奉杰 | A kind of colored gap filler easily cleaned |
| CN110563928A (en) * | 2019-10-11 | 2019-12-13 | 周林凡 | Transparent paste crack beautifying agent curing agent and preparation method thereof |
| CN111892892A (en) * | 2020-08-20 | 2020-11-06 | 常州市建筑科学研究院集团股份有限公司 | High-performance durable environment-friendly wallpaper adhesive and preparation method thereof |
| CN111892893A (en) * | 2020-08-20 | 2020-11-06 | 常州市建筑科学研究院集团股份有限公司 | Novel environment-friendly seam beautifying agent and preparation method thereof |
| CN112226186A (en) * | 2020-09-27 | 2021-01-15 | 上海牛元工贸有限公司 | Long-service-life seam beautifying agent and preparation method thereof |
| CN112300644A (en) * | 2020-09-27 | 2021-02-02 | 广东粤固建材科技有限公司 | Corrosion-resistant joint beautifying agent for ceramic tile joints and preparation method thereof |
| CN112375525A (en) * | 2020-11-27 | 2021-02-19 | 武汉派高新材料科技有限公司 | Household crack sealer and preparation method thereof |
| CN116285822A (en) * | 2023-04-06 | 2023-06-23 | 安徽牛元新材料有限公司 | Mildew-proof joint beautifying agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5714532A (en) * | 1995-04-12 | 1998-02-03 | Osi Specialties, Inc. | Composition of epoxysilane emulsion additives in water based reactive polymer dispersions and methods of preparation |
| CN101798465A (en) * | 2010-03-16 | 2010-08-11 | 龙海市奈特化工有限责任公司 | Composite material capable of releasing volatile substances persistently and preparation method thereof |
| CN102674751A (en) * | 2012-04-27 | 2012-09-19 | 刘伟 | Bi-component epoxy caulking agent and preparation method thereof |
| CN106281161A (en) * | 2016-08-10 | 2017-01-04 | 上海亚瓦新型建筑材料有限公司 | Three-component epoxy gap filler and preparation method thereof |
| CN107099213A (en) * | 2017-06-13 | 2017-08-29 | 合肥市旺友门窗有限公司 | A kind of glass curtain wall energy-saving coatings and preparation method thereof |
-
2017
- 2017-09-21 CN CN201710859132.3A patent/CN107573883B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5714532A (en) * | 1995-04-12 | 1998-02-03 | Osi Specialties, Inc. | Composition of epoxysilane emulsion additives in water based reactive polymer dispersions and methods of preparation |
| CN101798465A (en) * | 2010-03-16 | 2010-08-11 | 龙海市奈特化工有限责任公司 | Composite material capable of releasing volatile substances persistently and preparation method thereof |
| CN102674751A (en) * | 2012-04-27 | 2012-09-19 | 刘伟 | Bi-component epoxy caulking agent and preparation method thereof |
| CN106281161A (en) * | 2016-08-10 | 2017-01-04 | 上海亚瓦新型建筑材料有限公司 | Three-component epoxy gap filler and preparation method thereof |
| CN107099213A (en) * | 2017-06-13 | 2017-08-29 | 合肥市旺友门窗有限公司 | A kind of glass curtain wall energy-saving coatings and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王建超: ""季铵盐改性氨烃基硅油的制备与应用"", 《广州化工》 * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841288A (en) * | 2018-05-24 | 2018-11-20 | 厦门东顺涂料有限公司 | Aqueous U.S. seam cream |
| CN109401535A (en) * | 2018-09-25 | 2019-03-01 | 江苏理工学院 | A kind of nano silver joint trimming agent and preparation method thereof |
| CN109796920A (en) * | 2019-01-30 | 2019-05-24 | 派丽(上海)管理有限公司 | A kind of detection method of water-whitening resistance U.S. porcelain cement and its performance |
| CN109735278B (en) * | 2019-02-01 | 2021-06-01 | 北京同益中新材料科技股份有限公司 | Water-based epoxy adhesive and application thereof in bonding high-performance fiber bulletproof plate |
| CN109735278A (en) * | 2019-02-01 | 2019-05-10 | 北京同益中新材料科技股份有限公司 | A kind of water-base epoxy adhesive and its application in high-performance fiber bulletproof plate bonding |
| CN110229584A (en) * | 2019-05-29 | 2019-09-13 | 胡奉杰 | A kind of colored gap filler easily cleaned |
| CN110563928A (en) * | 2019-10-11 | 2019-12-13 | 周林凡 | Transparent paste crack beautifying agent curing agent and preparation method thereof |
| CN111892892A (en) * | 2020-08-20 | 2020-11-06 | 常州市建筑科学研究院集团股份有限公司 | High-performance durable environment-friendly wallpaper adhesive and preparation method thereof |
| CN111892893A (en) * | 2020-08-20 | 2020-11-06 | 常州市建筑科学研究院集团股份有限公司 | Novel environment-friendly seam beautifying agent and preparation method thereof |
| CN112226186A (en) * | 2020-09-27 | 2021-01-15 | 上海牛元工贸有限公司 | Long-service-life seam beautifying agent and preparation method thereof |
| CN112300644A (en) * | 2020-09-27 | 2021-02-02 | 广东粤固建材科技有限公司 | Corrosion-resistant joint beautifying agent for ceramic tile joints and preparation method thereof |
| CN112226186B (en) * | 2020-09-27 | 2022-11-29 | 上海牛元工贸有限公司 | Long-service-life seam beautifying agent and preparation method thereof |
| CN112375525A (en) * | 2020-11-27 | 2021-02-19 | 武汉派高新材料科技有限公司 | Household crack sealer and preparation method thereof |
| CN116285822A (en) * | 2023-04-06 | 2023-06-23 | 安徽牛元新材料有限公司 | Mildew-proof joint beautifying agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107573883B (en) | 2020-06-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107573883A (en) | A kind of aqueous double-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof | |
| CN107652835B (en) | A kind of two-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof | |
| CN103602197B (en) | A kind of true mineral varnish and preparation method thereof | |
| CN105802451B (en) | A kind of two component epoxy joint trimming agent and preparation method thereof | |
| CN102733289B (en) | Water-borne acrylic resin plastic runway and production method thereof | |
| CN106381117A (en) | Double-ingredient epoxy seam beautifying glue | |
| WO2006084849A3 (en) | Solid pigment preparations containing fillers and water-soluble surface-active additives | |
| CN106398519B (en) | High-permeability waterproof coating and preparation method and application thereof | |
| CN112322236B (en) | Antibacterial crack sealer and preparation method and application thereof | |
| CN104610863A (en) | Single-component and double-component compound water-based wood top-coat paint and preparation method thereof | |
| MX2011006674A (en) | Adhesive compound. | |
| CN105623336A (en) | Medical waterproof bactericidal paint and preparation method thereof | |
| JP4320675B2 (en) | Fill joint material and joint joint construction method | |
| CN105017719B (en) | One kind is fire-retardant to carve epoxy mortar and preparation method thereof | |
| CN102775899A (en) | Waterborne polyurethane elastic coating and preparation method thereof | |
| CN104692710A (en) | Epoxy resin terrazzo mixing proportion | |
| CN105219246B (en) | A kind of water-based warm wooden priming paint and preparation method thereof | |
| CN107151127A (en) | Environment-friendly colorful flower fragrance crack sealer for ceramic tiles and preparation method thereof | |
| CN106281161A (en) | Three-component epoxy gap filler and preparation method thereof | |
| CN102559015A (en) | Algae-proof coating composition and preparing process thereof | |
| CN103756508B (en) | A kind of preparation method of the environmental protection coating material for container inner surface | |
| CN107384284A (en) | A kind of mono-component organic silicone is modified porcelain seam fluid sealant and preparation method thereof | |
| CN104403377B (en) | A kind of modified alta-mud that improves mechanical property and preparation method thereof | |
| CN108690452A (en) | A kind of epoxy tangerine line floor paint and its preparation method and application | |
| CN105017895A (en) | Water-based traffic paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |