CN107540100A - A kind of activated sludge bulking prewarning analysis system and its application method based on OUR - Google Patents

A kind of activated sludge bulking prewarning analysis system and its application method based on OUR Download PDF

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CN107540100A
CN107540100A CN201710970270.9A CN201710970270A CN107540100A CN 107540100 A CN107540100 A CN 107540100A CN 201710970270 A CN201710970270 A CN 201710970270A CN 107540100 A CN107540100 A CN 107540100A
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sewage
biogels
low
activated sludge
bacterium
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CN107540100B (en
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张文龙
顾金飞
李轶
张弛
赵瑞琪
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Hohai University HHU
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Hohai University HHU
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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Abstract

The invention discloses a kind of activated sludge bulking prewarning analysis system based on OUR,Including effluent filter,Sewage pump,Aeration tank,Aerator,Confined reaction pond,Separate dividing plate,A variety of biogels,DO electrode probes corresponding with the biogel quantity,PLC controls early warning system and delivery port,The effluent filter water inlet is connected with the intake on pretreatment system and biochemistry pool connecting pipe,The sewage pump is connected with the effluent filter and the aeration tank respectively,The aeration tank delivery port is connected with the confined reaction pond,The biogel includes der Pilz,Zoogloea,Low temperature,Low pH,Low N,Low P,High H2S and more soluble organics biogel,It is individually positioned in different separated regions,Detected using the DO electrode probes,The delivery port in the confined reaction pond is connected with the pretreatment system.The present invention, which has, to be carried out real-time, multistage early warning to sewage and carries out real-time analytic function to the sludge bulking origin cause of formation.

Description

A kind of activated sludge bulking prewarning analysis system and its application method based on OUR
Technical field
The present invention relates to a kind of activated sludge bulking prewarning analysis system and its application method based on OUR, belong to sewage Handle the unbalance real-time early warning technical field of activated sludge.
Background technology
With China's economic society especially industrial expansion, largely industrial wastewater and sanitary sewage without dealing carefully with Mixing is discharged into municipal sewage plant, causes the fluctuation of influent quality, so as to which the stable operation to handling process brings impact.Especially It is the widely used activated sludge process in existing municipal sewage plant of China, and activated Sludge System can be because contain in sewage The impact of poisonous and harmful substance causes unbalance failure, occurs sludge bulking, the problems such as sludge decomposition, therefore influent quality is fluctuated Real-time early warning it is just very necessary.The effort during check fee of conventional water quality and sludge physical and chemical index, early warning not in time, are forbidden Really, online bio-toxicity detection technique can analyze the water inlet toxicity and degree of sewage plant by slowdown monitoring soon, there is good research And application value.
The biology that online bio-toxicity detection technique is used for monitoring toxicity is divided into individual level(Fish, flea class, algae), it is micro- Biological level(Photobacteria, nitrobacteria), subcellsular level(Enzyme, DNA)It is horizontal with microbiologic population.Traditional fish, flea Class, algae bio Toxicity Monitoring cycle length, sensitivity is not high, and enzyme, DNA sensor accuracy of detection are high, but prepares and preserve difficult, cost Height, and be easy to preserve culture using microorganism detection toxicity, have enzyme effect process concurrently, the low practicality of cost is high, should as research With most commonly used photobacteria and nitrobacteria Toxicity Monitoring, though the toxicity of water quality can be reflected to a certain degree, can not be very Good reflects its intoxication conditions to activated sludge in sewage treatment plant.Therefore based on the horizontal online biology poison of microbiologic population The research of property detection technique turns into focus.
Research now and application are more widely the respiratory rates using activated Sludge System(OUR)Characterize activated sludge The activity of microbiologic population, the bio-toxicity of sewage is understood by the measure analysis can changed to activated sludge OUR.It is but existing With the presence of the following deficiency and shortcoming of the sewage toxicity real-time early warning system based on OUR:
(1)Existing OUR biological toxicity tests system early warning is not comprehensive, can only early warning sewage cause exhaling for activated Sludge System Inhale the situation of speed reduction, but influence of the fluctuation of water quality to sludge be more than the microbiologic population all to sludge have suppression this Kind situation, it is also possible to cause the unbalance of active sludge microorganism.For example the change of water quality of sewage may promote der Pilz Excessive breeding, the respiratory rate of whole activated Sludge System may not become and even increase, but activated Sludge System has occurred that Expansion, causes water degradation.
(2)Existing OUR biological toxicity tests system is fetched water from biochemistry pool, and sewage comes into biochemistry pool, caused pre- Police is not in time.Sludge is extracted from biochemistry pool also to affect to the form of activated Sludge System, microbial activities.
The content of the invention
Real-time, multistage early warning is carried out and to sludge to sewage the technical problem to be solved by the invention is to provide a kind of It is expanded into the sewage plant activated sludge bulking early warning analysis device and its application method because being analyzed in real time.
In order to solve the above technical problems, the technical solution adopted by the present invention is:
A kind of activated sludge bulking prewarning analysis system based on OUR, including effluent filter, sewage pump, aeration tank, aeration dress Put, confined reaction pond, separation dividing plate, a variety of biogels, DO electrode probes corresponding with the biogel quantity, PLC control Early warning system processed and delivery port, the effluent filter water inlet and the water intaking on pretreatment system and biochemistry pool connecting pipe Mouth is connected, and described sewage pump one end is connected with the effluent filter, and the other end is connected with the aeration tank water inlet, the exposure The aerator is provided with gas pond, the aeration tank delivery port is connected with the confined reaction pond, and separation dividing plate is used for institute State confined reaction pond and be separated out at least eight separated region, it is solidifying that the biogel includes der Pilz biogel, zoogloea biology Glue, low-temperature biological gel, low pH biogels, low N biogels, low P biogels, high H2S biogels and how solvable Organic matter biogel, the different biogels are used to be placed on the different separated regions that the confined reaction pond is separated out It is interior, place a DO electrode probe in each separated region respectively, all DO electrode probes with the PLC Early warning system connection is controlled, the delivery port in the confined reaction pond is connected with the pretreatment system.
Microorganism is embedded in by the biogel using investment to be mixed with the gel that airborne body is formed, and will be prepared Biogel soaked with buffer solution after be respectively placed in the different confined reaction bottom of pond portions.
The biogel preparation method is as follows:
Enrichment culture is carried out to bacterium needed for activated sludge in sewage treatment plant, isolates and purifies and identifies;
Cultured 1600-2000 mL bacterial suspension is centrifuged into 5-10 min under 5000-7500 r/min rotating speed, Supernatant is poured out, then adds 6-10 mLpH7.0 buffer solution;
Weigh 8-10 g polyvinyl alcohol, 0.6-0.8 g sodium alginates, 40-50 g CaCl2 And 1.0-1.4 g NaNO3 , add Enter 50-60 mL without ammoniacal liquor, heating stirring is to being completely dissolved;
The mixed liquor of cooling and required bacteria concentrates are pressed 1:1 volume mixture, pour into lucifuge in mould and stand 1-1.5 h, Gel takes out and cleaned twice with without ammoniacal liquor, you can.
Bacterium in the der Pilz biogel includes health and moving sticks bacteria, Bacillus cercus, Flavobacterium, unwrapping wire shape Nocard's bacillus, middle Escherichia, pseudomonas and saccharomycete;Bacterium in the zoogloea biogel includes microfilament Bacterium, football shirt bacterium, silk sulphur bacterium, Type 0041,0092 and 021N types;Bacterium in the low-temperature biological gel includes microfilament bacterium And the types of Type 0041;Bacterium in the low pH biogels includes fungi Filamentous bacterium;It is thin in the low N biogels Bacterium bag includes Type 021N types and silk sulphur bacterium Thiothrix II;Bacterium in the low P biogels includes N.limicola Ⅲ;The high H2Bacterium in S biogels includes silk sulphur bacterium and Type 021N types;More soluble organic biologies are solidifying Bacterium in glue includes microfilament bacterium and Type0092 types;Bacterium in the low DO biogels includes football shirt bacterium.
A kind of activated sludge bulking prewarning analysis system application method based on OUR, comprises the following steps:
Start the sewage pump, being extracted from the intake on pretreatment system and biochemistry pool connecting pipe will enter by pretreatment Enter the sewage of biochemistry pool, sewage first passes through the effluent filter, for removing the impurity contained in sewage, subsequently into described In aeration tank, preaeration is carried out to sewage, for eliminating breathing speed of the change of the dissolved oxygen in sewage to der Pilz and zoogloea The influence of rate;
Sewage by preaeration enters in the confined reaction pond from the outlet of the aeration tank, when reaching default sewage quantity When, the entrance in the confined reaction pond is closed, the separation dividing plate is placed in the confined reaction pond, described in preparing Der Pilz biogel and the zoogloea biogel are respectively placed in the different separated region bottoms, der Pilz biology Gel and zoogloea biogel carry out metabolism respiration using the DO in sewage and nutrients;
The silk that the DO electrode probes being arranged in the different separated regions will measure at the end of reaction starts and reacts Shape bacterium and the DO values D of zoogloea0And D1Data be transferred to PLC control early warning system, the PLC controls early warning system The respiratory rate that der Pilz and zoogloea are calculated according to default control program carries out real-time comparative analysis, judges whether to report Alert and alarm rank;
When sending der Pilz activated sludge bulking alarm, the PLC control system sends control instruction, by the low-temperature biological Gel, the low pH biogels, the low N biogels, the low P biogels, the high H2It is S biogels, described More soluble organic biogels and the low DO biogels are respectively placed in different separated regions, described by corresponding to DO electrode probes are immersed below sewage level, and the DO electrode probes are pre- to PLC controls by the real-time Data Transmission measured Alert system;
The PLC control early warning systems are expanded into because analysis and Control program calculates the dominant silk of varying environment according to default The respiratory rate of shape bacterium carries out real-time comparative analysis, obtains the factor of leading activated sludge bulking and implement to control accordingly to arrange Apply;
Confined reaction pond delivery port is opened, by sewage backflow into the pretreatment system.
The PLC controls default control program of early warning system concretely comprises the following steps:
(1)The DO data that the DO electrode probes are measured, according to default formula, OUR=(D0 - D1)/ T, wherein OUR are Respiratory rate of the microorganism in time T, the respiratory rate OUR of der Pilz and zoogloea is calculated respectively1And OUR2
(2)According to previous experiments, the normal breathing rates of der Pilz are OURs when being set into normal sewage, zoogloea it is normal Respiratory rate is OURJ , according to the inhibiting rate Ps and P of the real-time respiratory rate of formula calculating der Pilz/zoogloeaJ , wherein Negative represents promotion rate, its formula be respectively Ps=(OURs-OUR1)/ OURs, PJ=(OURJ-OUR2 )/OURJ
(3)According to the comparison and analysis to der Pilz/zoogloea respiratory rate and its inhibiting rate, following warning level is set:
A. as | Ps | < 10%, | PJ | < 10%, do not alarm, illustrate that the water inlet of now sewage plant is not fluctuated;
B. as Ps > 35%, PJ > 35%, alarm one is sent, illustrates that bio-toxicity is very strong in sewage, activated sludge can be brought Damaging impact, sewage should be stopped immediately and enter biochemical reaction tank, cause the collapse of activated Sludge System;
C. as Ps < ﹣ 10%, PJ < ﹣ 10%, alarm two is sent, illustrates that sewage load is too high, it is necessary to increase aeration quantity or prolong Residence time of the long sewage in biochemistry pool;
D. except a, b, c other in the case of, as Ps-PJ > 25%, send alarm three, illustrate suppression of the sewage to der Pilz more By force, the zoogloea in activated sludge can occupy advantage, cause activated sludge loosely fragile, and flco is broken to form needle-like floccule body Non-filamentous bacteria occurs for sludge, and water quality treatment is not up to standard, need to analyze reason and change related operation process, add medicament to solve Certainly problem;
E. except a, b, c other in the case of, as PJ-Ps > 25%, send alarm four, illustrate suppression of the sewage to zoogloea more By force, the der Pilz in activated sludge can occupy advantage, cause activated sludge bulking, settling of floccus degradation, water quality treatment is not It is up to standard, reason need to be analyzed and change related operation process, add flocculant and medicament to solve problem;
F. as | Ps-PJ | < 25%, send alarm five, sewage has one fixing to the respiratory rate of der Pilz and zoogloea Ring, having on the balance of der Pilz and zoogloea necessarily influences, it is necessary to pay close attention to prevent from being worse off;
When sending alarm three, the PLC control system operation is expanded into because of analysis and Control program, including step in detail below:
By the low-temperature biological gel, the low pH biogels, the low N biogels, the low P biogels, described High H2S biogels, more soluble organic biogels and the low DO biogels are respectively placed in different separations In region, the DO electrode probes are immersed below sewage level by corresponding to, the real time data that the DO electrode probes will measure It is transferred to the PLC controls early warning system;
The DO data that DO electrode probes are measured, according to default formula, OUR=(D0 - D1)/ T, wherein OUR are microorganism Respiratory rate in time T, the respiratory rate OUR of different type der Pilz is calculated respectivelyn, n takes 1 ~ 6, represents respectively low Warm, low pH, low N, low P, high H2S, der Pilz dominant under more soluble organic environment;
According to previous experiments, the normal breathing rates of the dominant der Pilz of varying environment are set as OUR0n , n takes 1 ~ 6, according to Formula calculates the promotion rate Y of the real-time respiratory rate of the dominant der Pilz of varying environmentn , wherein negative represents inhibiting rate, its Formula is respectively Yn=(OURn - OUR0n)/ OUR0n
According to the dominant respiratory rate of der Pilz of varying environment and the comparison of its inhibiting rate and analysis, set following pre- It is alert:
A. when the dominant der Pilz of only some or several environment real-time respiratory rate promotion rate Yn > 20%, says This or these environmental condition corresponding in bright sewage, promotes the generation of activated sludge bulking, and the PLC controls early warning System sends instruction and implements corresponding control measure, reduces influence of the variation water quality to activated Sludge System of sewage;
B. when the dominant der Pilz of a variety of environment real-time respiratory rate promotion rate Yn For just, some or several environment The promotion rate Y of the real-time respiratory rate of dominant der Pilzn Than other Yn It is big by more than 15%, illustrate sewage this or this Several environmental conditions, it is the main reason for activated sludge bulking occurs, the PLC controls early warning system sends instruction priority setting Take measures to control these environmental conditions, reduce the influence to activated Sludge System.
The beneficial effect that the present invention is reached:
1. the respiratory rate for being monitored different type der Pilz and zoogloea in real time using DO electrodes and PLC system is changed, by dividing The main reason for sludge bulking occurs for disconnected whether alarm of analysis research, and analysis obtains causing sludge bulking simultaneously provides control measure, has The advantages of effective directly perceived, early warning is rapid, stable, easy to operate, high-efficiency and economic;
2. an equipment sewage pump extracts to enter by pretreatment from the intake of pretreatment system and biochemistry pool connecting pipe Enter the sewage of biochemistry pool, timely early warning can avoid toxicity sewage from entering biochemistry pool and destroy activated Sludge System.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention;
Fig. 2 is biogel and DO electrode probe scheme of installations in the present invention.
Embodiment
The invention will be further described below in conjunction with the accompanying drawings.Following examples are only used for clearly illustrating the present invention Technical scheme, and can not be limited the scope of the invention with this.
As shown in Figure 1 and Figure 2, a kind of activated sludge bulking prewarning analysis system based on OUR, including effluent filter 1, Sewage pump 2, aeration tank 3, aerator, confined reaction pond 6, separation dividing plate 7,8 kind of biogel 8 and the quantity pair of biogel 8 The DO electrode probes 9 answered, PLC control early warning systems 10 and delivery port 11, the water inlet of effluent filter 1 and pretreatment system and Intake on biochemistry pool connecting pipe is connected, and the one end of sewage pump 2 is connected with effluent filter 1, and the other end is intake with aeration tank 3 Mouth connection, aeration tank 3 is interior to be provided with aeration tube 4, and aeration tube 4 is connected with aerator 5, the delivery port of aeration tank 3 and confined reaction pond 10 Connection, separation dividing plate 7 are used to confined reaction pond 6 being separated out 8 separated regions, biogel 8 include der Pilz biogel, Zoogloea biogel, low-temperature biological gel, low pH biogels, low N biogels, low P biogels, high H2S biologies are solidifying Glue and more soluble organic biogels, different biogels 8 are used to be placed on the difference point that confined reaction pond 6 is separated out A DO electrode probe 9 is placed in septal area domain, in each separated region respectively, all DO electrode probes 9 control early warning with PLC System 10 is connected, and the delivery port 11 in confined reaction pond 10 is connected with pretreatment system.
Microorganism is embedded in by biogel using investment to be mixed with the gel that airborne body is formed, the life that will be prepared Thing gel is respectively placed in the different bottoms of confined reaction pond 6 after being soaked with buffer solution.
Bacterium in der Pilz biogel includes health and moving sticks bacteria, Bacillus cercus, Flavobacterium, unwrapping wire shape promise card Salmonella, middle Escherichia, pseudomonas and saccharomycete;Bacterium in zoogloea biogel includes microfilament bacterium, football shirt Bacterium, silk sulphur bacterium, Type 0041,0092 and 021N types;Bacterium in low-temperature biological gel includes microfilament bacterium and Type 0041 type;Bacterium in low pH biogels includes fungi Filamentous bacterium;Bacterium in low N biogels includes Type 021N types And silk sulphur bacterium Thiothrix II;Bacterium in low P biogels includes N.limicola III;High H2In S biogels Bacterium includes silk sulphur bacterium and Type 021N types;Bacterium in more soluble organic biogels include microfilament bacterium and Type0092 types;Bacterium in low DO biogels includes football shirt bacterium.
Biogel preparation method is as follows:
Enrichment culture is carried out to bacterium needed for activated sludge in sewage treatment plant, isolates and purifies and identifies;
Cultured 1600-2000 mL required bacterial suspension is centrifuged into 5-10 under 5000-7500 r/min rotating speed Min, supernatant is poured out, then add 6-10 mL pH7.0 buffer solution;
Weigh 8-10 g polyvinyl alcohol, 0.6-0.8g sodium alginates, 40-50 g CaCl2And 1.0-1.4 g NaNO3, add Enter 50-60 mL without ammoniacal liquor, heating stirring is to being completely dissolved;
The mixed liquor of cooling and required bacteria concentrates are pressed 1:1 volume mixture, pour into lucifuge in mould and stand 1-1.5 h, Film takes out and cleaned twice with without ammoniacal liquor, you can.
A kind of activated sludge bulking prewarning analysis system application method based on OUR, comprises the following steps:
Start sewage pump 2, being extracted from the intake on pretreatment system and biochemistry pool connecting pipe will enter by pretreatment The sewage of biochemistry pool, sewage first pass through effluent filter 1, for removing the impurity contained in sewage, subsequently into aeration tank 3 It is interior, preaeration is carried out to sewage, for eliminating the change of the dissolved oxygen in sewage to der Pilz and the shadow of the respiratory rate of zoogloea Ring, aerator 5 makes its DO concentration reach 2.5-2.8 mg/L by aeration tube 4 to sewage aeration, then stops aeration;
Sewage by preaeration enters in confined reaction pond 6 from the outlet of aeration tank 3, when reaching default sewage quantity, closes Close the entrance in confined reaction pond 6, separation dividing plate 7 be placed in confined reaction pond 6, by the der Pilz biogel prepared and Zoogloea biogel is respectively placed in different separated region bottoms, and der Pilz biogel and zoogloea biogel utilize DO and nutrients in sewage carry out metabolism respiration, and with the extension in reaction time, DO concentration gradually reduces.According to correlation Experiment, it has been found that in 5-10 min time, DO concentration decline is most obvious, so reaction of the present invention in confined reaction pond Time is 6 min;
The DO electrode probes 9 being arranged in different separated regions by reaction start and reaction at the end of the der Pilz that measures and The DO values D of zoogloea0And D1Data be transferred to PLC control early warning system 10, PLC control early warning system 10 according to default control Processing procedure sequence calculates der Pilz and the respiratory rate of zoogloea carries out real-time comparative analysis, judges whether the level alarmed and alarmed Not;
When send der Pilz activated sludge bulking alarm when, PLC control system 10 sends control instruction, by low-temperature biological gel, Low pH biogels, low N biogels, low P biogels, high H2S biogels, more soluble organic biogels and low DO biogels are respectively placed in different separated regions, corresponding DO electrode probes 9 are immersed below sewage level, DO electrodes The real-time Data Transmission measured is controlled early warning system 10 by probe 9 to PLC;
PLC controls early warning system 10 to be expanded into according to default because analysis and Control program calculates the thread of varying environment dominance The respiratory rate of bacterium carries out real-time comparative analysis, obtains the factor of leading activated sludge bulking and implements corresponding control measure;
The delivery port 11 of confined reaction pond 6 is opened, by sewage backflow into pretreatment system.
PLC controls 10 default control program of early warning system concretely comprises the following steps:
(1)The DO data that DO electrode probes are measured, according to default formula, OUR=D0 - D1/ T, wherein OUR are microorganism Respiratory rate in time T, the respiratory rate OUR of der Pilz and zoogloea is calculated respectively1And OUR2
(2)According to previous experiments, the normal breathing rates of der Pilz are OURs when being set into normal sewage, zoogloea it is normal Respiratory rate is OURJ , according to the inhibiting rate Ps and P of the real-time respiratory rate of formula calculating der Pilz/zoogloeaJ , wherein Negative represents promotion rate, and its formula is respectively Ps=OURs-OUR1/ OURs, PJ=OURJ-OUR2 /OURJ
(3)According to the comparison and analysis to der Pilz/zoogloea respiratory rate and its inhibiting rate, following warning level is set:
A. as | Ps | < 10%, | PJ | < 10%, do not alarm, illustrate that the water inlet of now sewage plant is not fluctuated;
B. as Ps > 35%, PJ > 35%, alarm one is sent, illustrates that bio-toxicity is very strong in sewage, activated sludge can be brought Damaging impact, sewage should be stopped immediately and enter biochemical reaction tank, cause the collapse of activated Sludge System;
C. as Ps < ﹣ 10%, PJ < ﹣ 10%, alarm two is sent, illustrates that sewage load is too high, it is necessary to increase aeration quantity or prolong Residence time of the long sewage in biochemistry pool;
D. except a, b, c other in the case of, as Ps-PJ > 25%, send alarm three, illustrate suppression of the sewage to der Pilz more By force, the zoogloea in activated sludge can occupy advantage, cause activated sludge loosely fragile, and flco is broken to form needle-like floccule body Non-filamentous bacteria occurs for sludge, and water quality treatment is not up to standard, need to analyze reason and change related operation process, add medicament to solve Certainly problem;
E. except a, b, c other in the case of, as PJ-Ps > 25%, send alarm four, illustrate suppression of the sewage to zoogloea more By force, the der Pilz in activated sludge can occupy advantage, cause activated sludge bulking, settling of floccus degradation, water quality treatment is not It is up to standard, reason need to be analyzed and change related operation process, add flocculant and medicament to solve problem;
F. as | Ps-PJ | < 25%, send alarm five, sewage has one fixing to the respiratory rate of der Pilz and zoogloea Ring, having on the balance of der Pilz and zoogloea necessarily influences, it is necessary to pay close attention to prevent from being worse off;
(4)When sending alarm three, the operation of PLC control system 10 is expanded into because of analysis and Control program, including step in detail below:
By low-temperature biological gel, low pH biogels, low N biogels, low P biogels, high H2It is S biogels, how solvable Organic matter biogel and low DO biogels are respectively placed in different separated regions, and corresponding DO electrode probes 9 are soaked Enter below sewage level, the real-time Data Transmission measured is controlled early warning system 10 by DO electrode probes 9 to PLC;
The DO data that DO electrode probes are measured, according to default formula, OUR=D0 - D1/ T, wherein OUR are that microorganism exists Respiratory rate in time T, the respiratory rate OUR of different type der Pilz is calculated respectivelyn, n takes 1 ~ 6, represents respectively low Warm, low pH, low N, low P, high H2S, der Pilz dominant under more soluble organic environment;
According to previous experiments, the normal breathing rates of the dominant der Pilz of varying environment are set as OUR0n , n takes 1 ~ 6, according to Formula calculates the promotion rate Y of the real-time respiratory rate of the dominant der Pilz of varying environmentn , wherein negative represents inhibiting rate, its Formula is respectively Yn=OURn - OUR0n/ OUR0n
According to the dominant respiratory rate of der Pilz of varying environment and the comparison of its inhibiting rate and analysis, set following pre- It is alert:
A. when the dominant der Pilz of only some or several environment real-time respiratory rate promotion rate Yn > 20%, says This or these environmental condition corresponding in bright sewage, promote the generation of activated sludge bulking, PLC control early warning systems 10, which send instruction, implements corresponding control measure, reduces influence of the variation water quality to activated Sludge System of sewage;
B. when the dominant der Pilz of a variety of environment real-time respiratory rate promotion rate Yn For just, some or several environment The promotion rate Y of the real-time respiratory rate of dominant der Pilzn Than other Yn It is big by more than 15%, illustrate sewage this or this Several environmental conditions, are the main reason for activated sludge bulking occur, and PLC controls early warning system 10 sends instruction priority setting and adopted These environmental conditions of controlling measurement are taken, reduce the influence to activated Sludge System.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, some improvement and deformation can also be made, these are improved and deformation Also it should be regarded as protection scope of the present invention.

Claims (6)

1. a kind of activated sludge bulking prewarning analysis system based on OUR, it is characterized in that, including effluent filter(1), sewage pump (2), aeration tank(3), aerator, confined reaction pond(6), separation dividing plate(7), a variety of biogels(8)And the biology is solidifying Glue(8)DO electrode probes corresponding to quantity(9), PLC control early warning system(10)And delivery port(11), the effluent filter (1)Water inlet is connected with the intake on pretreatment system and biochemistry pool connecting pipe, the sewage pump(2)One end and the dirt Water filter(1)Connection, the other end and the aeration tank(3)Water inlet connects, the aeration tank(3)It is interior to be provided with the aeration dress Put, the aeration tank(3)Delivery port and the confined reaction pond(6)Connection, separate dividing plate(7)For by the confined reaction pond (6)It is separated out at least eight separated region, the biogel(8)Including der Pilz biogel, zoogloea biogel, low Warm biogel, low pH biogels, low N biogels, low P biogels, high H2S biogels and more soluble organics Biogel, the different biogels(8)For being placed on the confined reaction pond(6)The different separated regions being separated out It is interior, a DO electrode probe is placed respectively in each separated region(9), all DO electrode probes(9)With The PLC controls early warning system(10)Connection, the confined reaction pond(10)Delivery port(11)Connect with the pretreatment system Connect.
2. a kind of activated sludge bulking prewarning analysis system based on OUR according to claim 1, it is characterized in that, it is described Microorganism is embedded in by biogel using investment to be mixed with the gel that airborne body is formed, and the biogel prepared is used The different confined reaction ponds is respectively placed in after buffer solution wetting(6)Bottom.
3. a kind of activated sludge bulking prewarning analysis system based on OUR according to claim 2, it is characterized in that, it is described Biogel preparation method is as follows:
Enrichment culture is carried out to bacterium needed for activated sludge in sewage treatment plant, isolates and purifies and identifies;
Cultured 1600-2000 mL bacterial suspension is centrifuged into 5-10 min under 5000-7500 r/min rotating speed, Supernatant is poured out, then adds 6-10 mL pH7.0 buffer solution;
Weigh 8-10 g polyvinyl alcohol, 0.6-0.8 g sodium alginates, 40-50 g CaCl2 And 1.0-1.4 g NaNO3 , add Enter 50-60 mL without ammoniacal liquor, heating stirring is to being completely dissolved;
The mixed liquor of cooling and required bacteria concentrates are pressed 1:1 volume mixture, pour into lucifuge in mould and stand 1-1.5 h, Gel takes out and cleaned twice with without ammoniacal liquor, you can.
4. a kind of activated sludge bulking prewarning analysis system based on OUR according to claim 1, it is characterized in that, it is described Bacterium in der Pilz biogel include health and moving sticks bacteria, Bacillus cercus, Flavobacterium, unwrapping wire shape Nocard's bacillus, in Between Escherichia, pseudomonas and saccharomycete;Bacterium in the zoogloea biogel include microfilament bacterium, football shirt bacterium, Silk sulphur bacterium, Type 0041,0092 and 021N types;Bacterium in the low-temperature biological gel includes microfilament bacterium and Type 0041 type;Bacterium in the low pH biogels includes fungi Filamentous bacterium;Bacterium in the low N biogels includes Type 021N types and silk sulphur bacterium Thiothrix II;Bacterium in the low P biogels includes N.limicola III;The height H2Bacterium in S biogels includes silk sulphur bacterium and Type 021N types;Bacterium in more soluble organic biogels Including microfilament bacterium and Type0092 types;Bacterium in the low DO biogels includes football shirt bacterium.
5. a kind of activated sludge bulking prewarning analysis system application method based on OUR according to claim 1, its feature It is to comprise the following steps:
Start the sewage pump(2), it is by pretreatment from the intake extraction on pretreatment system and biochemistry pool connecting pipe The sewage of biochemistry pool will be entered, sewage first passes through the effluent filter(1), for removing the impurity contained in sewage, then Into the aeration tank(3)It is interior, preaeration is carried out to sewage, for eliminating the change of the dissolved oxygen in sewage to der Pilz and bacterium glue The influence of the respiratory rate of group;
Sewage by preaeration is from the aeration tank(3)Outlet enter the confined reaction pond(6)In, it is default when reaching During sewage quantity, the confined reaction pond is closed(6)Entrance, by the separation dividing plate(7)It is placed in the confined reaction pond(6) In, the der Pilz biogel prepared and the zoogloea biogel are respectively placed in the different marker spaces Domain bottom, der Pilz biogel and zoogloea biogel carry out metabolism breathing using the DO in sewage and nutrients and made With;
The DO electrode probes being arranged in the different separated regions(9)By what is measured at the end of reaction starts and reacts Der Pilz and the DO values D of zoogloea0And D1Data be transferred to PLC control early warning system(10), the PLC controls are in advance Alert system(10)The respiratory rate that der Pilz and zoogloea are calculated according to default control program carries out real-time comparative analysis, Judge whether the rank alarmed and alarmed;
When sending der Pilz activated sludge bulking alarm, the PLC control system(10)Control instruction is sent, by the low temperature Biogel, the low pH biogels, the low N biogels, the low P biogels, the high H2S biogels, More soluble organic biogels and the low DO biogels are respectively placed in different separated regions, by corresponding to The DO electrode probes(9)Immerse below sewage level, the DO electrode probes(9)By the real-time Data Transmission measured to described PLC controls early warning system(10);
The PLC controls early warning system(10)It is expanded into according to default because analysis and Control program calculates varying environment dominance The respiratory rate of der Pilz carry out real-time comparative analysis, obtain the factor of leading activated sludge bulking and implement corresponding control Measure;
By the confined reaction pond(6)Delivery port(11)Open, by sewage backflow into the pretreatment system.
6. a kind of activated sludge bulking prewarning analysis system application method based on OUR according to claim 5, its feature It is that the PLC controls early warning system(10)Default control program concretely comprises the following steps:
The DO data that the DO electrode probes are measured, according to default formula, OUR=(D0 - D1)/ T, wherein OUR are micro- Respiratory rate of the biology in time T, the respiratory rate OUR of der Pilz and zoogloea is calculated respectively1And OUR2
According to previous experiments, the normal breathing rates of der Pilz are OURs when being set into normal sewage, and the normal of zoogloea is exhaled Suction speed is OURJ , according to the inhibiting rate Ps and P of the real-time respiratory rate of formula calculating der Pilz/zoogloeaJ , wherein negative Number represent promotion rate, its formula be respectively Ps=(OURs-OUR1)/ OURs, PJ=(OURJ-OUR2 )/OURJ
According to the comparison and analysis to der Pilz/zoogloea respiratory rate and its inhibiting rate, following warning level is set:
A. as | Ps | < 10%, | PJ | < 10%, do not alarm, illustrate that the water inlet of now sewage plant is not fluctuated;
B. as Ps > 35%, PJ > 35%, alarm one is sent, illustrates that bio-toxicity is very strong in sewage, activated sludge can be brought Damaging impact, sewage should be stopped immediately and enter biochemical reaction tank, cause the collapse of activated Sludge System;
C. as Ps < ﹣ 10%, PJ < ﹣ 10%, alarm two is sent, illustrates that sewage load is too high, it is necessary to increase aeration quantity or prolong Residence time of the long sewage in biochemistry pool;
D. except a, b, c other in the case of, as Ps-PJ > 25%, send alarm three, illustrate suppression of the sewage to der Pilz more By force, the zoogloea in activated sludge can occupy advantage, cause activated sludge loosely fragile, and flco is broken to form needle-like floccule body Non-filamentous bacteria occurs for sludge, and water quality treatment is not up to standard, need to analyze reason and change related operation process, add medicament to solve Certainly problem;
E. except a, b, c other in the case of, as PJ-Ps > 25%, send alarm four, illustrate suppression of the sewage to zoogloea more By force, the der Pilz in activated sludge can occupy advantage, cause activated sludge bulking, settling of floccus degradation, water quality treatment is not It is up to standard, reason need to be analyzed and change related operation process, add flocculant and medicament to solve problem;
F. as | Ps-PJ | < 25%, send alarm five, sewage has one fixing to the respiratory rate of der Pilz and zoogloea Ring, having on the balance of der Pilz and zoogloea necessarily influences, it is necessary to pay close attention to prevent from being worse off;
When sending alarm three, the PLC control system(10)Operation is expanded into because of analysis and Control program, including is walked in detail below Suddenly:
By the low-temperature biological gel, the low pH biogels, the low N biogels, the low P biogels, described High H2S biogels, more soluble organic biogels and the low DO biogels are respectively placed in different separations In region, the DO electrode probes by corresponding to(9)Immerse below sewage level, the DO electrode probes(9)The reality that will be measured When data be transferred to PLC control early warning system(10);
The DO data that DO electrode probes are measured, according to default formula, OUR=(D0 - D1)/ T, wherein OUR are microorganism Respiratory rate in time T, the respiratory rate OUR of different type der Pilz is calculated respectivelyn, n takes 1 ~ 6, represents respectively low Warm, low pH, low N, low P, high H2S, der Pilz dominant under more soluble organic environment;
According to previous experiments, the normal breathing rates of the dominant der Pilz of varying environment are set as OUR0n , n takes 1 ~ 6, according to Formula calculates the promotion rate Y of the real-time respiratory rate of the dominant der Pilz of varying environmentn , wherein negative represents inhibiting rate, its Formula is respectively Yn=(OURn - OUR0n)/ OUR0n
According to the dominant respiratory rate of der Pilz of varying environment and the comparison of its inhibiting rate and analysis, set following pre- It is alert:
A. when the dominant der Pilz of only some or several environment real-time respiratory rate promotion rate Yn > 20%, says This or these environmental condition corresponding in bright sewage, promotes the generation of activated sludge bulking, and the PLC controls early warning System(10)Send instruction and implement corresponding control measure, reduce influence of the variation water quality to activated Sludge System of sewage;
B. when the dominant der Pilz of a variety of environment real-time respiratory rate promotion rate Yn For just, some or several environment The promotion rate Y of the real-time respiratory rate of dominant der Pilzn Than other Yn It is big by more than 15%, illustrate sewage this or this Several environmental conditions, are the main reason for activated sludge bulking occur, and the PLC controls early warning system(10)It is preferential to send instruction Emphasis takes measures to control these environmental conditions, reduces the influence to activated Sludge System.
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CN112266071A (en) * 2020-10-29 2021-01-26 中原环保股份有限公司 Sewage treatment method for inhibiting activated sludge bulking
CN109111041B (en) * 2018-09-13 2021-05-07 福建海峡环保集团股份有限公司 Method for inhibiting biological foams caused by Nocardia in aeration tank

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CN101907596A (en) * 2010-08-30 2010-12-08 重庆大学 Method for monitoring and estimating inlet water toxicity of urban wastewater treatment plant on line
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CN101759333A (en) * 2010-02-10 2010-06-30 彭永臻 Apparatus for stably maintaining sludge micro-bulking for saving energy in biological denitrification technology and method thereof
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CN112266071A (en) * 2020-10-29 2021-01-26 中原环保股份有限公司 Sewage treatment method for inhibiting activated sludge bulking
CN112266071B (en) * 2020-10-29 2022-12-20 中原环保股份有限公司 Sewage treatment method for inhibiting activated sludge bulking

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