CN107531481A - 用于从气体中去除硫化合物的具有氢化和直接氧化步骤的方法 - Google Patents
用于从气体中去除硫化合物的具有氢化和直接氧化步骤的方法 Download PDFInfo
- Publication number
- CN107531481A CN107531481A CN201680015041.5A CN201680015041A CN107531481A CN 107531481 A CN107531481 A CN 107531481A CN 201680015041 A CN201680015041 A CN 201680015041A CN 107531481 A CN107531481 A CN 107531481A
- Authority
- CN
- China
- Prior art keywords
- gas
- reactor
- hydrogenation
- catalyst
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005864 Sulphur Substances 0.000 title claims abstract description 86
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 80
- 230000003647 oxidation Effects 0.000 title claims abstract description 71
- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 70
- 238000000034 method Methods 0.000 title claims abstract description 64
- -1 sulphur compound Chemical class 0.000 title claims abstract description 22
- 239000003054 catalyst Substances 0.000 claims abstract description 111
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 98
- 230000008929 regeneration Effects 0.000 claims abstract description 25
- 238000011069 regeneration method Methods 0.000 claims abstract description 25
- 239000007789 gas Substances 0.000 claims description 140
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 30
- 229910052760 oxygen Inorganic materials 0.000 claims description 30
- 239000001301 oxygen Substances 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- 230000003197 catalytic effect Effects 0.000 claims description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 230000008859 change Effects 0.000 claims description 8
- 230000002779 inactivation Effects 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 6
- 239000003345 natural gas Substances 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 229910003294 NiMo Inorganic materials 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- 230000009719 regenerative response Effects 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 230000007423 decrease Effects 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 230000004087 circulation Effects 0.000 abstract description 10
- 230000008569 process Effects 0.000 abstract description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 36
- 229910052717 sulfur Inorganic materials 0.000 description 13
- 239000011593 sulfur Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000001816 cooling Methods 0.000 description 9
- 238000011084 recovery Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 5
- 239000002826 coolant Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000011552 falling film Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
- B01D53/8615—Mixtures of hydrogen sulfide and sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
- C01B17/0439—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion at least one catalyst bed operating below the dew-point of sulfur
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
- C01B17/0469—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide at least one catalyst bed operating below the dew-point of sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
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- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
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- B01D2255/20746—Cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2255/20753—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D2255/20—Metals or compounds thereof
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- B01D2255/20761—Copper
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2255/20776—Tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20784—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D—SEPARATION
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- B01D2255/209—Other metals
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- B01D—SEPARATION
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2255/70—Non-metallic catalysts, additives or dopants
- B01D2255/702—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/903—Multi-zoned catalysts
- B01D2255/9032—Two zones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/904—Multiple catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/306—Organic sulfur compounds, e.g. mercaptans
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/308—Carbonoxysulfide COS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Description
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15158886.0A EP3067109B1 (en) | 2015-03-12 | 2015-03-12 | Process for removing sulfur compounds from a gas with hydrogenation and direct oxidation steps |
EP15158886.0 | 2015-03-12 | ||
PCT/EP2016/055323 WO2016142528A1 (en) | 2015-03-12 | 2016-03-11 | Process for removing sulfur compounds from a gas with hydrogenation and direct oxidation steps |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107531481A true CN107531481A (zh) | 2018-01-02 |
CN107531481B CN107531481B (zh) | 2020-09-15 |
Family
ID=52810944
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201680015041.5A Active CN107531481B (zh) | 2015-03-12 | 2016-03-11 | 用于从气体中去除硫化合物的具有氢化和直接氧化步骤的方法 |
Country Status (12)
Country | Link |
---|---|
US (1) | US9586177B2 (zh) |
EP (1) | EP3067109B1 (zh) |
JP (1) | JP2018510777A (zh) |
CN (1) | CN107531481B (zh) |
AU (1) | AU2016231057A1 (zh) |
BR (1) | BR112017018578A2 (zh) |
CA (1) | CA2977451C (zh) |
ES (1) | ES2711612T3 (zh) |
MX (1) | MX2017011401A (zh) |
RU (1) | RU2703247C2 (zh) |
SA (1) | SA517382277B1 (zh) |
WO (1) | WO2016142528A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110937648A (zh) * | 2019-12-25 | 2020-03-31 | 浙江工业大学 | 一种连续化处理高浓度有机废水的工艺及装置 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107441875A (zh) * | 2017-09-08 | 2017-12-08 | 中冶焦耐(大连)工程技术有限公司 | 一种克劳斯尾气冷凝处理装置 |
CN112014261B (zh) * | 2020-09-04 | 2022-04-26 | 西南石油大学 | 一种基于溶剂溶解原理测量吸附硫含量的装置及方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2758913A (en) * | 1951-10-11 | 1956-08-14 | Stanolind Oil & Gas Co | Process for sulfur recovery |
DE3526706A1 (de) * | 1985-07-25 | 1987-01-29 | Linde Ag | Verfahren und reaktor zur katalytischen umsetzung von schwefelwasserstoff zu elementarem schwefel |
CN1105175A (zh) * | 1993-03-16 | 1995-07-12 | 埃尔夫·阿奎坦生产公司 | 除去克劳斯硫回收装置残余气体类型的残余气体中的硫化合物并以元素硫形态回收 |
CN1105178A (zh) * | 1993-03-16 | 1995-07-12 | 埃尔夫·阿奎坦生产公司 | 从气体中除去硫化氢并回收硫的方法 |
CN101583413A (zh) * | 2006-09-22 | 2009-11-18 | 杰克布斯荷兰股份有限公司 | 用于以高效率从含硫气体中回收硫的方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1900751A (en) * | 1928-02-27 | 1933-03-07 | Ig Farbenindustrie Ag | Purification of gases |
NL171144B (nl) * | 1970-07-17 | 1982-09-16 | Shell Int Research | Werkwijze voor het verlagen van het totale zwavelgehalte van clausafgassen. |
DE2501557A1 (de) * | 1975-01-16 | 1976-07-22 | Metallgesellschaft Ag | Verfahren und vorrichtung zur gewinnung von elementarem schwefel |
FR2481254A1 (fr) * | 1980-04-23 | 1981-10-30 | Elf Aquitaine | Procede pour l'incineration catalytique de gaz residuaires renfermant en faible concentration au moins un compose du soufre choisi parmi cos, cs2, et les mercaptans et eventuellement au moins un membre du groupe forme par h2s, so2, soufre vapeur et/ou vesiculaire |
US4507275A (en) * | 1983-08-30 | 1985-03-26 | Standard Oil Company (Indiana) | Process for producing and recovering elemental sulfur from acid gas |
US5202107A (en) * | 1988-06-08 | 1993-04-13 | Societe National Elf Aquitaine (Prod.) | Process for improving the sulphur yield of a complex for the production of sulphur followed by a purification unit |
DE4409203A1 (de) * | 1994-03-17 | 1995-09-21 | Linde Ag | Verfahren zur Gewinnung von elementarem Schwefel aus einem H¶2¶S enthaltenden Gasgemisch |
FR2740767B1 (fr) * | 1995-11-03 | 1997-12-26 | Elf Aquitaine | Procede d'oxydation complete en soufre de l'h2s present dans un gaz et son application a la recuperation quasi totale, sous la forme de soufre, des composes soufres contenus dans un gaz residuaire d'usine a soufre |
FR2740703B1 (fr) * | 1995-11-03 | 1997-12-05 | Elf Aquitaine | Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre |
FR2762592B1 (fr) | 1997-04-24 | 1999-06-18 | Elf Aquitaine | Procede d'elimination des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre avec recuperation desdits composes sous la forme de soufre |
DE19719375A1 (de) | 1997-05-07 | 1998-11-12 | Linde Ag | Verfahren und Reaktor zur Herstellung von Ethylenoxid |
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2015
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- 2016-03-11 AU AU2016231057A patent/AU2016231057A1/en not_active Abandoned
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CN110937648A (zh) * | 2019-12-25 | 2020-03-31 | 浙江工业大学 | 一种连续化处理高浓度有机废水的工艺及装置 |
CN110937648B (zh) * | 2019-12-25 | 2021-03-30 | 浙江工业大学 | 一种连续化处理高浓度有机废水的工艺及装置 |
US11767232B2 (en) | 2019-12-25 | 2023-09-26 | Zhejiang University Of Technology | Process and device for continuous treatment of high-concentration organic wastewater |
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EP3067109A1 (en) | 2016-09-14 |
WO2016142528A1 (en) | 2016-09-15 |
SA517382277B1 (ar) | 2022-06-26 |
RU2017134117A (ru) | 2019-04-03 |
MX2017011401A (es) | 2017-12-20 |
ES2711612T3 (es) | 2019-05-06 |
RU2703247C2 (ru) | 2019-10-15 |
EP3067109B1 (en) | 2018-12-05 |
BR112017018578A2 (pt) | 2018-04-24 |
CA2977451A1 (en) | 2016-09-15 |
CA2977451C (en) | 2022-12-13 |
US9586177B2 (en) | 2017-03-07 |
RU2017134117A3 (zh) | 2019-05-14 |
US20160263524A1 (en) | 2016-09-15 |
CN107531481B (zh) | 2020-09-15 |
AU2016231057A1 (en) | 2017-09-14 |
JP2018510777A (ja) | 2018-04-19 |
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