CN107522451A - A kind of preparation method of ceramics - Google Patents

A kind of preparation method of ceramics Download PDF

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CN107522451A
CN107522451A CN201710700228.5A CN201710700228A CN107522451A CN 107522451 A CN107522451 A CN 107522451A CN 201710700228 A CN201710700228 A CN 201710700228A CN 107522451 A CN107522451 A CN 107522451A
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ceramics
preparation
pug
herbal medicine
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顾玉城
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10—Lime cements or magnesium oxide cements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28C—PREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C1/00—Apparatus or methods for obtaining or processing clay
    • B28C1/02—Apparatus or methods for obtaining or processing clay for producing or processing clay suspensions, e.g. slip
    • B28C1/04—Producing suspensions, e.g. by blunging or mixing; with means for removing stones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28C—PREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C1/00—Apparatus or methods for obtaining or processing clay
    • B28C1/10—Apparatus or methods for obtaining or processing clay for processing clay-containing substances in non-fluid condition ; Plants
    • B28C1/14—Apparatus or methods for obtaining or processing clay for processing clay-containing substances in non-fluid condition ; Plants specially adapted for homogenising, comminuting or conditioning clay in non-fluid condition or for separating undesired admixtures therefrom
    • B28C1/16—Apparatus or methods for obtaining or processing clay for processing clay-containing substances in non-fluid condition ; Plants specially adapted for homogenising, comminuting or conditioning clay in non-fluid condition or for separating undesired admixtures therefrom for homogenising, e.g. by mixing, kneading ; forcing through slots
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61—Coating or impregnation
    • C04B41/62—Coating or impregnation with organic materials
    • C04B41/63—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00956—Uses not provided for elsewhere in C04B2111/00 for making sculptures or artistic casts
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/2092—Resistance against biological degradation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a kind of preparation method of ceramics, comprise the following steps：Prepare Chinese herbal medicine powder；Prepare pug；Prepare zirconia ceramics powder；Mix：Each raw material of base substrate is formed into dispensing according to weight, and prepares zirconia ceramics powder and pug using grinder grinding 2h, then addition, stirs, obtain batch mixing；Batch mixing is added into appropriate water and carries out rolling, and is stirred；Shaping：Batch mixing through pugging and it is old after, it is compressing under 40Mpa pressure；Prepare base substrate：Carry out natural curing, you can obtain the preparation method base substrate of Chinese herbal medicine ceramics；Spraying：Each raw material of coating is formed into dispensing according to weight, and uses grinder wet-milling 2h, stirs, obtains paint slurry；Spraying slurry, obtain ceramics；Preparation method science of the present invention is easy, and obtained ceramics has sterilization, antibacterial, performance of refreshing oneself, and smell is pure and fresh, health environment-friendly, and mechanical properties strength is higher.

Description

A kind of preparation method of ceramics
Technical field
The present invention relates to ceramic processing technique field, specially a kind of preparation method of ceramics.
Background technology
Traditional ceramics is typically by hand typically using more traditional color such as blueness, large red, handicraft The product of skill.Existing ceramics preparation method too complex, and obtained ceramics and mechanical properties strength compared with Low, handicraft is the product that is process raw material or semi-finished product by craft or machine, is to the total of one group of value art work Claim.Handicraft creates the value higher than life from life.It is people's crystallization of wisdom, has fully demonstrated people The creativeness and artistry of class, it is the priceless treasure of the mankind, but with requirement more and more higher of the people for handicraft, for The properties of handicraft also have higher requirement, in addition to viewing and admiring function with routine, it is also desirable to which handicraft has more The performance of more environmentally friendly, more added values, to meet everybody various demands.
So how to design a kind of preparation method of ceramics, turning into us will currently solve the problems, such as.
The content of the invention
The present invention provides a kind of preparation method of ceramics, and preparation method science is easy, obtained ceramics With sterilization, antibacterial, performance of refreshing oneself, smell is pure and fresh, health environment-friendly, and mechanical properties strength is higher, can effectively solve above-mentioned The problem of in background technology.
To achieve the above object, the present invention provides following technical scheme：A kind of preparation method of ceramics,
Handicraft base substrate weight composition is as follows：White clay 59-99 parts；Kaolin 50-80 parts；Alumine 30-40 parts；Black mud 20-40 parts；Quick lime 20-30 parts；Calcium hydroxide 8-20 parts；Silicon powder 5-8 parts；Nano aluminium oxide 5-8 parts；Fiber 5-8 parts；Silicic acid Zirconium 1-2 parts；Monoethanolamine 1-2 parts；Potassium chloride 1-2 parts；Sodium carbonate 1-2 parts；Chinese herbal medicine powder 1-3 parts；Water reducer 1-2 parts；
The weight composition of the handicraft coating is as follows：Water-base resin 30-35 parts；Chinese herbal medicine powder 1-2 parts；Additive 8-10 parts；Water 100-120 parts；
The preparation method of the handicraft is：
1）Prepare Chinese herbal medicine powder：Weigh pine needle meal, earthworm, peppermint, Lan Xiangshi, the achene of Siberian cocklebur, cloves, granatum, luffa vine, Chinese mugwort Leaf, Fructus Corni, Asiatic plantain, Chinese gall, cassia bark, chrysanthemum, desmodium triquetrum, aloe, santal, rhizome of cyrtomium, honeysuckle, orange peel, first done It is dry, then crush, obtain Chinese herbal medicine powder；
2）Prepare pug：Raw material is weighed according to above-mentioned raw materials proportioning, by feldspar, illite and mullite and the mixture of corundum First it is sanded, and it is 340 mesh screen residue 0.02-0.08 to control fineness, then plus water is tuned into slurry, then once feeds intake, will expect Slurry is incorporated clay and mineralizer, mixing and ball milling 3.0-4.0 hours again, and it is 250 mesh screen residue 0.4-0.8 to control fineness, then passes through Repeatedly sieving, multiple iron removaling, press filt and secondary thick white silk, it is finally old to be no less than 120 hours；Obtain pug；
3）Prepare zirconia ceramics powder：Hydrochloric acid solution is added into yttria solution, generates yttrium chloride solution；Yttrium chloride is molten After liquid, zirconyl chloride solution and polyethylene glycol mixing, ammonia spirit, generation yttrium hydroxide precipitation and precipitated zirconium hydroxide are instilled； Yttrium hydroxide precipitation and precipitated zirconium hydroxide are washed and filtered, then cleans and dries using absolute ethyl alcohol, obtains zirconium oxide pottery Porcelain presoma；Zirconia ceramics presoma is scattered in absolute ethyl alcohol, after drying and calcining, ball milling is carried out, obtains zirconium oxide Ceramic powder；
4）Mix：Each raw material of base substrate is formed into dispensing according to weight, and oxygen is prepared using grinder grinding 2h, then addition Change zircon ceramic powder and pug, stir, obtain batch mixing；Batch mixing is added into appropriate water and carries out rolling, and is stirred；
5）Shaping：Batch mixing through pugging and it is old after, it is compressing under 40Mpa pressure；
6）Prepare base substrate：Carry out natural curing, you can obtain the preparation method base substrate of Chinese herbal medicine ceramics；
7）Spraying：Each raw material of coating is formed into dispensing according to weight, and uses grinder wet-milling 2h, stirs, obtains coating Slurry；Spraying slurry, obtain ceramics.
According to above-mentioned technical proposal, the parts by weight of raw materials of the Chinese herbal medicine powder is：Pine needle meal 7-20 parts, earthworm 8-12 parts, Peppermint 8-10 parts, blue fragrant stone 8-12 parts, achene of Siberian cocklebur 6-9 parts, cloves 6-8 parts, granatum 5-10 parts, luffa vine 1-3 parts, folium artemisiae argyi 6- 10 parts, Fructus Corni 5-8 parts, Asiatic plantain 7-20 parts, Chinese gall 7-20 parts, cassia bark 20-30 parts, chrysanthemum 3-4 parts, desmodium triquetrum 3-4 parts, Aloe 3-4 parts, santal 3-4 parts, rhizome of cyrtomium 3-4 parts, honeysuckle 3-4 parts, orange peel 3-4 parts.
According to above-mentioned technical proposal, the step 1）The temperature of middle drying is 30-40 DEG C, needs to be sieved after it crushed Choosing, screening is 40-80 mesh with the specification of sieve.
According to above-mentioned technical proposal, the step 2）In after obtaining pug can will pug put into vacuum deairing machine in practice Mud；Dried in the shade again by electricity and the pug after pugging is dried, old processing after drying.
According to above-mentioned technical proposal, the preparation method of the water reducer is：First take the raw material of following parts by weight：Active oxidation Magnesium 5-10 parts, tufa stone micro mist 10-15 parts, Desulphurization 9-16 parts, melamine urea-formaldehyde resin 12-18 parts, microporous calcium silicate 6- 12 parts, polyisobutene 5-10 parts, tertiary ethylene carbonate 4-6 parts, 2- methyl -2,4-PD polyoxyethylene polyoxypropylene ether 2-4 Part, sodium pentachlorophenol 1.5-2.5 parts, Coconut Fatty Acid Monoethanolamide 3-5 parts, bone meal 4-8 parts, PDDA 2-4 parts, sulfonated phenylethylene-maleic anhydride multipolymer 5-10 parts；Then sulfonated phenylethylene-maleic anhydride is copolymerized Thing, PDDA, 2- methyl -2,4- pentanediol polyoxyethylene polyoxypropylene ethers are well mixed, Ran Houyi It is secondary to add activated magnesia, tufa stone micro mist, Desulphurization, 10-15min is stirred under 45-55 DEG C of bath temperature, is cooled to normal temperature, Drying, obtains compound A；Bone meal, microporous calcium silicate are well mixed again, then sequentially add melamine urea-formaldehyde resin, cocounut oil Sour single ethanol amide, polyisobutene, tertiary ethylene carbonate, sodium pentachlorophenol, scattered 5-10min, drying, obtains compound B at a high speed； Finally compound A and compound B are well mixed, produce water reducer.
According to above-mentioned technical proposal, the step 6）The environment of middle natural curing is that temperature is room temperature, and relative humidity is 85%.
According to above-mentioned technical proposal, the step 5）In old time be 100h.
Compared with prior art, beneficial effects of the present invention：Preparation method science of the present invention is easy, obtained ceramic process Product have sterilization, antibacterial, performance of refreshing oneself, and smell is pure and fresh, health environment-friendly, and mechanical properties strength is higher.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, and a part for constitution instruction, the reality with the present invention Apply example to be used to explain the present invention together, be not construed as limiting the invention.
In the accompanying drawings：
Fig. 1 is the preparation flow figure of the present invention.
Embodiment
The preferred embodiments of the present invention are illustrated below in conjunction with accompanying drawing, it will be appreciated that described herein preferred real Apply example to be merely to illustrate and explain the present invention, be not intended to limit the present invention.
Embodiment 1：As shown in figure 1, the present invention provides a kind of preparation method of ceramics,
Handicraft base substrate weight composition is as follows：59 parts of white clay；50 parts of kaolin；30 parts of alumine；20 parts of black mud；Quick lime 20 parts；8 parts of calcium hydroxide；5 parts of silicon powder；5 parts of nano aluminium oxide；5 parts of fiber；1 part of zirconium silicate；1 part of monoethanolamine；1 part of potassium chloride； 1 part of sodium carbonate；1 part of Chinese herbal medicine powder；1 part of water reducer；
The weight composition of the handicraft coating is as follows：30 parts of water-base resin；1 part of Chinese herbal medicine powder；8 parts of additive；100 parts of water；
The preparation method of the handicraft is：
1）Prepare Chinese herbal medicine powder：Weigh pine needle meal, earthworm, peppermint, Lan Xiangshi, the achene of Siberian cocklebur, cloves, granatum, luffa vine, Chinese mugwort Leaf, Fructus Corni, Asiatic plantain, Chinese gall, cassia bark, chrysanthemum, desmodium triquetrum, aloe, santal, rhizome of cyrtomium, honeysuckle, orange peel, first done It is dry, then crush, obtain Chinese herbal medicine powder；
2）Prepare pug：Raw material is weighed according to above-mentioned raw materials proportioning, by feldspar, illite and mullite and the mixture of corundum First it is sanded, and it is 340 mesh screen residue 0.02-0.08 to control fineness, then plus water is tuned into slurry, then once feeds intake, will expect Slurry is incorporated clay and mineralizer, mixing and ball milling 3.0-4.0 hours again, and it is 250 mesh screen residue 0.4-0.8 to control fineness, then passes through Repeatedly sieving, multiple iron removaling, press filt and secondary thick white silk, it is finally old to be no less than 120 hours；Obtain pug；
3）Prepare zirconia ceramics powder：Hydrochloric acid solution is added into yttria solution, generates yttrium chloride solution；Yttrium chloride is molten After liquid, zirconyl chloride solution and polyethylene glycol mixing, ammonia spirit, generation yttrium hydroxide precipitation and precipitated zirconium hydroxide are instilled； Yttrium hydroxide precipitation and precipitated zirconium hydroxide are washed and filtered, then cleans and dries using absolute ethyl alcohol, obtains zirconium oxide pottery Porcelain presoma；Zirconia ceramics presoma is scattered in absolute ethyl alcohol, after drying and calcining, ball milling is carried out, obtains zirconium oxide Ceramic powder；
4）Mix：Each raw material of base substrate is formed into dispensing according to weight, and oxygen is prepared using grinder grinding 2h, then addition Change zircon ceramic powder and pug, stir, obtain batch mixing；Batch mixing is added into appropriate water and carries out rolling, and is stirred；
5）Shaping：Batch mixing through pugging and it is old after, it is compressing under 40Mpa pressure；
6）Prepare base substrate：Carry out natural curing, you can obtain the preparation method base substrate of Chinese herbal medicine ceramics；
7）Spraying：Each raw material of coating is formed into dispensing according to weight, and uses grinder wet-milling 2h, stirs, obtains coating Slurry；Spraying slurry, obtain ceramics.
According to above-mentioned technical proposal, the parts by weight of raw materials of the Chinese herbal medicine powder is：7 parts of pine needle meal, 8 parts of earthworm, peppermint 8 Part, blue fragrant 8 parts of stone, 6 parts of the achene of Siberian cocklebur, 6 parts of cloves, 5 parts of granatum, 1 part of luffa vine, 6 parts of folium artemisiae argyi, 5 parts of Fructus Corni, Asiatic plantain 7 Part, 7 parts of Chinese gall, 20 parts of cassia bark, 3 parts of chrysanthemum, 3 parts of desmodium triquetrum, 3 parts of aloe, 3 parts of santal, 3 parts of rhizome of cyrtomium, 3 parts of honeysuckle, tangerine 3 parts of skin.
According to above-mentioned technical proposal, the step 1）The temperature of middle drying is 30-40 DEG C, needs to be sieved after it crushed Choosing, screening is 40-80 mesh with the specification of sieve.
According to above-mentioned technical proposal, the step 2）In after obtaining pug can will pug put into vacuum deairing machine in practice Mud；Dried in the shade again by electricity and the pug after pugging is dried, old processing after drying.
According to above-mentioned technical proposal, the preparation method of the water reducer is：First take the raw material of following parts by weight：Active oxidation Magnesium 5-10 parts, tufa stone micro mist 10-15 parts, Desulphurization 9-16 parts, melamine urea-formaldehyde resin 12-18 parts, microporous calcium silicate 6- 12 parts, polyisobutene 5-10 parts, tertiary ethylene carbonate 4-6 parts, 2- methyl -2,4-PD polyoxyethylene polyoxypropylene ether 2-4 Part, sodium pentachlorophenol 1.5-2.5 parts, Coconut Fatty Acid Monoethanolamide 3-5 parts, bone meal 4-8 parts, PDDA 2-4 parts, sulfonated phenylethylene-maleic anhydride multipolymer 5-10 parts；Then sulfonated phenylethylene-maleic anhydride is copolymerized Thing, PDDA, 2- methyl -2,4- pentanediol polyoxyethylene polyoxypropylene ethers are well mixed, Ran Houyi It is secondary to add activated magnesia, tufa stone micro mist, Desulphurization, 10-15min is stirred under 45-55 DEG C of bath temperature, is cooled to normal temperature, Drying, obtains compound A；Bone meal, microporous calcium silicate are well mixed again, then sequentially add melamine urea-formaldehyde resin, cocounut oil Sour single ethanol amide, polyisobutene, tertiary ethylene carbonate, sodium pentachlorophenol, scattered 5-10min, drying, obtains compound B at a high speed； Finally compound A and compound B are well mixed, produce water reducer.
According to above-mentioned technical proposal, the step 6）The environment of middle natural curing is that temperature is room temperature, and relative humidity is 85%.
According to above-mentioned technical proposal, the step 5）In old time be 100h.
Embodiment 2：As shown in figure 1, the present invention provides a kind of preparation method of ceramics,
Handicraft base substrate weight composition is as follows：99 parts of white clay；80 parts of kaolin；40 parts of alumine；40 parts of black mud；Quick lime 30 parts；20 parts of calcium hydroxide；8 parts of silicon powder；8 parts of nano aluminium oxide；8 parts of fiber；2 parts of zirconium silicate；2 parts of monoethanolamine；Potassium chloride 2 Part；2 parts of sodium carbonate；3 parts of Chinese herbal medicine powder；2 parts of water reducer；
The weight composition of the handicraft coating is as follows：35 parts of water-base resin；2 parts of Chinese herbal medicine powder；10 parts of additive；120 parts of water；
The preparation method of the handicraft is：
1）Prepare Chinese herbal medicine powder：Weigh pine needle meal, earthworm, peppermint, Lan Xiangshi, the achene of Siberian cocklebur, cloves, granatum, luffa vine, Chinese mugwort Leaf, Fructus Corni, Asiatic plantain, Chinese gall, cassia bark, chrysanthemum, desmodium triquetrum, aloe, santal, rhizome of cyrtomium, honeysuckle, orange peel, first done It is dry, then crush, obtain Chinese herbal medicine powder；
2）Prepare pug：Raw material is weighed according to above-mentioned raw materials proportioning, by feldspar, illite and mullite and the mixture of corundum First it is sanded, and it is 340 mesh screen residue 0.02-0.08 to control fineness, then plus water is tuned into slurry, then once feeds intake, will expect Slurry is incorporated clay and mineralizer, mixing and ball milling 3.0-4.0 hours again, and it is 250 mesh screen residue 0.4-0.8 to control fineness, then passes through Repeatedly sieving, multiple iron removaling, press filt and secondary thick white silk, it is finally old to be no less than 120 hours；Obtain pug；
3）Prepare zirconia ceramics powder：Hydrochloric acid solution is added into yttria solution, generates yttrium chloride solution；Yttrium chloride is molten After liquid, zirconyl chloride solution and polyethylene glycol mixing, ammonia spirit, generation yttrium hydroxide precipitation and precipitated zirconium hydroxide are instilled； Yttrium hydroxide precipitation and precipitated zirconium hydroxide are washed and filtered, then cleans and dries using absolute ethyl alcohol, obtains zirconium oxide pottery Porcelain presoma；Zirconia ceramics presoma is scattered in absolute ethyl alcohol, after drying and calcining, ball milling is carried out, obtains zirconium oxide Ceramic powder；
4）Mix：Each raw material of base substrate is formed into dispensing according to weight, and oxygen is prepared using grinder grinding 2h, then addition Change zircon ceramic powder and pug, stir, obtain batch mixing；Batch mixing is added into appropriate water and carries out rolling, and is stirred；
5）Shaping：Batch mixing through pugging and it is old after, it is compressing under 40Mpa pressure；
6）Prepare base substrate：Carry out natural curing, you can obtain the preparation method base substrate of Chinese herbal medicine ceramics；
7）Spraying：Each raw material of coating is formed into dispensing according to weight, and uses grinder wet-milling 2h, stirs, obtains coating Slurry；Spraying slurry, obtain ceramics.
According to above-mentioned technical proposal, the parts by weight of raw materials of the Chinese herbal medicine powder is：20 parts of pine needle meal, 12 parts of earthworm, peppermint 10 parts, blue fragrant 12 parts of stone, 9 parts of the achene of Siberian cocklebur, 8 parts of cloves, 10 parts of granatum, 3 parts of luffa vine, 10 parts of folium artemisiae argyi, 8 parts of Fructus Corni, car First careless 20 parts, 20 parts of Chinese gall, 30 parts of cassia bark, 4 parts of chrysanthemum, 4 parts of desmodium triquetrum, 4 parts of aloe, 4 parts of santal, 4 parts of rhizome of cyrtomium, honeysuckle 4 parts, 4 parts of orange peel.
According to above-mentioned technical proposal, the step 1）The temperature of middle drying is 30-40 DEG C, needs to be sieved after it crushed Choosing, screening is 40-80 mesh with the specification of sieve.
According to above-mentioned technical proposal, the step 2）In after obtaining pug can will pug put into vacuum deairing machine in practice Mud；Dried in the shade again by electricity and the pug after pugging is dried, old processing after drying.
According to above-mentioned technical proposal, the preparation method of the water reducer is：First take the raw material of following parts by weight：Active oxidation Magnesium 5-10 parts, tufa stone micro mist 10-15 parts, Desulphurization 9-16 parts, melamine urea-formaldehyde resin 12-18 parts, microporous calcium silicate 6- 12 parts, polyisobutene 5-10 parts, tertiary ethylene carbonate 4-6 parts, 2- methyl -2,4-PD polyoxyethylene polyoxypropylene ether 2-4 Part, sodium pentachlorophenol 1.5-2.5 parts, Coconut Fatty Acid Monoethanolamide 3-5 parts, bone meal 4-8 parts, PDDA 2-4 parts, sulfonated phenylethylene-maleic anhydride multipolymer 5-10 parts；Then sulfonated phenylethylene-maleic anhydride is copolymerized Thing, PDDA, 2- methyl -2,4- pentanediol polyoxyethylene polyoxypropylene ethers are well mixed, Ran Houyi It is secondary to add activated magnesia, tufa stone micro mist, Desulphurization, 10-15min is stirred under 45-55 DEG C of bath temperature, is cooled to normal temperature, Drying, obtains compound A；Bone meal, microporous calcium silicate are well mixed again, then sequentially add melamine urea-formaldehyde resin, cocounut oil Sour single ethanol amide, polyisobutene, tertiary ethylene carbonate, sodium pentachlorophenol, scattered 5-10min, drying, obtains compound B at a high speed； Finally compound A and compound B are well mixed, produce water reducer.
According to above-mentioned technical proposal, the step 6）The environment of middle natural curing is that temperature is room temperature, and relative humidity is 85%.
According to above-mentioned technical proposal, the step 5）In old time be 100h.
Based on above-mentioned, it is an advantage of the current invention that preparation method science is easy, obtained ceramics have sterilization, Antibacterial, performance of refreshing oneself, smell is pure and fresh, health environment-friendly, and mechanical properties strength is higher.
Finally it should be noted that：The preferred embodiment of the present invention is the foregoing is only, is not intended to limit the invention, to the greatest extent The present invention is described in detail with reference to the foregoing embodiments for pipe, and for those skilled in the art, it still can be with Technical scheme described in foregoing embodiments is modified, or equivalent substitution is carried out to which part technical characteristic.It is all Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., it should be included in the guarantor of the present invention Within the scope of shield.

Claims (7)

  1. A kind of 1. preparation method of ceramics, it is characterised in that：
    Handicraft base substrate weight composition is as follows：White clay 59-99 parts；Kaolin 50-80 parts；Alumine 30-40 parts；Black mud 20-40 parts；Quick lime 20-30 parts；Calcium hydroxide 8-20 parts；Silicon powder 5-8 parts；Nano aluminium oxide 5-8 parts；Fiber 5-8 parts；Silicic acid Zirconium 1-2 parts；Monoethanolamine 1-2 parts；Potassium chloride 1-2 parts；Sodium carbonate 1-2 parts；Chinese herbal medicine powder 1-3 parts；Water reducer 1-2 parts；
    The weight composition of the handicraft coating is as follows：Water-base resin 30-35 parts；Chinese herbal medicine powder 1-2 parts；Additive 8-10 parts；Water 100-120 parts；
    The preparation method of the handicraft is：
    1）Prepare Chinese herbal medicine powder：Weigh pine needle meal, earthworm, peppermint, Lan Xiangshi, the achene of Siberian cocklebur, cloves, granatum, luffa vine, Chinese mugwort Leaf, Fructus Corni, Asiatic plantain, Chinese gall, cassia bark, chrysanthemum, desmodium triquetrum, aloe, santal, rhizome of cyrtomium, honeysuckle, orange peel, first done It is dry, then crush, obtain Chinese herbal medicine powder；
    2）Prepare pug：Raw material is weighed according to above-mentioned raw materials proportioning, by feldspar, illite and mullite and the mixture of corundum First it is sanded, and it is 340 mesh screen residue 0.02-0.08 to control fineness, then plus water is tuned into slurry, then once feeds intake, will expect Slurry is incorporated clay and mineralizer, mixing and ball milling 3.0-4.0 hours again, and it is 250 mesh screen residue 0.4-0.8 to control fineness, then passes through Repeatedly sieving, multiple iron removaling, press filt and secondary thick white silk, it is finally old to be no less than 120 hours；Obtain pug；
    3）Prepare zirconia ceramics powder：Hydrochloric acid solution is added into yttria solution, generates yttrium chloride solution；Yttrium chloride is molten After liquid, zirconyl chloride solution and polyethylene glycol mixing, ammonia spirit, generation yttrium hydroxide precipitation and precipitated zirconium hydroxide are instilled； Yttrium hydroxide precipitation and precipitated zirconium hydroxide are washed and filtered, then cleans and dries using absolute ethyl alcohol, obtains zirconium oxide pottery Porcelain presoma；Zirconia ceramics presoma is scattered in absolute ethyl alcohol, after drying and calcining, ball milling is carried out, obtains zirconium oxide Ceramic powder；
    4）Mix：Each raw material of base substrate is formed into dispensing according to weight, and oxygen is prepared using grinder grinding 2h, then addition Change zircon ceramic powder and pug, stir, obtain batch mixing；Batch mixing is added into appropriate water and carries out rolling, and is stirred；
    5）Shaping：Batch mixing through pugging and it is old after, it is compressing under 40Mpa pressure；
    6）Prepare base substrate：Carry out natural curing, you can obtain the preparation method base substrate of Chinese herbal medicine ceramics；
    7）Spraying：Each raw material of coating is formed into dispensing according to weight, and uses grinder wet-milling 2h, stirs, obtains coating Slurry；Spraying slurry, obtain ceramics.
  2. A kind of 2. preparation method of ceramics according to claim 1, it is characterised in that：The original of the Chinese herbal medicine powder Expect that parts by weight are：Pine needle meal 7-20 parts, earthworm 8-12 parts, peppermint 8-10 parts, blue fragrant stone 8-12 parts, achene of Siberian cocklebur 6-9 parts, cloves 6- 8 parts, granatum 5-10 parts, luffa vine 1-3 parts, folium artemisiae argyi 6-10 parts, Fructus Corni 5-8 parts, Asiatic plantain 7-20 parts, Chinese gall 7-20 Part, cassia bark 20-30 parts, chrysanthemum 3-4 parts, desmodium triquetrum 3-4 parts, aloe 3-4 parts, santal 3-4 parts, rhizome of cyrtomium 3-4 parts, honeysuckle 3-4 Part, orange peel 3-4 parts.
  3. A kind of 3. preparation method of ceramics according to claim 1, it is characterised in that：The step 1）Middle drying Temperature be 30-40 DEG C, need to be screened after it crushed, screening is 40-80 mesh with the specification of sieve.
  4. A kind of 4. preparation method of ceramics according to claim 1, it is characterised in that：The step 2）In Pug can be put into pugging in vacuum deairing machine after to pug；Dried in the shade again by electricity and the pug after pugging is dried, done Old processing after dry.
  5. A kind of 5. preparation method of ceramics according to claim 1, it is characterised in that：The preparation of the water reducer Method is：First take the raw material of following parts by weight：Activated magnesia 5-10 parts, tufa stone micro mist 10-15 parts, Desulphurization 9-16 parts, Melamine urea-formaldehyde resin 12-18 parts, microporous calcium silicate 6-12 parts, polyisobutene 5-10 parts, tertiary ethylene carbonate 4-6 parts, 2- Methyl -2,4-PD polyoxyethylene polyoxypropylene ether 2-4 parts, sodium pentachlorophenol 1.5-2.5 parts, Coconut Fatty Acid Monoethanolamide 3- 5 parts, bone meal 4-8 parts, PDDA 2-4 parts, sulfonated phenylethylene-maleic anhydride multipolymer 5-10 Part；Then by sulfonated phenylethylene-maleic anhydride multipolymer, PDDA, 2- methyl -2,4- penta 2 Alcohol polyoxyethylene polyoxypropylene ether is well mixed, and then sequentially adds activated magnesia, tufa stone micro mist, Desulphurization, 45-55 DEG C 10-15min is stirred under bath temperature, is cooled to normal temperature, dries, obtains compound A；Bone meal, microporous calcium silicate are well mixed again, Then melamine urea-formaldehyde resin, Coconut Fatty Acid Monoethanolamide, polyisobutene, tertiary ethylene carbonate, pentachlorophenol are sequentially added Sodium, scattered 5-10min, drying, obtains compound B at a high speed；Finally compound A and compound B are well mixed, produce water reducer.
  6. A kind of 6. preparation method of ceramics according to claim 1, it is characterised in that：The step 6）Middle nature The environment of maintenance is that temperature is room temperature, relative humidity 85%.
  7. A kind of 7. preparation method of ceramics according to claim 1, it is characterised in that：The step 5）In it is old Time be 100h.
CN201710700228.5A 2017-08-16 2017-08-16 A kind of preparation method of ceramics Pending CN107522451A (en)

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CN108358620A (en) * 2018-01-24 2018-08-03 合肥智龙机械设计有限公司 A kind of medical composite ceramic material and preparation method thereof that mechanical property is good
CN108407052A (en) * 2018-04-20 2018-08-17 佛山汇众森泰科技有限公司 A kind of anti-aging Ceramic manufacturing method
CN109624051A (en) * 2018-10-29 2019-04-16 湖北万硕新型材料有限公司 A kind of porcelain tendre production line
CN114409334A (en) * 2022-01-24 2022-04-29 武汉理工大学 Carbon mineralized material based on extrusion molding and preparation method thereof

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CN104829204A (en) * 2015-04-11 2015-08-12 苏州神林堂中医药研究所 Landscape component containing Chinese herbal medicines
CN105347789A (en) * 2015-11-24 2016-02-24 东莞信柏结构陶瓷有限公司 Preparation method for zirconium oxide porous ceramic artwork
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CN104119019A (en) * 2014-06-25 2014-10-29 芜湖市三兴混凝土外加剂有限公司 Water-reducing agent containing peanut shell powder
CN104742634A (en) * 2015-04-11 2015-07-01 苏州市博群生物科技有限公司 Chinese herbal medicine ceramic artwork
CN104744015A (en) * 2015-04-11 2015-07-01 苏州神林堂中医药研究所 Preparation method of garden component containing Chinese herbal medicines
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108358620A (en) * 2018-01-24 2018-08-03 合肥智龙机械设计有限公司 A kind of medical composite ceramic material and preparation method thereof that mechanical property is good
CN108407052A (en) * 2018-04-20 2018-08-17 佛山汇众森泰科技有限公司 A kind of anti-aging Ceramic manufacturing method
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CN114409334A (en) * 2022-01-24 2022-04-29 武汉理工大学 Carbon mineralized material based on extrusion molding and preparation method thereof
CN114409334B (en) * 2022-01-24 2022-12-13 武汉理工大学 Carbon mineralized material based on extrusion molding and preparation method thereof

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