CN106116454A - A kind of it is difficult to dirty ceramic ware for daily use - Google Patents

Abstract

The invention discloses and a kind of be difficult to dirty ceramic ware for daily use, it is made up of the raw material of following weight portion: bauxite clay 12 18, silicon dioxide 34, brown ocher 8 10, calcite in powder 10 13, rectorite 14 15, carboxymethyl cellulose 34, shaddock peel powder 8 10, P-hydroxybenzoic acid 23, waste ceramic powder 10 13, dimethicone 12, flyash 40 45, white glaze ball 35 40, cullet 68, Maifanitum 10 14, green tea 21 25, Pericarpium citri sinensis 14 17, conch meal 68, shrimp shell meal 46, polyvinyl alcohol 0.2 0.3, tributyl phosphate 0.2 0.3, deionized water is appropriate；The domestic ceramics of the present invention is difficult to dirty, easy to clean, also has and kills antibacterial, fungistatic effect, raw materials used abundance, cheap, without any side effects to human body, has wide market prospect.

Description

A kind of it is difficult to dirty ceramic ware for daily use

Technical field

The present invention relates to domestic ceramics technical field, particularly relate to a kind of be difficult to dirty ceramic ware for daily use.

Background technology

China's not only rich in mineral resources, is also coal production state maximum in the world and consumption of coal state, in recent years simultaneously Coming, China's thermal power generation quickly grows, and wherein great majority are with coal as fuel, and generated energy reaches 1.3 hundred million kW h, shared by thermal power generation Ratio has reached 79.6%, thus causes flyash discharge capacity to increase year by year.In the end of the year 2010, discharge capacity reaches nearly 300,000,000 tons, in a large number The discharge of flyash have received to be paid close attention to the most widely.China started just to how utilizing flyash as resource from 1987 The breach of comprehensive utilization, comprehensively utilizes it, becomes a long-range policy of economy and social development.Cullet class thing Its chemical stability of matter is extremely strong, without putrefaction, does not burns, can not degrade, and substantial amounts of cullet both took up an area, and polluted again environment, reclaimed Being to save the energy, the optimal path of protection environment with utilizing, and have good economy, the main component of glass is dioxy SiClx, it is possible to promote the sintering of pottery.In Production of Ceramics, firing temperature is the highest, and firing time is the longest, and energy consumption is the highest, according to Heat Balance Calculation, firing temperature often reduces by 100 DEG C, then unit product heat consumption can reduce by more than 10%, and firing time often shortens 10%, Then yield increases by 10%, and heat consumption reduces by 4%, so reduction firing temperature and time have significant energy-saving and emission-reduction social meaning.

Over nearly 20 years, ceramic industry enters developmental stage with rapid changepl. never-ending changes and improvements, new technique, a large amount of uses of new equipment, pottery Porcelain yield also increases by a fairly big margin.New ceramics, as a kind of new material, solely sets one with the performance of its excellence at Material Field Flag, is paid much attention to by people.Domestic ceramics occupies an important position at Material Field as traditional ceramics material, because it Relating to the every aspect of people's life, the development of domestic ceramics is more wanted along with the raising of people's living standard proposes Asking, the most antibacterial is to propose most common requirement at present.Due to the wilderness demand of porcelain, a large amount of exploitations of china clay resource are just with frightened The speed of people reduces, and is non-renewable resources, if can not find alternate resources, it is likely that can face No Assets later The difficult situation that can adopt.Yang Yuwei et al. is at " utilizing the industrial wastes such as flyash to prepare the research of a domestic ceramics " literary composition middle finger Go out, utilize the flyash of power plant emission, a large amount of useless saggars of ceramic industry generation, useless porcelain powder to utilize Orthogonal Experiment and Design to join Side, develops cleaning and produces the formula of domestic ceramics, wherein flyash, useless saggar, the content of useless porcelain powder be 10% respectively, 10%, 8%, applying this technology can be that enterprise brings considerable economic benefit, and the recycling for flyash finds an exit, although carry High Social benefit and economic benefit, but a lot of performance is not reaching to the requirement of people, the most antibacterial, high temperature resistance, freeze proof etc. The shortcoming that performance is the highest, service life is not grown.

Summary of the invention

The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of be difficult to dirty ceramic ware for daily use.

The present invention is achieved by the following technical solutions:

A kind of it is difficult to dirty ceramic ware for daily use, is made up of the raw material of following weight portion: bauxite clay 12-18, dioxy SiClx 3-4, brown ocher 8-10, calcite in powder 10-13, rectorite 14-15, carboxymethyl cellulose 3-4, shaddock peel powder 8-10, right Hydroxy benzoic acid 2-3, waste ceramic powder 10-13, dimethicone 1-2, flyash 40-45, white glaze ball 35-40, cullet 6- 8, Maifanitum 10-14, green tea 21-25, Pericarpium citri sinensis 14-17, conch meal 6-8, shrimp shell meal 4-6, polyvinyl alcohol 0.2-0.3, phosphoric acid Tributyl 0.2-0.3, deionized water are appropriate.

Described a kind of it is difficult to dirty ceramic ware for daily use, is made up of following concrete steps:

(1) being mixed by the deionized water of carboxymethyl cellulose, shaddock peel powder and 40-50 times amount, heated and stirred forms pastel, then adds Enter P-hydroxybenzoic acid, waste ceramic powder, dimethicone continuation stirring, grind the even complex antimicrobials that obtains, dry after vacuum defoamation Dry standby；

(2) by Maifanitum clean dry after wear into fine powder, by green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal mixing be added to 75% second In alcoholic solution, decoct 20-30min when 50-60 DEG C, be continuously heating to when 90-100 DEG C decoct 10-20min, be cooled to room temperature After carry out centrifugation, take after its supernatant concentration and polyvinyl alcohol, medical stone powder, tributyl phosphate ball milling 30-40min, knot While being stirred continuously slurry with direct current drive blender after bundle, it is standby that spray drying makes nano medical stone microsphere；

(3) cullet is cleaned up post-drying to crush, be then added to ground 100-200 mesh sieve in colloid mill, by glass Glass powder and flyash, rectorite, bauxite clay, brown ocher are mixed to get dry material, add and account for dry material gross mass 40-50% Deionized water, obtained the slurry of 300-400 mesh through ball mill pulverizing；

(4) the slurry magnetic separator that step (3) obtains is carried out iron removal by magnetic separation, make content≤0.2% of ferrum in slurry, by slurry It is added to drying and moulding in forming machine and obtains base substrate, base substrate is put in the sintering furnace that in-furnace temperature is 100-200 DEG C, at 1250- Carrying out at a temperature of 1280 DEG C calcining 5-7h, after being cooled to room temperature, polishing is scraped standby；

(5) antibacterial mixing white glaze ball, silicon dioxide, calcite in powder and step (1) obtained, is added in ball mill to carry out wet Method ball milling, adds the deionized water of material gross weight 45-55%, the glaze slip after ball milling is crossed 200 mesh, 300 mesh sieves respectively, removes Impurity and coarse granule, obtain thin glaze slip, by glaze slip glazing on biscuit prepared by step (4), sinters 4-at 1160-1200 DEG C 5h；

(6) nano medical stone microsphere and the phosphoric acid hydrogen al binder step (2) prepared mix according to 2-3:1 ratio, are coated in Ceramic surface prepared by step (5), after drying in the shade, at 120-140 DEG C, constant temperature 2h is the most available.

The invention have the advantage that the present invention utilizes waste resource flyash as Ceramic Material, reduce the dirt to environment Dye, and wherein silicon oxide, alumina content are higher, and specific grain surface is long-pending big in loose structure, easily grinds, can reduce system The firing temperature of product, reaches energy-conservation purpose, and discarded glass, with flyash sintering process, melts at low temperatures, is formed Glass phase, plays the effect of bonding agent, reduces firing temperature, and it is smooth, freeze proof, easy to clean, anti-to improve ceramic surface The performance of the aspects such as impact, by the antibacterial of synthesis and glaze mixing glazing on biscuit of ceramics surface, improves ceramic antibacterial Performance, reduces the danger coefficient that the mankind are ill, and uses the decoction of green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal to extract trace Element Maifanitum cladding forms nano medical stone microsphere, utilizes binding agent to be bonded in ceramic surface, solvable by being heated for a long time Going out the multiple trace element useful to human body, the body for people provides nutrition, building body, regulates metabolism, to human body Benefiting, the domestic ceramics of the present invention is difficult to dirty, easy to clean, simultaneously under light and heat condition, also has and kills antibacterial and press down Make vegetative special-effect, and the raw materials used abundance of the present invention, cheap, without any side effects to human body, There is wide market prospect.

Detailed description of the invention

A kind of it is difficult to dirty ceramic ware for daily use, is made up of the raw material of following weight portion (kilogram): bauxite clay 12, silicon dioxide 3, brown ocher 8, calcite in powder 10, rectorite 14, carboxymethyl cellulose 3, shaddock peel powder 8, P-hydroxybenzoic acid 2, waste ceramic powder 10, dimethicone 1, flyash 40, white glaze ball 35, cullet 6, Maifanitum 10, green tea 21, Pericarpium citri sinensis 14, conch meal 6, shrimp shell meal 4, polyvinyl alcohol 0.2, tributyl phosphate 0.2, deionized water are appropriate.

Described a kind of it is difficult to dirty ceramic ware for daily use, is made up of following concrete steps:

(1) being mixed by the deionized water of carboxymethyl cellulose, shaddock peel powder and 40 times amount, heated and stirred forms pastel, adds P-hydroxybenzoic acid, waste ceramic powder, dimethicone continue stirring, grind the even complex antimicrobials that obtains, and are dried after vacuum defoamation Standby；

(2) by Maifanitum clean dry after wear into fine powder, by green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal mixing be added to 75% second In alcoholic solution, decoct 20min when 50 DEG C, when being continuously heating to 90 DEG C, decoct 10min, be centrifuged after being cooled to room temperature point From, take after its supernatant concentration and polyvinyl alcohol, medical stone powder, tributyl phosphate ball milling 30min, after terminating, use unidirectional current Slurry is stirred continuously by dynamic blender, and it is standby that spray drying makes nano medical stone microsphere；

(3) cullet is cleaned up post-drying to crush, be then added to ground 100 mesh sieves in colloid mill, by glass dust It is mixed to get dry material with flyash, rectorite, bauxite clay, brown ocher, adds the deionization accounting for dry material gross mass 40% Water, obtained the slurry of 300 mesh through ball mill pulverizing；

(4) the slurry magnetic separator that step (3) obtains is carried out iron removal by magnetic separation, make content≤0.2% of ferrum in slurry, by slurry It is added to drying and moulding in forming machine and obtains base substrate, base substrate is put in the sintering furnace that in-furnace temperature is 100 DEG C, 1250 DEG C of temperature Under carry out calcine 5h, after being cooled to room temperature polishing scrape standby；

(5) antibacterial mixing white glaze ball, silicon dioxide, calcite in powder and step (1) obtained, is added in ball mill to carry out wet Method ball milling, adds the deionized water of material gross weight 45%, the glaze slip after ball milling is crossed 200 mesh, 300 mesh sieves respectively, goes the removal of impurity And coarse granule, obtain thin glaze slip, by glaze slip glazing on biscuit prepared by step (4), at 1160 DEG C, sinter 4h；

(6) nano medical stone microsphere and the phosphoric acid hydrogen al binder step (2) prepared mix according to 2:1 ratio, are coated in step Suddenly the ceramic surface that prepared by (5), after drying in the shade, at 120 DEG C, constant temperature 2h is the most available.

Test data:

Product appearance is regular, and glaze is smooth；Thermal shock resistance test reaches heat exchange in 20 DEG C of water of 200 DEG C of inputs and does not splits；Machine Tool intensity >=140mp2；Glaze vickers microhardness >=6.0GPa；Sunlight germicidal efficiency >=76% of lower 1 hour；Shock resistance is strong Degree >=1.3J/cm2.

Claims (2)

1. one kind is difficult to dirty ceramic ware for daily use, it is characterised in that be made up of the raw material of following weight portion: aluminum matter is glued Soil 12-18, silicon dioxide 3-4, brown ocher 8-10, calcite in powder 10-13, rectorite 14-15, carboxymethyl cellulose 3-4, Fructus Citri grandis Corium farinosum 8-10, P-hydroxybenzoic acid 2-3, waste ceramic powder 10-13, dimethicone 1-2, flyash 40-45, white glaze ball 35- 40, cullet 6-8, Maifanitum 10-14, green tea 21-25, Pericarpium citri sinensis 14-17, conch meal 6-8, shrimp shell meal 4-6, polyvinyl alcohol 0.2-0.3, tributyl phosphate 0.2-0.3, deionized water are appropriate.

A kind of it is difficult to dirty ceramic ware for daily use, it is characterised in that by following concrete steps system Prepare into:

(1) being mixed by the deionized water of carboxymethyl cellulose, shaddock peel powder and 40-50 times amount, heated and stirred forms pastel, then adds Enter P-hydroxybenzoic acid, waste ceramic powder, dimethicone continuation stirring, grind the even complex antimicrobials that obtains, dry after vacuum defoamation Dry standby；

(2) by Maifanitum clean dry after wear into fine powder, by green tea, Pericarpium citri sinensis, conch meal, shrimp shell meal mixing be added to 75% second In alcoholic solution, decoct 20-30min when 50-60 DEG C, be continuously heating to when 90-100 DEG C decoct 10-20min, be cooled to room temperature After carry out centrifugation, take after its supernatant concentration and polyvinyl alcohol, medical stone powder, tributyl phosphate ball milling 30-40min, knot While being stirred continuously slurry with direct current drive blender after bundle, it is standby that spray drying makes nano medical stone microsphere；

(3) cullet is cleaned up post-drying to crush, be then added to ground 100-200 mesh sieve in colloid mill, by glass Glass powder and flyash, rectorite, bauxite clay, brown ocher are mixed to get dry material, add and account for dry material gross mass 40-50% Deionized water, obtained the slurry of 300-400 mesh through ball mill pulverizing；

(4) the slurry magnetic separator that step (3) obtains is carried out iron removal by magnetic separation, make content≤0.2% of ferrum in slurry, by slurry It is added to drying and moulding in forming machine and obtains base substrate, base substrate is put in the sintering furnace that in-furnace temperature is 100-200 DEG C, at 1250- Carrying out at a temperature of 1280 DEG C calcining 5-7h, after being cooled to room temperature, polishing is scraped standby；

(5) antibacterial mixing white glaze ball, silicon dioxide, calcite in powder and step (1) obtained, is added in ball mill to carry out wet Method ball milling, adds the deionized water of material gross weight 45-55%, the glaze slip after ball milling is crossed 200 mesh, 300 mesh sieves respectively, removes Impurity and coarse granule, obtain thin glaze slip, by glaze slip glazing on biscuit prepared by step (4), sinters 4-at 1160-1200 DEG C 5h；

(6) nano medical stone microsphere and the phosphoric acid hydrogen al binder step (2) prepared mix according to 2-3:1 ratio, are coated in Ceramic surface prepared by step (5), after drying in the shade, at 120-140 DEG C, constant temperature 2h is the most available.