CN107502011A

CN107502011A - Antistatic inorganic nano paint composition, clear coat and antistatic product

Info

Publication number: CN107502011A
Application number: CN201710936679.9A
Authority: CN
Inventors: 张麒
Original assignee: Zhangjiagang Aliens New Mstar Technology Ltd
Current assignee: Shenzhen Harm Reduction Technology Co.,Ltd.
Priority date: 2017-10-10
Filing date: 2017-10-10
Publication date: 2017-12-22
Anticipated expiration: 2037-10-10
Also published as: CN107502011B

Abstract

The invention discloses a kind of antistatic inorganic nano paint composition, clear coat and antistatic product.Implement peroxy modified surface modification hydroxyl to the electric conductivity in synthesis or after synthesis and rockiness nano material using the modifying agent containing peroxy-O-O-, repelled each other because of its particle surface band hydroxyl negative electrical charge of the same race and inhibit particle agglomeration, make these nano materials without dispersant just can in the liquid such as water it is dispersed into stable nano paint, without adhesive or organic resinoid, with regard to that this kind of nano paint can be coated into photovoltaic panel, glass, the body surfaces such as glasses simultaneously make product obtain antistatic inorganic nano clear coat, the nano material of surface modification hydroxyl after low temperature and cold curing because can form inter-molecular attraction in coating, or dehydration formation-O- covalent bonds on curing at elevated temperature, all there is qualified rub resistance and adhesive force in product surface.

Description

Antistatic inorganic nano paint composition, clear coat and antistatic product

Technical field

The present invention relates to antistatic inorganic nano paint composition, clear coat and antistatic product, belong to nano material Field.

Background technology

The inorganic nano materials such as tin oxide, tin indium oxide have higher electric conductivity, and tungsten oxide, cerium oxide etc. are inorganic receives Rice material has higher rockiness, and this is the general knowledge of Material Field, in order to give play to the excellent properties of these nano materials, people Generally by they be made nano paint use, this is also widely known.When disperseing nano material in a liquid, if only borrowed Help stirring or milling apparatus obtained by nano paint be easy to sedimentation layering, even if coating film forming, the adhesive force of coating also can be very Difference.Therefore, people can only add the compounding material such as the auxiliary agents such as dispersant, film forming agent and resin, adhesive, could receive these Rice material is dispersed and the qualified nano paint of adhesive force is made, but these auxiliary agents and compounding material would generally be with nanometer materials Material is cured in prepared coating together, and this can undoubtedly reduce original performance of nano material in article coatings, such as have The auxiliary agents such as machine class dispersant, film forming agent can reduce the electric conductivity, resin, adhesive etc. in coating between nano indium oxide tin particles Compounding material can reduce hardness of nano-cerium oxide coating etc..

Electrostatic can be commonly used by people for spraying and duplicate etc. in equipment, but electrostatic shows as brokenly in human being's production life Bad person, such as trigger electrical short-circuit, workshop fire and cause a large amount of laying dusts of body surface etc..

According to existing national standards《GB/T 1410-2006 solid insulating materials specific insulations and surface resistivity experiment Method》Definition：Sheet resistance be between two electrodes on its surface of sample institute's making alive with being flowed in the defined electrochemical time The business of two interelectrode electric currents is crossed, the polarization being likely to form on two electrodes is ignored.Surface resistivity (ρ s) is in material DC electric field intensity and the business of electric current per unit length in superficial layer, i.e., the sheet resistance in unit area, the size of area is not Important.The SI units of surface resistivity are ohm (Ω), and actually conventional " Europe is per square unit " represents that symbol is Ω/ Or Ω/sq.

The sheet resistance or surface resistivity of material are smaller to be less susceptible to produce electrostatic.

Surface resistivity ρ s ＞ 10¹²The material of (Ω/) is insulator, and being also easy to produce electrostatic and itself can not release, thus Without electrostatic-proof function.

Surface resistivity is 10⁵(Ω/) ＜ ρ s≤10¹²The material of (Ω/) is referred to as because having static electricity discharge function Electrostatically dissipative material.

Static conductive and electrostatically dissipative material are collectively referred to as antistatic material.

It is attempted to prepare anti-static coating in insulator surface by anti-static coatings, reduces its surface and produce electrostatic Harm.

Currently, anti-static coatings disclosed in patent document are typically in epoxy resin, polyurethane resin, acrylic resin etc. Conductive filler is added in macromolecule organic resin or organic emulsion（As conductive mica powder, conductive zinc oxide, conductive potassium titanate are brilliant Palpus, conductive auxiliary agent etc.）, the application number such as 03816920.7 of such patent, 201510743569.1,201610603379.4, 201410791784.4、201510858308.4、201310456714.9、201410414741.4、201610590841.1、 201310058652.6、201610603620.3、201610238732.3、2014104310062.5、201510455248.1、 201310338916.3、201510458075.9、201510806724.X、201610371777.8、2016103308100.7、 201510859184.1、200810041949.0、201510786491.1、201410831053.8、2014105199.3、 20141038807.9、201310516318.0、201510069301.4、201510460435.9、201410680438.9、 201510516728.4、201310728978.5、201310366329.5、201410735864.8、2016107256465、 201410624512.5、201110307596.6、201510609403.0、201410823568.3、2016102877100.0、 201310587846.5、201510361227.3、201610256618.3、201510877227.9、201210590489.3、 201610204271.8、201510678789.0、201310338916.3、201310654484.7、201410741592.2、 200510025368.4 wait.These anti-static coatings all because containing organic matters such as resins, can not only reduce coating and product Anti-static effect, it can also reduce its outdoor service life.

Currently, electrostatic dissipation coating disclosed in patent document, also all adds the organic matters such as resin, as number of patent application is 201480021995.8 electrostatic dissipation coating includes organic matters such as " fluoropolymer, organosilicon or hydrocarbon polymers "；Patent Shen It please contain 5-15wt% polymer adhesives in number coating for being 201180034645.1；Application No. 200480032649.6 Patent is to add conducting polymer in the organic colloidal sol such as polyvinyl chloride and polymethyl methacrylate；Number of patent application is 200780034249.2 coating in contain the organic adhesive such as polyolefin, polyester；Application No. 200880122764.0 Patent discloses the electrostatically dissipative multi-layer sheet being process by twin-screw thermoplastic extrusion, is not belonging to coating category；Application number The electrostatically dissipative polycarbonate compositions that are process of thermoplastic extrusion are disclosed for 201280024640.5 patent, are not also belonged to In coating category；The patent of Application No. 201510606526.9 discloses " a kind of aluminum oxide anti-electrostatic ceramic material and its system Preparation Method ", although the antistatic material is also purely inorganic thing, essence is the oxygen sintered under 1100 DEG C~1600 DEG C high temperature Change aluminium ceramic body, be not belonging to coating category.The patent of Application No. 201510078567.5 discloses will using polycondensation reaction Organic antistatic additive is doped to the method in pet polymer material, is equally also not belonging to coating category.

Currently, nesa coating coating disclosed in patent document, also all resinous etc. organic components, such as application number For coating disclosed in 201010003998.2 patent " nesa coating containing Conductive inorganic particle and resin component ", and Coating disclosed in Application No. CN03101618.9 patent is containing auxiliary agents such as " adhesive such as organic resin " and " surfactants ".

To obtain the qualified coating of finely dispersed anti-static coatings and adhesive force, in coating disclosed in above-mentioned patent document All it is forced to add the organic matters such as dispersing aid, resin, adhesive, and can remains in its coating, this can be reduced in coating Electric conductivity between conductive material, it is difficult to overcome that its coating anti-static effect is poor, hardness is low, non-refractory and outdoor short life etc. Disadvantage.

Although the also publication and document of some inorganic anti-static coatings, the anti-static coating prepared by them is all It is opaque, it can not require to use on the object of coating transparent in electronic display, glass, glasses, photovoltaic panel etc..For example, Shen It number please be 201410104925.0 patent, although also disclosing that " a kind of dust-proof antistatic inorganic compounding coating ", employ Conventional inorganics rather than nano material, so its coating is opaque.It is well known that nano material refers in three dimensions extremely It is rare it is one-dimensional be in nano-scale (0.1~100nm) or the material being made up of them as elementary cell, this is clearly distinguishable from nothing The conventional inorganics of size characteristic.Application No. 201410447099.X patent, although disclose a kind of transparent anti static without The preparation method of machine film layer, but belong to physics magnetron sputtering method, rather than formed by coating coating.

The content of the invention

Problems to be solved by the invention

All because containing organic matters such as dispersant, resin, adhesives in current anti-static coatings, coating and product can be not only reduced Anti-static effect, its outdoor service life can be also reduced, and electronic display, glass, glasses, photovoltaic panel etc. require that it is anti- Electrostatic coating has the transparency, flexible, outdoor weathe resistance etc. simultaneously, therefore it is intended that is prepared with inorganic nano paint This kind of anti-static coating.But current many inorganic matter nano materials are synthesized by techniques such as high-temperature calcinations, cause this A little nano-material surfaces lack the sexual function group that repels each other（Such as hydroxyl）, need the auxiliary agents such as addition dispersant could be equal again It is even to be distributed in the liquid such as water, and also need to add the compounding material ability such as organic bond, macromolecule resin during coating film forming The qualified coating of coating adhesion is obtained, but these organic analog assistants and compounding material would generally be cured together with nano material In prepared coating, this can reduce original performance of nano material in article coatings, such as the material such as nano-indium stannum oxide Electric conductivity and antistatic performance.Although high-temperature calcination can also remove organic matter in removing coating, caused by hole can deteriorate coating Adhesive force and weatherability, and many base material non-refractories.

The solution used to solve the problem

The principle of the invention：In electric conductivity and rockiness inorganic nano material building-up process or after synthesis, with containing peroxy（- O-O-）Modifying agent processing is modified to them, make these Surface-modification of Nanoparticles hydroxyl negative electrical charge of the same race and each other Repel and suppress its particle agglomeration.Result is that dispersant need not be added in its nano paint, can also keep dispersed and long-term Be layered without sedimentation, after film forming is coated and solvent volatilization is fully cured, the negative electrical charge on hydroxyl is released through coating, no matter low temperature Nano material attracts the intermolecular force to be formed, or hydroxyl during hot setting with product surface by hydroxyl each other during solidification Dehydration is condensed the covalent bond to be formed, and the coating can be made to obtain powerful adhesive force, thus the nothing in this inorganic nano paint The materials such as dispersant, resin, adhesive need to be added, made coating is by pure electric conductivity and rockiness inorganic nano material group Into to improve the static electricity resistance of the article coatings, the transparency, weatherability and outdoor service life.

The present invention is realized by following concrete technical schemes：

1st, make versus buy Conductive inorganic nano material.Conductive inorganic nano material is characterised by that its powder is by nanometer The particulate composition of yardstick, the microscopic appearance of these particulates include nano particle, nanometer rods, nanotube, nano wire, nanometer sheet etc., Surface resistivity ρ s are less than 1 × 10 after these particulates are pressed into solid thin slice with universal testing machine⁵Ω/□.Electric conductivity without Machine nano material includes but is not limited to：Tin-doped indium oxide (SnO₂-In₂O₃That is ITO), tin oxide (SnO₂), antimony doped tin oxide (Sb₂O₃-SnO₂That is ATO), mix bismuth tin oxide (Bi₂O₃-SnO₂That is BTO), p-doped tin oxide (P₂O₅-SnO₂That is PTO), fluorine doped oxygen Change tin (F-SnO₂That is FTO), the fluorin-doped tin oxide (P of phosphorus₂O₅-F-SnO₂That is PFTO), mix antimony zinc oxide (Sb₂O₃- ZnO is AZO bismuth zinc oxide (Bi), is mixed₂O₃- ZnO is BZO), CNT (CNT), graphene (C), tin alkene (Sn), Nano Silver (Ag), nitrogen Change dicalcium (Ca₂N), stannic acid beryllium (BeSnO₃), magnesium stannate (MgSnO₃), calcium stannate (CaSnO₃), stronitum stannate (SrSnO₃), barium stannate (BaSnO₃), zinc stannate (ZnSnO₃), wolframic acid caesium (Cs_xWO₃, x ＜ 1), vanadic acid beryllium, vanadic acid magnesium, calcium vanadate, strontium vanadate and vanadic acid One or more in barium, such Conductive inorganic nano material is represented with alphabetical A.

2nd, make versus buy rockiness inorganic nano material.Rockiness inorganic nano material is characterised by, its powder by The particulate composition of nanoscale, the microscopic appearance of these particulates include nano particle, nanometer rods, nanotube, nano wire, nanometer sheet Deng after this nano material is made into compactness film, its film hardness is more than 5H.Rockiness inorganic nano material include but It is not limited to：Silica (SiO₂), tungsten oxide (WO₃), titanium oxide (TiO₂), cerium oxide (CeO₂), aluminum oxide (Al₂O₃) in one Kind is a variety of.Such rockiness inorganic nano material is represented with letter b.

3rd, surface is modified, and makes above-mentioned A and B Surface-modification of Nanoparticles hydroxyl using modifying agent, and modifying agent is characterised by, Compound containing peroxy-O-O-.Modifying agent includes but is not limited to：Hydrogen peroxide (H₂O₂), peroxidating receives (Na₂O₂), potassium peroxide (K₂O₂), calper calcium peroxide (CaO₂), peromag (MgO₂), zinc peroxide (ZnO₂), hydrogen peroxymonosulfate Potassium (KHSO₅), strontium peroxide (SrO₂), barium peroxide (BaO₂), potassium peroxydisulfate (K₂S₂O₈) in one or more.Can be by modification Agent, which is added in reaction system, implements peroxy modified surface modification hydroxyl to the nano material in synthesis, also can by modifying agent with The dispersion liquid of after above-mentioned synthesis or outsourcing inorganic nano material, which is put into reactor, implements the modification of peroxy modified surface Hydroxyl.Reactor such as high-pressure reactor, normal pressure reactor, hydrothermal reaction kettle, organic thermal response kettle, microwave reaction kettle, stirring The conventional equipments such as machine, nano-level grinder, ball mill, sand mill, homogenizer, reactor corollary apparatus for example heater, cooler, Pressurizer, agitator, microwave generator etc., then wash away the impurity such as modifying agent residue, it is possible to obtain peroxy modification table The above-mentioned inorganic nano material A and B of hydroxyl is modified in face.Peroxy modified surface modifies principle schematic such as Fig. 1 and figure of hydroxyl 2。

4th, the inorganic nano material for treating above-mentioned surface modifier, directly it is dispersed in parent using stirring or milling apparatus This kind of antistatic nano coating is made in aqueous solvent, its composition is：

Peroxy modified surface modifies the parts by weight of Conductive inorganic nano material 0.001~60 of hydroxyl；

Peroxy modified surface modifies the parts by weight of rockiness inorganic nano material 0.001~20 of hydroxyl；

The parts by weight of hydrophilic solvent 20~99.998.

The preferred water of hydrophilic solvent, can also and with water and hydrophilic organic solvent., can example as hydrophilic organic solvent Enumerate methanol, ethanol, normal propyl alcohol, isopropanol, n-butanol, isobutanol, sec-butyl alcohol, the tert-butyl alcohol, n-amyl alcohol, sec-amyl alcohol, tert-pentyl alcohol, 1- ethyl -1- propyl alcohol, 2-methyl-1-butene alcohol, n-hexyl alcohol and cyclohexanol etc..

A and B nano materials are after peroxy modifying and decorating hydroxyl, because of its surface carrying hydroxyl negative electrical charge of the same race each other Repulsion inhibits mutual reunion, this kind of nano paint is also kept dispersed nothing for a long time even if the auxiliary agents such as dispersant are added without Sedimentation.

5th, the object of hydroxyl, previously prepared layer of silicon dioxide bottom membrane are lacked for surface, preparation method such as magnetic control splashes Penetrate method, Ludox method, silica rubbing method etc., the existing many open source literatures of these specific methods, also by relevant enterprise personnel Known and use, it is the method that those skilled in the art's " need not pay creative work again " can just implement.

6th, above-mentioned antistatic inorganic nano paint is coated in object table using instruments such as spraying, showering, roller coat and spin coatings Face, and low temperature, room temperature and hot setting at -50 DEG C~4000 DEG C.Water and organic solvent exist only in antistatic nano painting In material, it is not present in coating and product, so not influenceing the feature that the anti-static coating is made up of inorganic nano material.

The effect of invention

The present invention implements modification to inorganic nano material by the modifying agent containing peroxy-O-O- and modifies hydroxyl Afterwards, nano-material surface hydroxy radical content dramatically increases（Its hydroxyl enhancing signal can be detected by infrared spectrum）, because of nano material Surface band hydroxyl negative electrical charge of the same race and repel each other and inhibit particle agglomeration, also can be by these nanometer of material even if dispersant is added without The dispersed and coating without sedimentation for a long time is made in material.

When this kind of nano paint is coated into the hydrophilic solvent such as body surface, water, methanol, ethanol, isopropanol in low temperature And the product with antistatic inorganic nano clear coat has just been made after volatilization completely naturally at room temperature, now conductive nanometer The negative electrical charge that materials A and rockiness nano material B surface hydroxyl carry is released by coating, its nano particle and body surface Inter-molecular attraction will be formed because attracting each other the hydrogen atom between hydroxyl each other and oxygen atom（Also referred to as Van der Waals force, it is former Reason such as Fig. 3）, the attraction can make the low temperature and the coating of cold curing obtain qualified adhesive force and wearability.

When be heating and curing at 100~4000 DEG C above-mentioned coating when, hydroxyl, the nano material B surface on nano material A surfaces Hydroxyl and body surface hydroxyl will lose a hydrone because two hydroxyls are heated after be changed into-O- covalent bonds（Principle is such as Fig. 4）, the attraction can make the coating have very strong adhesive force, hardness and wearability.And because coating composition is to receive Rice material, even if the thickness of the coating, more than one micron, its visible light transmittance rate still can be more than 51%.

Above-mentioned clear coat is because containing Conductive inorganic nano material, it is easy to reaches surface resistivity less than 10¹²Ω/□ Antistatic requirement.It can be obtained after being coated with the object of anti-static coatings of the present invention, low temperature and cold curing or hot setting Antistatic inorganic coating, thus acquisition static electricity discharge and self-cleaning function, its surface area dust quantity are greatly reduced.Antistatic of the present invention Inorganic nano paint is applied in the aircraft such as the car bodies such as high ferro, motor-car, automobile, aerodone, unmanned plane, Mobile phone screen, TV screen, The electronics class display such as computer screen, billboard, sculpture, portrait, building, furniture, clothing shoes and hats, ceramics, ceramic tile, plastics, glass The body surfaces such as glass, photovoltaic panel, glasses, floor implement coating, and gained coating antistatic, transparent, adhesive force is high, the outdoor life-span It is long.

It is this to prepare antistatic transparent inorganic nano coating, product, coating composition moreover, according to known to the applicant Method is not to be disclosed what is reported so far in academia and industrial circle.

Brief description of the drawings

Fig. 1 conductive nanometer material peroxies modified surface modifies hydroxyl schematic diagram, wherein 11 be conductive nanometer material Material, 12 be conductive nanometer material of the surface after peroxy modifying and decorating hydroxyl.

Fig. 2 rockiness nano material peroxies modified surface modifies hydroxyl schematic diagram, wherein 21 be rockiness nanometer material Material, 22 be rockiness nano material of the surface after peroxy modifying and decorating hydroxyl.

Fig. 3 cold curings prepare the schematic diagram of antistatic inorganic nano clear coat, wherein 31 things coated for preparation Body (similarly hereinafter), 32 be previously prepared silica bottom membrane (similarly hereinafter), and 33 be Conductive inorganic nano-material surface hydroxyl and oxygen Intermolecular force is formed between SiClx bottom membrane hydroxyl, 34 form molecule between Conductive inorganic nano-material surface hydroxyl Intermolecular forces, 35 formation point between Conductive inorganic nano-material surface hydroxyl and rockiness inorganic nano material surface hydroxyl Sub- intermolecular forces, 36 form intermolecular force between rockiness inorganic nano material surface hydroxyl, and 37 be that rockiness is inorganic Intermolecular force is formed between nano-material surface hydroxyl and silica bottom membrane hydroxyl.

Fig. 4 hot settings prepare the schematic diagram of antistatic inorganic nano clear coat, wherein 41 receive for Conductive inorganic Dehydration is condensed to form-O- covalent bonds between rice material surface hydroxyl and silica bottom membrane hydroxyl, and 42 receive for Conductive inorganic Dehydration is condensed to form-O- covalent bonds between rice material surface hydroxyl, and 43 be rockiness inorganic nano material surface hydroxyl and oxygen Dehydration is condensed to form-O- covalent bonds between SiClx bottom membrane hydroxyl, and 44 be Conductive inorganic nano-material surface hydroxyl and heavily fortified point Dehydration is condensed to form-O- covalent bonds between rigid inorganic nano material surface hydroxyl, and 45 be rockiness inorganic nano material table Dehydration is condensed to form-O- covalent bonds between the hydroxyl of face, and 31 and 32 is identical with Fig. 3.

Embodiment

Embodiment 1

(1) SnO is made by oneself₂Conductive nanometer material and peroxy modified surface modification hydroxyl.By 10 parts by weight butters of tin (SnCl₄·5H₂O) hydrate dissolution is into 100 parts by weight of deionized water, and the 25wt% concentrated ammonia liquors of 30 parts by weight are added dropwise, make tin from Son is fully converted to Sn (OH)₄Precipitation, be washed with water and remove removing chloride etc. for 5 times, redisperse into 100 parts by weight of deionized water simultaneously And it is 10.5 to adjust pH with ammoniacal liquor, quickly puts into the surface modifier sodium peroxide Na of 1.2 parts by weight under agitation₂O₂, all turn Move on in the hydrothermal reaction kettle with microwave generator（Microwave reaction kettle）, microwave reaction cools after 0.5 hour until room temperature, is borrowed Help aperture about 1nm NF membrane to be washed with deionized 5 times and remove and receive the modifying agent residual impurity such as ion, will filtering net surface ash Whiteness is transferred in container and supplements a small amount of water, just obtains the SnO of surface modifier processing₂Conductive nanometer material Dispersion liquid.

(2) SiO is made by oneself₂Rockiness nano material and peroxy modified surface modification hydroxyl.By the positive silicic acid second of 28 parts by weight Ester (TEOS) is added in the absolute ethyl alcohol of 29 parts by weight, and the deionized water and 1.25 parts by weight of 5.5 parts by weight is then added dropwise 1M aqueous hydrochloric acid solutions, stirring are aged 100 hours, are then washed with deionized 5 times by NF membrane at room temperature after 40 minutes The residual impurities such as demineralizing acid are removed, generation material is transferred in the hydrothermal reaction kettle with agitator, adds going for 15 parts by weight The surface modifier sodium peroxide Na of ionized water and 2 parts by weight₂O₂, it is stirred continuously down and is warming up to 180 DEG C, insulation is dropped after 10 hours Temperature arrive room temperature, then wash 5 removals with NF membrane and deionized water and receive ion etc., shifts screen surface colourless substance into container And a small amount of water is supplemented, just obtains the SiO of surface modifier processing₂The dispersion liquid of rockiness nano material.

(3) antistatic inorganic nano paint is prepared.Because in above-mentioned filtering, washing and transfer process, nano material has on a small quantity It is lost in, prepares antistatic inorganic nano paint to be accurate, above-mentioned nano SnO need to be calculated₂Dispersion liquid and Nano-meter SiO_2₂Dispersion liquid is each From solid content.Method is：Respectively take 1 milliliter of nano SnO₂Dispersion liquid and Nano-meter SiO_2₂Dispersion liquid is to totally dry vial In, then dispersion liquid is dried in 120 DEG C of baking ovens, the quality value added before and after weighing up vial with assay balance is (accurate To milligram), respective average value is calculated in triplicate, and then just obtaining the respective solid content of above two dispersion liquid, (unit is Grams per milliliter, g/ml).The scattered fluid solid content computational methods are simple and easy, are that those skilled in the art " need not pay creation again Property work " the just method that can implement, be equally applicable to following each embodiments.It is mixed proper amount of above-mentioned to receive according to respective solid content Rice SnO₂And Nano-meter SiO_2₂Dispersion liquid, and deionized water is added, the main component for making the antistatic inorganic nano paint is 1 weight Measure part nano material SnO₂, 0.1 parts by weight nano material SiO₂With 98.9 parts by weight of deionized water, because of SnO₂And SiO₂Nanometer material Material by peroxy modified surface modify hydroxyl after, its particle surface band hydroxyl negative electrical charge of the same race and repel each other and inhibit particle Reunite, the nano paint is kept dispersed no sedimentation for a long time even if the auxiliary agents such as dispersant are added without.

(4) antistatic transparent inorganic nano coating and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, It is 1956mm × 992mm that a piece of silica antireflective coating and length, width and height size of being prepared for uniformly is coated to using spin coating tool On × 100mm monocrystalline silicon photovoltaic panel, after 25 DEG C of following table solidization, just obtain a piece of there is antistatic inorganic nano SnO₂- SiO₂The monocrystalline silicon photovoltaic panel of clear coat.

(5) product photovoltaic panel surface inorganic nano SnO is detected₂-SiO₂The static electricity resistance of coating, the transparency, self-cleaning property, The performances such as rub resistance, are shown in Table 1.

Embodiment 2

(1) FTO conductive nanometers material and peroxy modified surface modification hydroxyl are made by oneself.By 10 parts by weight butters of tin (SnCl₄·5H₂O) hydrate dissolution is into 100 parts by weight of deionized water, and the 25wt% concentrated ammonia liquors of 30 parts by weight are added dropwise, make tin from Son is fully converted to Sn (OH)₄Precipitation, it is washed with water 5 times after removing removing chloride and shifts sediment into hydrothermal reaction kettle, add 0.1 parts by weight hydrofluoric acid (HF), 5 parts by weight 30wt% oxydol H₂O₂After the deionized water of 20 parts by weight, by hydro-thermal reaction Kettle is warming up to 180 DEG C and constant temperature is cooled to room temperature after 15 hours.Sunk light green color is obtained after the turbid solution separation in reactor Starch, show that fluorine ion has been adulterated into SnO₂Lattice generation conductive nanometer FTO (fluorine doped tin oxide, F-SnO₂), by NF membrane is washed with deionized 5 times and goes the removal of impurity, and filtering net surface sediment is transferred in container and supplements a small amount of water, Just obtain the FTO nano dispersion fluids of peroxy modified surface modification hydroxyl.

(2) SiO is made by oneself₂Rockiness nano material and peroxy modified surface modification hydroxyl, it is same as Example 1.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer FTO and Nano-meter SiO_2₂The solid content of dispersion liquid, side Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer FTO and Nano-meter SiO_2 are mixed₂Dispersion liquid, and add from Sub- water and ethanol, the main component for making the antistatic inorganic nano paint are 1 parts by weight FTO, 0.1 parts by weight SiO₂, 88.9 weights Measure part water and the ethanol of 10 parts by weight, nanometer FTO and Nano-meter SiO_2₂After the peroxy modified surface modification hydroxyl of surface, its particle table Face band hydroxyl negative electrical charge of the same race and repel each other and inhibit particle agglomeration, enable the nano paint to keep dispersed nothing to sink for a long time Drop.

(4) antistatic transparent inorganic nano coating and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Using spray gun even application to it is a piece of prepared silica antireflective coating and length, width and height size be 1956mm × 992mm × On 100mm energy ultrawhite figured glass, after room temperature surface drying again through 700 DEG C it is High temperature tempered processing 30 seconds after obtain antistatic glass.Will The cover-plate glass of the antistatic glass as Monocrystalline silicon cell piece, it is a piece of with anti-with regard to that can assemble with reference to other photovoltaic accessories Electrostatic inorganic nano FTO-SiO₂The monocrystalline silicon photovoltaic panel of clear coat.

(5) product photovoltaic panel surface inorganic nano FTO-SiO is detected₂The static electricity resistance of coating, the transparency, self-cleaning property, The performances such as rub resistance, are shown in Table 1.

Embodiment 3

(1) outsourcing ITO conductive nanometers material and peroxy modified surface modification hydroxyl.By the ITO nanometers of 10 parts by weight outsourcings The potassium peroxide K of powder, 5 parts by weight₂O₂It is mixed into 100 parts by weight of deionized water in the material pot of nano-level grinder, at 5 DEG C After being ground 3 hours under 2000rpm/min parameter, 5 removal potassium ions are washed by NF membrane and deionized water, were shifted Screen surface light yellow mass is into container and adds a small amount of water, just obtains the nanometer of peroxy modified surface modification hydroxyl ITO dispersion liquids.

Make WO by oneself₃Rockiness nano material and peroxy modified surface modification hydroxyl.Take 1.5 parts by weight tungsten hexachloride powder End is dissolved into the absolute ethyl alcohol of 10 parts by weight, adds the deionized water of 30 parts by weight and 3 parts by weight 30wt% oxydol H₂O₂ It is sealed to together in hydrothermal reaction kettle afterwards, is warming up to 160 DEG C and cools to room temperature after being incubated 10 hours, by NF membrane and go Ion water washing goes the removal of impurity for 5 times, and transfer screen surface yellow substance into container and supplements a small amount of water, just obtains peroxy Modified surface modifies the nanometer WO of hydroxyl₃Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nano-ITO, Nano-meter SiO_2₂With nanometer WO₃Dispersion liquid is consolidated Content, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nano-ITO, Nano-meter SiO_2 are mixed₂With nanometer WO₃It is scattered Liquid, and add deionized water and methanol, the main component for making the antistatic inorganic nano paint is 1 parts by weight nano-ITO, 0.2 parts by weight Nano-meter SiO_2₂, 0.1 parts by weight nanometer WO₃, 78.7 parts by weight water and 20 parts by weight Methanol, nano-ITO, SiO₂With WO₃After surface peroxy modified surface modification hydroxyl, its particle surface band hydroxyl negative electrical charge of the same race and repelling each other inhibits Grain is reunited, and the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic transparent inorganic nano coating and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, The monocrystaline silicon solar cell that a piece of length, width and height size is 1956mm × 992mm × 100mm is uniformly coated to using roller coat instrument On panel, after 20 DEG C of following table solidization, just obtain a piece of there is antistatic inorganic nano ITO-SiO₂-WO₃The monocrystalline of clear coat Silicon photovoltaic panel.

(5) product photovoltaic panel surface inorganic nano ITO-SiO is detected₂-WO₃Static electricity resistance, the transparency, the automatically cleaning of coating The performances such as property, rub resistance, are shown in Table 1.

Embodiment 4

(1) SnO is made by oneself₂Conductive nanometer material and peroxy modified surface modification hydroxyl, it is same as Example 1.

Make FTO conductive nanometers material and peroxy modified surface modification hydroxyl by oneself, it is same as Example 2.

Make WO by oneself₃Rockiness nano material and peroxy modified surface modification hydroxyl, it is same as Example 3.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nano SnO₂, nanometer FTO, Nano-meter SiO_2₂With nanometer WO₃ The solid content of dispersion liquid, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nano SnO is mixed₂, nanometer FTO, receive Rice SiO₂With nanometer WO₃Dispersion liquid, and adding deionized water makes the main component of the antistatic inorganic nano paint be 1 weight Part SnO₂, 0.5 parts by weight FTO, 0.3 parts by weight SiO₂, 0.2 parts by weight WO₃, 88 parts by weight water and 10 parts by weight Methanol, nanometer SnO₂、FTO、SiO₂And WO₃After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race and arrange each other Reprimand inhibits particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic transparent inorganic nano coating and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Uniformly it is coated to using showering instrument on the energy ultrawhite figured glass that a piece of length, width and height size is 1956mm × 992mm × 100mm, room Coated glass is obtained after 30 seconds through 700 DEG C of High temperature tempered processing again after the lower surface drying of temperature.Using the coated glass as monocrystalline silicon battery The cover-plate glass of piece, with reference to other photovoltaic accessories, a piece of there is antistatic inorganic nano SnO with regard to that can assemble₂-FTO-SiO₂- WO₃The monocrystalline silicon photovoltaic panel of clear coat.

(5) product photovoltaic panel surface inorganic nano SnO is detected₂-FTO-SiO₂-WO₃The static electricity resistance of coating, the transparency, The performances such as self-cleaning property, rub resistance, are shown in Table 1.

Embodiment 5

(1) outsourcing graphene conductive nano material and peroxy modified surface modification hydroxyl.By the graphite of 10 parts by weight outsourcings Alkene (C) nano material, 5 parts by weight 30wt% oxydol H₂O₂It is mixed into 100 parts by weight of deionized water with cooling and stirring In the nano-level grinder material pot of device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane and go Ion water washing goes the removal of impurity for 5 times, and transfer screen pack surface black material into container and adds a small amount of water, just obtains peroxide Base modified surface modifies the nano-graphene dispersion liquid of hydroxyl.

Make TiO by oneself₂Rockiness nano material and peroxy modified surface modification hydroxyl.1 parts sulfuric acid oxygen titanium is molten Solution is added dropwise the 25wt% concentrated ammonia liquors of 30 parts by weight, titanium ion is fully converted to Ti (OH) into the deionized water of 100 parts by weight₄ Precipitation, is washed with water 5 times after going sulfate radical and ammonium ion, precipitation is transferred in hydrothermal reaction kettle, added under agitation The potassium peroxide K of 0.5 parts by weight₂O₂, it is warming up to 180 DEG C and constant temperature cools after 3 hours until room temperature, spends by NF membrane 5 removal potassium ions of ion water washing, screen pack superficial white material is transferred in container and supplements a small amount of water, is just obtained Peroxy modified surface modifies the nano-TiO of hydroxyl₂Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned graphene, Nano-meter SiO_2₂And nano-TiO₂Dispersion liquid is consolidated Content, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned graphene, Nano-meter SiO_2 are mixed₂And nano-TiO₂It is scattered Liquid, and deionized water and methanol are added, the main component for making the antistatic inorganic nano paint is 1 parts by weight of graphite alkene, 0.2 Parts by weight Nano-meter SiO_2₂, 0.3 parts by weight nano-TiO₂, 88.5 parts by weight water and 10 parts by weight methanol, graphene, Nano-meter SiO_2₂ And nano-TiO₂After surface peroxy modified surface modification hydroxyl, its particle surface band hydroxyl negative electrical charge of the same race and the suppression that repels each other Particle agglomeration has been made, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic transparent coating and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, utilize Spin coating tool be uniformly coated to a piece of antireflective coating containing silica and length, width and height size be 1956mm × 992mm × On 100mm monocrystaline silicon solar cell panel, after 30 DEG C of following table solidization, just obtain a piece of there is antistatic inorganic nano C- SiO₂-TiO₂The monocrystalline silicon photovoltaic panel of clear coat.

(5) product photovoltaic panel surface inorganic nano C-SiO is detected₂-TiO₂Static electricity resistance, the transparency, the automatically cleaning of coating The performances such as property, rub resistance, are shown in Table 1.

Embodiment 6

(1) outsourcing ITO conductive nanometers material and peroxy modified surface modification hydroxyl, with the phase of embodiment 3

Make TiO by oneself₂Rockiness nano material and peroxy modified surface modification hydroxyl, it is same as Example 5.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nano-ITO, Nano-meter SiO_2₂, nano-TiO₂With nanometer WO₃ The solid content of dispersion liquid, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nano dispersion fluid is mixed, and add Appropriate deionized water and methanol, the main component for making the antistatic inorganic nano paint is 1 parts by weight ITO, 0.2 parts by weight SiO₂, 0.2 parts by weight TiO₂, 0.1 parts by weight WO₃, 88.5 parts by weight water and 10 parts by weight Methanol, nano-ITO, SiO₂、TiO₂With WO₃After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race and repel each other and inhibit cluster of grains It is poly-, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, It is 1 square metre of glass surface that area is uniformly coated to using spin coating tool, at room temperature after surface drying solidification, is just made in glass surface Antistatic inorganic nano ITO-SiO₂-TiO₂-WO₃Clear coat.

(5) product glass surface inorganic nano ITO-SiO is detected₂-TiO₂-WO₃The static electricity resistance of coating, the transparency, from clear The performances such as clean property, rub resistance, are shown in Table 1.

Embodiment 7

(1) outsourcing CTO conductive nanometers material and peroxy modified surface modification hydroxyl.Caesium oxygen is mixed into 10 parts by weight outsourcings Change tungsten nano-powder (also known as wolframic acid caesium, CTO, molecular formula Cs_xWO₃, X ＜ 1), 5 parts by weight 30wt% oxydol H₂O₂With 100 parts by weight of deionized water are mixed into the nano-level grinder material pot with cooling and agitating device, in 5 DEG C and 2000rpm/ After being ground 3 hours under min parameter, wash 5 times by NF membrane and deionized water and go the removal of impurity, shift screen pack surface solid Material is into container and adds a small amount of water, just obtains the nanometer CTO of peroxy modified surface modification hydroxyl dispersion liquid.

(2) rockiness Nano-meter SiO_2 is made by oneself₂And peroxy modified surface modifies hydroxyl, same as Example 1.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer CTO and Nano-meter SiO_2₂The solid content of dispersion liquid, side Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer CTO and Nano-meter SiO_2 are mixed₂Dispersion liquid, and add from Sub- water makes the main component of the antistatic inorganic nano paint be 1 parts by weight CTO, 0.1 parts by weight SiO₂, 98.9 parts by weight water, Nanometer CTO and Nano-meter SiO_2₂After surface peroxy modified surface modification hydroxyl, its particle surface band hydroxyl negative electrical charge of the same race and that This repulsion inhibits particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.100 milliliters of above-mentioned antistatic inorganic nanos are applied Material, it is 1 square metre of glass surface to be uniformly coated to area using showering instrument, is handled again through about 450 DEG C of hot blasts after room temperature surface drying 30 minutes, antistatic inorganic nano CTO-SiO just is made in glass surface₂Clear coat.

(5) product glass surface inorganic nano CTO-SiO is detected₂Static electricity resistance, the transparency, self-cleaning property, the antifriction of coating The performances such as wiping property, are shown in Table 1.

Embodiment 8

(1) outsourcing ATO conductive nanometers material and peroxy modified surface modification hydroxyl.Antimony oxygen is mixed into 10 parts by weight outsourcings Change tin (Sb₂O₃-SnO₂That is ATO) nano-powder, the peromag MgO of 1.3 parts by weight₂It is mixed into 100 parts by weight of deionized water In nano-level grinder material pot with cooling and agitating device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, 5 times are washed by NF membrane and deionized water and removes the impurity such as magnesium ion, and transfer filtering net surface dusty blue material is into container And a small amount of water is added, just obtains the nano ATO dispersion liquid of peroxy modified surface modification hydroxyl.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nano ATO and Nano-meter SiO_2₂Consolidating for dispersion liquid contains Amount, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nano ATO and Nano-meter SiO_2 are mixed₂Dispersion liquid, and mend Add deionized water and ethanol, the main component for making the antistatic inorganic nano paint is 1 parts by weight ATO, 0.1 parts by weight SiO₂、 98.9 parts by weight water, nano ATO and Nano-meter SiO_2₂After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl of the same race is born Electric charge and repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, The glass surface that area is 1 square metre is uniformly coated to using roller coat instrument, at room temperature after surface drying solidification, just in glass surface system Obtain antistatic inorganic nano ATO-SiO₂Clear coat.

(5) product glass surface inorganic nano ATO-SiO is detected₂Static electricity resistance, the transparency, self-cleaning property, the antifriction of coating The performances such as wiping property, are shown in Table 1.

Embodiment 9

(1) outsourcing CNT conductive nanometers material and peroxy modified surface modification hydroxyl.By the carbon nanometer of 10 parts by weight outsourcings Manage (CNT) powder, 5 parts by weight 30wt% oxydol H₂O₂It is mixed into 100 parts by weight of deionized water with agitating device and increasing In the reactor of pressure device.It is warming up to 180 DEG C and injecting pressure-air makes reactor pressure be 10MPa, after is incubated 10 hours Decrease temperature and pressure washs 5 times by NF membrane and deionized water and goes the removal of impurity, shift screen pack surface black thing until room temperature normal pressure Matter is into container and adds a small amount of water, just obtains the CNT CNT of peroxy modified surface modification hydroxyl dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned CNT CNT and Nano-meter SiO_2₂Consolidating for dispersion liquid contains Amount, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned CNT CNT and Nano-meter SiO_2 are mixed₂Dispersion liquid, and And appropriate deionized water is added, the main component for making the antistatic inorganic nano paint is 1 parts by weight CNT, 0.1 parts by weight SiO₂, 98.9 parts by weight water, CNT CNT and Nano-meter SiO_2₂After the peroxy modifying and decorating hydroxyl of surface, its particle surface band is same Plant hydroxyl negative electrical charge and repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic transparent inorganic nano coating and its product are prepared.By 5 milliliters of above-mentioned antistatic inorganic nano paints, profit A secondary ophthalmic len surface for being prepared for one layer of silica bottom membrane with magnetron sputtering method in advance is uniformly coated to spraying equipment, At room temperature after surface drying solidification, just in lens surface coating antistatic inorganic nano CNT-SiO₂Clear coat.

(5) product lens surface inorganic nano CNT-SiO is detected₂Static electricity resistance, the transparency, self-cleaning property, the antifriction of coating The performances such as wiping property, are shown in Table 1.

Embodiment 10

(1) outsourcing graphene conductive nano material and peroxy modified surface modification hydroxyl, it is same as Example 5.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nano-graphene, Nano-meter SiO_2₂, nano-TiO₂And nanometer WO₃The solid content of dispersion liquid, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nano dispersion fluid is mixed, and Appropriate deionized water and methanol are added, the main component for making the antistatic inorganic nano paint is 1 parts by weight of graphite alkene, 0.2 Parts by weight SiO₂, 0.2 parts by weight TiO₂, 0.1 parts by weight WO₃, 88.5 parts by weight water and 10 parts by weight Methanol, nano-graphene, SiO₂、TiO₂And WO₃After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race and the suppression that repels each other Particle agglomeration has been made, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to using spin coating tool as 1 square metre and deposited one layer of silica bottom with silica rubbing method in advance The electronic message surface of film layer, handle 30 minutes through 110 DEG C of hot blasts after room temperature surface drying, be just made in electronic message surface again Antistatic inorganic nano C-SiO₂-TiO₂-WO₃Clear coat.

(5) product electronic message surface inorganic nano C-SiO is detected₂-TiO₂-WO₃The static electricity resistance of coating, the transparency, The performances such as self-cleaning property, rub resistance, are shown in Table 1.

Embodiment 11

(1) outsourcing tin alkene Sn conductive nanometers material and peroxy modified surface modification hydroxyl.By the tin alkene of 10 parts by weight outsourcings Calper calcium peroxide (the CaO of Sn nano-powders, 1.2 parts by weight₂) and 100 parts by weight of deionized water be mixed into cooling and stirring dress In the nano-level grinder material pot put, after grind 3 hours under 5 DEG C and 2000rpm/min parameters, by NF membrane with go from Impurity, the transfer screen pack surface solid materials such as sub- 5 removal calcium ions of water washing into container and add a small amount of water, must To the nanometer tin alkene Sn dispersion liquids of peroxy modified surface modification hydroxyl.

(2) outsourcing Al₂O₃Rockiness nano material and peroxy modified surface modification hydroxyl.By the oxygen of 10 parts by weight outsourcings Change aluminium (Al₂O₃) nano-powder, 3 parts by weight zinc peroxide (ZnO₂) and 100 parts by weight of deionized water be mixed into cooling and stir In the nano-level grinder material pot for mixing device, after grind 3 hours under 5 DEG C and 2000rpm/min parameters, by NF membrane with Deionized water washs 5 times and removes the impurity such as zinc ion, shifts screen pack superficial white material into container and adds a small amount of water, Just obtain the nanometer Al of peroxy modified surface modification hydroxyl₂O₃Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer tin alkene Sn and nanometer Al₂O₃Consolidating for dispersion liquid contains Amount, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer tin alkene Sn and Nano-meter SiO_2 are mixed₂Dispersion liquid, and Appropriate deionized water is added, the main component for making the antistatic inorganic nano paint is 1 parts by weight nanometer tin alkene Sn, 0.1 weight Measure part Al₂O₃, 98.9 parts by weight water, nanometer tin alkene Sn and nanometer Al₂O₃After the peroxy modifying and decorating hydroxyl of surface, its particle table Face band hydroxyl negative electrical charge of the same race and repel each other and inhibit particle agglomeration, enable the nano paint to keep dispersed nothing to sink for a long time Drop.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to using spray gun to be 1 square metre and have been previously deposited with one layer of silica bottom membrane with magnetron sputtering method TV screen surfaces, after the solidification of room temperature surface drying, antistatic inorganic nano Sn-Al just is made in TV screen surfaces₂O₃Clear coat.

(5) product TV screen surfaces inorganic nano Sn-Al is detected₂O₃It is the static electricity resistance of coating, the transparency, self-cleaning property, resistance to The performances such as frictional property, are shown in Table 1.

Embodiment 12

(1) outsourcing ITO conductive nanometers material and peroxy modified surface modification hydroxyl, it is same as Example 3.

(2) TiO is made by oneself₂Rockiness nano material and peroxy modified surface modification hydroxyl, it is same as Example 5.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nano-ITO, nano-TiO₂With nanometer WO₃Dispersion liquid is consolidated Content, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nano-ITO, nano-TiO are mixed₂With nanometer WO₃It is scattered Liquid, and deionized water is added, the main component for making the antistatic inorganic nano paint is 1 parts by weight ITO, 0.2 parts by weight TiO₂, 0.1 parts by weight WO₃With 98.7 parts by weight water, nano-ITO, TiO₂And WO₃After the peroxy modified surface modification hydroxyl of surface, Its particle surface band hydroxyl negative electrical charge of the same race and repel each other and inhibit particle agglomeration, the nano paint is kept uniform for a long time Disperse without sedimentation.

(4) antistatic inorganic nano clear coat and its product are prepared.1000 milliliters of above-mentioned antistatic inorganic nanos are applied Material, a car body for being prepared for one layer of silica bottom membrane with Ludox method in advance is uniformly coated to using spin coating tool Surface, antistatic inorganic nano ITO-TiO just is made on car body surface after the solidification of room temperature surface drying₂-WO₃Clear coat.

(5) product car body surface inorganic nano ITO-TiO is detected₂-WO₃Static electricity resistance, the transparency, the automatically cleaning of coating The performances such as property, rub resistance, are shown in Table 1.

Embodiment 13

(1) outsourcing Ca₂N conductive nanometers material and peroxy modified surface modification hydroxyl.By the nitridation two of 10 parts by weight outsourcings Calcium (Ca₂N) nano-powder, 5 parts by weight 30wt% oxydol H₂O₂It is mixed into cooling and stirs with 100 parts by weight of deionized water In the nano-level grinder material pot for mixing device, after grind 3 hours under 5 DEG C and 2000rpm/min parameters, by NF membrane with Deionized water washs 5 times and goes the removal of impurity, and transfer screen pack surface solid material into container and is added a small amount of water, just obtained Epoxide modified surface modifies the nanometer Ca of hydroxyl₂N dispersion liquids.

(2) outsourcing WO₃Rockiness nano material and peroxy modified surface modification hydroxyl, it is same as Example 3.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer Ca₂N and nanometer WO₃The solid content of dispersion liquid, side Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer Ca is mixed₂N and nanometer WO₃Dispersion liquid, and add appropriate Deionized water, the main component for making the antistatic inorganic nano paint is 1 parts by weight Ca₂N, 0.1 parts by weight WO₃₃, 98.9 weights Measure part water, nanometer Ca₂N and nanometer WO₃After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race and Repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to using high-pressure spray gun as 1 square metre and has been prepared for one layer of silica bottom with silica rubbing method in advance The high ferro car body surface of film layer, after the solidification of room temperature surface drying, antistatic inorganic nano Ca just is made in high ferro car body surface₂N-WO₃Thoroughly Bright coating.

(5) product high ferro car body surface inorganic nano Ca is detected₂N-WO₃The static electricity resistance of coating, the transparency, self-cleaning property, The performances such as rub resistance, are shown in Table 1.

Embodiment 14

(1) outsourcing BTO conductive nanometers material and peroxy modified surface modification hydroxyl.Bismuth oxygen is mixed into 10 parts by weight outsourcings Change tin (Bi₂O₃-SnO₂That is BTO) nano-powder, the zinc peroxide ZnO of 1.3 parts by weight₂It is mixed into 100 parts by weight of deionized water In nano-level grinder material pot with cooling and agitating device, after being ground 2 hours under 5 DEG C and 2000rpm/min of parameter, Wash the impurity such as 5 removal zinc ions by NF membrane and deionized water, transfer filtering net surface blue material into container simultaneously And a small amount of water is added, just obtain the nanometer BTO dispersion liquids of peroxy modified surface modification hydroxyl.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer BTO and Nano-meter SiO_2₂The solid content of dispersion liquid, side Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer BTO and Nano-meter SiO_2 are mixed₂Dispersion liquid, and add from Sub- water and isopropanol, the main component for making the antistatic inorganic nano paint are 1 parts by weight BTO, 0.1 parts by weight SiO₂、88.9 Parts by weight water and 10 parts by weight of isopropyl alcohol, nanometer BTO and Nano-meter SiO_2₂After peroxy modified surface modification hydroxyl, its particle surface Repel each other with hydroxyl negative electrical charge of the same race and inhibit particle agglomeration, enable the nano paint to keep dispersed nothing to sink for a long time Drop.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to using spray gun as 1 square metre and is coated in advance with Ludox method and have cured one layer of silica bottom The ceramic tile surface of film layer, it is heating and curing 30 minutes through 650 DEG C again after room temperature surface drying, is just made that antistatic is inorganic to be received in ceramic tile surface Rice BTO-SiO₂Clear coat.

(5) product ceramic tile surface inorganic nano BTO-SiO is detected₂Static electricity resistance, the transparency, self-cleaning property, the antifriction of coating The performances such as wiping property, are shown in Table 1.

Embodiment 15

(1) outsourcing ATO conductive nanometers material and peroxy modified surface modification hydroxyl, it is same as Example 8.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nano ATO and Nano-meter SiO_2₂The solid content of dispersion liquid, side Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nano ATO and Nano-meter SiO_2 are mixed₂Dispersion liquid, and add from Sub- water, the main component for making the antistatic inorganic nano paint are 1 parts by weight ATO, 0.1 parts by weight SiO₂With 98.9 parts by weight Water, nano ATO and Nano-meter SiO_2₂Peroxy modified surface modification hydroxyl after, its particle surface band hydroxyl negative electrical charge of the same race and each other Repulsion inhibits particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to using spray gun as 1 square metre and is coated in advance with Ludox and have cured one layer of silica counterdie The ceramic surface of layer, it is heating and curing 30 minutes through 650 DEG C again after room temperature surface drying, antistatic inorganic nano just is made in ceramic tile surface ATO-SiO₂Clear coat.

(5) product ceramic surface inorganic nano ATO-SiO is detected₂Static electricity resistance, the transparency, self-cleaning property, the antifriction of coating The performances such as wiping property, are shown in Table 1.

Embodiment 16

(1) outsourcing AZO conductive nanometers material and peroxy modified surface modification hydroxyl.Antimony oxygen is mixed into 10 parts by weight outsourcings Change zinc (Sb₂O₃- ZnO is AZO) nano-powder, the potassium hydrogen peroxymonosulfate KHSO of 1.3 parts by weight₅Mixed with 100 parts by weight of deionized water Close in the nano-level grinder material pot with cooling and agitating device, grinding 2 is small under 5 DEG C and 2000rpm/min of parameter Shi Hou, wash 5 times by NF membrane and deionized water and remove potassium ion etc., transfer filtering net surface canescence material is into container And a small amount of water is added, just obtains the nanometer AZO of peroxy modified surface modification hydroxyl dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer AZO and Nano-meter SiO_2₂The solid content of dispersion liquid, side Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer AZO and Nano-meter SiO_2 are mixed₂Dispersion liquid, and add appropriate Deionized water, the main component for making the antistatic inorganic nano paint is 1 parts by weight AZO, 0.1 parts by weight SiO₂, 98.9 weights Measure part water, nanometer AZO and Nano-meter SiO_2₂After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race and Repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to as 1 square metre using showering instrument and is coated in advance with Ludox and be have cured one layer of silica The frosting of bottom membrane, after the solidification of room temperature surface drying, antistatic inorganic nano AZO-SiO just is made in frosting₂Transparent painting Layer.

(5) product frosting inorganic nano AZO-SiO is detected₂Static electricity resistance, the transparency, self-cleaning property, the antifriction of coating The performances such as wiping property, are shown in Table 1.

Embodiment 17

(1) outsourcing BeSnO₃Conductive nanometer material and peroxy modified surface modification hydroxyl.By the stannic acid of 10 parts by weight outsourcings Beryllium (BeSnO₃) nano-powder, 5 parts by weight 30wt% oxydol H₂O₂With 100 parts by weight of deionized water be mixed into cooling and In the nano-level grinder material pot of agitating device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane 5 times are washed with deionized water and goes the removal of impurity, and transfer screen pack surface solid material into container and is added a small amount of water, just obtained Peroxy modified surface modifies the nanometer BeSnO of hydroxyl₃Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer BeSnO₃And Nano-meter SiO_2₂The solid content of dispersion liquid, Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer BeSnO is mixed₃And Nano-meter SiO_2₂Dispersion liquid, and add Appropriate deionized water, the main component for making the antistatic inorganic nano paint are 1 parts by weight stannic acid beryllium BeSnO₃, 0.1 weight Part SiO₂, 98.9 parts by weight water, nanometer BeSnO₃And Nano-meter SiO_2₂After peroxy modified surface modification hydroxyl, its particle surface band Hydroxyl negative electrical charge of the same race and repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.1000 milliliters of above-mentioned antistatic inorganic nanos are applied Material, area is uniformly coated to using high-pressure spray gun as 10 square metres and is coated in advance with Ludox and have cured one layer of oxygen On the building masonry wall of SiClx bottom membrane, after the solidification of room temperature surface drying, antistatic inorganic nano is just made on building masonry wall BeSnO₃-SiO₂Clear coat.

(5) product building masonry wall surface inorganic nano BeSnO is detected₃-SiO₂The static electricity resistance of coating, the transparency, from clear The performances such as clean property, rub resistance, are shown in Table 1.

Embodiment 18

(1) outsourcing MgSnO₃Conductive nanometer material and peroxy modified surface modification hydroxyl.By the stannic acid of 10 parts by weight outsourcings Magnesium (MgSnO₃) nano-powder, 5 parts by weight 30wt% oxydol H₂O₂With 100 parts by weight of deionized water be mixed into cooling and In the nano-level grinder material pot of agitating device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane 5 times are washed with deionized water and goes the removal of impurity, and transfer screen pack surface solid material into container and is added a small amount of water, just obtained Peroxy modified surface modifies the nanometer MgSnO of hydroxyl₃Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer MgSnO₃And nano-TiO₂The solid content of dispersion liquid, Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer MgSnO is mixed₃And nano-TiO₂Dispersion liquid, and add Appropriate deionized water, the main component for making the antistatic inorganic nano paint are 1 parts by weight MgSnO₃, 0.1 parts by weight TiO₂、 98.9 parts by weight water, nanometer MgSnO₃And nano-TiO₂After peroxy modified surface modification hydroxyl, its particle surface band hydroxyl of the same race Negative electrical charge and repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.1000 milliliters of above-mentioned antistatic inorganic nanos are applied Material, area is uniformly coated to using high-pressure spray gun as 10 square metres and is prepared for one layer of oxidation with silica rubbing method in advance On the portrait of silicon bottom membrane, after the solidification of room temperature surface drying, antistatic inorganic nano MgSnO is just made on portrait₃-TiO₂Transparent painting Layer.

(5) product portrait surface inorganic nano MgSnO is detected₃-TiO₂It is the static electricity resistance of coating, the transparency, self-cleaning property, resistance to The performances such as frictional property, are shown in Table 1.

Embodiment 19

(1) outsourcing CaSnO₃Conductive nanometer material and peroxy modified surface modification hydroxyl.By the stannic acid of 10 parts by weight outsourcings Calcium (CaSnO₃) nano-powder, 5 parts by weight 30wt% oxydol H₂O₂With 100 parts by weight of deionized water be mixed into cooling and In the nano-level grinder material pot of agitating device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane 5 times are washed with deionized water and goes the removal of impurity, and transfer screen pack surface solid material into container and is added a small amount of water, just obtained Peroxy modified surface modifies the nanometer CaSnO of hydroxyl₃Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer CaSnO₃And Nano-meter SiO_2₂The solid content of dispersion liquid, Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer CaSnO is mixed₃And Nano-meter SiO_2₂Dispersion liquid, and add Deionized water, the main component for making the antistatic inorganic nano paint are 1 parts by weight CaSnO₃, 0.1 parts by weight SiO₂, 98.9 weights Measure part water, nanometer CaSnO₃And Nano-meter SiO_2₂After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race And repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.1000 milliliters of above-mentioned antistatic inorganic nanos are applied Material, area is uniformly coated to using high-pressure spray gun as 10 square metres and is prepared for one layer of oxidation with silica rubbing method in advance The billboard surface of silicon bottom membrane, after the solidification of room temperature surface drying, antistatic inorganic nano CaSnO just is made on billboard surface₃- SiO₂Clear coat.

(5) product billboard surface C aSnO is detected₃-SiO₂The static electricity resistance of inorganic nano coating, the transparency, self-cleaning property, The performances such as rub resistance, are shown in Table 1.

Embodiment 20

(1) outsourcing BaSnO₃Conductive nanometer material and peroxy modified surface modification hydroxyl.By the nanometer of 10 parts by weight outsourcings Barium stannate (BaSnO₃) powder, 5 parts by weight 30wt% oxydol H₂O₂With 100 parts by weight of deionized water be mixed into cooling and In the nano-level grinder material pot of agitating device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane 5 times are washed with deionized water and goes the removal of impurity, and transfer screen pack surface solid material into container and is added a small amount of water, just obtained Peroxy modified surface modifies the nanometer BaSnO of hydroxyl₃Dispersion liquid.

(2) outsourcing rockiness CeO₂Nano material and peroxy modified surface modification hydroxyl.By the oxygen of 10 parts by weight outsourcings Change cerium (CeO₂) nano-powder, the peromag MgO of 1.5 parts by weight₂With 100 parts by weight of deionized water be mixed into cooling and In the nano-level grinder material pot of agitating device, after being ground 2 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane 5 times are washed with deionized water and removes the impurity such as magnesium ion, and the transfer filtering faint yellow material of net surface is into container and adds few Water is measured, just obtains the nano Ce O of peroxy modified surface modification hydroxyl₂Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer BaSnO₃With nano Ce O₂The solid content of dispersion liquid, Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer BaSnO is mixed₃With nano Ce O₂Dispersion liquid, and add Deionized water, the main component for making the antistatic inorganic nano paint are 1 parts by weight BaSnO₃, 0.1 parts by weight CeO₂, 98.9 weights Measure part water, nanometer BaSnO₃With nano Ce O₂After peroxy modified surface modification hydroxyl, its particle surface band hydroxyl negative electrical charge of the same race And repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to using high-pressure spray gun to be about 0.5 square metre and be prepared for one layer of silica bottom with Ludox method in advance The unmanned plane surface of film layer, after the solidification of room temperature surface drying, antistatic inorganic nano BaSnO just is made on unmanned plane surface₃-CeO₂Thoroughly Bright coating.

(5) product unmanned plane surface inorganic nano BaSnO is detected₃-CeO₂The static electricity resistance of coating, the transparency, self-cleaning property, The performances such as rub resistance, are shown in Table 1.

Embodiment 21

(1) outsourcing ZnSnO₃Conductive nanometer material and peroxy modified surface modification hydroxyl.By the stannic acid of 10 parts by weight outsourcings Zinc (ZnSnO₃) nano-powder, 5 parts by weight 30wt% oxydol H₂O₂With 100 parts by weight of deionized water be mixed into cooling and In the nano-level grinder material pot of agitating device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane 5 times are washed with deionized water and goes the removal of impurity, and transfer screen pack surface solid material into container and is added a small amount of water, just obtained Peroxy modified surface modifies the nanometer ZnS nO of hydroxyl₃Dispersion liquid.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer ZnS nO₃And Nano-meter SiO_2₂The solid content of dispersion liquid, Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer ZnS nO is mixed₃And Nano-meter SiO_2₂Dispersion liquid, and add Deionized water, the main component for making the antistatic inorganic nano paint are 1 parts by weight ZnSnO₃, 0.1 parts by weight SiO₂, 98.9 weights Measure part water, nanometer ZnS nO₃And Nano-meter SiO_2₂After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race And repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.By 100 milliliters of above-mentioned antistatic inorganic nano paints, Area is uniformly coated to using high-pressure spray gun to be about 1 square metre and coated with Ludox in advance and have cured one layer of oxidation The furniture surface of silicon bottom membrane, after the solidification of room temperature surface drying, antistatic inorganic nano ZnSnO just is made in furniture surface₃-SiO₂Thoroughly Bright coating.

(5) product furniture surface inorganic nano ZnSnO is detected₃-SiO₂It is the static electricity resistance of coating, the transparency, self-cleaning property, resistance to The performances such as frictional property, are shown in Table 1.

Embodiment 22

(1) outsourcing SrSnO₃Conductive nanometer material and peroxy modified surface modification hydroxyl.By the stannic acid of 10 parts by weight outsourcings Strontium (SrSnO₃) nano-powder, 5 parts by weight 30wt% oxydol H₂O₂With 100 parts by weight of deionized water be mixed into cooling and In the nano-level grinder material pot of agitating device, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane 5 times are washed with deionized water and goes the removal of impurity, and transfer screen pack surface solid material into container and is added a small amount of water, just obtained Peroxy modified surface modifies the nanometer SrSnO of hydroxyl₃Dispersion liquid.

(2) outsourcing CeO₂Rockiness nano material and peroxy modified surface modification hydroxyl are identical with embodiment 20.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned nanometer SrSnO₃With nano Ce O₂The solid content of dispersion liquid, Method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned nanometer SrSnO is mixed₃With nano Ce O₂Dispersion liquid, and add Deionized water, the main component for making the antistatic inorganic nano paint are 1 parts by weight SrSnO₃, 0.1 parts by weight CeO₂, 98.9 weights Measure part water, nanometer SrSnO₃With nano Ce O₂After the peroxy modifying and decorating hydroxyl of surface, its particle surface band hydroxyl negative electrical charge of the same race And repel each other and inhibit particle agglomeration, the nano paint is kept dispersed no sedimentation for a long time.

(4) antistatic inorganic nano clear coat and its product are prepared.1000 milliliters of above-mentioned antistatic inorganic nanos are applied Material, area is uniformly coated to using spin-coating equipment as 100 square metres and has been prepared for one layer of silica with Ludox method in advance The floor surface of bottom membrane, after the solidification of room temperature surface drying, antistatic inorganic nano SrSnO just is made in floor surface₃-CeO₂It is transparent Coating.

(5) product floor surface inorganic nano SrSnO is detected₃-CeO₂It is the static electricity resistance of coating, the transparency, self-cleaning property, resistance to The performances such as frictional property, are shown in Table 1.

Embodiment 23

(1) outsourcing silver conductive nanometer material and peroxy modified surface modification hydroxyl.The silver (Ag) of 10 parts by weight outsourcings is received Peromag (the MgO of ground rice body, 1.2 parts by weight₂) and 100 parts by weight of deionized water be mixed into cooling and agitating device In nano-level grinder material pot, after being ground 3 hours under 5 DEG C and 2000rpm/min of parameter, by NF membrane and deionized water Impurity, the transfer screen pack surface solid materials such as 5 removal magnesium ions of washing into container and are added a small amount of water, just obtained The dispersion liquid of the Nano Silver of epoxide modified surface modification hydroxyl.

(3) antistatic inorganic nano paint is prepared.Calculate above-mentioned Nano Silver, Nano-meter SiO_2₂And nano-TiO₂Dispersion liquid is consolidated Content, method is the same as embodiment 1.According to respective solid content, proper amount of above-mentioned Nano Silver, Nano-meter SiO_2 are mixed₂And nano-TiO₂It is scattered Liquid, and appropriate deionized water is added, the main component for making the antistatic inorganic nano paint is 1 parts by weight Nano Silver, 0.2 Parts by weight Nano-meter SiO_2₂, 0.1 parts by weight TiO₂, 98.7 parts by weight water, Nano Silver, SiO₂And TiO₂Surface peroxy modifying and decorating After hydroxyl, its particle surface band hydroxyl negative electrical charge of the same race and repel each other and inhibit particle agglomeration, enable the nano paint long-term Keep dispersed no sedimentation.

(4) antistatic inorganic nano clear coat and its product are prepared.By above-mentioned antistatic inorganic nano paint, spray is utilized Rifle be uniformly coated to surface in advance with silica rubbing method be prepared for the clothes of one layer of silica bottom membrane, trousers, shoes and Cap surface, antistatic inorganic nano Ag-SiO just is made on clothing shoes and hats surface after the solidification of room temperature surface drying₂-TiO₂Clear coat.

(5) product clothing shoes and hats surface inorganic nano Ag-SiO is detected₂-TiO₂Static electricity resistance, the transparency, the automatically cleaning of coating The performances such as property, rub resistance, are shown in Table 1.

Table 1 is：

Embodiment supplemental content

(1) the hydroxyl of Surface-modification of Nanoparticles is detected

Utilize the type infrared spectrometers of Nicolet 670 and high vacuum（Vacuum is 1 × 10^-4Pa）Device in situ, detection it is above-mentioned The hydroxyl enhancing signal of the modified surface modification of nano material peroxy in embodiment, is 3418cm in wave number^-1、3631cm^-1、3647cm^-1、3683cm^-1And 3735cm^-1Neighbouring hydroxyl group absorption intensity is bigger, shows the modified table of nano material peroxy The hydroxyl quantity of face modification is more.

(2) current industrial circle prepares three kinds of methods of silica bottom membrane.

1. magnetron sputtering method.The titanium dioxide silicon target for the use of purity being 99.9% is target, and the argon gas that purity is 99.9% is to splash Emanate body, vacuumizing makes chamber vacuum degree be less than 1 × 10^-3Magnetron sputtering is come into effect after Pa, this is current coated glass enterprise Common practice, be also applied in above-described embodiment in the previously prepared oxygen of the insulator surfaces such as ceramic tile, TV screen, electronic display SiClx bottom membrane.

2. Ludox method.Silica antireflective anti-reflection film is coated on ultra-white photovoltaic glass surface using Ludox, first by business The regulation of product Ludox solidification amount arrives about 3%, then using equipment such as roller coat, sprayings, in ultra-white photovoltaic glass surface coating, room temperature After lower surface drying, then it is heating and curing at 100~700 DEG C, is just prepared for silica bottom membrane on ultra-clear glasses surface, this is current The common practice of photovoltaic glass manufacturing enterprise, it is also applied in above-described embodiment in energy ultrawhite figured glass, glass, ceramic tile, ceramics Deng the previously prepared silica bottom membrane in high-temperature insulation body surface face.

3. silica rubbing method.It is real directly to object with equipment such as sprayings at room temperature using the nano oxidized silicon coating of commodity Application is covered, and for hydrophilic solvent surface drying solidify afterwards into silica bottom membrane, this method has had many success use cases in China, should Method is suitable for above-described embodiment in the object table of the non-refractories such as billboard, portrait, car body, floor, glasses, clothing shoes and hats The previously prepared silica bottom membrane in face.

Article coatings performance evaluation

1. static electricity resistance.Be coated with the said products of antistatic inorganic nano clear coat, detect its surface resistivity less than 1 × 10¹¹Represented when (Ω/) to be qualified with zero, less than 1 × 10⁸(Ω/) uses to be good ● represents, less than 1 × 10⁷(Ω/□) Represented to be outstanding with ★.Detection method is that sheet resistance tester directly is placed on into product surface and Pen-down detection key, root Its surface resistivity is determined according to the indicator lamp on instrument, with reference to current standard《GA/T 1410-2006 solid insulating material volumes Resistivity and surface resistivity test method》.

2. the transparency.It is coated with the said products of antistatic inorganic nano clear coat, the wherein transparency such as glass, glasses Body, its visible light transmittance rate directly can be measured using light transmittance detector, and it is nontransparent for car body, display screen and billboard etc. Object, its identical coating is prepared using glass etc., its visible light transmittance rate is measured using light transmittance detector, measurement indirectly should The light transmittance of antistatic inorganic nano coating.If coating visible light transmittance rate T_Vis>=51% judges that the coating transparent is qualified Represented with zero, T_Vis>=75% uses to be good ● represents, T_Vis>=80% is represented to be outstanding with ★.Should alternatively, it is also possible to ready visual contrast Article coatings region and the aberration of neighboring area, such as indifference, then show that coating does not cover in original color of object, also may be used Judge that coating transparent is qualified.

3. thicknesses of layers.The said products of antistatic inorganic nano clear coat are coated with, using THICKNESS GAUGE FOR THE MEASUREMENT OF THIN FOILS etc. Equipment detects its specific thickness.If thickness is 0.1~1000 nanometer and cannot recognize that surface relief injustice with human eye, i.e., Judge that the coating layer thickness is qualified to be represented with zero, it is well to use that average thickness, which is 10~700 nanometers, ● represent, average thickness be 50~ 150 nanometers are represented to be outstanding with ★.

4. self-cleaning property.Under the same conditions, to the said products surface for being coated with antistatic inorganic nano clear coat With the identical items surface without the coating, the dirty solution containing 1wt% fine earths, 0.1wt% vegetable oil and 98.9wt% water is sprayed, When stopping being less than uncoated article residual soil surface area 50% such as the surface area of fruit product residual soil after spraying, you can judge The self-cleaning property of the product is qualified to be represented with zero, is used less than 30% to be good ● is represented, is represented less than 10% to be outstanding with ★.Should be certainly Detecting method with reference to current standard《GA/T 31815-2015 outer surface of building self-cleaning coatings》,《JC/T 2210-2014 Architectural pottery self-cleaning performance method of testing》With《GA/T 23764-2009 photocatalytic self-cleaning material performance test methods》 Deng.

5. rub resistance.The coating abrasion performance of said products is determined with rotation friction rubber wheel method, i.e., in temperature (23 ± 2) DEG C, relative humidity (100 ± 5) %, rotating be experimental condition that 60 ± 2r/min and arm carry 500g counterweights Under, use external diameter to wear away coating surface for (51.6 ± 0.1) mm vulcanie friction wheel（Such as CS-10F abrasive wheels）, coating is resistance to Mill property is lost the laboratory mean values three times of (weight-loss method) to grind coating quality after 50 revolutions and evaluated, and is accurate to 0.1mg, such as Mass loss can determine that rub resistance is qualified less than 0.05g and be represented with zero, be used less than 0.03g to be good ● represent, less than 0.01g Represented to be outstanding with ★.In addition, the adhesive force of coating rub resistance and coating, weatherability, hardness etc. are substantially coincident, i.e., it is resistance to When frictional property is qualified, the adhesive force of the coating, weatherability, hardness etc. are also qualified.The detection method is with reference to existing international mark It is accurate《ISO 7784-2-1997, Paints and varnishes, Determination of resistance to Abrasion, Part 2: Rotating abrasive rubber wheel method》With《GA/T 1768-2006 colored paints With the measure rotation rubber emery wheel method of varnish wearability》.

The foregoing is merely illustrative of the preferred embodiments of the present invention, and not to limit the present invention, it is all the present invention's All any modification, equivalent and improvement made within spirit and principle etc., should be included in the scope of the protection.

Claims

1. a kind of antistatic inorganic nano paint composition, it is characterised in that its composition is in parts by weight：Peroxy is modified table 0.001~60 part of the Conductive inorganic nano material of face modification hydroxyl, the rockiness of peroxy modified surface modification hydroxyl are inorganic 0.001~20 part of nano material, 20~99.998 parts of hydrophilic solvent.

2. antistatic inorganic nano paint composition according to claim 1, it is characterised in that the peroxy is modified table The Conductive inorganic nano material of face modification hydroxyl is tin-doped indium oxide, tin oxide, antimony doped tin oxide, mixes bismuth tin oxide, p-doped The fluorin-doped tin oxide of tin oxide, fluorine doped tin oxide, phosphorus, mix antimony zinc oxide, mix bismuth zinc oxide, CNT, graphene, tin Alkene, Nano Silver, nitridation dicalcium, stannic acid beryllium, magnesium stannate, calcium stannate, stronitum stannate, barium stannate, zinc stannate, wolframic acid caesium, vanadic acid beryllium, vanadium One or more in sour magnesium, calcium vanadate, strontium vanadate, vanadic acid barium；The rockiness of peroxy modified surface modification hydroxyl without Machine nano material is the one or more in cerium oxide, tungsten oxide, titanium oxide, silica, aluminum oxide；The hydrophilic solvent is Water, methanol, ethanol, normal propyl alcohol, isopropanol, n-butanol, isobutanol, sec-butyl alcohol, the tert-butyl alcohol, n-amyl alcohol, sec-amyl alcohol, tert-pentyl alcohol, One or more in 1- ethyl -1- propyl alcohol, 2-methyl-1-butene alcohol, n-hexyl alcohol and cyclohexanol.

3. antistatic inorganic nano paint composition according to claim 1 or 2, it is characterised in that to the electric conductivity Inorganic nano material and rockiness inorganic nano material carry out the modifying agent that is all used during peroxy modified surface modification hydroxyl for Hydrogen peroxide, sodium peroxide, potassium peroxide, calper calcium peroxide, peromag, zinc peroxide, potassium hydrogen peroxymonosulfate, strontium peroxide, mistake One or more in barium monoxide, potassium peroxydisulfate.

4. antistatic inorganic nano paint composition according to claim 3, it is characterised in that the progress peroxy changes Property surface modification hydroxyl when modification be in inorganic nano material building-up process carry out or inorganic nano material synthesize After carry out.

5. antistatic inorganic nano paint composition according to claim 3, it is characterised in that the modifying agent addition For 0.001~1000 times of the electric conductivity or rockiness inorganic nano material quality, preferably 0.01~100 times, more preferably For 0.1~10 times.

6. a kind of antistatic inorganic nano clear coat, it is characterised in that any described antistatics of claim 1-5 is inorganic Nano paint composition is coated in body surface and is formed by curing antistatic inorganic nano clear coat.

7. antistatic inorganic nano clear coat according to claim 6, it is characterised in that described applied to spraying, leaching One or more combinations in painting, roller coat, spin coating；The temperature of the solidification be -50 DEG C~4000 DEG C, preferably 10 DEG C~800 DEG C, more preferably 25 DEG C~700 DEG C.

8. antistatic inorganic nano clear coat according to claim 6, it is characterised in that the antistatic inorganic nano The visible light transmissivity of clear coat is 51%~99%, preferably 70%~98%, more preferably 80%~90%；It is described anti-quiet The surface resistivity ρ s of electric inorganic nano clear coat are less than 1 × 10¹¹Ω/, preferably 10³Ω/□≤ρs≤10⁹Ω/, More preferably 10⁴Ω/□≤ρs≤10⁷Ω/□。

9. antistatic inorganic nano clear coat according to claim 6, it is characterised in that the antistatic inorganic nano Clear coat has antistatic, is made up of inorganic nano material, transparent feature.

10. a kind of antistatic product, it is characterised in that the surface of the antistatic product is provided with any institutes of claim 1-9 The antistatic inorganic nano clear coat stated.