CN106700675A - External wall substrate antistatic antifouling coating agent and preparation method thereof - Google Patents

External wall substrate antistatic antifouling coating agent and preparation method thereof Download PDF

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Publication number
CN106700675A
CN106700675A CN201611219019.0A CN201611219019A CN106700675A CN 106700675 A CN106700675 A CN 106700675A CN 201611219019 A CN201611219019 A CN 201611219019A CN 106700675 A CN106700675 A CN 106700675A
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CN
China
Prior art keywords
tin oxide
minutes
silica
parts
exterior wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611219019.0A
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Chinese (zh)
Inventor
张维仁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Green Environmental Protection Co Ltd
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Guangzhou Green Environmental Protection Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Green Environmental Protection Co Ltd filed Critical Guangzhou Green Environmental Protection Co Ltd
Priority to CN201611219019.0A priority Critical patent/CN106700675A/en
Publication of CN106700675A publication Critical patent/CN106700675A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints

Abstract

The invention relates to an external wall substrate antistatic antifouling coating agent which is composed of the following components in parts by weight: 85-92 parts of methanol, 5-10 parts of solvent, 0.10-0.14 part of tin oxide and 1.6-2.6 parts of silicon dioxide. The invention also discloses a preparation method of the coating agent. The method comprises the following steps: S1. material preparation: preparing the materials according to parts by weight, preparing the tin oxide into nano tin oxide while controlling the particle size at 20-30nm, and preparing the silicon dioxide into nano silicon dioxide while controlling the particle size at 20-40nm; S2. sequentially pouring the methanol and solvent into a cleaned container with a stirrer according to the proportion, stirring for 1-3 minutes, and standing for 5-10 minutes to obtain a mixed solution; and S3. mixing: sequentially adding the tin oxide and silicon dioxide into the mixed solution, stirring with a stirrer for 10-20 minutes, and standing for 30-60 minutes to obtain the product. The coating agent has the advantages of simple preparation technique, short production cycle, low cost, environment friendliness and no pollution, prevents static electricity from generation, and has favorable antifouling effects.

Description

Exterior wall base material antistatic antifouling coat agent and preparation method thereof
Technical field
The present invention relates to building material technical field, the particularly agent of exterior wall base material antistatic antifouling coat and its preparation side Method.
Background technology
Building exterior wall material can be largely classified into three major types:Coating, face brick and glass curtain wall.Because urban air pollution is tight Weight, pernicious gas composition or dust in environment are easy to External Wall coating and cause to corrode contamination, are caused after coating is contaminated Outer surface of building is variegated, has a strong impact on its external image, is brushed again after typically it can only being cleaned or is rooted out, this The use cost of building can be considerably increased again.And some buildings use face brick or glass curtain wall as outer wall material, can not Exempt the pollution problem on surface, can only periodically be cleaned, this not only increased use cost, and cleaning process produce it is useless Liquid waste residue will cause secondary pollution again, while cleaning process belongs to work high above the ground mostly, there is certain potential safety hazard.At present, The developing trend of building exterior wall material is in the functional coating of safety environment protecting energy saving, but the high cost of this coating.
The content of the invention
Shortcoming it is an object of the invention to overcome prior art, there is provided a kind of low cost, prepare it is convenient and simple and Convenient exterior wall base material antistatic antifouling coat agent of coating and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:Exterior wall base material antistatic antifouling coat agent, by following heavy Measure the component composition of part:
Methyl alcohol 85-92 parts,
Solvent 5-10 parts,
Tin oxide 0.10-0.14 parts,
Silica 1 .6-2.6 parts.
Preferably, described exterior wall base material antistatic antifouling coat agent, is made up of the component of following weight portion:
89 parts of methyl alcohol,
8 parts of solvent,
0.12 part of tin oxide,
2.1 parts of silica.
Preferably, the solvent is water.
Preferably, the tin oxide is nano level granules of stannic oxide, and the silica is nano level silica Particle.
The preparation method of described exterior wall base material antistatic antifouling coat agent, comprises the following steps:
S1, get the raw materials ready:Got the raw materials ready by the component of above-mentioned each weight portion, tin oxide is made nano tin oxide, controlled it Silica is made nanometer grade silica by particle size range between 20-30 nanometers, controls its particle size range to be received in 20-40 Between rice;
S2, prepare solution:The first alcohol and solvent of proportional quantities is poured into successively clean up, in the container with agitator, Stirring 1-3 minutes, stands 5-10 minutes, obtains mixed solution;
S3, batch mixing:Tin oxide and silica are sequentially added in above-mentioned mixed solution, then 10-20 is stirred with agitator Minute, 30-60 minutes is stood, obtain product.
The present invention has advantages below:
1st, the plastics that the present invention is prepared using common used material, its preparation process is simple, with short production cycle, cost It is low, it is adaptable to which that medium-sized and small enterprises are produced in batches.
2nd, the present invention forms a tunic at normal temperatures after being coated on exterior wall surface, and External Wall can be played well Protective effect, while preventing electrostatic from producing, anti-fouling effect might as well.
Specific embodiment
With reference to embodiment, the present invention will be further described, but protection scope of the present invention is not limited to following institute State.
【Embodiment 1】:
Exterior wall base material antistatic antifouling coat agent, is made up of the component of following weight portion:
85 parts of methyl alcohol,
5 parts of solvent,
0.10 part of tin oxide,
Silica 1 .6 parts.
Preferably, the solvent is water.
Preferably, the tin oxide is nano level granules of stannic oxide, and the silica is nano level silica Particle.
The preparation method of described exterior wall base material antistatic antifouling coat agent, comprises the following steps:
S1, get the raw materials ready:Got the raw materials ready by the component of above-mentioned each weight portion, tin oxide is made nano tin oxide, controlled it Silica is made nanometer grade silica by particle size range at 20 nanometers, controls its particle size range at 20 nanometers;
S2, prepare solution:The first alcohol and solvent of proportional quantities is poured into successively clean up, in the container with agitator, Stirring 1 minute, stands 5 minutes, obtains mixed solution;
S3, batch mixing:Tin oxide and silica are sequentially added in above-mentioned mixed solution, then 10 points are stirred with agitator Clock, stands 30 minutes, obtains product.
【Embodiment 2】:
Exterior wall base material antistatic antifouling coat agent, is made up of the component of following weight portion:
89 parts of methyl alcohol,
8 parts of solvent,
0.12 part of tin oxide,
2.1 parts of silica.
Preferably, the solvent is water.
Preferably, the tin oxide is nano level granules of stannic oxide, and the silica is nano level silica Particle.
The preparation method of described exterior wall base material antistatic antifouling coat agent, comprises the following steps:
S1, get the raw materials ready:Got the raw materials ready by the component of above-mentioned each weight portion, tin oxide is made nano tin oxide, controlled it Silica is made nanometer grade silica by particle size range between 25 nanometers, controls its particle size range between 30 nanometers;
S2, prepare solution:The first alcohol and solvent of proportional quantities is poured into successively clean up, in the container with agitator, Stirring 2 minutes, stands 8 minutes, obtains mixed solution;
S3, batch mixing:Tin oxide and silica are sequentially added in above-mentioned mixed solution, then 15 points are stirred with agitator Clock, stands 45 minutes, obtains product.
【Embodiment 3】:
Exterior wall base material antistatic antifouling coat agent, is made up of the component of following weight portion:
92 parts of methyl alcohol,
10 parts of solvent,
0.14 part of tin oxide,
2.6 parts of silica.
Preferably, the solvent is water.
Preferably, the tin oxide is nano level granules of stannic oxide, and the silica is nano level silica Particle.
The preparation method of described exterior wall base material antistatic antifouling coat agent, comprises the following steps:
S1, get the raw materials ready:Got the raw materials ready by the component of above-mentioned each weight portion, tin oxide is made nano tin oxide, controlled it Silica is made nanometer grade silica by particle size range at 30 nanometers, controls its particle size range at 40 nanometers;
S2, prepare solution:The first alcohol and solvent of proportional quantities is poured into successively clean up, in the container with agitator, Stirring 3 minutes, stands 10 minutes, obtains mixed solution;
S3, batch mixing:Tin oxide and silica are sequentially added in above-mentioned mixed solution, then 20 points are stirred with agitator Clock, stands 60 minutes, obtains product.
【Embodiment 4】:
Exterior wall base material antistatic antifouling coat agent, is made up of the component of following weight portion:
88 parts of methyl alcohol,
10 parts of solvent,
0.11 part of tin oxide,
Silica 1 .8 parts.
Preferably, the solvent is water.
Preferably, the tin oxide is nano level granules of stannic oxide, and the silica is nano level silica Particle.
The preparation method of described exterior wall base material antistatic antifouling coat agent, comprises the following steps:
S1, get the raw materials ready:Got the raw materials ready by the component of above-mentioned each weight portion, tin oxide is made nano tin oxide, controlled it Silica is made nanometer grade silica by particle size range at 20 nanometers, controls its particle size range at 40 nanometers;
S2, prepare solution:The first alcohol and solvent of proportional quantities is poured into successively clean up, in the container with agitator, Stirring 3 minutes, stands 7 minutes, obtains mixed solution;
S3, batch mixing:Tin oxide and silica are sequentially added in above-mentioned mixed solution, then 16 points are stirred with agitator Clock, stands 60 minutes, obtains product.

Claims (5)

1. exterior wall base material antistatic antifouling coat agent, it is characterised in that:It is made up of the component of following weight portion:
2. exterior wall base material antistatic antifouling coat agent according to claim 1, it is characterised in that:By the group of following weight portion It is grouped into:
3. exterior wall base material antistatic antifouling coat agent according to claim 1 and 2, it is characterised in that:The solvent is water.
4. exterior wall base material antistatic antifouling coat agent according to claim 1 and 2, it is characterised in that:The tin oxide is Nano level granules of stannic oxide, the silica is nano level silica dioxide granule.
5. the preparation method of exterior wall base material antistatic antifouling coat agent as claimed in claim 1 or 2, it is characterised in that:Including Following steps:
S1, get the raw materials ready:Got the raw materials ready by the component of above-mentioned each weight portion, tin oxide is made nano tin oxide, controlled its particle diameter Silica is made nanometer grade silica by scope between 20-30 nanometers, controls its particle size range in 20-40 nanometers Between;
S2, prepare solution:The first alcohol and solvent of proportional quantities is poured into successively clean up, in the container with agitator, stirring 1-3 minutes, 5-10 minutes is stood, obtain mixed solution;
S3, batch mixing:Tin oxide and silica are sequentially added in above-mentioned mixed solution, then are stirred 10-20 minutes with agitator, 30-60 minutes is stood, product is obtained.
CN201611219019.0A 2016-12-26 2016-12-26 External wall substrate antistatic antifouling coating agent and preparation method thereof Pending CN106700675A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611219019.0A CN106700675A (en) 2016-12-26 2016-12-26 External wall substrate antistatic antifouling coating agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611219019.0A CN106700675A (en) 2016-12-26 2016-12-26 External wall substrate antistatic antifouling coating agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106700675A true CN106700675A (en) 2017-05-24

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502011A (en) * 2017-10-10 2017-12-22 张家港外星人新材料科技有限公司 Antistatic inorganic nano paint composition, clear coat and antistatic product
CN108641415A (en) * 2018-03-29 2018-10-12 广州碧然环保有限公司 The automatic cleaning coating material and preparation method thereof that a kind of organic and inorganic phase combines
CN115286950A (en) * 2022-08-02 2022-11-04 华南理工大学 External coating type antistatic agent for engineering plastics and preparation thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1481342A (en) * 2000-12-21 2004-03-10 �����ɷ� Substrates with self-cleaning surface, process for their prodn. and their use
CN101423634A (en) * 2008-12-18 2009-05-06 江南大学 Method for preparing multifunctional nano composite material
CN102333831A (en) * 2009-02-27 2012-01-25 Lg化学株式会社 Outstandingly abrasion resistant and pollution resistant coating composition and coating film
CN102746718A (en) * 2012-05-08 2012-10-24 金季平 Room temperature drying type coating material and preparation method for high light transmittance, static electricity resistance and self-cleaning glass
CN103112231A (en) * 2013-03-01 2013-05-22 南京倍立达新材料***工程股份有限公司 Self-cleaning layer with photocatalysis and anti-static compounding functions and production method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1481342A (en) * 2000-12-21 2004-03-10 �����ɷ� Substrates with self-cleaning surface, process for their prodn. and their use
CN101423634A (en) * 2008-12-18 2009-05-06 江南大学 Method for preparing multifunctional nano composite material
CN102333831A (en) * 2009-02-27 2012-01-25 Lg化学株式会社 Outstandingly abrasion resistant and pollution resistant coating composition and coating film
CN102746718A (en) * 2012-05-08 2012-10-24 金季平 Room temperature drying type coating material and preparation method for high light transmittance, static electricity resistance and self-cleaning glass
CN103112231A (en) * 2013-03-01 2013-05-22 南京倍立达新材料***工程股份有限公司 Self-cleaning layer with photocatalysis and anti-static compounding functions and production method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502011A (en) * 2017-10-10 2017-12-22 张家港外星人新材料科技有限公司 Antistatic inorganic nano paint composition, clear coat and antistatic product
CN107502011B (en) * 2017-10-10 2019-12-17 张家港外星人新材料科技有限公司 Antistatic inorganic nano-coating composition, transparent coating and antistatic product
CN108641415A (en) * 2018-03-29 2018-10-12 广州碧然环保有限公司 The automatic cleaning coating material and preparation method thereof that a kind of organic and inorganic phase combines
CN115286950A (en) * 2022-08-02 2022-11-04 华南理工大学 External coating type antistatic agent for engineering plastics and preparation thereof

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Application publication date: 20170524

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