CN107500574A - The 200MPa of compression strength 120 eco-concrete and preparation method thereof - Google Patents

The 200MPa of compression strength 120 eco-concrete and preparation method thereof Download PDF

Info

Publication number
CN107500574A
CN107500574A CN201710694353.XA CN201710694353A CN107500574A CN 107500574 A CN107500574 A CN 107500574A CN 201710694353 A CN201710694353 A CN 201710694353A CN 107500574 A CN107500574 A CN 107500574A
Authority
CN
China
Prior art keywords
eco
concrete
parts
200mpa
compression strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710694353.XA
Other languages
Chinese (zh)
Inventor
周癸豆
苏宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changdu Dragon Hi Tech Materials Ltd By Share Ltd
Original Assignee
Changdu Dragon Hi Tech Materials Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changdu Dragon Hi Tech Materials Ltd By Share Ltd filed Critical Changdu Dragon Hi Tech Materials Ltd By Share Ltd
Priority to CN201710694353.XA priority Critical patent/CN107500574A/en
Publication of CN107500574A publication Critical patent/CN107500574A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • C04B14/48Metal
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • C04B18/082Cenospheres
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/021Ash cements, e.g. fly ash cements ; Cements based on incineration residues, e.g. alkali-activated slags from waste incineration ; Kiln dust cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/12Natural pozzuolanas; Natural pozzuolana cements; Artificial pozzuolanas or artificial pozzuolana cements other than those obtained from waste or combustion residues, e.g. burned clay; Treating inorganic materials to improve their pozzuolanic characteristics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • C04B7/26Cements from oil shales, residues or waste other than slag from raw materials containing flue dust, i.e. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a kind of 200MPa of compression strength 120 eco-concrete and preparation method thereof, it is made up of the following components of parts by weight:600 750 parts of eco-cement, 400 450 parts of fly ash micro-sphere, 1,000 1600 parts of sand material, 150 160 parts of steel fibre, 8 12 parts of high efficiency water reducing agent, 0.1 0.3 parts of defoamer, 156 210 parts of water;The eco-cement, it is made up of powder body material and additive, the powder body material is at least one of limestone, lime stone, volcanic ash, volcano float stone, basalt, illite, montmorillonite, feldspar, shale, kaolin, clay, wollastonite, gangue, silicon ash, flyash, and the additive is at least one of halide, carbonate, sulfate, the alkaline matter of amine, silicate, aluminate, alkali metal hydroxide, alkaline earth metal hydroxide.Cost is cheap, and energy-conserving and environment-protective, raw material are easy to get, good fluidity, and construction is easy.

Description

Compression strength 120-200MPa eco-concrete and preparation method thereof
Technical field
The present invention relates to a kind of concrete and preparation method thereof, especially provides a kind of compression strength 120-200MPa ecology Concrete and preparation method thereof.
Background technology
With the rapid development of the national economy, engineering structure Chao Genggao, bigger, stronger direction develop, this is to concrete Performance proposes new requirement.With the progress of science and technology, ultra-high performance concrete is the Main way for solving this problem One of.Ultra-high performance concrete has good durability, can increase substantially the service life of concrete structure.Meanwhile With excellent mechanical property, it can significantly reduce scantling.In general, ultra-high performance concrete dead load is approximately to pass The 1/3 or 1/2 of system concrete structure, can effectively subtract dead load, save material and cost.But current engineer applied is not It is more:Some are because cost is too high, and some are because technology of preparing is too complicated, and some then the liquidity scales while intensity improves Decline and can not be applied among engineering.Therefore, to meet to be currently needed for, the very-high performance life of large fluidity low cost is configured State concrete, just seem extremely necessary.
At present for ultra-high performance concrete, although existing a small amount of engineer applied, most of to remain in reality Room conceptual phase is tested, existing ultra-high performance concrete often uses high temperature or steam press maintenance, complex manufacturing limit in production Application of the ultra-high performance concrete in Practical Project is made.Because water-cement ratio is very low, ultra-fine grain dosage is big, very-high performance mixes Solidifying soil shows the shortcomings that sticky big and slump is small.Moreover, the cement consumption of existing ultra-high performance concrete be up to 800~ 1000kg/m3, the heat of hydration is increased, produces contraction.Therefore, it is necessary to invent a kind of novel ecological concrete, cement consumption is reduced, Reduce and prepare cost, improve concrete flowability, and simplify production technology.
It is every in building material itself to pass through a series of physical, chemical action, or mixed with other materials (such as water) Hard solid can be become by slurry by a series of physical, chemical action together afterwards, and can be by loose material (such as sand, stone Deng) or block, flaky material (such as brick, stone) cementing integral material, referred to as binder materials.
Cement is the binder materials being commonly used, still, on the one hand, manufacture of cement power consumption is very big, accounts for world's total energy Consumption 15%, China's cement produces more than 200,000,000 tons per year, ranks first in the world, but China's cement specific energy consumption reaches 5280KJ/kg, compares generation Boundary cement average unit energy consumption 3260KJ/kg is high by 60%, and production energy consumption issues are especially prominent.All kinds of mineral moneys in another aspect China Source is very abundant, and industrial residue largely overstocks, and takes tract pollution environment, anxious utilization to be developed.Develop the low glue of energy consumption Gel material, while and can consumes substantial amounts of mineral resources, industrial residue needs to solve the problems, such as us.
The content of the invention
In order to solve the above-mentioned technical problem, it is an object of the invention to provide a kind of normal temperature and pressure maintenance compression strength 120- 200MPa eco-concrete, the present invention also provide its preparation method, and cost is low, energy-conserving and environment-protective, manufacture craft is simple, it is excellent to have Different application property, workability.
In order to realize above-mentioned first purpose, technical scheme is as follows:A kind of compression strength 120-200MPa life State concrete, it is characterised in that:It is made up of the following components of parts by weight:
The eco-cement, is made up of powder body material and additive, the powder body material be limestone, lime stone, volcanic ash, Volcano float stone, basalt, illite, montmorillonite, feldspar, shale, kaolin, clay, wollastonite, gangue, silicon ash, flyash At least one of, the additive is halide, carbonate, sulfate, the alkaline matter of amine, silicate, aluminate, alkali gold Belong at least one of hydroxide, alkaline earth metal hydroxide.
In such scheme:It is the limestone in powder body material, lime stone, volcanic ash, volcano float stone in the eco-cement, profound Wu Yan, illite, montmorillonite, feldspar, shale, kaolin, clay, wollastonite, gangue are needed after first passing through milling processing, then Processing is dried under 600-1000 DEG C of environment.The performance of eco-cement, improve intensity.
In such scheme:According to parts by weight, the powder body material is 80-100 parts, and the additive is 10-30 parts.
In such scheme:The additive is alkali metal hydroxide and/or alkaline earth metal hydroxide.
In such scheme:The additive is the alkaline matter of amine.
In such scheme:The alkaline matter of the amine is DTAC or quaternary amine alkali.Using quaternary amine The performance of obtained gel rubber material is more preferable.
In such scheme:The additive is at least one in halide, carbonate, sulfate, silicate, aluminate Kind.
It is preferred that:The fly ash micro-sphere is the fine heavy pearl of superfined flyash;
The sand material is particle diameter 0.3-0.6mm quartz sand, particle diameter 0.212-0.3mm quartz sand, particle diameter 0.106- At least one of 0.212mm quartz sand, maximum particle diameter≤0.6mm after mixing;
The steel fibre diameter d=0.12-0.3mm, length 3-10mm, and tensile strength is more than 4000MPa;
The high efficiency water reducing agent is Polycarboxylic Superplasticizer, water-reducing rate >=35%.
The defoamer is polyglycol solution, and wherein solids content is 30%.
The eco-cement of the present invention, using water as mass transfer media and reaction media, part water exists as constitution water after solidification Among reactant, the hydration reaction of calcium silicates is not present in the material, and its final product is based on ionic bond and covalent bond, Fan De Supplemented by Wa Lesi keys, and conventional cement is then based on van der waals bond and hydrogen bond, therefore its performance is better than conventional cement.
Compared with the cement of prior art, the eco-cement in the present invention has advantages below:(1), intensity is high, main power Learn performance indications and be better than glass and cement, can be compared favourably with metal materials such as ceramics, aluminum steels.And, should compared with other cement Material is after 650 DEG C are dried, and its intensity is without any loss.The material wear-resistant degree is 4.9, and same type of material is only 1.9.
(2), there is stronger corrosion resistance and preferable durability, there is high resistance to sulfate aggressivity, with other cement Compare, corroded by 4 hours 30% sulfuric acid, its loss of strength is only 1/5 to the 1/6 of cement, is significantly better than conventional cement material.
(3), there is preferably fast hard solidification, setting time is fast, and hardening is fast.The material is used for road repair, can be achieved Construction 2 hours after light duty traffic, can be open to traffic after 4 hours, airport can realize takeoff and landing after 6 hours.
(4), material high temperature resistant, good heat-insulation effect, its thermal conductivity factor is relatively low, can be compared favourably with light fire-clay brick.
(5) simple, low in raw material price, rich reserves, are formulated.
(6), energy consumption is low, and specific energy consumption is less than 600KJ/k, and its energy consumption only has the 1/20, the 1/70 of steel of ceramics, plastics 1/150.
(7), its unique cage structure, many new function and usages can be developed, film sorbing material is such as made.
(8) the concrete antifreezing grade produced by the present invention can reach F300, and same type of material is only F100.The present invention is made Concrete impervious grade can reach S40, same type of material is only S10.
(9), can low temperature, weather proof execution, curing cycle is short.
(10), the eco-cement, volume contraction be not small, easy to crack.
The concrete of the present invention is on the premise of ultra-high performance concrete indices are ensured, with water needed for eco-concrete Mud is few, reduces the heat of hydration, concrete is not likely to produce contraction, while has saved cost.
Fly ash micro-sphere, polycarboxylate water-reducer and defoamer are added in the concrete of the present invention, fly ash micro-sphere reduces Eco-concrete viscosity, polycarboxylic acids dehydragent make eco-concrete keep remaining in the case of compared with low water-cement ratio obtaining it is good Mobility.Defoamer, which is eliminated in ultra-high concrete, there is bubble, ensure that the compactness of the internal structure of eco-concrete, from And it ensure that the intensity of concrete;
Steel fibre is added in concrete of the present invention, the steel fibre of random distribution can effectively hinder inside concrete micro- The extension in crack and the formation of macrocrack, it is used cooperatively the tension for significantly improving concrete, bending resistance with eco-cement, resists Impact and anti-fatigue performance, have preferable ductility.
The eco-concrete compression strength that the present invention configures is in 120-200MPa, using only conventional raw materials, it is not necessary to special Different raw material, manufacturing cost are relatively low.
The eco-concrete that the present invention configures, is conserved using normal temperature and pressure, simplifies maintaining process.
In order to realize above-mentioned second purpose, the technical scheme is that:A kind of any one of the claim 1-9 resistance to compression The preparation method of intensity 120-200MPa eco-concrete, it is characterised in that:In accordance with the following steps:
(1) eco-cement, fly ash micro-sphere, sand material are mixed to form component A;High efficiency water reducing agent, defoamer and water are mixed Conjunction forms component B;
(2) first component A is placed in concrete mixer, open concrete mixer component A is thoroughly mixed 5~ After 20 seconds, then by component B addition mixers, it is stirred 2~4 minutes, uniformly adds when waiting compound to turn into slurry together Enter steel fibre, uniformly rear stopping to be mixed obtaining required concrete.
After the completion of stirring, gained concreting is entered into mould, form removal after 24h, is positioned in the environment of standard atmospheric pressure and supports Protect 28d.Simple production process, cost are low.
Beneficial effect:The eco-concrete that the present invention is configured does not need special source materials, and cost is cheap, energy-conserving and environment-protective, While concrete strength is improved, the mobility of concrete can be also increased substantially.With excellent construction workability.Together When, the concrete also tensile strength with superelevation, remarkable toughness and excellent durability.
Embodiment
With reference to embodiment, the invention will be further described:
Embodiment 1
The preparation of eco-cement
According to parts by weight, 60 parts of clay, 30 parts of tufa stone, 8 parts of sodium hydroxide, 2 parts of calcium hydroxide, clay and tufa stone Milling processing is first passed through, then does drying process at 700 DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 2
The preparation of eco-cement
According to parts by weight, 20 parts of tufa stone, 60 parts of shale, 10 parts of DTAC, 10 parts of sodium sulphate, After two kinds of rock millings, powder mixing, drying process is done at 600 DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 3
The preparation of eco-cement
According to parts by weight, 25 parts of silicon ash, 60 parts of kaolin, 15 parts of quaternary amine alkali, kaolin is after milling is handled, 600 Drying process is done at DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 4
The preparation of eco-cement
According to parts by weight, 45 parts of gangue, 35 parts of flyash, 15 parts of sodium metasilicate, 5 parts of sodium aluminate.Gangue is through milling Afterwards, drying process is done at 900 DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 5
The preparation of eco-cement
According to parts by weight, 40 parts of limestone, 50 parts of lime stone, 20 parts of potassium hydroxide.Limestone and lime stone after milling, Drying process is done at 850 DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 6
The preparation of eco-cement
According to parts by weight, 20 parts of volcanic ash, 60 parts of volcano float stone, 25 parts of magnesium hydroxide.Volcanic ash and volcano float stone warp After milling, drying process is done at 600 DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 7
The preparation of eco-cement
According to parts by weight, 25 parts of basalt, 55 parts of volcano float stone, 30 parts of sodium carbonate.Basalt and volcano float stone are through mill After powder, drying process is done at 600 DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 8
The preparation of eco-cement
According to parts by weight, totally 86 parts of illite, montmorillonite, feldspar, 22 parts of sodium phosphate.Illite, montmorillonite, feldspar warp After milling, drying process is done at 700 DEG C.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 9
The preparation of eco-cement
According to parts by weight, 100 parts of volcanic ash, 25 parts of sodium fluoride.Volcanic ash does dry place after milling at 600 DEG C Reason.Above-mentioned each material is well mixed to obtain eco-cement.
Embodiment 10
The preparation of eco-cement is according to parts by weight, and 82 parts of silicon ash, 20 parts of sodium chloride is well mixed to obtain eco-cement.
Embodiment 11-20 is the preparation method of concrete
The embodiment 1-10 of embodiment 11-20 respectively eco-cement, its composition are as shown in the table:
Data match according to parts by weight in table.
Sand material is particle diameter 0.3-0.6mm quartz sand, particle diameter 0.212-0.3mm quartz sand, particle diameter 0.106-0.212mm At least one of quartz sand, maximum particle diameter≤0.6mm after mixing.In the above-described embodiments, two kinds and above particle diameter model are selected The mixture of the quartz sand enclosed.
The steel fibre diameter d=0.12-0.3mm, length 3-10mm, and tensile strength is more than 4000MPa.
High efficiency water reducing agent is Polycarboxylic Superplasticizer, water-reducing rate >=35%.
Defoamer is polyglycol solution, and wherein solids content is 30%.
Eco-cement, fly ash micro-sphere, sand material are mixed to form component A during preparation.By high efficiency water reducing agent, defoamer and water It is mixed to form component B.
Component A is placed in concrete mixer, concrete mixer is opened and is thoroughly mixed component A 5~20 seconds Afterwards, then by component B add in mixer, be stirred together 2~4 minutes, steel is uniformly added into when waiting compound to turn into slurry Fiber, uniformly rear stopping to be mixed obtaining required concrete.
The present invention is not limited to above-mentioned specific embodiment, it will be appreciated that one of ordinary skill in the art is without creative Work can makes many modifications and variations according to the design of the present invention.In a word, all technician in the art are according to this The design of invention passes through the available technical side of logical analysis, reasoning, or a limited experiment on the basis of existing technology Case, all should be in the protection domain being defined in the patent claims.

Claims (10)

  1. A kind of 1. compression strength 120-200MPa eco-concrete, it is characterised in that:It is made up of the following components of parts by weight:
    The eco-cement, is made up of powder body material and additive, and the powder body material is limestone, lime stone, volcanic ash, volcano In float stone, basalt, illite, montmorillonite, feldspar, shale, kaolin, clay, wollastonite, gangue, silicon ash, flyash At least one, the additive are halide, carbonate, sulfate, the alkaline matter of amine, silicate, aluminate, alkali metal hydrogen At least one of oxide, alkaline earth metal hydroxide.
  2. 2. compression strength 120-200MPa eco-concrete according to claim 1, it is characterised in that:The eco-cement Powder body material in limestone, lime stone, volcanic ash, volcano float stone, basalt, illite, montmorillonite, feldspar, shale, kaolinite Soil, clay, wollastonite, gangue are needed after first passing through milling processing, then processing is dried under 600-1000 DEG C of environment.
  3. 3. compression strength 120-200MPa eco-concrete according to claim 2, it is characterised in that:According to parts by weight Number, the powder body material is 80-100 parts, and the additive is 10-30 parts.
  4. 4. according to any one of claim 1-3 compression strength 120-200MPa eco-concrete, it is characterised in that:It is described Additive is alkali metal hydroxide and/or alkaline earth metal hydroxide.
  5. 5. according to any one of claim 1-3 compression strength 120-200MPa eco-concrete, it is characterised in that:It is described Additive is the alkaline matter of amine.
  6. 6. compression strength 120-200MPa eco-concrete according to claim 5, it is characterised in that:The alkalescence of the amine Material is DTAC or quaternary amine alkali.
  7. 7. according to any one of claim 1-3 compression strength 120-200MPa eco-concrete, it is characterised in that:It is described Additive is at least one of halide, carbonate, sulfate, silicate, aluminate.
  8. 8. according to any one of claim 1-3 compression strength 120-200MPa eco-concrete, it is characterised in that:It is described The fly ash micro-sphere is the fine heavy pearl of superfined flyash;
    The sand material is particle diameter 0.3-0.6mm quartz sand, particle diameter 0.212-0.3mm quartz sand, particle diameter 0.106-0.212mm At least one of quartz sand;
    The steel fibre diameter d=0.12-0.3mm, length 3-10mm, and tensile strength is more than 4000MPa;
    The high efficiency water reducing agent is Polycarboxylic Superplasticizer, water-reducing rate >=35%.
  9. 9. compression strength 120-200MPa very-high performance eco-concrete according to claim 8, it is characterised in that:It is described Defoamer is polyglycol solution, and wherein solids content is 30%.
  10. 10. a kind of preparation method of any one of claim 1-9 compression strength 120-200MPa eco-concrete, it is special Sign is:In accordance with the following steps:
    (1) eco-cement, fly ash micro-sphere, sand material are mixed to form component A;High efficiency water reducing agent, defoamer and water are mixed into shape Into component B;
    (2) first component A is placed in concrete mixer, opens concrete mixer and be thoroughly mixed component A 5~20 seconds Afterwards, then by component B add in mixer, be stirred together 2~4 minutes, steel is uniformly added into when waiting compound to turn into slurry Fiber, uniformly rear stopping to be mixed obtaining required concrete.
CN201710694353.XA 2017-08-14 2017-08-14 The 200MPa of compression strength 120 eco-concrete and preparation method thereof Pending CN107500574A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710694353.XA CN107500574A (en) 2017-08-14 2017-08-14 The 200MPa of compression strength 120 eco-concrete and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710694353.XA CN107500574A (en) 2017-08-14 2017-08-14 The 200MPa of compression strength 120 eco-concrete and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107500574A true CN107500574A (en) 2017-12-22

Family

ID=60691021

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710694353.XA Pending CN107500574A (en) 2017-08-14 2017-08-14 The 200MPa of compression strength 120 eco-concrete and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107500574A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109293294A (en) * 2018-10-08 2019-02-01 科利尔环保科技有限责任公司 A kind of side slope deep layer gutter enhancement eco-concrete
CN109734403A (en) * 2019-03-18 2019-05-10 常熟理工学院 A kind of preparation method of tufa stone cementitious material
WO2021105823A1 (en) * 2019-11-26 2021-06-03 Navoday Sciences Private Limited Chemically processed mineral additive for increasing the durability of cement and concrete
CN113307583A (en) * 2021-07-05 2021-08-27 上海市地江建筑科技有限公司 Self-compacting neutron radiation prevention type ultrahigh-performance concrete and preparation method thereof
CN114180900A (en) * 2021-12-23 2022-03-15 石家庄市农林科学研究院 Water-retention ecological planting concrete material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1609031A (en) * 2004-11-09 2005-04-27 张立省 New type of ecological cement and its prepn and application
CN101580369A (en) * 2009-06-19 2009-11-18 清华大学 Fiber reinforced high-strength mortar used for concrete structure repair
CN101805160A (en) * 2010-04-21 2010-08-18 中南大学 Self-compacting concrete
JP2011116642A (en) * 2009-12-01 2011-06-16 Korea Inst Of Science & Technology Modified sulfur binding agent, hydraulic modified sulfur material composition containing the same, and their production method
CN103265247A (en) * 2013-04-24 2013-08-28 中国石油大学(北京) Airfield runway pavement layer prepared from high-toughness impact-resistant cement-based composite material
CN103274652A (en) * 2013-06-20 2013-09-04 中建三局建设工程股份有限公司 Reactive powder concrete for reinforcing buildings as well as preparation method and construction method thereof
CN107382102A (en) * 2017-08-14 2017-11-24 昌都龙者高新材料股份有限公司 Eco-cement for highlands

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1609031A (en) * 2004-11-09 2005-04-27 张立省 New type of ecological cement and its prepn and application
CN101580369A (en) * 2009-06-19 2009-11-18 清华大学 Fiber reinforced high-strength mortar used for concrete structure repair
JP2011116642A (en) * 2009-12-01 2011-06-16 Korea Inst Of Science & Technology Modified sulfur binding agent, hydraulic modified sulfur material composition containing the same, and their production method
CN101805160A (en) * 2010-04-21 2010-08-18 中南大学 Self-compacting concrete
CN103265247A (en) * 2013-04-24 2013-08-28 中国石油大学(北京) Airfield runway pavement layer prepared from high-toughness impact-resistant cement-based composite material
CN103274652A (en) * 2013-06-20 2013-09-04 中建三局建设工程股份有限公司 Reactive powder concrete for reinforcing buildings as well as preparation method and construction method thereof
CN107382102A (en) * 2017-08-14 2017-11-24 昌都龙者高新材料股份有限公司 Eco-cement for highlands

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109293294A (en) * 2018-10-08 2019-02-01 科利尔环保科技有限责任公司 A kind of side slope deep layer gutter enhancement eco-concrete
CN109734403A (en) * 2019-03-18 2019-05-10 常熟理工学院 A kind of preparation method of tufa stone cementitious material
CN109734403B (en) * 2019-03-18 2021-11-26 常熟理工学院 Preparation method of tuff cementing material
WO2021105823A1 (en) * 2019-11-26 2021-06-03 Navoday Sciences Private Limited Chemically processed mineral additive for increasing the durability of cement and concrete
CN113307583A (en) * 2021-07-05 2021-08-27 上海市地江建筑科技有限公司 Self-compacting neutron radiation prevention type ultrahigh-performance concrete and preparation method thereof
CN114180900A (en) * 2021-12-23 2022-03-15 石家庄市农林科学研究院 Water-retention ecological planting concrete material and preparation method thereof
CN114180900B (en) * 2021-12-23 2022-07-08 石家庄市农林科学研究院 Water-retention ecological planting concrete material and preparation method thereof

Similar Documents

Publication Publication Date Title
Ma et al. Study on compressive strength and durability of alkali-activated coal gangue-slag concrete and its mechanism
CN107500574A (en) The 200MPa of compression strength 120 eco-concrete and preparation method thereof
CN109928685B (en) Quick-hardening early-strength concrete prepared from various industrial solid wastes and preparation method thereof
CN103086662B (en) Method for preparing reactive powder concrete for construction member by utilizing coal gangue
Vikas et al. Setting time, workability and strength properties of alkali activated fly ash and slag based geopolymer concrete activated with high silica modulus water glass
CN109942235B (en) Normal-temperature curing geopolymer concrete with high strength and high anti-carbonization performance and preparation method thereof
CN108623196A (en) A kind of lime excitation large dosage industrial residue low-carbon cement and preparation method thereof
CN106082898A (en) Geopolymer composite material that 3D prints and its production and use
Zhang et al. A low-carbon alkali activated slag based ultra-high performance concrete (UHPC): Reaction kinetics and microstructure development
CN103224374A (en) Ecological type nanometer super high performance cement based composite material and preparation method thereof
CN103449744A (en) Fly ash based geopolymer and preparation method thereof
CN106517978A (en) Light-weight thermal mortar taking ardealite hydraulic compound gel material as principal material
CN102718423B (en) Preparation method of low-grade activated coal ash composite material
CN110526631A (en) Fly ash-based geopolymer material and preparation method thereof for solidifying chromium slag
CN106630700B (en) It is a kind of using flyash and cullet as inorganic coagulation material of raw material and preparation method thereof
CN104211436B (en) Add the powder ash air-entrained concrete building block of magnesium oxide, magnesium chloride
CN109776003A (en) A kind of calcium based geopolymer cementitious material of multiple elements design powder and preparation method thereof
CN106278102B (en) A kind of method and its product carrying out gypsum toughening using nickel slag
CN111847921B (en) Low clinker cement and preparation method and application thereof
Júnior et al. Effect of bottom ash waste on the rheology and durability of alkali activation pastes
CN114057454A (en) Self-compacting quick-setting dry powder mortar and preparation method thereof
Dave et al. Impact resistance of geopolymer concrete containing recycled plastic aggregates
CN113354314A (en) High-activity cementing material based on engineering muck
CN107746233A (en) A kind of mortar for building and its production method
CN107892533A (en) A kind of waterfront structure Grouting Cement mortar and its production method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20171222