CN107488408B - A kind of Anti-static adhesive and preparation method thereof for blue on piece - Google Patents
A kind of Anti-static adhesive and preparation method thereof for blue on piece Download PDFInfo
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- CN107488408B CN107488408B CN201710581032.9A CN201710581032A CN107488408B CN 107488408 B CN107488408 B CN 107488408B CN 201710581032 A CN201710581032 A CN 201710581032A CN 107488408 B CN107488408 B CN 107488408B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/02—Applications for biomedical use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
The present invention relates to a kind of Anti-static adhesives and preparation method thereof for medical blue on piece.After the Anti-static adhesive being prepared is coated on medical blue on piece, blue piece can be made to have the effect of antistatic, while showing smooth exquisiteness.By the material composition of following parts by weight: 400~460 parts of water, 15~25 parts of gelatin, 2~4 parts of jelly, 8~11 parts of nonionic surface active agent, 4~6 parts of anionic surfactant, 4~7 parts of brightening agent, 1~3 part of empgen BB, 30~40 parts of spectroscopic pure sodium oxide molybdena, 8~12 parts of alum.Preparation method includes: a. configuration jelly, takes gelatin and empgen BB to be uniformly mixed by weight for 2:1；B. water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is completely dissolved；D. nonionic surfactant is added quickly to stir 3 minutes；E. anionic surfactant is added quickly to stir 3 minutes；And etc..
Description
Technical field
The present invention relates to a kind of adhesive, in particular to a kind of Anti-static adhesive and its preparation for medical blue on piece
Method.
Background technique
In modern medical service, image film occupies very important position, PET(poly terephthalic acid second in medical diagnosis on disease
Diol-lipid) for material because of its good heat resistance, bending strength and elasticity, manufactured medical film is wide in medical diagnosis
General application, but the film texture of pure PET material is poor, is easy static electrification, the film of static electrification is not suitable for printing, and film
Between be easy absorption.PET material is exactly that surface is sliding and gloss as another disadvantage of film, is not suitable for writing.
Summary of the invention
The first object of the present invention disadvantage not smooth enough for the easy static electrification of medical blue piece, surface in the prior art, mentions
It can make indigo plant after Anti-static adhesive is coated on medical blue on piece for a kind of Anti-static adhesive for medical blue on piece
Piece has the effect of antistatic, while showing smooth exquisiteness.
The present invention is carried out by the following technical programs:
A kind of Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: 400~460 parts of water,
15~25 parts of gelatin, 2~4 parts of jelly, 8~11 parts of nonionic surface active agent, 4~6 parts of anionic surfactant, increase
White dose 4~7 parts, 1~3 part of empgen BB, 30~40 parts of spectroscopic pure sodium oxide molybdena, 8~12 parts of alum.
Preferably, the Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: water 410~
450 parts, 18~23 parts of gelatin, 2.5~3.8 parts of jelly, 8.5~10 parts of nonionic surface active agent, anionic surface is living
4.5~5.5 parts of agent of property, 4.5~6.5 parts of brightening agent, 1~2.5 part of empgen BB, 32~38 parts of spectroscopic pure sodium oxide molybdena,
9~11 parts of alum.
Preferably, the Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: 430 parts of water,
20 parts of gelatin, 3.5 parts of jelly, 9.25 parts of nonionic surface active agent, 5 parts of anionic surfactant, 5.2 parts of brightening agent,
1.5 parts of empgen BB, 35 parts of spectroscopic pure sodium oxide molybdena, 10.2 parts of alum.
Preferably, the jelly is the mixture of gelatin and empgen BB, gelatin and dodecyl beet
The weight ratio of alkali is 2 ﹕ 1.
Preferably, the nonionic surface active agent is alkyl glucoside, fatty glyceride, fatty acid sorb
One of smooth and polysorbate is a variety of.
Preferably, the anionic surfactant is stearic acid, neopelex and alkyl sulfonic acid
One of sodium is a variety of.
The second object of the present invention is to provide a kind of preparation method of Anti-static adhesive for medical blue on piece, packet
Include following steps: a. configures jelly, takes gelatin and empgen BB to be uniformly mixed by weight for 2:1；B. in agitated kettle
Middle addition water and gelatin stir 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is completely molten
Solution；D. nonionic surfactant is added quickly to stir 3 minutes；E. after addition anionic surfactant quickly stirs 3 minutes；
F. after addition brightening agent quickly stirs 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added
Stirring 3 minutes；I. alum is added to stir 3 minutes.
Empgen BB in adhesive provided by the invention is to eliminate the main factor of adhesive electrostatic, is being matched
Introduction volume is higher in side, and the antistatic property of adhesive is better, therefore introduces 12 in the jelly of phase configuration before this invention
Alkyl betaine plays anti-static purpose, and empgen BB is introduced back into during preparing adhesive and further eliminates glue
Glutinous agent electrostatic.
Nonionic surface active agent in adhesive provided by the invention includes hydrophilic radical (polar group) and hydrophobic
Group (non-polar group), according to similar compatibility principle, in conjunction with gelatin.
Gelatin in adhesive provided by the invention can make the adhesive more smooth exquisiteness in surface after coating.
The intensity of adhesive can be improved in spectroscopic pure sodium oxide molybdena in adhesive provided by the invention.
The beneficial effects of the present invention are: after adhesive of the invention is coated on medical blue on piece, there is antistatic energy
Power, while the smooth exquisiteness of coating surface；On the other hand, the adhesive does not contain heavy metal, halogen and harmful VOC object
Matter, therefore no pollution to the environment, it is harmless.
Specific embodiment
Below by embodiment, the technical solutions of the present invention will be further described；
Embodiment 1: a kind of Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: water 400
Part, 15 parts of gelatin, 2 parts of jelly, 8 parts of fatty glyceride, 4 parts of neopelex, 4 parts of brightening agent, dodecyl sweet tea
1 part of dish alkali, 30 parts of spectroscopic pure sodium oxide molybdena, 8 parts of alum.
Preparation method: a. configures jelly, takes gelatin and empgen BB to be uniformly mixed by weight for 2:1；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. fatty glyceride is added quickly to stir 3 minutes；E. after addition neopelex quickly stirs 3 minutes；
F. after addition brightening agent quickly stirs 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added
Stirring 3 minutes；I. it is added after alum stirs 3 minutes up to this product.
Embodiment 2: a kind of Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: water 460
Part, 25 parts of gelatin, 4 parts of jelly, 11 parts of alkyl glucoside, 6 parts of stearic acid, 7 parts of brightening agent, 3 parts of empgen BB, spectrum
40 parts of pure zirconia sodium, 12 parts of alum.
Preparation method: a. configures jelly, takes gelatin and empgen BB to be uniformly mixed by weight for 2:1；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. alkyl glucoside is added quickly to stir 3 minutes；E. after addition stearic acid quickly stirs 3 minutes；F. brightening agent is added
Quickly after stirring 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added to stir 3 minutes；i.
It is added after alum stirs 3 minutes up to this product.
Embodiment 3: a kind of Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: water 410
Part, 18 parts of gelatin, 2.5 parts of jelly, smooth 8.5 parts of fat acid sorb, 4.5 parts of sodium alkyl sulfonate, 4.5 parts of brightening agent, dodecyl sweet tea
1 part of dish alkali, 32 parts of spectroscopic pure sodium oxide molybdena, 9 parts of alum.
Preparation method: a. configures jelly, takes gelatin and empgen BB to be uniformly mixed by weight for 2:1；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. it is added the smooth quick stirring of fat acid sorb 3 minutes；E. after addition sodium alkyl sulfonate quickly stirs 3 minutes；F. it is added and increases
White dose quickly after stirring 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added and stirs 3 points
Clock；I. it is added after alum stirs 3 minutes up to this product.
Embodiment 4: a kind of Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: water 450
Part, 23 parts of gelatin, 3.8 parts of jelly, 10 parts of polysorbate, 5.5 parts of sodium alkyl sulfonate, 6.5 parts of brightening agent, empgen BB
2.5 parts, 38 parts of spectroscopic pure sodium oxide molybdena, 11 parts of alum.
Preparation method: a. configures jelly, takes gelatin and empgen BB to be uniformly mixed by weight for 2:1；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. polysorbate is added quickly to stir 3 minutes；E. after addition sodium alkyl sulfonate quickly stirs 3 minutes；F. it is added and brightens
After agent quickly stirs 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added to stir 3 minutes；
I. it is added after alum stirs 3 minutes up to this product.
Embodiment 5: a kind of Anti-static adhesive for medical blue on piece, by the material composition of following parts by weight: water 430
Part, 20 parts of gelatin, 3.5 parts of jelly, 9.25 parts of polysorbate, 5 parts of stearic acid, 5.2 parts of brightening agent, empgen BB 1.5
Part, 35 parts of spectroscopic pure sodium oxide molybdena, 10.2 parts of alum.
Preparation method: a. configures jelly, takes gelatin and empgen BB to be uniformly mixed by weight for 2:1；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. polysorbate is added quickly to stir 3 minutes；E. after addition stearic acid quickly stirs 3 minutes；F. it is fast that brightening agent is added
After speed stirring 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added to stir 3 minutes；I. plus
Enter after alum stirs 3 minutes up to this product.
Application examples: the adhesive that Examples 1 to 5 is prepared is poured into respectively in static pot, then passes through the filter core of 80um
It filters back in agitated kettle, which is uniformly coated on medical blue on piece, coating thickness is dry solidification at 9 μm, 125 DEG C
3min forms adhesive layer, 12~14 revs/min must be kept to stir at low speed in agitated kettle in coating process, to prevent gluing
Agent precipitating.
Specific embodiment described herein is only an example for the spirit of the invention.The neck of technology belonging to the present invention
The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method
In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.
Claims (6)
1. a kind of Anti-static adhesive for medical blue on piece, which is characterized in that by the material composition of following parts by weight: water
400~460 parts, 15~25 parts of gelatin, 2~4 parts of jelly, 8~11 parts of nonionic surface active agent, anionic surface activity
4~6 parts of agent, 4~7 parts of brightening agent, 1~3 part of empgen BB, 30~40 parts of spectroscopic pure sodium oxide molybdena, 8~12 parts of alum,
The jelly is the mixture of gelatin and empgen BB, and the weight ratio of gelatin and empgen BB is 2 ﹕ 1.
2. a kind of Anti-static adhesive for medical blue on piece according to claim 1, which is characterized in that by following heavy
The material composition of amount part: 410~450 parts of water, 18~23 parts of gelatin, 2.5~3.8 parts of jelly, nonionic surface active agent 8.5
~10 parts, 4.5~5.5 parts of anionic surfactant, 4.5~6.5 parts of brightening agent, 1~2.5 part of empgen BB,
32~38 parts of spectroscopic pure sodium oxide molybdena, 9~11 parts of alum.
3. a kind of Anti-static adhesive for medical blue on piece according to claim 1, which is characterized in that by following heavy
The material composition of amount part: 430 parts of water, 20 parts of gelatin, 3.5 parts of jelly, 9.25 parts of nonionic surface active agent, anionic surface
5 parts of activating agent, 5.2 parts of brightening agent, 1.5 parts of empgen BB, 35 parts of spectroscopic pure sodium oxide molybdena, 10.2 parts of alum.
4. a kind of Anti-static adhesive for medical blue on piece according to claim 1 or 2 or 3, which is characterized in that institute
The nonionic surface active agent stated is alkyl glucoside, fatty glyceride, one in fatty acid sorbitan and polysorbate
Kind is a variety of.
5. a kind of Anti-static adhesive for medical blue on piece according to claim 1 or 2 or 3, which is characterized in that institute
The anionic surfactant stated is stearic acid, one of neopelex and sodium alkyl sulfonate or a variety of.
6. a kind of Anti-static adhesive for medical blue on piece according to claim 1 or 2 or 3, which is characterized in that its
The preparation method comprises the following steps: a. configures jelly, gelatin and empgen BB is taken to be uniformly mixed by weight for 2:1；B. in agitated kettle
Middle addition water and gelatin stir 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is completely molten
Solution；D. nonionic surfactant is added quickly to stir 3 minutes；E. after addition anionic surfactant quickly stirs 3 minutes；
F. after addition brightening agent quickly stirs 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added
Stirring 3 minutes；I. alum is added to stir 3 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710581032.9A CN107488408B (en) | 2017-07-17 | 2017-07-17 | A kind of Anti-static adhesive and preparation method thereof for blue on piece |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710581032.9A CN107488408B (en) | 2017-07-17 | 2017-07-17 | A kind of Anti-static adhesive and preparation method thereof for blue on piece |
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| Publication Number | Publication Date |
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| CN107488408A CN107488408A (en) | 2017-12-19 |
| CN107488408B true CN107488408B (en) | 2019-05-14 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5888712A (en) * | 1997-12-16 | 1999-03-30 | Eastman Kodak Company | Electrically-conductive overcoat for photographic elements |
| CN1326116A (en) * | 2000-05-31 | 2001-12-12 | 富士胶片株式会社 | Silver halide color photosensitive material |
| CN106113962A (en) * | 2016-06-26 | 2016-11-16 | 乐凯医疗科技有限公司 | A kind of material capable of repeat printing |
| CN106928847A (en) * | 2015-12-30 | 2017-07-07 | 乐凯华光印刷科技有限公司 | A kind of silver halide image exports film bottom antistatic coating fluid and its preparation method and application |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030141487A1 (en) * | 2001-12-26 | 2003-07-31 | Eastman Kodak Company | Composition containing electronically conductive polymer particles |
-
2017
- 2017-07-17 CN CN201710581032.9A patent/CN107488408B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5888712A (en) * | 1997-12-16 | 1999-03-30 | Eastman Kodak Company | Electrically-conductive overcoat for photographic elements |
| CN1326116A (en) * | 2000-05-31 | 2001-12-12 | 富士胶片株式会社 | Silver halide color photosensitive material |
| CN106928847A (en) * | 2015-12-30 | 2017-07-07 | 乐凯华光印刷科技有限公司 | A kind of silver halide image exports film bottom antistatic coating fluid and its preparation method and application |
| CN106113962A (en) * | 2016-06-26 | 2016-11-16 | 乐凯医疗科技有限公司 | A kind of material capable of repeat printing |
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| CN107488408A (en) | 2017-12-19 |
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