CN107443945B - A kind of elasticity thermal transfer is carved characters film and its production method - Google Patents
A kind of elasticity thermal transfer is carved characters film and its production method Download PDFInfo
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- CN107443945B CN107443945B CN201710166285.XA CN201710166285A CN107443945B CN 107443945 B CN107443945 B CN 107443945B CN 201710166285 A CN201710166285 A CN 201710166285A CN 107443945 B CN107443945 B CN 107443945B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38235—Contact thermal transfer or sublimation processes characterised by transferable colour-forming materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/14—Multicolour printing
- B41M1/20—Multicolour printing by applying differently-coloured inks simultaneously to different parts of the printing surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Decoration By Transfer Pictures (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of elasticity thermal transfer is carved characters film, including carrying ground, protective layer back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph ink and adhesive layer thermosol, the formula of protective layer back coating liquid are as follows: 14 parts of amino resins, 4 parts of acrylic resin, 3 parts of silica, 1 part of amino resin crosslinking agent and 78 parts of mixed solvent；The formula of release layer pressure-sensitive adhesive agent are as follows: 10 parts of organic pressure-sensitive gel, 15 parts of silica gel, 2 parts of platinum catalyst and 73 parts of 120# solvent；The formula of chromatograph ink are as follows: 25 parts of high resiliency high temperature resistant TPU resin, 10 parts of toner, 3 parts of wetting and dispersing leveling auxiliary agent and 62 parts of mixed solvent；The formula of adhesive layer thermosol are as follows: 30 parts and 5 parts of TPU opening agent of high-elastic 65 parts of low form TPU resin, high melting means low form TPU resin.The elasticity heat transfer film, with batch E≤4 homochromy color difference △, resistance to mill property≤90% of thermoprint layer, off-type force=(0.10 ~ 3.00) N/25mm is water-fastness, washes colour fading rate≤10%, and basic security technical requirements meet B class in GB18401.
Description
Technical field
The present invention relates to thermal transfer technology fields, specifically refer to that a kind of elastic thermal transfer is carved characters film and its producer
Method.
Background technique
Thermal transfer is a kind of emerging printing technology.The technique mode of printing is first to print transfer film, i.e., first by pattern
Or text is imprinted on film surface, then by thermal transfer process equipment, is transferred in the picture and text on die by heating pressurization and holds
Object surface is printed, dress and personal adornment, T-shirt, Shirt with advertisement, gym suit, washing mark, gloves, shoes and hats, luggage textile are widely used in
Decoration on.But existing transfer film is all to need to first pass through the manufacturing procedures such as text design, plate-making, printing mostly, there is
Minimum quantity of an order is big, it is costly, be designed into thermoprint into the drawbacks such as the production cycle is long of finished product.
Summary of the invention
The present invention provides a kind of elastic thermal transfer and carves characters film and its production method, and main purpose is to overcome existing transfer
The defects such as the production cycle of film long, the small expense height of amount.
In order to solve the above technical problems, the present invention adopts the following technical scheme:
A kind of elasticity thermal transfer is carved characters film, including carrying ground, protective layer back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph
Ink and adhesive layer thermosol, the carrying ground use the biaxially oriented polyester film of 100um thickness；The protection
Layer back coating liquid is coated on the back side of carrying ground, is formulated in parts by weight by following components: 14 parts of amino resins, acrylic acid
4 parts of resin, 3 parts of silica, 1 part of amino resin crosslinking agent and 78 parts of mixed solvent；The release layer pressure-sensitive adhesive agent applies
Cloth is formulated: 10 parts of organic pressure-sensitive gel, 15 parts of silica gel, platinum in parts by weight in the front of carrying ground by following components
2 parts of Au catalyst and 73 parts of 120# solvent；The chromatograph ink is coated in the film forming face of release layer pressure-sensitive adhesive agent, by with
Lower component is formulated in parts by weight: 25 parts of high resiliency high temperature resistant TPU resin, 10 parts of toner, 3 parts of wetting and dispersing leveling auxiliary agent
And 62 parts of mixed solvent；The adhesive layer thermosol is coated on chromatograph ink, is matched in parts by weight by following components
It makes: 30 parts and 5 parts of TPU opening agent of high-elastic 65 parts of low form TPU resin, high melting means low form TPU resin.
The preparation method of the protective layer back coating liquid be by 14 parts of amino resins, 4 parts of acrylic resins, 3 parts of silica,
And 1 part of amino resin crosslinking agent is added to 78 parts of in the mixed solvents, dissolution in high-speed stirred 30 minutes is uniformly mixed.
The preparation method of the release layer pressure-sensitive adhesive agent is by 10 parts of organic pressure-sensitive gels, 15 parts of silica gel and 2 parts of platinum
Au catalyst is added into 73 parts of 120# solvents, is uniformly mixed within high-speed stirred 30 minutes.
The preparation method of the chromatograph ink is by 25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toners, 3 parts of wettings point
Scattered leveling auxiliary agent is added to 62 parts of in the mixed solvent, and high-speed stirred dissolves after mixing, then be ground to partial size 5um with
Under.
Mixed solvent used by the protective layer back coating liquid and chromatograph ink is for ethyl acetate, butyl acetate, third
Ketone, butanone, cyclohexanone, isopropanol and butanol mixed liquor.
A kind of above-mentioned elastic thermal transfer is carved characters the production method of film, successively the following steps are included:
A, protective layer back coating liquid, coating speed are coated in the anilox roll of 200 lines of the back side of biaxially oriented polyester film
80m/min, is coated with dry measure 0.06g/ ㎡ by 160 DEG C of oven temperature；
B, the front of biaxially oriented polyester film is coated with the agent of release layer pressure-sensitive adhesive, coating speed with comma scraper method in a
Spend 30m/min, 170 DEG C of oven temperature, coating layer thickness 10um；
C, chromatograph ink, coating speed 15m/min, oven temperature 140 are coated with comma scraper method in release layer surface
DEG C, coating layer thickness 40um；
D, adhesive layer thermosol, die head temperature control are coated with hot melt die head gap extrusion molding in chromatograph ink pellet surface
System is at 195 DEG C, coating layer thickness 80um；
E, reel or sheet shape finally are processed by cutting, rewinding or the first transaction of a day's business.
By the above-mentioned description of this invention it is found that compared to the prior art, the invention has the following beneficial effects:
1, elastic heat transfer film of the invention, same batch of E≤4 homochromy color difference △, resistance to mill property≤90% of thermoprint layer, off-type force=
(0.10 ~ 3.00) N/25mm, it is water-fastness, colour fading Shuai≤10% is washed, basic security technical requirements meet B class in GB18401, can
It is widely used in the industries such as the higher sports dress ornament of individual requirement, tourism and advertisement, meets broad masses of the people to a
The expectation (more, fast, good, province) of propertyization mark and demand.
2, elastic heat transfer film of the invention, production is simple and convenient, with short production cycle, it can be achieved that large-scale production.It uses
Shi Caiyong carving machine or cutting machine first carve out required picture and text, then tear off the material other than picture and text, heat through thermal transfer equipment
Pressurized adhesion removes carrying ground, required and bright picture and text can be obtained in surface of the stock after cooling.
3, elastic heat transfer film of the invention, protective layer back coating liquid are that subsequent processing and use solve adhesion and skidding
The problem of；The agent of release layer pressure-sensitive adhesive can cement with PET and have a certain range of off-type force with chromatograph, to guarantee to carve
Picture and text after carving well, especially tiny text can easily tear off again without departing from PET and not destroy die surface；Chromatograph oil
Ink can make die have high resiliency, high bright-coloured high color, high-wearing feature, washing property of high water resistance, high-environmental safety；Adhesive layer hot melt
Adhesive has higher bonding force to various textile fabrics, and can guarantee that die has high resiliency and washing property of high water resistance, has both surface
Smooth performance etc..
4, using anilox roll, comma scraper, the get to know coating methods such as gap extrusion and each work of suitable technological parameter completion
Sequence coating, control is accurate, and painting amount is uniform, and method is proper.
Specific embodiment
Illustrate a specific embodiment of the invention below.In order to fully understand the present invention, many details are described below, but
To those skilled in the art, the present invention can also be realized without these details.For well known method and process, below not
It is described in detail again.
A kind of elasticity thermal transfer is carved characters film, including carrying ground, protective layer back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph
Ink and adhesive layer thermosol.Wherein, carrying ground uses the biaxially oriented polyester film (PET) of 100um thickness.
Above-mentioned protective layer back coating liquid be coated on carrying ground the back side, be coated in PET film the back side play anti-sticking antistatic and
The effect of anti-slip, preparation method are by 14 parts of amino resins, 4 parts of acrylic resins, 3 parts of silica and 1 part of amino
Resin cross-linking agent is added to 78 parts of in the mixed solvents, and dissolution in high-speed stirred 30 minutes is uniformly mixed.
Above-mentioned release layer pressure-sensitive adhesive agent is coated on the front for carrying ground, it is desirable that and it is secured with PET film bonding, but with painting
Chromatograph above it can easily be torn off out again, and preparation method is by 10 parts of organic pressure-sensitive gels, 15 parts of silica gel and 2 parts of platinum
Au catalyst is added into 73 parts of 120# solvents, is uniformly mixed within high-speed stirred 30 minutes.
Above-mentioned chromatograph ink is coated in the film forming face of release layer pressure-sensitive adhesive agent, usually there is white, black, bright red, glimmering
25 kinds of colors such as light Huang, fluorescence green, sky blue, preparation method are by 25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toners, 3 parts
Wetting and dispersing leveling auxiliary agent is added to 62 parts of in the mixed solvent, and high-speed stirred dissolves after mixing, then is ground to partial size and exists
5um or less.
Above-mentioned adhesive layer thermosol is coated on chromatograph ink, it, which is played, firmly glues chromatograph by temperature-pressure
Effect on the substrate is connect, peels off the PET with protective layer and release layer after the completion of thermoprint, and chromatograph constitutes die
Stay in surface of the stock, formula be 65% high-elastic low form TPU resin, 30% high melting means low form TPU resin, 5% TPU
The hot-melt extruded coating that is available on the machine is mixed evenly in opening agent.
Mixed solvent used by above-mentioned protective layer back coating liquid and chromatograph ink is for ethyl acetate, butyl acetate, third
Ketone, butanone, cyclohexanone, isopropanol and butanol mixed liquor.
A kind of above-mentioned elastic thermal transfer is carved characters the production method of film, successively the following steps are included:
A, protective layer back coating liquid, coating speed are coated in the anilox roll of 200 lines of the back side of biaxially oriented polyester film
80m/min, is coated with dry measure 0.06g/ ㎡ by 160 DEG C of oven temperature；
B, the front of biaxially oriented polyester film is coated with the agent of release layer pressure-sensitive adhesive, coating speed with comma scraper method in a
Spend 30m/min, 170 DEG C of oven temperature, coating layer thickness 10um；
C, chromatograph ink, coating speed 15m/min, oven temperature 140 are coated with comma scraper method in release layer surface
DEG C, coating layer thickness 40um；
D, adhesive layer thermosol, die head temperature control are coated with hot melt die head gap extrusion molding in chromatograph ink pellet surface
System is at 195 DEG C, coating layer thickness 80um；
E, reel or sheet shape finally are processed by cutting, rewinding or the first transaction of a day's business.
Required picture and text are first carved out when use using carving machine or cutting machine, then tear off the material other than picture and text, through heat
Transfer apparatus heats pressurized adhesion in surface of the stock, and carrying ground is removed after cooling, can be obtained required and bright
Picture and text.
The above is only a specific embodiment of the present invention, but the design concept of the present invention is not limited to this, all to utilize this
Design makes a non-material change to the present invention, and should all belong to behavior that violates the scope of protection of the present invention.
Claims (6)
- The film 1. a kind of elasticity thermal transfer is carved characters, including carrying ground, protective layer back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph oil Ink and adhesive layer thermosol, it is characterised in that: the carrying ground is thin using the biaxial stretching polyester of 100um thickness Film；The protective layer back coating liquid is coated on the back side of carrying ground, is formulated in parts by weight by following components: amino resins 14 parts, 4 parts of acrylic resin, 3 parts of silica, 1 part of amino resin crosslinking agent and 78 parts of mixed solvent；The release lamination Quick adhesive is coated on the front of carrying ground, is formulated in parts by weight by following components: 10 parts of organic pressure-sensitive gel, silicon 15 parts of glue, 2 parts of platinum catalyst and 73 parts of 120# solvent；The chromatograph ink is coated on the film forming of release layer pressure-sensitive adhesive agent It on face, is formulated in parts by weight by following components: 25 parts of high resiliency high temperature resistant TPU resin, 10 parts of toner, wetting and dispersing stream 3 parts of flat auxiliary agent and 62 parts of mixed solvent；The adhesive layer thermosol is coated on chromatograph ink, by following components by weight Amount number is formulated: 30 parts and 5 parts of TPU opening agent of high-elastic 65 parts of low form TPU resin, high melting means low form TPU resin.
- The film 2. a kind of elastic thermal transfer as described in claim 1 is carved characters, it is characterised in that: the preparation of the protective layer back coating liquid Method is that 14 parts of amino resins, 4 parts of acrylic resins, 3 parts of silica and 1 part of amino resin crosslinking agent are added to 78 Part in the mixed solvent, dissolution in high-speed stirred 30 minutes are uniformly mixed.
- The film 3. a kind of elastic thermal transfer as described in claim 1 is carved characters, it is characterised in that: the release layer pressure-sensitive adhesive agent Preparation method is that 10 parts of organic pressure-sensitive gels, 15 parts of silica gel and 2 parts of platinum catalysts are added into 73 parts of 120# solvents, high Speed stirring is uniformly mixed for 30 minutes.
- The film 4. a kind of elastic thermal transfer as described in claim 1 is carved characters, it is characterised in that: the preparation method of the chromatograph ink It is that 25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toners, 3 parts of wetting and dispersing leveling auxiliary agents are added to 62 parts of mixed solvent In, high-speed stirred dissolves after mixing, then is ground to partial size in 5um or less.
- 5. claim 1,3 or 4 it is any as described in a kind of elastic thermal transfer carve characters film, it is characterised in that: the protective layer back Mixed solvent used by masking liquid and chromatograph ink is for ethyl acetate, butyl acetate, acetone, butanone, cyclohexanone, isopropanol And the mixed liquor of butanol.
- The production method of film 6. a kind of thermal transfer elastic as described in claim 1-4 is any is carved characters, which is characterized in that successively include Following steps:A, protective layer back coating liquid, coating speed 80m/ are coated in the anilox roll of 200 lines of the back side of biaxially oriented polyester film Min, is coated with dry measure 0.06g/ ㎡ by 160 DEG C of oven temperature；B, the front of biaxially oriented polyester film is coated with the agent of release layer pressure-sensitive adhesive, coating speed with comma scraper method in a 30m/min, 170 DEG C of oven temperature, coating layer thickness 10um；C, it is coated with chromatograph ink with comma scraper method in release layer surface, coating speed 15m/min, is applied by 140 DEG C of oven temperature Thickness degree 40um；D, it is coated with adhesive layer thermosol with hot melt die head gap extrusion molding in chromatograph ink pellet surface, die head temperature control exists 195 DEG C, coating layer thickness 80um；E, reel or sheet shape finally are processed by cutting, rewinding or the first transaction of a day's business.
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| CN201710166285.XA CN107443945B (en) | 2017-03-20 | 2017-03-20 | A kind of elasticity thermal transfer is carved characters film and its production method |
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| CN201710166285.XA CN107443945B (en) | 2017-03-20 | 2017-03-20 | A kind of elasticity thermal transfer is carved characters film and its production method |
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| CN107443945B true CN107443945B (en) | 2019-02-19 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108583047B (en) * | 2018-01-31 | 2019-06-07 | 广东天跃新材料股份有限公司 | A kind of TPU fitting silicon rubber is carved characters film, coating process and its application |
| CN108610997B (en) * | 2018-04-13 | 2021-02-19 | 卢汉军 | High-elasticity silicone rubber lettering film and preparation method and application method thereof |
| CN108690515B (en) * | 2018-04-13 | 2021-02-19 | 卢汉军 | High-elasticity silicone rubber lettering film and preparation method thereof |
| CN109263322A (en) * | 2018-09-11 | 2019-01-25 | 东莞市松烁硅胶科技有限公司 | A kind of silica gel push-button mould is interior to be integrally formed picture and text transfer method |
| CN110183914B (en) * | 2019-05-14 | 2021-08-17 | 浙江天成工程设计有限公司 | Back coating paint for thermal transfer printing film carrier |
| CN110626088A (en) * | 2019-09-30 | 2019-12-31 | 安徽创研新材料有限公司 | High-elasticity silicone rubber lettering film and preparation method thereof |
| CN111055605B (en) * | 2019-10-25 | 2021-08-03 | 鸣腾科技(厦门)有限责任公司 | Lettering film capable of being printed and preparation method thereof |
| CN111251743A (en) * | 2020-01-17 | 2020-06-09 | 江西赛欧特科新材料有限公司 | Lettering film and preparation method thereof |
| CN112457709B (en) * | 2020-11-30 | 2022-08-02 | 吉安天晟新材料有限公司 | Preparation method and application of degradable thermal transfer printing lettering film |
| CN113263850B (en) * | 2021-05-13 | 2022-11-01 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
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| CN1214710A (en) * | 1996-12-10 | 1999-04-21 | 大赛璐化学工业株式会社 | Porous film, process for producing the same, and laminate films and recording sheets made with the use porous film |
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| CN105538941A (en) * | 2015-12-23 | 2016-05-04 | 喻盛 | Thermal transfer printing method |
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| CN107443945A (en) | 2017-12-08 |
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Denomination of invention: Elastic heat transfer printing lettering film and production method thereof Effective date of registration: 20190625 Granted publication date: 20190219 Pledgee: Bank of China Limited by Share Ltd Jinjiang branch Pledgor: Our press (Fujian) Technology Co. Ltd. Registration number: 2019990000609 |