CN107443945A - A kind of elastic thermal transfer is carved characters film and its production method - Google Patents
A kind of elastic thermal transfer is carved characters film and its production method Download PDFInfo
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- CN107443945A CN107443945A CN201710166285.XA CN201710166285A CN107443945A CN 107443945 A CN107443945 A CN 107443945A CN 201710166285 A CN201710166285 A CN 201710166285A CN 107443945 A CN107443945 A CN 107443945A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38235—Contact thermal transfer or sublimation processes characterised by transferable colour-forming materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/14—Multicolour printing
- B41M1/20—Multicolour printing by applying differently-coloured inks simultaneously to different parts of the printing surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Decoration By Transfer Pictures (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of elastic thermal transfer is carved characters film, including carrying ground, overcoat back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph ink and adhesive layer thermosol, the formula of overcoat back coating liquid are：78 parts of 14 parts of amino resins, 4 parts of acrylic resin, 3 parts of silica, 1 part of amino resin crosslinking agent and mixed solvent；The formula of release layer pressure-sensitive adhesive agent is：73 parts of 10 parts of organic pressure-sensitive gel, 15 parts of silica gel, 2 parts of platinum catalyst and 120# solvents；The formula of chromatograph ink is：62 parts of 25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toner, 3 parts of wetting and dispersing leveling auxiliary agent and mixed solvent；The formula of adhesive layer thermosol is：5 parts of high-elastic 65 parts of low form TPU resins, 30 parts of high melting means low form TPU resins and TPU opening agents.The elastic heat transfer film, with batch homochromy aberration △ E≤4, resistance to mill property≤90% of thermoprint layer, off-type force=（0.10~3.00）N/25mm, it is water-fastness, colour fading Shuai≤10% is washed, basic security technical requirements meet B classes in GB18401.
Description
Technical field
The present invention relates to Thermal-printing Technology field, specifically refer to that a kind of elastic thermal transfer is carved characters film and its producer
Method.
Background technology
Thermal transfer is a kind of emerging typography.The technique mode of printing is first to print transfer film, i.e., first by pattern
Or word is imprinted on film surface, then by thermal transfer process equipment, the picture and text on die is transferred in by heating pressurization and held
Thing surface is printed, is widely used in dress and personal adornment, T-shirt, Shirt with advertisement, gym suit, washing mark, gloves, shoes and hats, case and bag textile
Decoration on.But existing transfer film, all it is to need to first pass through the manufacturing procedures such as text design, plate-making, printing mostly, there is
Minimum quantity of an order is big, it is costly, be designed into thermoprint and the drawback such as grow into the production cycle of finished product.
The content of the invention
The present invention provides a kind of elastic thermal transfer and carved characters film and its production method, and its main purpose is to overcome existing transfer
The defects such as the production cycle of film long, the small expense height of amount.
In order to solve the above technical problems, the present invention adopts the following technical scheme that：
A kind of elastic thermal transfer is carved characters film, including carrying ground, overcoat back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph ink
And adhesive layer thermosol, the carrying ground use the biaxially oriented polyester film of 100um thickness；The overcoat back of the body
Masking liquid is coated on the back side of carrying ground, is formulated in parts by weight by following components：14 parts of amino resins, acrylic resin
78 parts of 4 parts, 3 parts of silica, 1 part of amino resin crosslinking agent and mixed solvent；The release layer pressure-sensitive adhesive agent is coated on
The front of ground is carried, is formulated in parts by weight by following components：10 parts of organic pressure-sensitive gel, 15 parts of silica gel, platinum are urged
73 parts of 2 parts of agent and 120# solvents；The chromatograph ink is coated in the film forming face of release layer pressure-sensitive adhesive agent, by with the following group
Divide and be formulated in parts by weight：25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toner, 3 parts of wetting and dispersing leveling auxiliary agent and
62 parts of mixed solvent；The adhesive layer thermosol is coated on chromatograph ink, prepared in parts by weight by following components and
Into：5 parts of high-elastic 65 parts of low form TPU resins, 30 parts of high melting means low form TPU resins and TPU opening agents.
The compound method of the overcoat back coating liquid be by 14 parts of amino resins, 4 parts of acrylic resins, 3 parts of silica,
And 1 part of amino resin crosslinking agent is added to 78 parts of in the mixed solvents, high-speed stirred dissolving in 30 minutes and is well mixed.
The compound method of the release layer pressure-sensitive adhesive agent is by 10 parts of organic pressure-sensitive gels, 15 parts of silica gel and 2 parts of platinum
Au catalyst is added into 73 parts of 120# solvents, and high-speed stirred is well mixed for 30 minutes.
The compound method of the chromatograph ink is by 25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toners, 3 parts of wettings point
Scattered leveling auxiliary agent is added to 62 parts of in the mixed solvent, after high-speed stirred dissolving is well mixed, then be ground to particle diameter 5um with
Under.
Mixed solvent is for ethyl acetate, butyl acetate, third used by the overcoat back coating liquid and chromatograph ink
Ketone, butanone, cyclohexanone, the mixed liquor of isopropanol and butanol.
A kind of above-mentioned elastic thermal transfer is carved characters the production method of film, is comprised the following steps successively：
A, overcoat back coating liquid, coating speed 80m/ are coated with the anilox roll of 200 lines at the back side of biaxially oriented polyester film
Min, 160 DEG C of oven temperature, coating dry measure 0.06g/ ㎡；
B, the front of biaxially oriented polyester film is coated with release layer pressure-sensitive adhesive agent, coating speed with comma scraper method in a
30m/min, 170 DEG C of oven temperature, coating layer thickness 10um；
C, coating speed 15m/min, 140 DEG C of oven temperature, applied with comma scraper method coating chromatograph ink in release layer surface
Thickness degree 40um；
D, existed in chromatograph ink pellet surface with hot melt die head gap extrusion molding coating adhesive layer thermosol, die head temperature control
195 DEG C, coating layer thickness 80um；
E, reel or sheet shape finally are processed into by cutting, rewinding or the first transaction of a day's business.
From the above-mentioned description of this invention, compared to the prior art, the present invention has the advantages that：
1st, elastic heat transfer film of the invention, with batch homochromy aberration △ E≤4, resistance to mill property≤90% of thermoprint layer, off-type force=（0.10~
3.00）N/25mm, it is water-fastness, colour fading Shuai≤10% is washed, basic security technical requirements meet B classes in GB18401, can answered extensively
The industries such as sports dress ornament, tourism and the advertisement higher for individual requirement, meet that broad masses of the people mark to personalization
Expectation (more, fast, the good, province of knowledge）With demand.
2nd, elastic heat transfer film of the invention, production is simple and convenient, with short production cycle, and large-scale production can be achieved.Use
Shi Caiyong carving machines or cutting machine first carve out required picture and text, then tear off the material beyond picture and text, are heated through thermal transfer equipment
Pressurized adhesion is in stock surface, stripping carrying ground after cooling, you can obtain required and bright picture and text.
3rd, elastic heat transfer film of the invention, overcoat back coating liquid are that follow-up processing and use solve adhesion and skidding
The problem of；The agent of release layer pressure-sensitive adhesive can cement with PET, and and can has a range of off-type force with chromatograph, to ensure to carve
Picture and text after carving well, especially tiny word easily tear off without departing from PET and cans and do not destroy die surface；Chromatograph oil
Ink can make die have high resiliency, high bright-coloured high color, high-wearing feature, high water-wash resistance, high-environmental security；Adhesive layer heats
Adhesive has higher bonding force to various yarn fabrics, and and can ensures that die has high resiliency and high water-wash resistance, has surface concurrently
Smooth performance etc..
4th, using anilox roll, comma scraper, the get to know coating methods such as gap extrusion and each work of suitable technological parameter completion
Sequence is coated with, and control is accurate, and painting amount is uniform, and method is proper.
Embodiment
Illustrate the embodiment of the present invention below.For the comprehensive understanding present invention, many details are described to below, but
To those skilled in the art, the present invention can also be realized without these details.For known method and process, below not
It is described in detail again.
A kind of elastic thermal transfer is carved characters film, including carrying ground, overcoat back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph
Ink and adhesive layer thermosol.Wherein, the biaxially oriented polyester film that ground uses 100um thickness is carried（PET）.
Above-mentioned overcoat back coating liquid be coated on carrying ground the back side, be coated in PET film the back side play anti-sticking antistatic and
The effect of anti-slip, its compound method are by 14 parts of amino resins, 4 parts of acrylic resins, 3 parts of silica and 1 part of amino
Resin cross-linking agent adds well mixed to 78 parts of in the mixed solvents, high-speed stirred dissolving in 30 minutes.
Above-mentioned release layer pressure-sensitive adhesive agent is coated on the front for carrying ground, it is desirable to and it is firm with PET film bonding, but with painting
Chromatograph and can in the above is easily torn off out, and its compound method is by 10 parts of organic pressure-sensitive gels, 15 parts of silica gel and 2 parts of platinum
Au catalyst is added into 73 parts of 120# solvents, and high-speed stirred is well mixed for 30 minutes.
Above-mentioned chromatograph ink is coated in the film forming face of release layer pressure-sensitive adhesive agent, generally there is white, black, bright red, glimmering
25 kinds of colors such as light Huang, fluorescence green, sky blue, its compound method be by 25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toners, 3 parts
Wetting and dispersing leveling auxiliary agent is added to 62 parts of in the mixed solvent, after high-speed stirred dissolving is well mixed, then is ground to particle diameter and is existed
Below 5um.
Above-mentioned adhesive layer thermosol is coated on chromatograph ink, and it, which is played, firmly glues chromatograph by temperature-pressure
Effect on the substrate is connect, peels off the PET with overcoat and release layer after the completion of thermoprint, itself and chromatograph form die
Stay on stock surface, it is formulated as 65% high-elastic low form TPU resins, 30% high melting means low form TPU resins, 5% TPU
Opening agent, the hot-melt extruded coating that is available on the machine is mixed evenly.
Mixed solvent is for ethyl acetate, butyl acetate, third used by above-mentioned overcoat back coating liquid and chromatograph ink
Ketone, butanone, cyclohexanone, the mixed liquor of isopropanol and butanol.
A kind of above-mentioned elastic thermal transfer is carved characters the production method of film, is comprised the following steps successively：
A, overcoat back coating liquid, coating speed 80m/ are coated with the anilox roll of 200 lines at the back side of biaxially oriented polyester film
Min, 160 DEG C of oven temperature, coating dry measure 0.06g/ ㎡；
B, the front of biaxially oriented polyester film is coated with release layer pressure-sensitive adhesive agent, coating speed with comma scraper method in a
30m/min, 170 DEG C of oven temperature, coating layer thickness 10um；
C, coating speed 15m/min, 140 DEG C of oven temperature, applied with comma scraper method coating chromatograph ink in release layer surface
Thickness degree 40um；
D, existed in chromatograph ink pellet surface with hot melt die head gap extrusion molding coating adhesive layer thermosol, die head temperature control
195 DEG C, coating layer thickness 80um；
E, reel or sheet shape finally are processed into by cutting, rewinding or the first transaction of a day's business.
Required picture and text are first carved out during use using carving machine or cutting machine, then tear off the material beyond picture and text, through heat
Transfer apparatus heats pressurized adhesion in stock surface, stripping carrying ground after cooling, you can needed for obtaining and bright
Picture and text.
The embodiment of the present invention is above are only, but the design concept of the present invention is not limited thereto, it is all to utilize this
Conceive the change that unsubstantiality is carried out to the present invention, the behavior for invading the scope of the present invention all should be belonged to.
Claims (6)
- The film 1. a kind of elastic thermal transfer is carved characters, including carrying ground, overcoat back coating liquid, the agent of release layer pressure-sensitive adhesive, chromatograph oil Ink and adhesive layer thermosol, it is characterised in that：The carrying ground is thin using the biaxial stretching polyester of 100um thickness Film；The overcoat back coating liquid is coated on the back side of carrying ground, is formulated in parts by weight by following components：Amino resins 78 parts of 14 parts, 4 parts of acrylic resin, 3 parts of silica, 1 part of amino resin crosslinking agent and mixed solvent；The release lamination Quick adhesive is coated on the front of carrying ground, is formulated in parts by weight by following components：10 parts of organic pressure-sensitive gel, silicon 73 parts of 15 parts of glue, 2 parts of platinum catalyst and 120# solvents；The chromatograph ink is coated on the film forming of release layer pressure-sensitive adhesive agent On face, it is formulated in parts by weight by following components：25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toner, wetting and dispersing stream 62 parts of 3 parts of flat auxiliary agent and mixed solvent；The adhesive layer thermosol is coated on chromatograph ink, by following components by weight Amount number is formulated：5 parts of high-elastic 65 parts of low form TPU resins, 30 parts of high melting means low form TPU resins and TPU opening agents.
- The film 2. a kind of elastic thermal transfer as claimed in claim 1 is carved characters, it is characterised in that：The preparation of the overcoat back coating liquid Method is to add 14 parts of amino resins, 4 parts of acrylic resins, 3 parts of silica and 1 part of amino resin crosslinking agent to 78 Part in the mixed solvent, high-speed stirred dissolving in 30 minutes are well mixed.
- The film 3. a kind of elastic thermal transfer as claimed in claim 1 is carved characters, it is characterised in that：The release layer pressure-sensitive adhesive agent Compound method is to add 10 parts of organic pressure-sensitive gels, 15 parts of silica gel and 2 parts of platinum catalysts into 73 parts of 120# solvents, high Speed stirring is well mixed for 30 minutes.
- The film 4. a kind of elastic thermal transfer as claimed in claim 1 is carved characters, it is characterised in that：The compound method of the chromatograph ink It is to add 25 parts of high resiliency high temperature resistant TPU resins, 10 parts of toners, 3 parts of wetting and dispersing leveling auxiliary agents to 62 parts of mixed solvent In, after high-speed stirred dissolving is well mixed, then particle diameter is ground in below 5um.
- The film 5. a kind of elastic thermal transfer as described in claim 1,3 or 4 are any is carved characters, it is characterised in that：The overcoat back of the body Mixed solvent is for ethyl acetate, butyl acetate, acetone, butanone, cyclohexanone, isopropanol used by masking liquid and chromatograph ink And the mixed liquor of butanol.
- The production method of film 6. a kind of elastic thermal transfer as described in claim 1-4 is any is carved characters, it is characterised in that include successively Following steps：A, overcoat back coating liquid, coating speed 80m/ are coated with the anilox roll of 200 lines at the back side of biaxially oriented polyester film Min, 160 DEG C of oven temperature, coating dry measure 0.06g/ ㎡；B, the front of biaxially oriented polyester film is coated with release layer pressure-sensitive adhesive agent, coating speed with comma scraper method in a 30m/min, 170 DEG C of oven temperature, coating layer thickness 10um；C, coating speed 15m/min, 140 DEG C of oven temperature, applied with comma scraper method coating chromatograph ink in release layer surface Thickness degree 40um；D, existed in chromatograph ink pellet surface with hot melt die head gap extrusion molding coating adhesive layer thermosol, die head temperature control 195 DEG C, coating layer thickness 80um；E, reel or sheet shape finally are processed into by cutting, rewinding or the first transaction of a day's business.
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| CN201710166285.XA CN107443945B (en) | 2017-03-20 | 2017-03-20 | A kind of elasticity thermal transfer is carved characters film and its production method |
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| CN201710166285.XA CN107443945B (en) | 2017-03-20 | 2017-03-20 | A kind of elasticity thermal transfer is carved characters film and its production method |
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| CN107443945B CN107443945B (en) | 2019-02-19 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108583047A (en) * | 2018-01-31 | 2018-09-28 | 广东天跃新材料股份有限公司 | A kind of TPU fitting silicon rubber is carved characters film, coating process and its application |
| CN109263322A (en) * | 2018-09-11 | 2019-01-25 | 东莞市松烁硅胶科技有限公司 | A kind of silica gel push-button mould is interior to be integrally formed picture and text transfer method |
| CN110183914A (en) * | 2019-05-14 | 2019-08-30 | 浙江天成工程设计有限公司 | A kind of back coating coating for thermal transfer thin-film carrier |
| CN110626088A (en) * | 2019-09-30 | 2019-12-31 | 安徽创研新材料有限公司 | High-elasticity silicone rubber lettering film and preparation method thereof |
| CN111055605A (en) * | 2019-10-25 | 2020-04-24 | 鸣腾科技(厦门)有限责任公司 | Lettering film capable of being printed and preparation method thereof |
| CN111251743A (en) * | 2020-01-17 | 2020-06-09 | 江西赛欧特科新材料有限公司 | Lettering film and preparation method thereof |
| CN108690515B (en) * | 2018-04-13 | 2021-02-19 | 卢汉军 | High-elasticity silicone rubber lettering film and preparation method thereof |
| CN108610997B (en) * | 2018-04-13 | 2021-02-19 | 卢汉军 | High-elasticity silicone rubber lettering film and preparation method and application method thereof |
| CN112457709A (en) * | 2020-11-30 | 2021-03-09 | 吉安天晟新材料有限公司 | Preparation method and application of degradable thermal transfer printing lettering film |
| CN113263850A (en) * | 2021-05-13 | 2021-08-17 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108583047A (en) * | 2018-01-31 | 2018-09-28 | 广东天跃新材料股份有限公司 | A kind of TPU fitting silicon rubber is carved characters film, coating process and its application |
| CN108690515B (en) * | 2018-04-13 | 2021-02-19 | 卢汉军 | High-elasticity silicone rubber lettering film and preparation method thereof |
| CN108610997B (en) * | 2018-04-13 | 2021-02-19 | 卢汉军 | High-elasticity silicone rubber lettering film and preparation method and application method thereof |
| CN109263322A (en) * | 2018-09-11 | 2019-01-25 | 东莞市松烁硅胶科技有限公司 | A kind of silica gel push-button mould is interior to be integrally formed picture and text transfer method |
| CN110183914A (en) * | 2019-05-14 | 2019-08-30 | 浙江天成工程设计有限公司 | A kind of back coating coating for thermal transfer thin-film carrier |
| CN110626088A (en) * | 2019-09-30 | 2019-12-31 | 安徽创研新材料有限公司 | High-elasticity silicone rubber lettering film and preparation method thereof |
| CN111055605A (en) * | 2019-10-25 | 2020-04-24 | 鸣腾科技(厦门)有限责任公司 | Lettering film capable of being printed and preparation method thereof |
| CN111055605B (en) * | 2019-10-25 | 2021-08-03 | 鸣腾科技(厦门)有限责任公司 | Lettering film capable of being printed and preparation method thereof |
| CN111251743A (en) * | 2020-01-17 | 2020-06-09 | 江西赛欧特科新材料有限公司 | Lettering film and preparation method thereof |
| CN112457709A (en) * | 2020-11-30 | 2021-03-09 | 吉安天晟新材料有限公司 | Preparation method and application of degradable thermal transfer printing lettering film |
| CN112457709B (en) * | 2020-11-30 | 2022-08-02 | 吉安天晟新材料有限公司 | Preparation method and application of degradable thermal transfer printing lettering film |
| CN113263850A (en) * | 2021-05-13 | 2021-08-17 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
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| CN107443945B (en) | 2019-02-19 |
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Denomination of invention: Elastic heat transfer printing lettering film and production method thereof Effective date of registration: 20190625 Granted publication date: 20190219 Pledgee: Bank of China Limited by Share Ltd Jinjiang branch Pledgor: Our press (Fujian) Technology Co. Ltd. Registration number: 2019990000609 |
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