CN107400807A - A kind of power battery case aluminium alloy and its processing method - Google Patents

A kind of power battery case aluminium alloy and its processing method Download PDF

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Publication number
CN107400807A
CN107400807A CN201710610484.5A CN201710610484A CN107400807A CN 107400807 A CN107400807 A CN 107400807A CN 201710610484 A CN201710610484 A CN 201710610484A CN 107400807 A CN107400807 A CN 107400807A
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battery case
power battery
aluminium alloy
processing method
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杨仲彬
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/116Primary casings; Jackets or wrappings characterised by the material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The invention discloses a kind of power battery case aluminium alloy and its processing method.Power battery case aluminium alloy meter, by being prepared including following component:Mn:1.1~1.8 wt.%;Cu:0.05~0.25 wt.%;Fe:0.1~0.3 wt.%;Si:0.05~0.2 wt.%;Mg:0.05~0.2 wt.%;Zr:0.01~0.10 wt.%;Ti:≤0.10 wt.%;Surplus is Al and inevitable impurity.Power battery case aluminium alloy according to embodiments of the present invention, by the optimization of constituent and technique, welding, intensity and the forming property of material are improved, suitable for power battery case.

Description

A kind of power battery case aluminium alloy and its processing method
Technical field
The present invention relates to a kind of metal and metal processing sectors, and in particular to a kind of power battery case aluminium alloy and its Processing method.
Background technology
With petroleum resources reduction and car ownership increase environmental pollution aggravation, new-energy automobile it is excellent Gesture is more and more obvious.Moreover, national industrial policies also support the development of new-energy automobile industry energetically.Therefore, new energy Automobile industry has come into high-speed development period.The aluminium alloy of general manufacture new-energy automobile critical component-power battery case For 3003 aluminium alloys.The alloy generally has preferable deep-draw, welding and intensity, but still suffers from some problems:During laser welding It is bad easily to there is quality, such as stomata and gas leakage;When welding pool depth is excessive(Such as more than 0.3mm), weldpool uniformity variation, easily Splash, have a strong impact on the sealing and battery safety of housing.But with battery capacity increase and the increase of housing wall thickness, melt Tank depth will necessarily also increase;Exist between deep-draw, welding and intensity three and influence each other, may be reduced if improving intensity deep Punching performance.CN103409668A discloses a kind of housing of power cell Al-Mn alloys, composition to Al-Mn alloys and microcosmic Tissue is limited, and has preferable welding performance, but the mechanical property of material is relatively low;CN101910434A discloses one kind 1 line aluminium alloy of housing of power cell, but the mechanical property of the material is too low, and use range will be extremely restricted;Patent CN102206775A has invented a kind of aluminium alloy for power battery case, in order to improve the welding performance of material, invention Person reduces the strength character of material.It is therefore desirable to develop a kind of electrokinetic cell for taking into account intensity, forming property, welding performance Shell aluminium alloy and its corresponding processing method, to meet the needs of industry development.
The content of the invention
In view of this, the present invention provides a kind of power battery case aluminium alloy.
The present invention also provides a kind of processing method of above-mentioned power battery case aluminium alloy.
In order to solve the above technical problems, the present invention uses following technical scheme:
A kind of power battery case aluminium alloy, by weight percentage, by being prepared including following component:
Mn:1.1~1.8 wt.%;
Cu:0.05~0.25 wt.%;
Fe:0.1~0.3 wt.%;
Si:0.05~0.2 wt.%;
Mg:0.05~0.2 wt.%;
Zr:0.01~0.10 wt.%;
Ti:≤0.10 wt.%;
Surplus is Al and inevitable impurity.
Preferably, inevitable impurity content is no more than 0.10 wt.%, it is further preferred that inevitable impurity Content is no more than 0.005 wt.%, and most preferably, the content of inevitable impurity is 0 wt.%.It is heretofore described to keep away The impurity exempted from refers to the impurity as caused by production.
Further, count in mass ratio, Mg/Si=0.9 ~ 1.1.
Further, the face fraction 2% ~ 5% of coarse InterMetallic Compound, and spacing is 10 ~ 20 microns.
Further, the face fraction of disperse intermetallic is 1 ~ 3%, and spacing is 1 ~ 3 micron.
Further, the size of the coarse InterMetallic Compound is more than 1 micron, the size of the disperse intermetallic Less than 1 micron.
Present invention additionally comprises a kind of power battery case aluminium alloy processing method, including step:
S1, the power battery case described in constituent and claim any one of 1-5 is carried out with aluminium alloy identical ingot casting Homogenizing annealing processing;
S2, then hot rolling is carried out, obtain hot rolled plate;
S3, cold rolling is carried out to hot rolled plate, obtains cold-reduced sheet.
Further, in step S1, annealing includes step:400 ~ 440 °C are raised to 40 ~ 80 °C/h speed Insulation 4 ~ 8 hours, then it is raised to 590 ~ 640 °C with same heating rate again and is incubated 8 ~ 10 hours.
Further, in step S2, to drop to 500 ~ 540 °C of progress hot rollings less than 100 °C/hour speed.
Further, step is also included after step S3:S4, cold-reduced sheet is incubated 1 ~ 3 hour at 350 ~ 430 °C.
The beneficial effect that the present invention is reached:
Mn is the essential element in the invention alloy, and it mainly plays solution strengthening and dispersion-strengtherning.Mn contents are higher, It is more obvious to strengthen effect.But Mn too high levels, then due to forming the coarse InterMetallic Compound of a large amount of unmanageable distributions, and make Obtain material processability to decline, its composition is advisable in 1.1 ~ 1.8 wt.%;
Cu is trace additives, and the intensity of material can be improved by solution strengthening effect.But otherwise its addition excessively should not be held Easily cause the increase of weld crack tendency and increase material cost.Therefore the wt.% of Cu 0.05 ~ 0.25 are advisable;
Fe, Ti, Zr are trace additives, mainly start to control the effect of combinations grain.But its content should not be excessive, otherwise on the one hand will A large amount of coarse InterMetallic Compounds are formed, are unfavorable for the lifting of performance;On the other hand, its content is excessive, also can not be effective again Reduce the crystal grain of material.Therefore the wt.% of Fe 0.1 ~ 0.3 wt.%, Zr 0.01 ~ 0.10 wt.%, Ti≤0.10 is advisable;
Si can form intermetallic compound with Al, Fe, Mn element, be advantageous to intensity, forming property and welding performance, but its content It is unsuitable too high, the forming property of material is otherwise influenceed, its content should be the wt.% of Si 0.05 ~ 0.2;Mg mainly rise solution strengthening with And the effect of ageing strengthening, its content should be 0.05 ~ 0.2 wt.%.Mg/Si mass ratioes are 0.9 ~ 1.1 simultaneously, are advantageous to strengthen The precipitation of phase.
Fire processing, rolling and annealing need to be carried out to above alloy.Homogenizing annealing is carried out to ingot casting with 40 ~ 80 ° C/h speed is raised to 400 ~ 440 °C and is incubated 4 ~ 8 hours, is then raised to 590 ~ 640 °C with same heating rate again and protects Temperature 8 ~ 10 hours;Then to drop to 500 ~ 540 °C of progress hot rollings less than 100 °C/hour speed, and hot rolled plate is carried out cold Roll;Cold-reduced sheet is incubated 1 ~ 3 hour at 350 ~ 430 °C.During fire, control heating rate and set low and high temperature degree fiery The purpose of platform is to promote coarse InterMetallic Compound(Size is more than 1 micron)Transformation and disperse intermetallic compound (Size is less than 1 micron)Precipitation and grow up.Burning hot processing more than, can make coarse InterMetallic Compound(Size is big In 1 micron)Face fraction 2% ~ 5%, and spacing be 10 ~ 20 microns;Disperse intermetallic(Size is less than 1 micron)Face fraction For 1 ~ 3%, spacing is 1 ~ 3 micron.The intermetallic compound of the distribution characteristics, it may be such that suction of the material in laser beam welding Yield increases, i.e., under less laser power, you can reach larger fusion penetration, avoid failure welding(Such as splash)Hair It is raw.Intensity and forming property are improved as well as the effective Orowan effects of intermetallic compound;Cold-reduced sheet 350 ~ 430 °C are incubated 1 ~ 3 hour, mainly for improving the forming property of material.Simultaneously under the conditions of suitable Mg/Si(Such as this patent 0.9 ~ 1.1), in annealing process, it will there is appropriate hardening constituent to be formed, further improve the strength of materials.Certain reinforcing Mutually in follow-up welding process will dissolving, but in weldment cooling procedure, can still separate out and strengthening material again.
Embodiment
With reference to specific embodiment, the invention will be further described.Following examples are only used for clearly illustrating Technical scheme, and can not be limited the scope of the invention with this.
Embodiment 1
The power battery case aluminium alloy of the present embodiment, by weight percentage, by being prepared including following component:
Mn 1.2 wt.%, Cu 0.2 wt.%, Fe 0.25 wt.%, Si 0.15 wt.%, Mg 0.16 wt.%, Zr 0.01 The wt.% of wt.%, Ti 0.03, surplus is Al and inevitable impurity, and Mg/Si mass ratioes are 0.9 ~ 1.1.
The power battery case of the present embodiment is prepared with aluminium alloy by following processing method, including step:
S1. homogenizing annealing is carried out with aluminium alloy identical ingot casting to constituent and above-mentioned power battery case, made annealing treatment Including step:420 °C are raised to 63 °C/h speed and is incubated 5 hours, are then raised to 620 ° again with same heating rate C is simultaneously incubated 9 hours;
S2. and then to drop to 500 °C of progress hot rollings less than 100 °C/hour speed, hot rolled plate is obtained;
S3. cold rolling is carried out to hot rolled plate, obtains cold-reduced sheet;
S4. cold-reduced sheet is incubated 3 hours at 350 °C.
Embodiment 2
The power battery case aluminium alloy of the present embodiment, by weight percentage, component is as follows:
Mn 1.4 wt.%, Cu 0.12 wt.%, Fe 0.23 wt.%, Si 0.11 wt.%, Mg 0.12 wt.%, Zr 0.10 Wt.%, Ti 0.02 wt.%, surplus Al.
The power battery case of the present embodiment is prepared with aluminium alloy by following processing method, including step:
S1. homogenizing annealing, annealing steps are carried out with aluminium alloy identical ingot casting to constituent and above-mentioned power battery case Including:440 °C are raised to 80 °C/h speed and is incubated 4 hours, are then raised to 590 °C simultaneously again with same heating rate Insulation 10 hours;
S2. and then to drop to 540 °C of progress hot rollings less than 100 °C/hour speed, hot rolled plate is obtained;
S3. cold rolling is carried out to hot rolled plate, obtains cold-reduced sheet;
S4. cold-reduced sheet is incubated 1 hour at 430 °C.
Embodiment 3
The power battery case aluminium alloy of the present embodiment, by weight percentage, component is as follows:
Mn 1.8 wt.%, Cu 0.25 wt.%, Fe 0.3 wt.%, Si 0.05 wt.%, Mg 0.05 wt.%, Zr 0.05 Wt.%, Ti 0.10 wt.%, surplus Al.
The power battery case of the present embodiment is prepared with aluminium alloy by following processing method, including step:
S1. homogenizing annealing, annealing steps are carried out with aluminium alloy identical ingot casting to constituent and above-mentioned power battery case Including:400 °C are raised to 40 °C/h speed and is incubated 8 hours, are then raised to 640 °C simultaneously again with same heating rate Insulation 8 hours;
S2. and then to drop to 500 °C of progress hot rollings less than 100 °C/hour speed, hot rolled plate is obtained;
S3. cold rolling is carried out to hot rolled plate, obtains cold-reduced sheet;
S4. cold-reduced sheet is incubated 2 hours at 400 °C.
Embodiment 4
The power battery case aluminium alloy of the present embodiment, by weight percentage, component is as follows:
Mn 1.3 wt.%, Cu 0.05 wt.%, Fe 0.3 wt.%, Si 0.2 wt.%, Mg 0.2 wt.%, Zr 0.02 Wt.%, Ti 0.05 wt.%, surplus Al.
The power battery case of the present embodiment is prepared with aluminium alloy by following processing method, including step:
S1. homogenizing annealing, annealing steps are carried out with aluminium alloy identical ingot casting to constituent and above-mentioned power battery case Including:420 °C are raised to 50 °C/h speed and is incubated 6 hours, are then raised to 610 °C simultaneously again with same heating rate Insulation 9 hours;
S2. and then to drop to 530 °C of progress hot rollings less than 100 °C/hour speed, hot rolled plate is obtained;
S3. cold rolling is carried out to hot rolled plate, obtains cold-reduced sheet;
S4. cold-reduced sheet is incubated 1.5 hours at 410 °C.
Embodiment 5
The power battery case aluminium alloy of the present embodiment, by weight percentage, component is as follows:
Mn 1.36 wt.%, Cu 0.16 wt.%, Fe 0.21 wt.%, Si 0.12 wt.%, Mg 0.11 wt.%, Zr 0.03 Wt.%, Ti 0.03 wt.%, surplus Al.
The power battery case of the present embodiment is prepared with aluminium alloy by following processing method, including step:
S1. homogenizing annealing, annealing steps are carried out with aluminium alloy identical ingot casting to constituent and above-mentioned power battery case Including:410 °C are raised to 70 °C/h speed and is incubated 6 hours, are then raised to 620 °C simultaneously again with same heating rate Insulation 9 hours;
S2. and then to drop to 515 °C of progress hot rollings less than 100 °C/hour speed, hot rolled plate is obtained;
S3. cold rolling is carried out to hot rolled plate, obtains cold-reduced sheet;
S4. cold-reduced sheet is incubated 3 hours at 410 °C.
Comparative example 1
The power battery case aluminium alloy of this comparative example, by weight percentage, component is as follows:
Mn 0.8 wt.%, Cu 0.02 wt.%, Fe 0.6 wt.%, Si 0.09 wt.%, Mg 0.02 wt.%, Ti 0.02 Wt.%, surplus Al.
The power battery case aluminium alloy processing method of this comparative example comprises the following steps:
Homogenizing annealing, annealing steps are carried out with aluminium alloy identical ingot casting to constituent and this comparative example power battery case Including:At 600 °C and it is incubated 9 hours;Then 500 °C are dropped to 120 °C/hour speed;Then hot rolling is carried out, obtains hot rolling Plate;And cold rolling is carried out to hot rolled plate, obtain cold-reduced sheet;Cold-reduced sheet is incubated 3 hours at 410 °C.
Comparative example 2
The power battery case aluminium alloy of this comparative example, by weight percentage, component is as follows:
Mn 2.1 wt.%, Cu 0.36 wt.%, Fe 0.61 wt.%, Si 0.25 wt.%, Mg 0.15 wt.%, Ti 0.23 Wt.%, surplus Al.
The power battery case aluminium alloy processing method of this comparative example comprises the following steps:
Homogenizing annealing, annealing steps are carried out with aluminium alloy identical ingot casting to constituent and this comparative example power battery case Including:410 °C are raised to 70 °C/h speed and is incubated 6 hours, are then raised to 620 °C simultaneously again with same heating rate Insulation 9 hours;Then to drop to 515 °C of progress hot rollings less than 100 °C/hour speed, hot rolled plate is obtained;And hot rolled plate is carried out Cold rolling, obtain cold-reduced sheet;Cold-reduced sheet is incubated 3 hours at 410 °C.
Comparative example 3
The power battery case aluminium alloy of this comparative example, by weight percentage, component is as follows:
Mn 2.1 wt.%, Cu 0.36 wt.%, Fe 0.11 wt.%, Si 0.25 wt.%, Mg 0.15 wt.%, Ti 0.23 Wt.%, surplus Al.
The power battery case aluminium alloy processing method of this comparative example comprises the following steps:
Homogenizing annealing is carried out at 600 °C with aluminium alloy identical ingot casting to constituent and this comparative example power battery case And it is incubated 9 hours;Then 500 °C of progress hot rollings are dropped to 120 °C/hour speed, obtains hot rolled plate;And hot rolled plate is carried out cold Roll, obtain cold-reduced sheet;Then cold-reduced sheet is incubated 3 hours at 410 °C.
Table 1 illustrates the performance of gained power battery case aluminium alloy in embodiment and comparative example, and table 2 illustrates alloy Tissue signature.
The results of property of alloy in the embodiment of table 1 and comparative example
Alloy structure feature in the embodiment of table 2 and comparative example
As shown in table 1 and table 2, the present invention may be such that material has preferably tissue and final by composition and process optimization Combination property, it is the ideal material for power battery case.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, some improvement and deformation can also be made, these are improved and deformation Also it should be regarded as protection scope of the present invention.

Claims (9)

1. a kind of power battery case aluminium alloy, it is characterised in that by weight percentage, by including following component preparation Form:
Mn:1.1~1.8 wt.%;
Cu:0.05~0.25 wt.%;
Fe:0.1~0.3 wt.%;
Si:0.05~0.2 wt.%;
Mg:0.05~0.2 wt.%;
Zr:0.01~0.10 wt.%;
Ti:≤0.10 wt.%;
Surplus is Al and inevitable impurity.
2. power battery case aluminium alloy according to claim 1, it is characterised in that count in mass ratio, Mg/Si=0.9 ~1.1。
3. power battery case aluminium alloy according to claim 1, it is characterised in that the face of coarse InterMetallic Compound Fraction 2% ~ 5%, and spacing is 10 ~ 20 microns.
4. power battery case aluminium alloy according to claim 3, it is characterised in that the face of disperse intermetallic point Number is 1 ~ 3%, and spacing is 1 ~ 3 micron.
5. power battery case aluminium alloy according to claim 4, it is characterised in that the coarse InterMetallic Compound Size be more than 1 micron, the size of the disperse intermetallic is less than 1 micron.
6. a kind of power battery case aluminium alloy processing method, it is characterised in that including step:
S1, the power battery case described in constituent and claim any one of 1-5 is carried out with aluminium alloy identical ingot casting Homogenizing annealing processing;
S2, then hot rolling is carried out, obtain hot rolled plate;
S3, cold rolling is carried out to hot rolled plate, obtains cold-reduced sheet.
7. power battery case according to claim 6 aluminium alloy processing method, it is characterised in that in step S1, move back Fire processing includes step:400 ~ 440 °C are raised to 40 ~ 80 °C/h speed and is incubated 4 ~ 8 hours, then again with same liter Warm speed is raised to 590 ~ 640 °C and is incubated 8 ~ 10 hours.
8. power battery case according to claim 7 aluminium alloy processing method, it is characterised in that in step S2, with 500 ~ 540 °C of progress hot rollings are dropped to less than 100 °C/hour speed.
9. the power battery case aluminium alloy processing method according to claim 6 or 8, it is characterised in that in step S3 Also include step afterwards:S4, cold-reduced sheet is incubated 1 ~ 3 hour at 350 ~ 430 °C.
CN201710610484.5A 2017-07-25 2017-07-25 A kind of power battery case aluminium alloy and its processing method Pending CN107400807A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116005042A (en) * 2023-01-10 2023-04-25 江西寰球新材料科技有限公司 Aluminum-manganese alloy extrusion material and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101054642A (en) * 2006-04-13 2007-10-17 深圳市比克电池有限公司 Aluminum alloy for preparing battery shell
CN101736182A (en) * 2009-12-28 2010-06-16 东北轻合金有限责任公司 Aluminum alloy strip for mobile phone battery shell and manufacturing method thereof
CN102354732A (en) * 2011-09-24 2012-02-15 李其真 Manufacture process of automobile power battery enclosure
CN102978484A (en) * 2012-11-30 2013-03-20 苏州有色金属研究院有限公司 Al-Fe alloy plate for shell of power battery and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101054642A (en) * 2006-04-13 2007-10-17 深圳市比克电池有限公司 Aluminum alloy for preparing battery shell
CN101736182A (en) * 2009-12-28 2010-06-16 东北轻合金有限责任公司 Aluminum alloy strip for mobile phone battery shell and manufacturing method thereof
CN102354732A (en) * 2011-09-24 2012-02-15 李其真 Manufacture process of automobile power battery enclosure
CN102978484A (en) * 2012-11-30 2013-03-20 苏州有色金属研究院有限公司 Al-Fe alloy plate for shell of power battery and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116005042A (en) * 2023-01-10 2023-04-25 江西寰球新材料科技有限公司 Aluminum-manganese alloy extrusion material and preparation method and application thereof

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Application publication date: 20171128