CN107384231A - A kind of preparation method of nano ceramics heat insulating membrane - Google Patents
A kind of preparation method of nano ceramics heat insulating membrane Download PDFInfo
- Publication number
- CN107384231A CN107384231A CN201710424759.6A CN201710424759A CN107384231A CN 107384231 A CN107384231 A CN 107384231A CN 201710424759 A CN201710424759 A CN 201710424759A CN 107384231 A CN107384231 A CN 107384231A
- Authority
- CN
- China
- Prior art keywords
- nano ceramics
- heat insulating
- nano
- insulating membrane
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/12—Ceramic
- C09J2400/123—Ceramic in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
Abstract
The invention belongs to the technical field of Ceramic manufacturing, and in particular to a kind of preparation method of nano ceramics heat insulating membrane.The present invention is with eight water oxygen zirconium chlorides, lanthanum nitrate is raw material, instill in ammoniacal liquor and be co-precipitated after mixing, centrifuged after dialysis cleans, zirconic acid lanthanum is made in calcining, then by zirconic acid lanthanum, nano aluminium oxide etc. is calcined with poly-vinyl alcohol solution ball milling, pass through the synergy of zirconic acid lanthanum and nano aluminium oxide etc., the good heat-insulated powder of nano ceramics of chemical stability is made, the heat-insulated powder of nano ceramics is configured to coating paste, transparent PET film base material upper surface is coated on as thermal insulation layer, one layer of nano antimony tin oxide is coated as scattering layer, one layer of UV oil polish is finally coated in semi-finished product thermal isolation film upper surface as scratch-resistant layer, after drying one layer of acrylate pressure sensitive adhesive is coated in lower surface, and one layer of mould release membrance of covering can obtain nano ceramics heat insulating membrane.Nano ceramics heat insulating membrane chemical stability produced by the present invention is good, is not easy to be oxidized, and effectively extends the service life of thermal isolation film.
Description
Technical field
The invention belongs to the technical field of Ceramic manufacturing, and in particular to a kind of preparation method of nano ceramics heat insulating membrane.
Background technology
One of the three big pillars of ceramic material as material, play very important work in daily life and industrial production
With still, because traditional ceramics texture material is more crisp, toughness, intensity are poor, thus its application is received larger limit
System, with the extensive use of nanometer technology, nano ceramics is produced therewith, it is desirable to the fragility of ceramic material is overcome with this, makes pottery
Porcelain has the pliability and machinability as metal.So-called nano ceramics, refer to that the thing in microstructure mutually has nanometer
The ceramic material of level yardstick, that is to say, that crystallite dimension, grain boundary width, the second distributed mutually, flaw size etc. are all in nanometer amount
In the level of level.Because the randomness of percent by volume that can be comparable with particle, small-size effect and interface is occupied at interface
Make it that there is the special performance different from traditional ceramics.
Ceramic membrane is also referred to as GT films, is one kind of solid film.Ceramic membrane is mainly Al2O3, ZrO2, TiO2And SiO2Etc. inorganic material
Expect the perforated membrane prepared, its aperture is 2~50mm.With acidproof, alkaline-resisting, organic solvent-resistant, mechanical strength is big, can reversely rush
Wash, anti-microbe ability is strong, high temperature resistant；The features such as pore-size distribution is narrow, and separative efficiency is high, in food industry, bioengineering, environment
Engineering, chemical industry, petrochemical industry, control the fields such as metal working industry and be widely used., can due to the superior performance of ceramic membrane
For thermal insulation applications.But existing thermal isolation film chemical stability is bad, be directly exposed in air and daylight in when, easy quilt
Oxidation, the defects of causing the service life of thermal isolation film not long.Therefore, it is good to research and develop a kind of chemical stability, service life length
Thermal isolation film have important practical significance.
The content of the invention
The technical problems to be solved by the invention：It is bad for existing thermal isolation film chemical stability, directly it is exposed to sky
When gas is neutralized in daylight, be oxidized easily, the defects of causing the service life of thermal isolation film not long, there is provided a kind of nano ceramics every
The method of hotting mask.
To solve technical problem, the present invention uses technical scheme as described below：
（1）Take eight water oxygen zirconium chlorides to be mixed with deionized water, add lanthanum nitrate hexahydrate, after stirring 20~30min, 50~60
Ammoniacal liquor is added dropwise at DEG C, staticly settles 24~30h, then is placed in bag filter and dialyses 3~4 days, collects trapped fluid, trapped fluid is centrifuged
Separation, must be precipitated, then calcine 3~4h after precipitation is dried, and obtain zirconic acid lanthanum；
（2）By zirconic acid lanthanum, nano aluminium oxide, titanium dioxide, silicon nitride and poly-vinyl alcohol solution 2~3h of mixing and ball milling, then through spray
Calcining and grinding after mist is dried, obtains the heat-insulated powder of nano ceramics；
（3）The heat-insulated powder of nano ceramics is added in absolute ethyl alcohol and is well mixed, coating paste is obtained, coating paste is coated on
Bright PET film substrate upper surface, one layer of nano antimony tin oxide ethylene glycol dispersion liquid is coated after drying, then obtains semi-finished product after drying
Thermal isolation film；
（4）One layer of UV oil polish is coated in semi-finished product thermal isolation film upper surface, one layer of propylene acid fracturing is coated in lower surface again after drying
Quick glue, and one layer of PET mould release membrance is covered, obtain nano ceramics heat insulating membrane.
Step（1）Eight described water oxygen zirconium chlorides and the mass ratio of deionized water are 0.16~0.48.
Step（1）The mass fraction of described lanthanum nitrate hexahydrate be 5~10%, dosage for eight water oxygen zirconium chloride quality 8~
15 times.
Step（1）The mass fraction of described ammoniacal liquor is 20~30%, and dosage is the 60~150 of eight water oxygen zirconium chloride quality
Times.
Step（1）Described calcining heat is 1200~1400 DEG C.
Step（2）Described zirconic acid lanthanum, nano aluminium oxide, titanium dioxide, the parts by weight of silicon nitride and poly-vinyl alcohol solution
For 5~8 parts of zirconic acid lanthanums, 8~10 parts of nano aluminium oxides, 4~6 parts of titanium dioxide, 40~50 parts of silicon nitrides, 150~180 parts of quality
Fraction is 2% poly-vinyl alcohol solution.
Step（2）Described calcination process is again heated to 700~800 to be heated to 500~550 DEG C of insulation 2~3h of calcining
DEG C insulation calcining 2~3h.
Step（3）The solid content of described coating paste is 20~40%, and coating weight is 1~5mg/cm2。
Step（3）The solid content of described nano antimony tin oxide ethylene glycol dispersion liquid is 1~5%, and coating weight is 1~5mg/
cm2。
Step（4）Described coating thickness is 0.010~0.012mm.
The method have the benefit that：The present invention instills ammonia using eight water oxygen zirconium chlorides, lanthanum nitrate as raw material after mixing
It is co-precipitated in water, is centrifuged after dialysis cleans, calcine and zirconic acid lanthanum is made, then by zirconic acid lanthanum, nano aluminium oxide etc. with gathering
Glycohol solution ball milling is calcined, and by the synergy of zirconic acid lanthanum and nano aluminium oxide etc., the good nanometer of chemical stability is made
Ceramic insulation powder, the heat-insulated powder of nano ceramics is configured to coating paste, be coated on transparent PET film base material upper surface be used as every
Thermosphere, one layer of nano antimony tin oxide is coated as scattering layer, finally coats one layer of UV glazing in semi-finished product thermal isolation film upper surface
Oil is used as scratch-resistant layer, coats one layer of acrylate pressure sensitive adhesive after drying in lower surface, and one layer of mould release membrance of covering can obtain nanometer pottery
Porcelain thermal isolation film.The present invention, which utilizes, to be had more room, crystal structure complexity and rear-earth-doped ion be present inside rare earth zirconic acid lanthanum,
The scattering of phonon is considerably increased, reduces mean free path of phonons, so as to have lower thermal conductivity.In addition, utilize rare earth
Zirconic acid lanthanum has the characteristics that high-melting-point, high-temperature-phase Stability Analysis of Structures and anti-sintering property are excellent compound with nano aluminium oxide, obtained
Nano ceramics heat insulating membrane chemical stability is good, is not easy to be oxidized, and effectively extends the service life of thermal isolation film.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is only to aid in understanding the present invention, is not construed as the concrete restriction to the present invention.
The water oxygen zirconium chlorides of 32~48g eight are weighed, are added in 100~200mL deionized waters, are stirred with 300~400r/min
20~30min, it is 10% lanthanum nitrate hexahydrate to add 320~480mL mass fractions, continues 20~30min of stirring, obtains mixed liquor,
Mixed liquor is then instilled into 3~5L mass fractions as in 30% ammoniacal liquor using 1~2mL/min, under 50~60 DEG C of waters bath with thermostatic control, held
Continuous stirring staticly settles 24~30h, obtains presoma mixed liquor, presoma mixed liquor is placed in into 8000~10000 to being added dropwise
Dialysed 3~4 days in the bag filter of dalton, collect trapped fluid, then continue in centrifuge and centrifuge, must precipitate, will precipitate
It is placed in drying box, is dried at 105~110 DEG C to constant weight, be subsequently filled into resistance furnace, 3 are calcined at 1200~1400 DEG C
~4h, after being cooled to room temperature, obtain zirconic acid lanthanum；Weigh 5~8g zirconic acid lanthanums, 8~10g nano aluminium oxides, 4~6g titanium dioxide, 40
~50g silicon nitrides, it is after being well mixed in 2% poly-vinyl alcohol solution, to be fitted into ball mill to add 150~160mL mass fractions,
With 250~300r/min, 2~3h of ball milling, then continue in spray dryer and be spray-dried, obtain reunion powder, reunion powder is put
In resistance furnace, 500~550 DEG C of insulation 2~3h of calcining are heated to, are again heated to 700~800 DEG C of insulation 2~3h of calcining, cooling
It is fitted into after to room temperature in mortar and grinds, crosses 400 mesh sieves, obtain the heat-insulated powder of nano ceramics；By the heat-insulated powder of nano ceramics, add
In 200~300mL absolute ethyl alcohols, 1~2h is stirred with 300~400r/min, coating paste is obtained, coating paste is pressed into 1~5mg/
cm2Coating weight be coated on transparent PET film base material upper surface, be subsequently placed in drying box, at 110~120 DEG C dry 1~
2h, then by 1~5mg/cm2Coating weight to be coated with one layer of solid content be 5% nano antimony tin oxide ethylene glycol dispersion liquid, 110~
After drying 1~2h at 120 DEG C, semi-finished product thermal isolation film is obtained；Coated in semi-finished product thermal isolation film upper surface a layer thickness for 0.010~
0.012mmUV oil polishes, after being dried at 80~100 DEG C, then it is 0.010 to coat a layer thickness in semi-finished product thermal isolation film lower surface
~0.012mm acrylate pressure sensitive adhesives, and the PET mould release membrances that a layer thickness is 0.012mm are covered, obtain nano ceramics heat insulating membrane.
Example 1
The water oxygen zirconium chlorides of 32g eight are weighed, are added in 100mL deionized waters, 20min is stirred with 300r/min, adds 320mL matter
Amount fraction is 10% lanthanum nitrate hexahydrate, continues to stir 20min, obtains mixed liquor, and mixed liquor then is instilled into 3L mass with 1mL/min
Fraction is in 30% ammoniacal liquor, under 50 DEG C of waters bath with thermostatic control, continues stirring until and is added dropwise, staticly settles 24h, obtains presoma mixing
Liquid, presoma mixed liquor is placed in the bag filter of 8000 dalton and dialysed 3 days, collected trapped fluid, then continue in centrifuge
Centrifuge, must precipitate, precipitation is placed in drying box, dry to constant weight, be subsequently filled into resistance furnace at 105 DEG C,
3h is calcined at 1200 DEG C, after being cooled to room temperature, obtains zirconic acid lanthanum；Weigh 5g zirconic acid lanthanums, 8g nano aluminium oxides, 4g titanium dioxide, 40g
Silicon nitride, it is after being well mixed in 2% poly-vinyl alcohol solution, to be fitted into ball mill, with 250r/min to add 150mL mass fractions
Ball milling 2h, is then continued in spray dryer and is spray-dried, and obtains reunion powder, and reunion powder is placed in resistance furnace, is heated to
500 DEG C of insulation calcining 2h, be again heated to 700 DEG C of insulation 2~3h of calcining, be cooled to after room temperature to be fitted into mortar and grind, 400 mesh
Sieve, obtains the heat-insulated powder of nano ceramics；By the heat-insulated powder of nano ceramics, add in 200mL absolute ethyl alcohols, stirred with 300r/min
1h, coating paste is obtained, coating paste is pressed into 1mg/cm2Coating weight be coated on transparent PET film base material upper surface, be subsequently placed at dry
In dry case, 1h is dried at 110 DEG C, then by 1mg/cm2Coating weight be coated with one layer of solid content be 5% nano antimony tin oxide second two
Alcohol dispersion liquid, after drying 1h at 110 DEG C, obtain semi-finished product thermal isolation film；Coating a layer thickness in semi-finished product thermal isolation film upper surface is
0.010mmUV oil polishes, after being dried at 80 DEG C, then it is 0.010mm third to coat a layer thickness in semi-finished product thermal isolation film lower surface
Olefin(e) acid pressure sensitive adhesive, and the PET mould release membrances that a layer thickness is 0.012mm are covered, obtain nano ceramics heat insulating membrane.
The nano ceramics heat insulating membrane obtained by the present invention is cut out according to glass size, long and wide each 3 centimeters of increase first
Cut, then 5 drop liquid detergents are added dropwise in the water sprager equipped with 500g water, glass surface is sprayed on after rocking uniformly, is scraped with soft
Plate scrapes 3 times and one layer of water is sprayed on glass from top to bottom, then spreads the lower surface of the nano ceramics heat insulating membrane after cutting
It is attached on glass surface, finally the water between film and glass is discharged with scraper plate, and unnecessary film is dismissed with cutter.Through
Detection, the nano ceramics heat insulating membrane of present invention gained have good a light transmission and heat-proof quality, and light transmittance 95% is ultraviolet
Line rejection rate is 99%, and infrared ray rejection rate is 97.3%, uses the phenomenon for not having to find xanthochromia, degumming, generation bubble after 15 years.
Example 2
The water oxygen zirconium chlorides of 48g eight are weighed, are added in 200mL deionized waters, 30min is stirred with 400r/min, adds 480mL matter
Amount fraction is 10% lanthanum nitrate hexahydrate, continues to stir 30min, obtains mixed liquor, and mixed liquor then is instilled into 5L mass with 2mL/min
Fraction is in 30% ammoniacal liquor, under 60 DEG C of waters bath with thermostatic control, continues stirring until and is added dropwise, staticly settles 30h, obtains presoma mixing
Liquid, presoma mixed liquor is placed in the bag filter of 10000 dalton and dialysed 4 days, collected trapped fluid, then continue in centrifuge
Centrifuge, must precipitate, precipitation is placed in drying box, dry to constant weight, be subsequently filled into resistance furnace at 110 DEG C,
4h is calcined at 1400 DEG C, after being cooled to room temperature, obtains zirconic acid lanthanum；Weigh 8g zirconic acid lanthanums, 10g nano aluminium oxides, 6g titanium dioxide,
50g silicon nitrides, it is after being well mixed in 2% poly-vinyl alcohol solution, to be fitted into ball mill, with 300r/ to add 160mL mass fractions
Min ball milling 3h, are then continued in spray dryer and are spray-dried, and obtain reunion powder, and reunion powder is placed in resistance furnace, heating
To 550 DEG C of insulation 2~3h of calcining, be again heated to 800 DEG C of insulation calcining 3h, be cooled to after room temperature to be fitted into mortar and grind, 400
Mesh sieve, obtain the heat-insulated powder of nano ceramics；By the heat-insulated powder of nano ceramics, add in 300mL absolute ethyl alcohols, stirred with 400r/min
2h, coating paste is obtained, coating paste is pressed into 5mg/cm2Coating weight be coated on transparent PET film base material upper surface, be subsequently placed at dry
In dry case, 2h is dried at 120 DEG C, then by 5mg/cm2Coating weight be coated with one layer of solid content be 5% nano antimony tin oxide second two
Alcohol dispersion liquid, after drying 2h at 120 DEG C, obtain semi-finished product thermal isolation film；Coating a layer thickness in semi-finished product thermal isolation film upper surface is
0.012mmUV oil polishes, after being dried at 100 DEG C, then it is 0.012mm third to coat a layer thickness in semi-finished product thermal isolation film lower surface
Olefin(e) acid pressure sensitive adhesive, and the PET mould release membrances that a layer thickness is 0.012mm are covered, obtain nano ceramics heat insulating membrane.
The nano ceramics heat insulating membrane obtained by the present invention is cut out according to glass size, long and wide each 5 centimeters of increase first
Cut, then 10 drop liquid detergents are added dropwise in the water sprager equipped with 500g water, glass surface is sprayed on after rocking uniformly, is scraped with soft
Plate scrapes 5 times and one layer of water is sprayed on glass from top to bottom, then spreads the lower surface of the nano ceramics heat insulating membrane after cutting
It is attached on glass surface, finally the water between film and glass is discharged with scraper plate, and unnecessary film is dismissed with cutter.Through
Detection, the nano ceramics heat insulating membrane of present invention gained have good a light transmission and heat-proof quality, and light transmittance 99% is ultraviolet
Line rejection rate is 99.8%, and infrared ray rejection rate is 99.5%, is showed using not having after 20 years to find xanthochromia, degumming, produce bubble
As.
Example 3
The water oxygen zirconium chlorides of 40g eight are weighed, are added in 150mL deionized waters, 25min is stirred with 350r/min, adds 400mL matter
Amount fraction is 10% lanthanum nitrate hexahydrate, continues to stir 25min, obtains mixed liquor, and mixed liquor then is instilled into 4L mass with 1mL/min
Fraction is in 30% ammoniacal liquor, under 55 DEG C of waters bath with thermostatic control, continues stirring until and is added dropwise, staticly settles 27h, obtains presoma mixing
Liquid, presoma mixed liquor is placed in the bag filter of 9000 dalton and dialysed 3 days, collected trapped fluid, then continue in centrifuge
Centrifuge, must precipitate, precipitation is placed in drying box, dry to constant weight, be subsequently filled into resistance furnace at 108 DEG C,
3.5h is calcined at 1300 DEG C, after being cooled to room temperature, obtains zirconic acid lanthanum；Weigh 7g zirconic acid lanthanums, 9g nano aluminium oxides, 7g titanium dioxide,
45g silicon nitrides, it is after being well mixed in 2% poly-vinyl alcohol solution, to be fitted into ball mill, with 275r/ to add 155mL mass fractions
Min ball milling 2.5h, are then continued in spray dryer and are spray-dried, and obtain reunion powder, and reunion powder is placed in resistance furnace, added
Heat is again heated to 750 DEG C of insulation calcining 2.5h, is cooled to after room temperature to be fitted into mortar and grinds to 525 DEG C of insulation calcining 2.5h, mistake
400 mesh sieves, obtain the heat-insulated powder of nano ceramics；Add in 250mL absolute ethyl alcohols, the heat-insulated powder of nano ceramics with 350r/min
1.5h is stirred, coating paste is obtained, coating paste is pressed into 3mg/cm2Coating weight be coated on transparent PET film base material upper surface, then
It is placed in drying box, 1.5h is dried at 115 DEG C, then by 3mg/cm2Coating weight to be coated with one layer of solid content be 5% nano oxidized
Tin antimony ethylene glycol dispersion liquid, after drying 1.5h at 115 DEG C, obtain semi-finished product thermal isolation film；Coated in semi-finished product thermal isolation film upper surface
A layer thickness is 0.011mmUV oil polishes, after being dried at 90 DEG C, then coats a layer thickness in semi-finished product thermal isolation film lower surface and is
0.011mm acrylate pressure sensitive adhesives, and the PET mould release membrances that a layer thickness is 0.012mm are covered, obtain nano ceramics heat insulating membrane.
The nano ceramics heat insulating membrane obtained by the present invention is cut out according to glass size, long and wide each 4 centimeters of increase first
Cut, then 8 drop liquid detergents are added dropwise in the water sprager equipped with 500g water, glass surface is sprayed on after rocking uniformly, is scraped with soft
Plate scrapes 4 times and one layer of water is sprayed on glass from top to bottom, then spreads the lower surface of the nano ceramics heat insulating membrane after cutting
It is attached on glass surface, finally the water between film and glass is discharged with scraper plate, and unnecessary film is dismissed with cutter.Through
Detection, the nano ceramics heat insulating membrane of present invention gained have good a light transmission and heat-proof quality, and light transmittance 97% is ultraviolet
Line rejection rate is 99.4%, and infrared ray rejection rate is 98.4%, while finds xanthochromia, degumming, generation bubble using no after 18 years
Phenomenon.
Claims (10)
1. a kind of preparation method of nano ceramics heat insulating membrane, it is characterised in that specifically preparation process is：
（1）Take eight water oxygen zirconium chlorides to be mixed with deionized water, add lanthanum nitrate hexahydrate, after stirring 20~30min, 50~60
Ammoniacal liquor is added dropwise at DEG C, staticly settles 24~30h, then is placed in bag filter and dialyses 3~4 days, collects trapped fluid, trapped fluid is centrifuged
Separation, must be precipitated, then calcine 3~4h after precipitation is dried, and obtain zirconic acid lanthanum；
（2）By zirconic acid lanthanum, nano aluminium oxide, titanium dioxide, silicon nitride and poly-vinyl alcohol solution 2~3h of mixing and ball milling, then through spray
Calcining and grinding after mist is dried, obtains the heat-insulated powder of nano ceramics；
（3）The heat-insulated powder of nano ceramics is added in absolute ethyl alcohol and is well mixed, coating paste is obtained, coating paste is coated on
Bright PET film substrate upper surface, one layer of nano antimony tin oxide ethylene glycol dispersion liquid is coated after drying, then obtains semi-finished product after drying
Thermal isolation film；
（4）One layer of UV oil polish is coated in semi-finished product thermal isolation film upper surface, one layer of propylene acid fracturing is coated in lower surface again after drying
Quick glue, and one layer of PET mould release membrance is covered, obtain nano ceramics heat insulating membrane.
A kind of 2. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（1）Described
Eight water oxygen zirconium chlorides and the mass ratio of deionized water are 0.16~0.48.
A kind of 3. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（1）Described
The mass fraction of lanthanum nitrate hexahydrate is 5~10%, and dosage is 8~15 times of eight water oxygen zirconium chloride quality.
A kind of 4. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（1）Described
The mass fraction of ammoniacal liquor is 20~30%, and dosage is 60~150 times of eight water oxygen zirconium chloride quality.
A kind of 5. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（1）Described
Calcining heat is 1200~1400 DEG C.
A kind of 6. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（2）Described
Zirconic acid lanthanum, nano aluminium oxide, titanium dioxide, the parts by weight of silicon nitride and poly-vinyl alcohol solution are 5~8 parts of zirconic acid lanthanums, 8~10 parts
Nano aluminium oxide, 4~6 parts of titanium dioxide, 40~50 parts of silicon nitrides, 150~180 parts of mass fractions are 2% poly-vinyl alcohol solution.
A kind of 7. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（2）Described
Calcination process is again heated to 700~800 DEG C of 2~3h of insulation calcining to be heated to 500~550 DEG C of insulation 2~3h of calcining.
A kind of 8. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（3）Described
The solid content of coating paste is 20~40%, and coating weight is 1~5mg/cm2。
A kind of 9. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（3）Described
The solid content of nano antimony tin oxide ethylene glycol dispersion liquid is 1~5%, and coating weight is 1~5mg/cm2。
A kind of 10. preparation method of nano ceramics heat insulating membrane as claimed in claim 1, it is characterised in that：Step（4）Described
Coating thickness is 0.010~0.012mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710424759.6A CN107384231A (en) | 2017-06-07 | 2017-06-07 | A kind of preparation method of nano ceramics heat insulating membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710424759.6A CN107384231A (en) | 2017-06-07 | 2017-06-07 | A kind of preparation method of nano ceramics heat insulating membrane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107384231A true CN107384231A (en) | 2017-11-24 |
Family
ID=60332123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710424759.6A Pending CN107384231A (en) | 2017-06-07 | 2017-06-07 | A kind of preparation method of nano ceramics heat insulating membrane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107384231A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112552760A (en) * | 2020-12-15 | 2021-03-26 | 李桂丽 | Composite nano waterproof heat-insulating coating for buildings and preparation method thereof |
| CN117210167A (en) * | 2023-11-08 | 2023-12-12 | 广东鑫瑞新材料有限公司 | Nanofiber ceramic high-heat-insulation sun-shading adhesive film and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407336A (en) * | 2008-06-30 | 2009-04-15 | 中国科学院上海硅酸盐研究所 | Method for preparing lanthanum zirconate powder |
| CN101506696A (en) * | 2006-08-22 | 2009-08-12 | 3M创新有限公司 | Solar control film |
| CN101611080A (en) * | 2007-02-26 | 2009-12-23 | 贝卡尔特股份有限公司 | The laminate structure that contains nano particle |
| CN103042781A (en) * | 2012-12-26 | 2013-04-17 | 武汉羿阳科技有限公司 | Heat-insulating ceramic membrane and window membrane prepared from same |
| CN104178047A (en) * | 2014-08-20 | 2014-12-03 | 昆山博益鑫成高分子材料有限公司 | Flexible transparent nano heat-insulation film and preparation method thereof |
| CN106183148A (en) * | 2016-08-30 | 2016-12-07 | 常州山由帝杉防护材料制造有限公司 | Nano ceramics heat-insulation and heat-preservation fenestrated membrane |
-
2017
- 2017-06-07 CN CN201710424759.6A patent/CN107384231A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101506696A (en) * | 2006-08-22 | 2009-08-12 | 3M创新有限公司 | Solar control film |
| CN101611080A (en) * | 2007-02-26 | 2009-12-23 | 贝卡尔特股份有限公司 | The laminate structure that contains nano particle |
| CN101407336A (en) * | 2008-06-30 | 2009-04-15 | 中国科学院上海硅酸盐研究所 | Method for preparing lanthanum zirconate powder |
| CN103042781A (en) * | 2012-12-26 | 2013-04-17 | 武汉羿阳科技有限公司 | Heat-insulating ceramic membrane and window membrane prepared from same |
| CN104178047A (en) * | 2014-08-20 | 2014-12-03 | 昆山博益鑫成高分子材料有限公司 | Flexible transparent nano heat-insulation film and preparation method thereof |
| CN106183148A (en) * | 2016-08-30 | 2016-12-07 | 常州山由帝杉防护材料制造有限公司 | Nano ceramics heat-insulation and heat-preservation fenestrated membrane |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112552760A (en) * | 2020-12-15 | 2021-03-26 | 李桂丽 | Composite nano waterproof heat-insulating coating for buildings and preparation method thereof |
| CN112552760B (en) * | 2020-12-15 | 2022-05-17 | 艾斯贝科环保科技(北京)有限公司 | Composite nano waterproof heat-insulating coating for buildings and preparation method thereof |
| CN117210167A (en) * | 2023-11-08 | 2023-12-12 | 广东鑫瑞新材料有限公司 | Nanofiber ceramic high-heat-insulation sun-shading adhesive film and preparation method and application thereof |
| CN117210167B (en) * | 2023-11-08 | 2024-01-09 | 广东鑫瑞新材料有限公司 | Nanofiber ceramic high-heat-insulation sun-shading adhesive film and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104803710B (en) | Ceramic membranes | |
| CN106110909B (en) | A kind of application of preparation method and its infiltration evaporation the processing high slat-containing wastewater of organosilicon membrane | |
| CN101649147B (en) | Water transparent heat insulation paint and preparation method thereof | |
| CN106009428B (en) | A kind of silica-filled PTFE composite and preparation method thereof | |
| CN105754381B (en) | A kind of nanometer anti-reflection coating liquid and its preparation method and application | |
| CN104725990B (en) | A kind of preparation method of the self-cleaning coating based on modified nano-titanium dioxide | |
| TWI483914B (en) | Method for producing a coated component of quartz glass | |
| CN110357135A (en) | A kind of preparation method of high-purity lithium battery diaphragm special-alumina | |
| CN107384231A (en) | A kind of preparation method of nano ceramics heat insulating membrane | |
| CN104194406B (en) | A kind of preparation method of nano-oxide composite pigment | |
| CN106673633A (en) | Antibacterial bathroom ceramic article and preparation method thereof | |
| CN107999110A (en) | A kind of Lacking oxygen tungsten oxide/nitridation carbon composite photocatalyst and its preparation method and application | |
| CN104610488A (en) | High-permeability anti-radiation coating and preparation method thereof | |
| CN105038338B (en) | Transparent hydrophobic spray and its preparation method and application | |
| CN102743979A (en) | Preparation method of zirconia ceramic ultrafiltration film | |
| CN105219146A (en) | A kind of aqueous colorful imitates stone coating system | |
| CN104193409B (en) | A kind of rare earth oxide coating and preparation method thereof | |
| CN109487245A (en) | A kind of preparation method of super-hydrophobic aqua oxidation aluminium film | |
| CN107746272A (en) | Microwave-medium ceramics, polytetrafluoroethylene (PTFE) ceramic composite substrate and preparation method | |
| CN102061107A (en) | Method for coating rutile type titanium dioxide with styrene or methacrylic acid | |
| Li et al. | Energy saving wood composite with temperature regulatory ability and thermoresponsive performance | |
| CN104151965A (en) | Exterior wall coating with solar heat reflecting function and preparation method of exterior wall coating | |
| CN107522451A (en) | A kind of preparation method of ceramics | |
| CN108069608A (en) | A kind of alkaline-resisting enamel | |
| CN109174044B (en) | Method for improving specific surface area and adsorption capacity of opal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180423 Address after: 213000 Chenxia village, Dingcun village committee, Xixia Town, Xinbei District, Changzhou, Jiangsu, 5 Applicant after: Yu Xiaofeng Address before: 213102 No. 18, No. 600 Tongjiang Middle Road, Xinbei District, Changzhou, Jiangsu 335 Applicant before: Changzhou Connaught composite material Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171124 |
|
| WD01 | Invention patent application deemed withdrawn after publication |