CN107383436A - A kind of Biodegradable mulch - Google Patents

A kind of Biodegradable mulch Download PDF

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Publication number
CN107383436A
CN107383436A CN201710480993.0A CN201710480993A CN107383436A CN 107383436 A CN107383436 A CN 107383436A CN 201710480993 A CN201710480993 A CN 201710480993A CN 107383436 A CN107383436 A CN 107383436A
Authority
CN
China
Prior art keywords
parts
starch
plasticizer
cellulose
polyvinyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710480993.0A
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Chinese (zh)
Inventor
许磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaanxi University of Technology
Original Assignee
Shaanxi University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaanxi University of Technology filed Critical Shaanxi University of Technology
Priority to CN201710480993.0A priority Critical patent/CN107383436A/en
Publication of CN107383436A publication Critical patent/CN107383436A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2429/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2429/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of Biodegradable mulch, is made up of starch, polyvinyl alcohol, cellulose, plasticizer, processing aid, and it is as follows that it is formulated constituent:40 60 parts of starch, 20 40 parts of polyvinyl alcohol, 7 10 parts of cellulose, 37 parts of plasticizer, 34 parts of processing aid, the plasticizer are glycerine and ethylene glycol mixture, and it is 12 that it, which is matched,:35, the starch is one kind in cornstarch, wheaten starch, farina, and the cellulose is one kind in sugarcane, stalk.The present invention can be degradable into carbon dioxide and water by microorganism after usage, does not have residual, reduces environmental pollution, improves the reliability of agricultural sustainable development.

Description

A kind of Biodegradable mulch
Technical field
The present invention relates to a kind of agricultural film, and in particular to a kind of Biodegradable mulch.
Background technology
The wide hair application of agricultural film soverlay technique, high degree promotes the development of agricultural, but ecological environment is made simultaneously Into greatly " white pollution ", the agricultural film fragment remained in soil can also influence the yield of crop, therefore, can after use Turned into the research direction of agricultural development from now on by the degradable environment-friendly type degradable agricultural film of microorganism.
The content of the invention
In order to solve the above-mentioned technical problem the present invention provides a kind of Biodegradable mulch, can resolve into two completely by microorganism Carbonoxide and water, the agricultural film pollution on the environment after use is prevented.
The technical scheme is that:A kind of Biodegradable mulch, by starch, polyvinyl alcohol, cellulose, plasticizer, plus Work auxiliary agent forms, and it is as follows that it is formulated constituent:Starch 40-60 parts, polyvinyl alcohol 20-40 parts, cellulose 7-10 parts, plasticizer 3-7 parts, processing aid 3-4 parts.
Further, the plasticizer is glycerine and ethylene glycol mixture, and its proportioning is 1-2:3-5.
Further, the starch is one kind in cornstarch, wheaten starch, farina.
Further, the cellulose is one kind in sugarcane, stalk.
Further, the formula constituent is:50 parts of starch, 35 parts of polyvinyl alcohol, 8 parts of cellulose, plasticizer 4 Part, 3 parts of processing aid.
Further, the formula constituent is:55 parts of starch, 30 parts of polyvinyl alcohol, 7 parts of cellulose, plasticizer 3 Part, 4 parts of processing aid.
The beneficial effects of the invention are as follows:The present invention can after usage by microorganism it is degradable into carbon dioxide and Water, residual is not had, reduces environmental pollution, improve the reliability of agricultural sustainable development.
Embodiment
Clearly complete description is done to the present invention below, so that those skilled in the art need not make creativeness Under conditions of work, it can fully implement the present invention.
Embodiment 1:A kind of Biodegradable mulch, it is made up of starch, polyvinyl alcohol, cellulose, plasticizer, processing aid, It is as follows that it is formulated constituent:Starch 40-60 parts, polyvinyl alcohol 20-40 parts, cellulose 7-10 parts, plasticizer 3-7 parts, processing Auxiliary agent 3-4 parts.
In the present embodiment, the plasticizer is glycerine and ethylene glycol mixture, and its proportioning is 1-2:3-5.
In the present embodiment, the starch is one kind in cornstarch, wheaten starch, farina.
In the present embodiment, the cellulose is one kind in sugarcane, stalk.
Embodiment 2:The difference of the present embodiment and other embodiment is that the formula constituent is:50 parts of starch, gather 35 parts of vinyl alcohol, 8 parts of cellulose, 4 parts of plasticizer, 3 parts of processing aid.
Embodiment 3:The difference of the present embodiment and other embodiment is that constituent is formulated described in the present embodiment is:Form sediment 55 parts of powder, 30 parts of polyvinyl alcohol, 7 parts of cellulose, 3 parts of plasticizer, 4 parts of processing aid.
Presently preferred embodiments of the present invention is described above, it should be pointed out that the invention is not limited in above-mentioned Particular implementation, wherein the equipment and structure be not described in detail to the greatest extent are construed as giving reality with the common mode in this area Apply;Any those skilled in the art, without departing from the scope of the technical proposal of the invention, the technology according to the present invention Essence still falls within technical solution of the present invention protection to any simple modifications, equivalents, and modifications made for any of the above embodiments In the range of.

Claims (6)

1. a kind of Biodegradable mulch, it is made up of starch, polyvinyl alcohol, cellulose, plasticizer, processing aid, it is characterised in that It is as follows that it is formulated constituent:Starch 40-60 parts, polyvinyl alcohol 20-40 parts, cellulose 7-10 parts, plasticizer 3-7 parts, processing Auxiliary agent 3-4 parts.
A kind of 2. Biodegradable mulch according to claim 1, it is characterised in that it is described formula constituent be:Starch 50 parts, 35 parts of polyvinyl alcohol, 8 parts of cellulose, 4 parts of plasticizer, 3 parts of processing aid.
A kind of 3. Biodegradable mulch according to claim 1, it is characterised in that it is described formula constituent be:Starch 55 parts, 30 parts of polyvinyl alcohol, 7 parts of cellulose, 3 parts of plasticizer, 4 parts of processing aid.
4. according to a kind of Biodegradable mulch described in claim any one of 1-3, it is characterised in that the plasticizer is glycerine With ethylene glycol mixture, its proportioning is 1-2:3-5.
5. according to a kind of Biodegradable mulch described in claim any one of 1-3, it is characterised in that the starch forms sediment for corn One kind in powder, wheaten starch, farina.
6. according to a kind of Biodegradable mulch described in claim any one of 1-3, it is characterised in that the cellulose is sweet One kind in sugarcane, stalk.
CN201710480993.0A 2017-06-22 2017-06-22 A kind of Biodegradable mulch Pending CN107383436A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710480993.0A CN107383436A (en) 2017-06-22 2017-06-22 A kind of Biodegradable mulch

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710480993.0A CN107383436A (en) 2017-06-22 2017-06-22 A kind of Biodegradable mulch

Publications (1)

Publication Number Publication Date
CN107383436A true CN107383436A (en) 2017-11-24

Family

ID=60333644

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710480993.0A Pending CN107383436A (en) 2017-06-22 2017-06-22 A kind of Biodegradable mulch

Country Status (1)

Country Link
CN (1) CN107383436A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115746576A (en) * 2022-11-10 2023-03-07 湖南文理学院 Green and environment-friendly agricultural mulching film and preparation method thereof
CN115926347A (en) * 2022-11-18 2023-04-07 河北工业大学 Biodegradable mulching film for slow release of fertilizer and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104656A (en) * 1993-12-31 1995-07-05 中国科学院兰州化学物理研究所 Biodegradable films and their production
CN101580642A (en) * 2009-06-10 2009-11-18 普正汇利生物科技(北京)有限公司 Full-biodegradation natural polymer alloy and preparation method thereof
CN102329435A (en) * 2011-07-23 2012-01-25 佛山市衡龙科技有限公司 Composite fully degradable agricultural mulching film material and preparation process thereof
CN105837864A (en) * 2016-06-07 2016-08-10 内蒙古龙泽节水灌溉科技有限公司 Fully biodegradable film and preparation method thereof
CN106750564A (en) * 2017-01-17 2017-05-31 内蒙古农业大学 A kind of high barrier biodegradable mulch film and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104656A (en) * 1993-12-31 1995-07-05 中国科学院兰州化学物理研究所 Biodegradable films and their production
CN101580642A (en) * 2009-06-10 2009-11-18 普正汇利生物科技(北京)有限公司 Full-biodegradation natural polymer alloy and preparation method thereof
CN102329435A (en) * 2011-07-23 2012-01-25 佛山市衡龙科技有限公司 Composite fully degradable agricultural mulching film material and preparation process thereof
CN105837864A (en) * 2016-06-07 2016-08-10 内蒙古龙泽节水灌溉科技有限公司 Fully biodegradable film and preparation method thereof
CN106750564A (en) * 2017-01-17 2017-05-31 内蒙古农业大学 A kind of high barrier biodegradable mulch film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115746576A (en) * 2022-11-10 2023-03-07 湖南文理学院 Green and environment-friendly agricultural mulching film and preparation method thereof
CN115926347A (en) * 2022-11-18 2023-04-07 河北工业大学 Biodegradable mulching film for slow release of fertilizer and preparation method and application thereof

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Application publication date: 20171124

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