CN107345174A - 超高速轴承加工磨削液 - Google Patents
超高速轴承加工磨削液 Download PDFInfo
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- 239000012530 fluid Substances 0.000 title claims abstract description 14
- 238000003754 machining Methods 0.000 title claims abstract description 12
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 241000047703 Nonion Species 0.000 claims abstract description 8
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 8
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 7
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims abstract description 7
- 229920000570 polyether Polymers 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 12
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 12
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- 239000000428 dust Substances 0.000 abstract description 6
- 238000001816 cooling Methods 0.000 abstract description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 2
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 abstract 1
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 abstract 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
- C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明公开了一种超高速轴承加工磨削液，由月桂二酸、苯并三氮唑、2‑氨基‑2‑甲基丙醇、三异丙醇胺、N,N,N',N'‑四甲基‑1，6‑己二胺、壬酸、新癸酸、非离子氟碳表面活性剂、脂肪酸甲酯乙氧基化物、聚乙烯胺、聚醚改性硅油、水组成。本发明使产品具有极佳的冷却性能和磨屑沉降性能，提高加工精度、延长刀具使用寿命。
Description
技术领域
本发明涉及一种轴承加工磨削液。
背景技术
超高速轴承加工磨削加工要求极高，由于国内研发工作起步较晚以及工艺、技术落后等原因，现在国内使用的这类磨削液大都从日本等发达国家进口，目前国内也有不少厂家纷纷开发此磨削液，但是存在诸多缺陷：一是冷却性能一般，容易引起工件表面局部烧伤；二是磨屑沉降性差，影响加工工件的表面粗糙度；三是加入了硫、氯等对人体和环境有害的物质。这些弊端制约了产品在超高速轴承加工行业中的推广。而本公司研究开发的“超高速轴承加工磨削液”项目，有效地解决了以上三大弊端，在实际的使用中获得了用户的广泛亲睐和肯定。
发明内容
本发明的目的在于提供一种却性能好、磨屑沉降性能好、产品安全卫生质量高的超高速轴承加工磨削液。
本发明的技术解决方案是：
一种超高速轴承加工磨削液，其特征是：由下列质量百分比的成分组成：
月桂二酸 3~8%
苯并三氮唑 0.2~0.8%
2-氨基-2-甲基丙醇 3~9%
三异丙醇胺 5~15%
N,N,N',N'-四甲基-1，6-己二胺 2~4%
壬酸 3~8%
新癸酸 2~5%
非离子氟碳表面活性剂 10~15%
脂肪酸甲酯乙氧基化物 3~8%
聚乙烯胺 1~4%
聚醚改性硅油 0.2~0.8%
水 40~60%；
上述各组分用量之和为100%。
所述的高速轴承加工磨削液，由下列质量百分比的成分组成：
月桂二酸 5%
苯并三氮唑 0.5%
2-氨基-2-甲基丙醇 6%
三异丙醇胺 10%
N,N,N',N'-四甲基-1，6-己二胺 3%
壬酸 5%
新癸酸 3%
非离子氟碳表面活性剂 12%
脂肪酸甲酯乙氧基化物 5%
聚乙烯胺 2.5%
聚醚改性硅油 0.5%
水 47.5%。
本发明选用性能优良的非离子氟碳表面活性剂与优质助剂配伍，使产品的冷却性能得到较高提升（经实验室测试，5%稀释液时，接触角≤25°）。本产品选用性能优良的低泡型脂肪酸甲酯乙氧基化物组伍，使产品的磨屑沉降性得到较大提高（5%稀释液时，磨屑沉降时间≤5S）。本产品中原料不使用危及人体健康和环境安全的有害物质，使产品的安全卫生质量得到大幅提升（经检测，产品急性经口毒性LD50≥5000mg/kg，急性吸入毒性LC50≥5000mg/m3，呼吸道粘膜刺激强度为0级）。
本发明使产品具有极佳的冷却性能和磨屑沉降性能，提高加工精度、延长刀具使用寿命。
下面结合实施例对本发明作进一步说明。
具体实施方式
实施例1：
一种高速轴承加工磨削液，由下列质量百分比的成分混合搅拌制成：
月桂二酸 5%
苯并三氮唑 0.5%
2-氨基-2-甲基丙醇 6%
三异丙醇胺 10%
N,N,N',N'-四甲基-1，6-己二胺 3%
壬酸 5%
新癸酸 3%
非离子氟碳表面活性剂 12%
脂肪酸甲酯乙氧基化物 5%
聚乙烯胺 2.5%
聚醚改性硅油 0.5%
水 47.5%。
实施例2：
一种超高速轴承加工磨削液，由下列质量百分比的成分混合搅拌制成：
月桂二酸 3~8%（例3%、4%、8%）
苯并三氮唑 0.2~0.8%（例0.2%、0.4%、0.8%）
2-氨基-2-甲基丙醇 3~9%（例3%、4%、8%）
三异丙醇胺 5~15%（例5%、11%、15%）
N,N,N',N'-四甲基-1，6-己二胺 2~4%（例2%、3%、4%）
壬酸 3~8%（例3%、4%、8%）
新癸酸 2~5%（例2%、4%、5%）
非离子氟碳表面活性剂 10~15%（例10%、12%、15%）
脂肪酸甲酯乙氧基化物 3~8%（例3%、4%、8%）
聚乙烯胺 1~4%（例1%、3%、4%）
聚醚改性硅油 0.2~0.8%（例0.2%、0.4%、0.8%）
水 40~60%（例41%、52%、59%）。
上述各组分用量之和为100%。
Claims (2)
1.一种超高速轴承加工磨削液，其特征是：由下列质量百分比的成分组成：
月桂二酸 3~8%
苯并三氮唑 0.2~0.8%
2-氨基-2-甲基丙醇 3~9%
三异丙醇胺 5~15%
N,N,N',N'-四甲基-1，6-己二胺 2~4%
壬酸 3~8%
新癸酸 2~5%
非离子氟碳表面活性剂 10~15%
脂肪酸甲酯乙氧基化物 3~8%
聚乙烯胺 1~4%
聚醚改性硅油 0.2~0.8%
水 40~60%；
上述各组分用量之和为100%。
2. 根据权利要求1所述的高速轴承加工磨削液，其特征是：由下列质量百分比的成分组成：
月桂二酸 5%
苯并三氮唑 0.5%
2-氨基-2-甲基丙醇 6%
三异丙醇胺 10%
N,N,N',N'-四甲基-1，6-己二胺 3%
壬酸 5%
新癸酸 3%
非离子氟碳表面活性剂 12%
脂肪酸甲酯乙氧基化物 5%
聚乙烯胺 2.5%
聚醚改性硅油 0.5%
水 47.5%。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111961523A (zh) * | 2020-09-01 | 2020-11-20 | 上海果石实业(集团)有限公司 | 一种不含矿物油的水基磨削液及其制备方法和应用 |
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| CN106281628A (zh) * | 2016-08-12 | 2017-01-04 | 浙江模德石化有限公司 | 一种水溶性磨削液及其制备方法 |
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- 2017-07-10 CN CN201710557162.9A patent/CN107345174A/zh active Pending
Patent Citations (4)
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| CN103525533A (zh) * | 2013-10-23 | 2014-01-22 | 东莞太平洋博高润滑油有限公司 | 一种全合成玻璃磨削液 |
| CN104450105A (zh) * | 2014-12-29 | 2015-03-25 | 长沙艾森设备维护技术有限公司 | 一种低气味低毒玻璃切削液 |
| CN105542931A (zh) * | 2015-12-29 | 2016-05-04 | 奎克化学（中国）有限公司 | 一种沉降性轴承加工用水溶性高速磨削液及其制备方法 |
| CN106281628A (zh) * | 2016-08-12 | 2017-01-04 | 浙江模德石化有限公司 | 一种水溶性磨削液及其制备方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111961523A (zh) * | 2020-09-01 | 2020-11-20 | 上海果石实业(集团)有限公司 | 一种不含矿物油的水基磨削液及其制备方法和应用 |
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