CN107345016A - A kind of HDPE steel band reinforced spiral ripple pipes and its production technology - Google Patents

A kind of HDPE steel band reinforced spiral ripple pipes and its production technology Download PDF

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Publication number
CN107345016A
CN107345016A CN201610307711.2A CN201610307711A CN107345016A CN 107345016 A CN107345016 A CN 107345016A CN 201610307711 A CN201610307711 A CN 201610307711A CN 107345016 A CN107345016 A CN 107345016A
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Prior art keywords
parts
hdpe
mixed
temperature
density polyethylene
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Chinese (zh)
Inventor
俞青松
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JIANGSU HUANTONG ENVIRONMENTAL TECHNOLOGY Co Ltd
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JIANGSU HUANTONG ENVIRONMENTAL TECHNOLOGY Co Ltd
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Priority to CN201610307711.2A priority Critical patent/CN107345016A/en
Publication of CN107345016A publication Critical patent/CN107345016A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0022Combinations of extrusion moulding with other shaping operations combined with cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • B29L2023/22Tubes or pipes, i.e. rigid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The present invention relates to a kind of HDPE steel band reinforced spiral ripple pipes and its production technology, include the raw material of following parts by weight:50 70 parts of high density polyethylene (HDPE), 28 parts of high-modulus PP20,47 parts of attapulgite, HDPE increase firm 58 parts of 25 30 parts of master batch, 26 29 parts of HDPE plasticizing mother particles, 58 parts of polyester modification acrylic resin, 24 parts of Silicone modified acryl's resin, 47 parts of ABS high glue powders, 14 parts of acrylic ester impact-resisting modifier ACR and color masterbatch.The double-wall corrugated multiple tubes of mining HDPE made of the production technology, have that low-temperature flexibility, rigidity, ring stiffness and creep resisting ability are preferable when not only, and during long-term use, will not be because of gravity deformation, so as to extend the service life of product, contribute to a wide range of popularization.

Description

A kind of HDPE steel band reinforced spiral ripple pipes and its production technology
Technical field
The present invention relates to a kind of HDPE steel band reinforced spiral ripple pipes and its production technology, belong to plastic pipe process technology Field.
Background technology
With the continual and steady rapid growth of Chinese national economy, good macroscopic view is provided for cities and towns infrastructure construction Environment and broad space.As China has put into effect a system for the pay attention to day by day of environmental protection, governments at all levels of both the central and local governments Row water saving, the policies and regulations of pollution treatment environmental protection.Supply water, economize on water, draining and waste water control will turn into urban municipal construction from now on Emphasis, this provides market development space for the popularization and application of heavy-caliber plastic pipe.Because structured wall popes can save raw material, Cost is reduced, therefore structured wall popes have become the main product of heavy caliber draining blow-off line.China is used for draining and blowdown The HDPE double-wall corrugated pipes of pipeline have a good rigidity, the advantages such as price is low;But also have the shortcomings that low temperature impact properties difference, especially exist Breakage is very easy to when north of china in winter is constructed.And PE double-wall corrugated pipes have obvious advantage in low-temperature flexibility, but due to PE materials Expect characteristic, its rigidity is poor compared with pipe of cement, and the ring stiffness and creep resisting ability of tubing are poor compared with HDPE bellowss, in long-term use of process In, easily by gravity deformation, influence product service life.
The content of the invention
It is an object of the invention to:A kind of the defects of for prior art, it is proposed that HDPE steel band reinforced spiral ripple pipes And its production technology, with the processing technology make HDPE steel band reinforced spiral ripple pipes, not only when have low-temperature flexibility, just Property, ring stiffness and creep resisting ability are preferable, and during long-term use, will not be because of gravity deformation, so as to extend The service life of product, contribute to a wide range of popularization.
The technical solution adopted in the present invention is:The HDPE steel band reinforced spiral ripple pipes, including following parts by weight Raw material:
In the present invention:Above-mentioned raw materials are mixed according to formula rate, the moisture in raw material is removed, gathers high density Ethylene raw semigel, loose powder is formed, makes auxiliary agent dispersed in high density polyethylene materials, wherein mixture temperature For:Mixed 80~120 DEG C of the temperature of heat, cold mixed 70~80 DEG C of temperature.
In the present invention:A kind of production technology of HDPE steel band reinforced spiral ripple pipes, comprises the following steps:
The first step, raw material mixing:By high density polyethylene materials, color masterbatch, stabilizer, defoamer, antioxidant etc. its He is proportionally successively added in dry mixed machine auxiliary material with technique, removes moisture removal, material is through fully drying, being entered after mixing The hopper of extruder, wherein dry temperature is less than 70 degree;
Second step, heat are mixed:The mixed purpose of heat be each component in material is sufficiently collided in the presence of blade, rubbed, Convection current, each component is reached farthest scattered, and material is heated up, reach preplasticizing, the mixed temperature general control of heat exists 95 DEG C or so, it is noted that the accuracy of hot mixing, the mixed temperature accuracy of Timing measurement heat, prevents the mixed temperature of heat in production process Out of control and material is burnt out;
It is 3rd step, cold mixed:It is cold it is mixed be sufficiently to cool down high-temperature material, avoid high density polyethylene (HDPE) material because for a long time compared with Decomposed in the environment of high-temperature, so that during tube forming, the materials degree of plasticification heterogeneity of batch mixing, production each time is not easy steady It is fixed;Simultaneously cold be mixed with helps to prevent material conglomeration, improves blanking, steady extruding amount, general cold mixed temperature control at 38 DEG C or so, At this temperature, material can be deposited more than 24 hours, and putting material situation is good, and main frame torque ripple is small, and production is stable;
4th step, extrusion:Extrusion is the core procedure of the shaping of plastic pipe;The hardcore of extrusion molding is extrusion Machine, and " heart " of extruder is screw rod and machine barrel, whether screw rod and the fine or not and supporting of machine barrel quality can rationally directly affect To the plasticizing capacity of board, so, for different extrusion equipments, unified formula should not be used, that is, being formulated design should be according to machine The plasticizing capacity of platform and determine;Principle is that degree of plasticification control is advisable 70~75% or so, and the setting of temperature can adopt " saddle The setting scheme of type ", both temperature settings at machine head port mould are in " saddle-shape " square cloth from machine barrel to merging core, then from merging core, Using this setting, thermograde is larger, and melt pressure is big, and product is more closely knit after shaping, and impact strength, hydraulic pressure resistant intensity are high. It is noted that main frame electric current will be controlled 50~60% or so in process of production, and it is unsuitable too high or too low, otherwise can shadow Ring and become apparent under main frame vacuum, particularly fuselage screw rod abrasion more serious situation, in addition can also cause to plastify Excessively or plasticizing is bad;
5th step, sizing, cooling:High density polyethylene (HDPE) Vacuum shaping cooler is used for the sizing of section bar, cooling, and vacuum is fixed Vacuum system and water circulation system for sizing and cooling is housed on type cooler, stainless steel casing, circulates water ring immersion cooling, Equipped with movable device and left and right, high high adjustment hand gear on Vacuum shaping cooler;
6th step, tubing traction:Hauling machine be used for it is continuous, automatically will cool down the section bar being hardened and drawn at head Come, frequency control;
7th step, cutting:After travel switch length control as requested, surface trimming, and the translation frame that is delayed are carried out, is carried out Production line, cutting machine complete cutting overall process using fixed length work switching signal as instruction, run and protect with section bar in cutting process Synchronization is held, cutting process is completed by electrical and pneumatic driving, and cutting machine is provided with dust exhaust apparatus, chip caused by cutting is inhaled in time Go out and reclaim;
8th step, stack:The action of tilting trestle stirring is realized that tilting trestle is spacing provided with one by cylinder by gas circuit control Device, after saw cutting section bar is cut, section bar continues to convey, and after delay, cylinder enters work, realizes that stirring acts, reaches Discharging purpose, automatically reset after discharging through the several seconds that is delayed, wait subsequent cycle.After adopting the above technical scheme, the present invention's has Beneficial effect is:With the processing technology make the double-wall corrugated multiple tubes of mining HDPE, not only when there is low-temperature flexibility, rigidity, ring Rigidity and creep resisting ability are preferable, and during long-term use, will not be because of gravity deformation, so as to extend product Service life, contribute to a wide range of popularization.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
A kind of HDPE steel band reinforced spiral ripple pipes, include the raw material of following parts by weight:
Above-mentioned raw materials are mixed according to formula rate, remove the moisture in raw material, make high density polyethylene materials half Gelation, loose powder is formed, makes auxiliary agent dispersed in high density polyethylene materials, wherein mixture temperature is:The mixed temperature of heat 80 DEG C of degree, cold mixed temperature 70 C.
Embodiment 2
A kind of HDPE steel band reinforced spiral ripple pipes, include the raw material of following parts by weight:
Above-mentioned raw materials are mixed according to formula rate, remove the moisture in raw material, make high density polyethylene materials half Gelation, loose powder is formed, makes auxiliary agent dispersed in high density polyethylene materials, wherein mixture temperature is:The mixed temperature of heat 120 DEG C of degree, cold mixed 80 DEG C of temperature.
Embodiment 3
A kind of HDPE steel band reinforced spiral ripple pipes, include the raw material of following parts by weight:
Above-mentioned raw materials are mixed according to formula rate, remove the moisture in raw material, make high density polyethylene materials half Gelation, loose powder is formed, makes auxiliary agent dispersed in high density polyethylene materials, wherein mixture temperature is:The mixed temperature of heat 105 DEG C of degree, cold mixed 75 DEG C of temperature.
In the present invention:A kind of production technology of HDPE steel band reinforced spiral ripple pipes, comprises the following steps:
The first step, raw material mixing:By high density polyethylene materials, color masterbatch, stabilizer, defoamer, antioxidant etc. its He is proportionally successively added in dry mixed machine auxiliary material with technique, removes moisture removal, material is through fully drying, being entered after mixing The hopper of extruder, wherein dry temperature is less than 70 degree;
Second step, heat are mixed:The mixed purpose of heat be each component in material is sufficiently collided in the presence of blade, rubbed, Convection current, each component is reached farthest scattered, and material is heated up, reach preplasticizing, the mixed temperature general control of heat exists 95 DEG C or so, it is noted that the accuracy of hot mixing, the mixed temperature accuracy of Timing measurement heat, prevents the mixed temperature of heat in production process Out of control and material is burnt out;
It is 3rd step, cold mixed:It is cold it is mixed be sufficiently to cool down high-temperature material, avoid high density polyethylene (HDPE) material because for a long time compared with Decomposed in the environment of high-temperature, so that during tube forming, the materials degree of plasticification heterogeneity of batch mixing, production each time is not easy steady It is fixed;Simultaneously cold be mixed with helps to prevent material conglomeration, improves blanking, steady extruding amount, general cold mixed temperature control at 38 DEG C or so, At this temperature, material can be deposited more than 24 hours, and putting material situation is good, and main frame torque ripple is small, and production is stable;
4th step, extrusion:Extrusion is the core procedure of the shaping of plastic pipe;The hardcore of extrusion molding is extrusion Machine, and " heart " of extruder is screw rod and machine barrel, whether screw rod and the fine or not and supporting of machine barrel quality can rationally directly affect To the plasticizing capacity of board, so, for different extrusion equipments, unified formula should not be used, that is, being formulated design should be according to machine The plasticizing capacity of platform and determine;Principle is that degree of plasticification control is advisable 70~75% or so, and the setting of temperature can adopt " saddle The setting scheme of type ", both temperature settings at machine head port mould are in " saddle-shape " square cloth from machine barrel to merging core, then from merging core, Using this setting, thermograde is larger, and melt pressure is big, and product is more closely knit after shaping, and impact strength, hydraulic pressure resistant intensity are high. It is noted that main frame electric current will be controlled 50~60% or so in process of production, and it is unsuitable too high or too low, otherwise can shadow Ring and become apparent under main frame vacuum, particularly fuselage screw rod abrasion more serious situation, in addition can also cause to plastify Excessively or plasticizing is bad;
5th step, sizing, cooling:High density polyethylene (HDPE) Vacuum shaping cooler is used for the sizing of section bar, cooling, and vacuum is fixed Vacuum system and water circulation system for sizing and cooling is housed on type cooler, stainless steel casing, circulates water ring immersion cooling, Equipped with movable device and left and right, high high adjustment hand gear on Vacuum shaping cooler;
6th step, tubing traction:Hauling machine be used for it is continuous, automatically will cool down the section bar being hardened and drawn at head Come, frequency control;
7th step, cutting:After travel switch length control as requested, surface trimming, and the translation frame that is delayed are carried out, is carried out Production line, cutting machine complete cutting overall process using fixed length work switching signal as instruction, run and protect with section bar in cutting process Synchronization is held, cutting process is completed by electrical and pneumatic driving, and cutting machine is provided with dust exhaust apparatus, chip caused by cutting is inhaled in time Go out and reclaim;
8th step, stack:The action of tilting trestle stirring is realized that tilting trestle is spacing provided with one by cylinder by gas circuit control Device, after saw cutting section bar is cut, section bar continues to convey, and after delay, cylinder enters work, realizes that stirring acts, reaches Discharging purpose, automatically reset after discharging through the several seconds that is delayed, wait subsequent cycle.
The embodiment of the present invention is described above, but the present invention is not limited to above description.For this For the technical staff in field, any equal modification and replacement to the technical program is all within the scope of the invention.Cause This, the impartial conversion made without departing from the spirit and scope of the invention and modification, should all cover in the scope of the present invention.

Claims (3)

  1. A kind of 1. HDPE steel band reinforced spiral ripple pipes, it is characterised in that:Include the raw material of following parts by weight:
    High density polyethylene (HDPE) 50-70 parts;
    High-modulus PP 20-28 parts;
    Attapulgite 4-7 parts;
    HDPE increases firm master batch 25-30 parts;
    HDPE plasticizing mother particle 26-29 parts;
    Polyester modification acrylic resin 5-8 parts;
    Silicone modified acryl's resin 2-4 parts;
    ABS high glue powder 4-7 parts;
    Acrylic ester impact-resisting modifier ACR 1-4 parts;
    Color masterbatch 5-8 parts.
  2. A kind of 2. HDPE steel band reinforced spiral ripple pipes according to claim 1, it is characterised in that:By above-mentioned raw materials according to Formula rate is mixed, and removes the moisture in raw material, makes high density polyethylene materials semigel, is formed loose powder, is made Auxiliary agent is dispersed in high density polyethylene materials, and wherein mixture temperature is:Mixed 80~120 DEG C of the temperature of heat, cold mixed temperature 70 ~80 DEG C.
  3. A kind of 3. production technology of HDPE steel band reinforced spiral ripple pipes, it is characterised in that:Comprise the following steps:
    The first step, raw material mixing:By other auxiliary materials such as high density polyethylene materials, color masterbatch, stabilizer, lubricant proportionally Successively being added with technique in dry mixed machine, remove moisture removal, material enters the hopper of extruder after fully drying, mix, Wherein dry temperature is less than 70 degree;
    Second step, heat are mixed:The mixed purpose of heat is that each component in material is sufficiently collided in the presence of blade, is rubbed, convection current, Each component is reached farthest scattered, and material is heated up, reach preplasticizing, the mixed temperature general control of heat is on 95 DEG C of left sides The right side, it is noted that the accuracy of hot mixing, the mixed temperature accuracy of Timing measurement heat in production process, prevent the mixed temperature control of heat and Material is burnt out;
    It is 3rd step, cold mixed:Cold mix is sufficiently to cool down high-temperature material, avoids high density polyethylene (HDPE) material because for a long time in higher temperatures Decomposed in the environment of degree, so that during tube forming, the materials degree of plasticification heterogeneity of batch mixing, production each time is not easy stabilization;Together Shi Leng, which is mixed with, to help prevent material conglomeration, improves blanking, steady extruding amount, general cold mixed temperature control is at 38 DEG C or so, herein At a temperature of, material can be deposited more than 24 hours, and putting material situation is good, and main frame torque ripple is small, and production is stable;
    4th step, extrusion:Extrusion is the core procedure of the shaping of plastic pipe;The hardcore of extrusion molding is extruder, and " heart " of extruder is screw rod and machine barrel, and whether screw rod and the fine or not and supporting of machine barrel quality can rationally directly influence board Plasticizing capacity, so, for different extrusion equipments, unified formula should not be used, i.e. formula design should be according to the modeling of board Change ability and determine;Principle is that degree of plasticification control is advisable 70~75% or so, and the setting of temperature can be adopted " saddle-shape " Setting scheme, both temperature settings at machine head port mould are in " saddle-shape " square cloth from machine barrel to merging core, then from merging core, using this Kind setting, thermograde is larger, and melt pressure is big, and product is more closely knit after shaping, and impact strength, hydraulic pressure resistant intensity are high.It is worth one It is mentioned that, main frame electric current will be controlled 50~60% or so in process of production, unsuitable too high or too low, otherwise can influence main frame The abrasion of vacuum, particularly fuselage screw rod is more become apparent under serious situation, in addition can also cause plasticizing excessively or Plastify bad;
    5th step, sizing, cooling:High density polyethylene (HDPE) Vacuum shaping cooler is used for the sizing of section bar, cooling, and Vacuum shaping is cold Vacuum system and water circulation system for sizing and cooling, stainless steel casing, circulation water ring immersion cooling, vacuum are but housed on machine Equipped with movable device and left and right, high high adjustment hand gear on sizing cooler;
    6th step, tubing traction:Hauling machine be used for it is continuous, automatically will cool down the section bar being hardened and extracted at head, become Frequency modulation speed;
    7th step, cutting:After travel switch length control as requested, surface trimming, and the translation frame that is delayed are carried out, carries out flowing water Production, cutting machine complete cutting overall process using fixed length work switching signal as instruction, keep same with section bar operation in cutting process Step, cutting process are completed by electrical and pneumatic driving, and cutting machine is provided with dust exhaust apparatus, and chip caused by cutting is suctioned out simultaneously in time Recovery;
    8th step, stack:The action of tilting trestle stirring is realized that tilting trestle is provided with a spacing dress by cylinder by gas circuit control Put, after saw cutting section bar is cut, section bar continues to convey, and after delay, cylinder enters work, realizes that stirring acts, reaches and unload Expect purpose, automatically reset after discharging through the several seconds that is delayed, wait subsequent cycle.
CN201610307711.2A 2016-05-06 2016-05-06 A kind of HDPE steel band reinforced spiral ripple pipes and its production technology Pending CN107345016A (en)

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CN201610307711.2A CN107345016A (en) 2016-05-06 2016-05-06 A kind of HDPE steel band reinforced spiral ripple pipes and its production technology

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109824956A (en) * 2019-01-22 2019-05-31 长沙天卓塑胶有限公司 A kind of formula and its preparation process of HDPE ribbon spiral bellows bell and spigot
CN111559062A (en) * 2020-05-12 2020-08-21 贵州力强科技发展有限公司 Production process of omega-shaped hard semicircular drain pipe

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN102786730A (en) * 2012-08-07 2012-11-21 安徽国通高新管业股份有限公司 HDPE (high-density polyethylene) double-wall corrugated pipe with high ring stiffness
CN104987618A (en) * 2015-07-06 2015-10-21 江苏圣通环境工程有限公司 Mining PVC three-layer composite pipe and production technology thereof
CN104987619A (en) * 2015-07-06 2015-10-21 江苏圣通环境工程有限公司 PVC-U environment-friendly water supply pipe and machining process thereof

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN102786730A (en) * 2012-08-07 2012-11-21 安徽国通高新管业股份有限公司 HDPE (high-density polyethylene) double-wall corrugated pipe with high ring stiffness
CN104987618A (en) * 2015-07-06 2015-10-21 江苏圣通环境工程有限公司 Mining PVC three-layer composite pipe and production technology thereof
CN104987619A (en) * 2015-07-06 2015-10-21 江苏圣通环境工程有限公司 PVC-U environment-friendly water supply pipe and machining process thereof

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Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109824956A (en) * 2019-01-22 2019-05-31 长沙天卓塑胶有限公司 A kind of formula and its preparation process of HDPE ribbon spiral bellows bell and spigot
CN111559062A (en) * 2020-05-12 2020-08-21 贵州力强科技发展有限公司 Production process of omega-shaped hard semicircular drain pipe

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