CN104371167B - A kind of enhancing HDPE double-wall corrugated pipe and preparation method thereof - Google Patents

A kind of enhancing HDPE double-wall corrugated pipe and preparation method thereof Download PDF

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CN104371167B
CN104371167B CN201410615158.XA CN201410615158A CN104371167B CN 104371167 B CN104371167 B CN 104371167B CN 201410615158 A CN201410615158 A CN 201410615158A CN 104371167 B CN104371167 B CN 104371167B
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corrugated pipe
wall corrugated
hdpe double
wood powder
diene rubber
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CN104371167A (en
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代营伟
李锦松
代卫东
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HENAN LIANSU INDUSTRIAL Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to a kind of enhancing HDPE double-wall corrugated pipe and preparation method thereof, the formula of described enhancing HDPE double-wall corrugated pipe is made up of the raw material of following weight parts: high density polyethylene (HDPE) 100 parts, wood powder 40~60 parts, titanate coupling agent 1~3 parts, ethylene propylene diene rubber 7~9 parts, wherein, and the mesh number of described wood powder is 80~110 mesh;The Mooney point of described ethylene propylene diene rubber is 70~90, and its ethylene, propylene is than being (55:45)~(65:35);The enhancing HDPE double-wall corrugated pipe that the present invention prepares has preferable low-temperature impact toughness, good rigidly, ring stiffness is high, creep resisting ability is excellent, has relatively low cost simultaneously, has broad application prospects.

Description

A kind of enhancing HDPE double-wall corrugated pipe and preparation method thereof
Technical field
The present invention relates to plastic pipe technical field, be specifically related to a kind of enhancing HDPE double-wall corrugated pipe and preparation side thereof Method.
Background technology
Along with the rapid growth that Chinese national economy is continual and steady, provide good macroscopic view for cities and towns infrastructure construction Environment and broad space.Along with China is for the pay attention to day by day of environmental protection, governments at all levels of both the central and local governments have put into effect one and have been Row water saving, the policies and regulations of pollution treatment protection environment.Supply water, water saving, draining and waste water control will become urban municipal construction from now on Emphasis, this is that the popularization and application of heavy-caliber plastic pipe provide market development space.Due to structured wall popes can with conservation, Reducing cost, therefore structured wall popes has become as the main product of heavy caliber draining blow-off line.China is used for draining and blowdown The U-PVC double-wall corrugated pipe of pipeline has good rigidity, the advantages such as price is low;But the shortcoming also having low temperature impact properties difference, especially Breakage it is very easy to when north of china in winter is constructed.And HDPE double-wall corrugated pipe has obvious advantage in low-temperature flexibility, but due to PE material behavior, its rigidity relatively pipe of cement is poor, and the ring stiffness of tubing and creep resisting ability relatively PVC bellows is poor, at Long-Time Service During, easily by gravity deformation, affect product service life.
Prior art seldom relates to have low-temperature flexibility, rigidity, ring stiffness and creep resisting ability simultaneously the most preferable Strengthen HDPE double-wall corrugated pipe;Therefore, exploitation one strengthens HDPE double-wall corrugated pipe, has great significance.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of enhancing HDPE double-wall corrugated pipe and preparation thereof Method, this enhancing HDPE double-wall corrugated pipe has preferable low-temperature impact toughness, good rigidly, ring stiffness is high, creep resisting ability is excellent Different, there is relatively low cost simultaneously, have broad application prospects.
It is an object of the invention to be achieved by following technical solution:
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
High density polyethylene (HDPE) 100 parts;
Wood powder 40~60 parts;
Titanate coupling agent 1~3 parts;
Ethylene propylene diene rubber 7~9 parts;
Wherein, the mesh number of described wood powder is 80~110 mesh;The Mooney point of described ethylene propylene diene rubber is 70~90, ethene Propylene is than being (55:45)~(65:35);
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Two-stage assembled pulse air-flow is i.e. used to be dried described wood powder employing dedicated drying production line, detailed process For: dry 1~3 hour at 120~180 DEG C so that it is moisture is less than 300mg/kg, mix with titanate coupling agent after being cooled to normal temperature Close, be heated to 60~70 DEG C, dispersed with stirring 5~7 minutes under 800~1100 revs/min of speed, it is subsequently adding ethylene-propylene-diene monomer Glue, cools down after stirring automatically;Then above-mentioned compound is mixed with high density polyethylene (HDPE), be then sent to extrusion Machine, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
In the present invention, have that yield is big but baking temperature can not be the highest, baking temperature mistake owing to wood powder is dried Height is the most on fire, uses traditional drying equipment to be difficult to meet the big requirement produced.Therefore the wood powder in the present invention is dried employing Special drying production line, i.e. uses two-stage assembled pulse pneumatic conveying drying.When dry, wet wood powder is entered continuously by feeder Enter in the drying tube of first order pulsed pneumatic dryer lower end.In drying tube, wood powder is broken up by high velocity, hot air and upwards moves Dynamic, material contacts fully with air-flow, and moisture is by rapid evaporation.Wood powder by after drying tube by cyclone collection, then enter Enter second level pulsed pneumatic dryer, be again dried, effectively extend the drying time of material and achieve well Effect.
Inventor finds in experimentation, and the mesh number of wood powder is to the low-temperature flexibility of tubing, rigidity, ring stiffness and anti-compacted Become capacity bigger;Wood mesh is less, and surface roughness is high, short texture, owing to high density polyethylene (HDPE) is nonpolar, and Wood powder is polarity, both poor compatibility, and high density polyethylene (HDPE) melt is difficult in wood powder infiltration, easily forms sky around wood powder Hole defect;And when wood mesh is excessive, wood powder particle diameter is little, easily reuniting, these defects form stress and concentrate, in less effect Under, be easily broken off, and the wood powder of 80~110 mesh, moderate in grain size, good with high density polyethylene (HDPE) compatibility, now impact strength and Bending strength is best.
It is further preferred that the mesh number of described wood powder is 100 mesh.
Preferably, described high density polyethylene (HDPE) is polyethylene PN049.
Inventor finds when adding the ethylene propylene diene rubber of relatively high Mooney, can significantly improve the hot strength of tubing And tearing strength, and in the molten state, it is possible to preferably mix with filler;It addition, ethene is different with the ratio of propylene, right Pipe performance also has certain impact, and when propane ratio is too high, the hot strength of tubing is higher, but low-temperature characteristics is poor, and third When alkene ratio is higher, benefit is exactly more preferable processing characteristics, more preferable low-temperature characteristics and preferably compressive deformation etc., but stretching Intensity is relatively low.Considering, the Mooney point of ethylene propylene diene rubber that the present invention uses is 70~90, ethylene, propylene than for (55: 45)~(65:35);It is further preferred that the Mooney point of described ethylene propylene diene rubber is 90 Mooneys (ML1 ± 4 125 °), ethene Propylene is than for 60:40.
Compared with prior art, there is advantages that the HDPE double-wall corrugated pipe that the present invention prepares In low-temperature flexibility, not only there is obvious advantage, the content of EPDM, its Mooney point and selection EPDM in being filled a prescription by regulation simultaneously In ethylene, propylene ratio, and the good rigidly of HDPE double-wall corrugated pipe for preparing of the selection etc. of wood mesh, ring stiffness are high, Creep resisting ability is strong, during Long-Time Service, because of gravity deformation, thus will not extend the service life of product;Produce simultaneously Low cost, has broad application prospects.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.These embodiments are only that the typical case to the present invention retouches State, but the invention is not restricted to this.Test method used in following embodiment if no special instructions, is conventional method, is made Raw material, reagent etc., if no special instructions, be the raw material and reagent that can obtain from commercial sources such as conventional markets.
Embodiment 1
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 40 parts;
Titanate coupling agent 1 part;
Ethylene propylene diene rubber 7 parts;
Wherein, the mesh number of described wood powder is 80 mesh;The Mooney point of described ethylene propylene diene rubber is 70, and ethylene, propylene ratio is 57:43;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 3 hours at 120 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 60 DEG C, under 1100 revs/min of speed, dispersed with stirring 7 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Embodiment 2
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
High density polyethylene (HDPE) 100 parts;
Wood powder 50 parts;
Titanate coupling agent 2 parts;
Ethylene propylene diene rubber 8 parts;
Wherein, the mesh number of described wood powder is 100 mesh;The Mooney point of described ethylene propylene diene rubber is 80, and ethylene, propylene ratio is 60:40;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 1 hour at 180 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 70 DEG C, under 800 revs/min of speed, dispersed with stirring 5 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Embodiment 3
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 60 parts;
Titanate coupling agent 3 parts;
Ethylene propylene diene rubber 9 parts;
Wherein, the mesh number of described wood powder is 110 mesh;The Mooney point of described ethylene propylene diene rubber is 90, and ethylene, propylene ratio is 61:39;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 2 hours at 160 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 65 DEG C, under 1000 revs/min of speed, dispersed with stirring 6 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Reference examples 1
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 20 parts;
Titanate coupling agent 1 part;
Ethylene propylene diene rubber 7 parts;
Wherein, the mesh number of described wood powder is 100 mesh;The Mooney point of described ethylene propylene diene rubber is 70, and ethylene, propylene ratio is 57:43;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 3 hours at 120 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 60 DEG C, under 1100 revs/min of speed, dispersed with stirring 7 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Reference examples 2
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 40 parts;
Titanate coupling agent 1 part;
Ethylene propylene diene rubber 7 parts;
Wherein, the mesh number of described wood powder is 20 mesh;The Mooney point of described ethylene propylene diene rubber is 70, and ethylene, propylene ratio is 57:43;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 3 hours at 120 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 60 DEG C, under 1100 revs/min of speed, dispersed with stirring 7 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Reference examples 3
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 40 parts;
Titanate coupling agent 1 part;
Ethylene propylene diene rubber 7 parts;
Wherein, the mesh number of described wood powder is 300 mesh;The Mooney point of described ethylene propylene diene rubber is 70, and ethylene, propylene ratio is 57:43;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 3 hours at 120 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 60 DEG C, under 1100 revs/min of speed, dispersed with stirring 7 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Reference examples 4
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 40 parts;
Titanate coupling agent 1 part;
Ethylene propylene diene rubber 7 parts;
Wherein, the mesh number of described wood powder is 100 mesh;The Mooney point of described ethylene propylene diene rubber is 25, and ethylene, propylene ratio is 75:25;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 3 hours at 120 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 60 DEG C, under 1100 revs/min of speed, dispersed with stirring 7 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Reference examples 5
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 40 parts;
Titanate coupling agent 1 part;
Ethylene propylene diene rubber 7 parts;
Wherein, the mesh number of described wood powder is 100 mesh;The Mooney point of described ethylene propylene diene rubber is 130, and ethylene, propylene ratio is 67:28;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Dedicated drying production line is used to dry 3 hours at 120 DEG C described wood powder so that it is moisture is less than 300mg/kg, cold But mixing with titanate coupling agent to normal temperature, be heated to 60 DEG C, under 1100 revs/min of speed, dispersed with stirring 7 minutes, then add Enter ethylene propylene diene rubber, automatically cool down after stirring;Then above-mentioned compound is mixed with polyethylene PN049, then Being delivered to extruder, plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Reference examples 6
A kind of enhancing HDPE double-wall corrugated pipe, the formula of described HDPE double-wall corrugated pipe is by the raw material group of following weight parts Become:
Polyethylene PN049 100 parts;
Wood powder 40 parts;
Titanate coupling agent 1 part;
Ethylene propylene diene rubber 7 parts;
Wherein, the mesh number of described wood powder is 100 mesh;The Mooney point of described ethylene propylene diene rubber is 70, and ethylene, propylene ratio is 57:43;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Described wood powder uses dedicated drying production line to dry 1 hour at 120 DEG C so that it is moisture is less than 300mg/kg, cooling Stir with polyethylene PN049 with titanate coupling agent, ethylene propylene diene rubber to normal temperature, be then sent to extruder, mould Change extrusion, mould molding i.e. obtains product.
Embodiment 1~3 and reference examples 1~6 preparation obtained by the performance of enhancing HDPE double-wall corrugated pipe as shown in table 1:
As shown in Table 1, the present invention is by selecting high density polyethylene (HDPE), wood powder, titanate coupling agent, ethylene propylene diene rubber four Kind of component and regulate the enhancing HDPE double-wall corrugated pipe that the content of each component prepares with raw material and not only have good Low-temperature impact toughness, simultaneously by making the restriction of the Mooney point of ethylene propylene diene rubber and ethylene, propylene ratio to prepare The good rigidly of HDPE double-wall corrugated pipe, ring stiffness are high, creep resisting ability strong, during Long-Time Service, will not because of gravity deformation, Thus extend the service life of product;Production cost is low simultaneously, has broad application prospects.By contrast, each reference examples system The standby rigidity of tubing, ring stiffness and the creep resisting ability obtained is all notable not as good as the present invention.

Claims (3)

1. one kind strengthens HDPE double-wall corrugated pipe, it is characterised in that the formula of described HDPE double-wall corrugated pipe is by following weight parts Raw material composition:
Wherein, the mesh number of described wood powder is 80~110 mesh;The Mooney point of described ethylene propylene diene rubber is 70~90, ethylene, propylene Than being (55:45)~(65:35);Described high density polyethylene (HDPE) is polyethylene PN049;
The preparation method of described HDPE double-wall corrugated pipe comprises the steps:
Described wood powder is used two-stage assembled pulse pneumatic conveying drying, dries 1~3 hour at 120~180 DEG C so that it is moisture is less than 300mg/kg, mixes with titanate coupling agent after being cooled to normal temperature, is heated to 60~70 DEG C, under 800~1100 revs/min of speed Dispersed with stirring 5~7 minutes, be subsequently adding ethylene propylene diene rubber, automatically cool down after stirring;Then by above-mentioned compound with high Density polyethylene mixes, and is then sent to extruder, and plasticizing extrusion, mould molding i.e. obtain enhancing HDPE double-wall corrugated pipe.
Enhancing HDPE double-wall corrugated pipe the most according to claim 1, it is characterised in that the mesh number of described wood powder is 100 mesh.
Enhancing HDPE double-wall corrugated pipe the most according to claim 1, it is characterised in that the Mooney of described ethylene propylene diene rubber Value is 90, and ethylene, propylene is than for 60:40.
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CN105906899A (en) * 2016-04-28 2016-08-31 安徽扬天塑业科技有限公司 Silane cross-linked polyethylene insulation material
CN107629338B (en) * 2017-10-18 2020-09-29 浙江德首新型建材有限公司 Low-temperature impact-resistant pipe and preparation method thereof
CN111016116A (en) * 2019-12-27 2020-04-17 安徽杰蓝特新材料有限公司 High-strength ultramicro glass fiber cotton reinforced HDPE double-wall corrugated pipe
CN113201182A (en) * 2021-05-26 2021-08-03 安徽杰蓝特新材料有限公司 Heat-resistant reinforced HDPE double-wall corrugated pipe

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