CN107286703B - A kind of high solarization dispersed black dye mixture and its application - Google Patents

A kind of high solarization dispersed black dye mixture and its application Download PDF

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CN107286703B
CN107286703B CN201710387589.9A CN201710387589A CN107286703B CN 107286703 B CN107286703 B CN 107286703B CN 201710387589 A CN201710387589 A CN 201710387589A CN 107286703 B CN107286703 B CN 107286703B
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dyestuff
formula
parts
fastness
independently selected
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CN107286703A (en
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邵辉
叶绪兵
陈美芬
孙岩峰
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Hangzhou Jihua Jiangdong Chemical Co Ltd
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Hangzhou Jihua Jiangdong Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046—Mixtures of two or more azo dyes
    • C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046—Mixtures of two or more azo dyes
    • C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
    • C09B67/0052—Mixtures of two or more reactive monoazo dyes
    • C09B67/0054—Mixtures of two or more reactive monoazo dyes all the reactive groups not being directly attached to a heterocyclic system
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0079—Azoic dyestuff preparations
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/008—Preparations of disperse dyes or solvent dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D06P1/18—Azo dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D06P1/19—Nitro dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D06P1/20—Anthraquinone dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Coloring (AREA)

Abstract

The present invention relates to technical field of dye, it is washable to solve common high solarization disperse dyes, the problem of fastness to rubbing cannot be taken into account, the present invention proposes a kind of high solarization dispersed black dye mixture, is mixed by 5-45 parts of dyestuff A, 3-35 parts of dyestuff B, 3-30 parts of dyestuff C, 1-10 parts of dyestuff D, dyestuff E 1-10 five kinds of components of part.Admixture of disperse dyes and its product of the invention increases the coverage rate to fabric in dyeing course, further increase the performance in terms of sunlight fastness and lifting force, this product not only has good fastness to washing, and there is brilliant fastness to rubbing, sunlight fastness, homogenized diet and lifting force index.

Description

A kind of high solarization dispersed black dye mixture and its application
Technical field
The present invention relates to technical field of dye, and it is black to relate in particular to a kind of high solarization dispersion for Car-use Fabric The mixture and product of dyestuff.
Background technique
Whether ahthraquinone disperse dye or azoic dye, heterocyclic type disperse dyes cannot all meet excellent simultaneously Sunlight fastness and washable, fastness to rubbing.However, with the increasingly raising of people's quality of life, based on market to automobile Interior trim fabric, high-grade gym suit, anorak, army's camouflage are growing with fabric demand, thus it requires there is kind of a disperse dyes It can satisfy the requirement of its high fastness to light, high crock fastness performance.For this purpose, developing a kind of sun-resistant, the dispersion dye of rub resistance Material becomes the task of top priority.
Application No. is 201210193829.9 Chinese patents to disclose a kind of admixture of disperse dyes and its application, described Admixture of disperse dyes can be applied to the dyeing of automobile inner ornament, but jewelry dyeing pair can't be fully met in superior automobile The demand of light fastness.Due to lacking low form constituent dye in the patent mixture, the even of disperse dyes cannot be thoroughly solved Metachromia problem is easy to appear uneven dyeing phenomenon, and lifting force also only reaches good level, while common high solarization disperse dyes are also There are the problem of washable, fastness to rubbing cannot be taken into account, and present specification has carried out excellent on the basis of the patent formulation thus Change, improve, not only solves the shortcoming in above-mentioned patented product, while improving the light fastness of dyestuff commodity.
Summary of the invention
To solve the problem of that the common high washable fastness to rubbing of solarization disperse dyes cannot be taken into account, the present invention proposes one kind High solarization dispersed black dye mixture, admixture of disperse dyes of the invention and its product increase in dyeing course to fabric Coverage rate, further increase the performance in terms of sunlight fastness and lifting force, this product not only has good fastness to washing, And there is brilliant fastness to rubbing, sunlight fastness, homogenized diet and lifting force index.
The present invention is achieved by the following technical solutions: a kind of high solarization dispersed black dye mixture, in parts by weight, By five kinds of A5-45 parts of dyestuff, 3-35 parts of dyestuff B, 3-30 parts of dyestuff C, 1-10 parts of dyestuff D, dyestuff E1-10 part component mixing It is made.
The structural formula of the dyestuff A is such as shown in (I):
In formula (I), X1, X2It is respectively and independently selected from halogen, a kind of, halogen preferably-Cl or-Br in hydrogen ,-CN；R1It is selected from H, a kind of in the alkyl or acrylic of C1-C4.Preferably, R1Selected from hydrogen, methyl or ethyl.
Preferably, dyestuff A is selected from one or more of the dyestuff with following general formula:
The structural formula of the dyestuff B is such as shown in (II):
In formula (II): R2, R3, R4It is respectively and independently selected from-OH ,-NH2、-NO2Middle one kind, R5Alkyl selected from-H or C1-C4, Preferably, R5Selected from-H and-CH2CH2OH。
Preferably, dyestuff B is selected from one or more of the dyestuff with following general formula:
The structural formula of the dyestuff C is as shown in (III):
In formula (III), R6, R7, R8, R9It is respectively and independently selected from-OH ,-NH2Middle one kind, X3For halogen, preferably, X3Choosing From-Br.
Two kind (III-a and III-b combinations) or (III-c and III-d of the dyestuff C in the dyestuff with following general formula Combination), preferably III-a and III-b combination, wherein 1 ' 5- dihydroxy structural material and 1 ' 8- dihydroxy structural material according to Mass ratio 30~85: 70~15 is used in mixed way:
The structural formula of the dyestuff D is such as shown in (IV):
In formula (IV), R10, R11It is respectively and independently selected from-OH ,-NH2Middle one kind；R12Selected from-H ,-CH3、-OCH3、-OC2H5、- OC6H5、-OC6H12OH、One of-NHCOC1-C4 amide groups, wherein R13, R14It is respectively and independently selected from the alkyl of C1-C4 a kind of.Preferably, R12Selected from-OC6H5, R13Alkyl selected from C1-C3, R14Alkyl selected from C1-C2；
Dyestuff D is selected from one or more of the dyestuff with following general formula:
The structural formula of the dyestuff E is such as shown in (V):
In formula (V): X4, X5It is respectively and independently selected from-H ,-Br ,-Cl, a kind of in-CN, halogen preferably-Cl ,-Br；R15, R16- It is respectively and independently selected from C1-C4 alkyl ,-CH2CH2CN、-CH2CH=CH2、-C2H4OC2H4OC2H5、-CH2C6H5Middle one kind, R17For- NHCO- (C1-C4) alkyl amide, preferably, R17For-NHCOCH3。
Preferably, dyestuff E is selected from one or more of the dyestuff with following general formula:
A kind of application of the high solarization dispersed black dye mixture on Car-use Fabric.Car-use Fabric choosing From hydrophobic fiber material.Preferably, hydrophobic fiber material is selected from terylene, vinegar fibre, eyeball synthetic fibre, poly-vinegar or blended.
Auxiliary agent, including dispersing agent, diffusant etc. can be added during commercialization of dyes.Dispersion dye according to the present invention It can also be mixed with a certain amount of auxiliary agent in material mixture, obtain corresponding dye preparations, auxiliary agent described above includes naphthalene sulfonic acids first The compound of one or more of aldehyde condensate, alkyl naphthalene formaldehyde sulfonic acid condensation object, lignosulfonates；Wherein diffusant NNO is naphthalene sulfonic acid-formaldehyde condensation product diffusant；Dispersant MF and dispersing agent CNF etc. are alkyl naphthalene formaldehyde sulfonic acid condensation object；It is commercially available Dispersing agent Reax 85A etc. be lignosulfonates.Auxiliary agent can be used alone, and two or more can also mix It uses.The gross mass of admixture of disperse dyes and the mass ratio of auxiliary agent are 1: 0.01~4, preferably, mass ratio is 1: 0.03 ~0.8.
Due to can inevitably generate some impurity during Dyestuff synthesis, while also It is not necessary to obtain sterling dye Material, therefore dyestuff according to the present invention is the product containing a small amount of impurity.
A kind of specific preparation method of disperse dyes dye preparations of the invention can be used a kind of in following three kinds of methods:
(1) be added after mixing dyestuff A, dyestuff B, dyestuff C, dyestuff D and dyestuff E according to the above ratio quantitative auxiliary agent and Water, then micronized is carried out with pulverizers such as sand mill or grinders；
(2) dyestuff A, dyestuff B, dyestuff C, dyestuff D and dyestuff E are proportionally mixed with auxiliary agent and water respectively, then distinguished Micronized is carried out with pulverizers such as sand mill or grinders, finally again proportionally mixes each component；
(3) since commercially available single commercial dye has already passed through micronized and contains auxiliary agent, can directly according to Aforementioned proportion mixes commercial dye, remixes after can also adding auxiliary agent.
Grinding is preferably carried out in various grinders such as ball mill, bobbing machine, sand mill or in kneader.When grinding according to Routine needs to add moisture content, helps to grind, moisture content dosage is generally 18~100 milliliters of 10g dry product dye solution.After grinding, The granular size of dyestuff is preferably from about 0.1~10 micron, particularly preferably about 1 micron.Drying can be by being dried in vacuo, doing by spraying Dry, freeze-drying is dried in rotary drum dryer, preferably, being dehydrated by spray drying.
Compared with prior art, the beneficial effects of the present invention are:
(1) dye mixture of the invention is for showing excellent profit when processing printing and dyeing liquid and padding liquor and printing paste Moisture performance can disperse rapidly without excess agitation.Uniform system is presented in dye liquor and printing paste, in modern Dyeing process The problems such as plug nozzle will not be generated；
(2) there is fairly good light resistance, rub resistance, increase dyestuff in dyeing course to the coverage rate of fabric, it is even Metachromia more preferably, while also having excellent lifting force index.
Specific embodiment
Below by specific embodiment, invention is further described in detail, and required raw material is commercially available, or uses Well known method is synthesized, but the scope of the present invention is not limited to that.
Embodiment 1
By 15.0 grams of dyestuff A with general formula (I-a), 10.0 grams of dyestuff B with general formula (II-a) and 4.4 grams, which have, to be led to Formula (III-a) and 3.6 grams have general formula (III-b) structure (being denoted as III-ab), and totally 8.0 grams of dyestuff C and 1.7 grams have composition General formula (IV-a) and 1.7 grams of dyestuff D and 3.6 grams of dyestuff E with general formula (V-a) with general formula (IV-b), with 100.0 grams of water And 10.0 grams of sodium lignin sulfonates are ground 3 hours together in sand mill, be then spray-dried (130 DEG C of inlet temperature, 60 DEG C of outlet temperature) to get arrive admixture of disperse dyes 1.
Embodiment 2
Respectively the dyestuff A and 2.0 grams of dispersing agent MFs and 40.0g water by 14.0 grams containing general formula (I-c), 12.0 grams containing general formula (II-a) dyestuff B and 2.0 grams of dispersing agent MFs and 34.0g water, containing 6 grams of general formula (III-a) and containing 4 grams of general formula (III-b) altogether 10.0 grams of dyestuff C and 0.5 gram of dispersing agent MF and 10.0g water, 2.3 grams of dyestuff D and 0.3 gram of dispersing agent MF containing general formula (IV-b) It is mixed with 0.2 gram of dispersing agent MF and 8.0g water with 8.0g water, 1.7 grams of dyestuff E containing general formula (V-b), then carries out grinding spray It is dry, finally five kinds of dyestuffs are mixed up to admixture of disperse dyes 2 again.
Embodiment 3
Dyestuff B by 16.5 grams of dyestuff A with general formula (I-b), 13.0 grams with general formula (II-d), 7.0 grams have it is logical The dyestuff C of formula (III-cd), 1.5 grams of dyestuff D with general formula (IV-e), 2.0 grams of dyestuff E with general formula (V-j), 4.0 grams Dispersing agent MF and 100.0g water are ground 3 hours together in sand mill, be then spray-dried (130 DEG C of inlet temperature, outlet Temperature 60 C) to get admixture of disperse dyes 3.
Embodiment 4
By the commercial dye A containing 13.0 grams of general formulas (I-d), the commercial dye B containing 10.0 grams of general formulas (II-e), contain The commercial dye C of 10.0 grams of general formulas (III-cd), the commercial dye D containing 3.5 grams of general formulas (IV-d) and contain 3.5 grams of general formulas (V-g) commercial dye E is mixed, then directly obtains the admixture of disperse dyes 4.
Embodiment 5~16
According to embodiment 2, the preparation method of embodiment 3 or 4, by continuous data shown in table 1 by the dyestuff containing logical formula (I) A, the dyestuff B containing logical formula (II), the dyestuff C containing logical formula (III), the dyestuff D containing logical formula (IV) and the dyestuff E containing logical formula (V) with Auxiliary agent mixing, is made admixture of disperse dyes 4~15 of the present invention.
Table 1: for embodiment 5-16
Test case
The admixture of disperse dyes for taking 1 gram of each embodiment is dispersed in 1000 milliliters of water.Above-mentioned solution is taken out 40 milliliters Mixed with 160 milliliters of water, then high temperature and pressure dye model machine in 5.0 grams of hyperfine polyester fibers, under the conditions of pH value 4~4.5, It is dyed 60 minutes in 130 DEG C.
Using national standard GB/T3921-2008, GB/T3920-2008, GB/T8427-2008, GB/T/2397-2012, test Its washing fastness, crock fastness, light fastness and lifting force.Test result is as shown in table 2.
Table 2: for the test result of embodiment.
Embodiment Washing fastness Crock fastness Light fastness Lifting force
Embodiment 1 5 5 6-7 It is excellent
Embodiment 2 5 5 6 It is excellent
Embodiment 3 4-5 5 6 It is excellent
Embodiment 4 5 5 6 It is excellent
Embodiment 5 5 5 6 It is excellent
Embodiment 6 5 5 6-7 It is excellent
Embodiment 7 5 5 6 It is excellent
Embodiment 8 4-5 5 6 It is excellent
Embodiment 9 5 4-5 6 It is excellent
Embodiment 10 5 5 6-7 It is excellent
Embodiment 11 5 5 6 It is excellent
Embodiment 12 5 5 6-7 It is excellent
Embodiment 13 4-5 5 6-7 It is excellent
Embodiment 14 5 5 6 It is excellent
Embodiment 15 5 5 6-7 It is excellent
Embodiment 16 5 5 6-7 It is excellent
2 data of table are shown: the mixture of the heretofore described high solarization dispersed black dye for Car-use Fabric, no Only there is superior washing fastness and crock fastness, and there is brilliant light fastness, all have good homogenized diet and Excellent lifting force index, dye sample meet the index requests such as fastness.

Claims (4)

1. a kind of high solarization dispersed black dye mixture, which is characterized in that the dispersed black dye mixture, with parts by weight Meter, is mixed by A5-45 parts of dyestuff, 3-35 parts of dyestuff B, 3-30 parts of dyestuff C, 1-10 parts of dyestuff D, dyestuff E1-10 five kinds of components of part Conjunction is made；
The structural formula of the dyestuff A is such as shown in (I):
In formula (I), X1, X2It is respectively and independently selected from halogen, a kind of, R in hydrogen ,-CN1One in alkyl or acrylic selected from H, C1-C4 Kind；
The structural formula of the dyestuff B is such as shown in (II):
In formula (II): R2, R3, R4It is respectively and independently selected from-OH ,-NH2、-NO2Middle one kind, R5Alkyl selected from-H or C1-C4；
The structural formula of the dyestuff C is as shown in (III), wherein 1 ' 5- dihydroxy structural material and 1 ' 8- dihydroxy in dyestuff C The mass ratio of structural material is 30~85: 70~15:
In formula (III), R6, R7, R8, R9It is respectively and independently selected from-OH ,-NH2Middle one kind, X3For halogen；
The structural formula of the dyestuff D is such as shown in (IV):
In formula (IV), R10, R11It is respectively and independently selected from-OH ,-NH2Middle one kind；R12Selected from-H ,-CH3、-OCH3、-OC2H5、- OC6H5、-OC6H12OH、One of-NHCOC1-C4 amide groups, Middle R13, R14It is respectively and independently selected from the alkyl of C1-C4 a kind of；
The structural formula of the dyestuff E is such as shown in (V):
In formula (V): X4, X5It is respectively and independently selected from-H ,-Br ,-Cl, a kind of in-CN, R15, R16It is respectively and independently selected from C1-C4 alkane Base ,-CH2CH2CN、-CH2CH=CH2、-C2H4OC2H4OC2H5、-CH2C6H5Middle one kind, R17For-NHCO-C1-C4 alkyl amide.
2. a kind of high solarization dispersed black dye mixture answering on Car-use Fabric a kind of as defined in claim 1 With.
3. a kind of application of high solarization dispersed black dye mixture according to claim 2, which is characterized in that automobile interior decoration Fabric is selected from hydrophobic fiber material.
4. a kind of application of high solarization dispersed black dye mixture according to claim 3, which is characterized in that hydrophobicity is fine It ties up material and is selected from terylene, vinegar fibre, acrylic fibers, blended.
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JPH04173874A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
JPH04173875A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
JPH04173871A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
JPH04173872A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
CN101309975A (en) * 2005-11-16 2008-11-19 纪和化学工业株式会社 Disperse die, disperse die composition, ink for ink-jet printing, and staining method and stained material using the die, composition or ink
CN102732056A (en) * 2012-06-01 2012-10-17 浙江吉华集团股份有限公司 Disperse dye mixture and application thereof
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JPH04164969A (en) * 1990-10-30 1992-06-10 Nippon Kayaku Co Ltd Disperse dye composition and method of dyeing hydrophobic fiber
JPH04173874A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
JPH04173875A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
JPH04173871A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
JPH04173872A (en) * 1990-11-07 1992-06-22 Nippon Kayaku Co Ltd Disperse dye composition and method for dyeing hydrophobic fiber
CN101309975A (en) * 2005-11-16 2008-11-19 纪和化学工业株式会社 Disperse die, disperse die composition, ink for ink-jet printing, and staining method and stained material using the die, composition or ink
CN102732056A (en) * 2012-06-01 2012-10-17 浙江吉华集团股份有限公司 Disperse dye mixture and application thereof
CN102775812A (en) * 2012-06-13 2012-11-14 浙江吉华集团股份有限公司 Disperse dye mixture and application thereof

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