CN107286703A - A kind of high Exposure to Sunlight dispersed black dye mixture and its application - Google Patents
A kind of high Exposure to Sunlight dispersed black dye mixture and its application Download PDFInfo
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- CN107286703A CN107286703A CN201710387589.9A CN201710387589A CN107286703A CN 107286703 A CN107286703 A CN 107286703A CN 201710387589 A CN201710387589 A CN 201710387589A CN 107286703 A CN107286703 A CN 107286703A
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- 0 **C=C(*)[C@@](C(C(*)=C)C(c1c2c(*)ccc1*)=O)C2=O Chemical compound **C=C(*)[C@@](C(C(*)=C)C(c1c2c(*)ccc1*)=O)C2=O 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
- C09B67/0052—Mixtures of two or more reactive monoazo dyes
- C09B67/0054—Mixtures of two or more reactive monoazo dyes all the reactive groups not being directly attached to a heterocyclic system
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0079—Azoic dyestuff preparations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/20—Anthraquinone dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The present invention relates to technical field of dye, it is washable to solve common high Exposure to Sunlight disperse dyes, the problem of fastness to rubbing can not be taken into account, the present invention proposes a kind of high Exposure to Sunlight dispersed black dye mixture, is mixed by 5 45 parts of dyestuff A, 3 35 parts of dyestuff B, 3 30 parts of dyestuff C, 1 10 parts of dyestuff D, dyestuff E 1 10 parts of five kinds of components.The admixture of disperse dyes and its product of the present invention adds the coverage rate to fabric in dyeing course, further improve the performance in terms of sunlight fastness and lifting force, this product not only has good fastness to washing, and with remarkable fastness to rubbing, sunlight fastness, homogenized diet and lifting force index.
Description
Technical field
The present invention relates to technical field of dye, relate in particular to a kind of high Exposure to Sunlight for Car-use Fabric and disperse black
The mixture and product of dyestuff.
Background technology
Whether ahthraquinone disperse dye or azoic dye, heterocyclic type disperse dyes, all can not meet excellent simultaneously
Sunlight fastness and washable, fastness to rubbing.However, with the increasingly raising of people's quality of life, based on market to automobile
Interior trim fabric, high-grade gym suit, anorak, army's camouflage are growing with fabric demand, thus it requires there is kind of a disperse dyes
It disclosure satisfy that its high fastness to light, the requirement of high crock fastness performance.Therefore, a kind of sun-resistant, scattered dye of rub resistance of exploitation
Material turns into the task of top priority.
The Chinese patent of Application No. 201210193829.9 discloses a kind of admixture of disperse dyes and its application, described
Admixture of disperse dyes can be applied to the dyeing of automobile inner ornament, but jewelry dyeing pair can't be fully met in superior automobile
The demand of light fastness.Due to lacking low form constituent dye in the patent mixture, it is impossible to thoroughly solve the even of disperse dyes
, easily there is uneven dyeing phenomenon in metachromia problem, and lifting force also only reaches good level, while common high Exposure to Sunlight disperse dyes are also
There is washable, the problem of fastness to rubbing can not be taken into account, it is excellent to be that this present specification has been carried out on the basis of the patent formulation
Change, improve, the weak point in above-mentioned patented product is not only solved, while improving the light fastness of dyestuff commodity.
The content of the invention
Washable to solve common high Exposure to Sunlight disperse dyes, the problem of fastness to rubbing can not be taken into account, the present invention proposes a kind of
High Exposure to Sunlight dispersed black dye mixture, admixture of disperse dyes and its product of the invention is added to fabric in dyeing course
Coverage rate, further improve the performance in terms of sunlight fastness and lifting force, this product not only has good fastness to washing,
And with remarkable fastness to rubbing, sunlight fastness, homogenized diet and lifting force index.
The present invention is achieved by the following technical solutions:A kind of high Exposure to Sunlight dispersed black dye mixture, in parts by weight,
By A5-45 parts of dyestuff, 3-35 parts of dyestuff B, 3-30 parts of dyestuff C, 1-10 parts of dyestuff D, the five kinds of component mixing of dyestuff E1-10 parts
It is made.
The structural formula of the dyestuff A is such as shown in (I):
In formula (I), X1, X2One kind in halogen, hydrogen ,-CN is respectively and independently selected from, halogen is preferably-Cl or-Br;R1It is selected from
It is a kind of in H, C1-C4 alkyl or acrylic.Preferably, R1Selected from hydrogen, methyl or ethyl.
Preferably, one or more of the dyestuff A in the dyestuff with below general formula:
The structural formula of the dyestuff B is such as shown in (II):
In formula (II):R2, R3, R4It is respectively and independently selected from-OH ,-NH2、-NO2Middle one kind, R5Alkyl selected from-H or C1-C4,
Preferably, R5Selected from-H and-CH2CH2OH。
Preferably, one or more of the dyestuff B in the dyestuff with below general formula:
The structural formula of the dyestuff C is as shown in (III):
In formula (III), R6, R7, R8, R9It is respectively and independently selected from-OH ,-NH2Middle one kind, X3For halogen, preferably, X3Choosing
From-Br.
Two kind (III-a and III-b combinations) or (III-c and III-d of the dyestuff C in the dyestuff with below general formula
Combination), preferably III-a and III-b combinations, wherein, 1 ' 5- dihydroxy structural material and 1 ' 8- dihydroxy structural material according to
Mass ratio 30~85: 70~15 is used in mixed way:
The structural formula of the dyestuff D is such as shown in (IV):
In formula (IV), R10, R11It is respectively and independently selected from-OH ,-NH2Middle one kind;R12Selected from-H ,-CH3、-OCH3、-OC2H5、-
OC6H5、-OC6H12OH、One kind in-NHCOC1-C4 amide groups, wherein
R13, R14It is respectively and independently selected from C1-C4 alkyl a kind of.Preferably, R12Selected from-OC6H5, R13Alkyl selected from C1-C3,
R14Alkyl selected from C1-C2;
One or more of the dyestuff D in the dyestuff with below general formula:
The structural formula of the dyestuff E is such as shown in (V):
In formula (V):X4, X5A kind of, halogen preferably-Cl ,-Br are respectively and independently selected from-H ,-Br ,-Cl ,-CN;R15, R16-
It is respectively and independently selected from C1-C4 alkyl ,-CH2CH2CN、-CH2CH=CH2、-C2H4OC2H4OC2H5、-CH2C6H5Middle one kind, R17For-
NHCO- (C1-C4) alkyl amide, preferably, R17For-NHCOCH3。
Preferably, one or more of the dyestuff E in the dyestuff with below general formula:
A kind of application of the described high Exposure to Sunlight dispersed black dye mixture on Car-use Fabric.Car-use Fabric is selected
From hydrophobic fiber material.Preferably, hydrophobic fiber material is selected from terylene, vinegar fibre, eyeball synthetic fibre, poly-vinegar or blending.
Auxiliary agent, including dispersant, diffusant etc. can be added during commercialization of dyes.Scattered dye involved in the present invention
A certain amount of auxiliary agent can also be mixed with material mixture, corresponding dye preparations are obtained, auxiliary agent described above includes naphthalene sulfonic acids first
One or more of compounds in aldehyde condensate, alkyl naphthalene formaldehyde sulfonic acid condensation thing, lignosulfonates;Wherein diffusant
NNO is naphthalene sulfonic acid-formaldehyde condensation product diffusant;Dispersant MF and dispersing agent CNF etc. are alkyl naphthalene formaldehyde sulfonic acid condensation thing;It is commercially available
Dispersant Reax 85A etc. be lignosulfonates.Auxiliary agent can be used alone, can also two kinds or two or more mixing
Use.The gross mass of admixture of disperse dyes and the mass ratio of auxiliary agent are 1: 0.01~4, preferably, mass ratio is 1: 0.03
~0.8.
Due to can inevitably produce some impurity during Dyestuff synthesis, while also It is not necessary to obtain sterling dye
Material, therefore dyestuff involved in the present invention is the product containing a small amount of impurity.
A kind of specific preparation method of disperse dyes dye preparations of the present invention can use a kind of in following three kinds of methods:
(1) added after mixing dyestuff A, dyestuff B, dyestuff C, dyestuff D and dyestuff E according to the above ratio quantitative auxiliary agent and
Water, then carry out micronized with pulverizers such as sand mill or grinders;
(2) dyestuff A, dyestuff B, dyestuff C, dyestuff D and dyestuff E are proportionally mixed with auxiliary agent and water respectively, then distinguished
Micronized is carried out with pulverizers such as sand mill or grinders, is finally again proportionally mixed each component;
(3) because commercially available single commercial dye passes through micronized and contains auxiliary agent, thus can directly according to
Aforementioned proportion mixes commercial dye, can also add after auxiliary agent and remix.
Grinding is preferably in various grinders such as ball mill, bobbing machine, sand mill or the progress in kneader.During grinding according to
Routine needs to add moisture content, contributes to grinding, and moisture content consumption is generally 18~100 milliliters of 10g dry products dye solution.After grinding,
The granular size of dyestuff is preferably from about 0.1~10 micron, particularly preferably about 1 micron.Drying can be dry by vacuum drying, spraying
Dry, freeze-drying, it is dried in rotary drum dryer, preferably, being dehydrated by being spray-dried.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) dye mixture of the invention is used to show excellent profit when processing printing and dyeing liquid and padding liquor and printing paste
Moisture performance, can disperse rapidly without excess agitation.Homogeneous system is presented in dye liquor and printing paste, in modern Dyeing process
The problems such as plug nozzle will not being produced;
(2) have in fairly good light resistance, rub resistance, dyeing course and add coverage rate of the dyestuff to fabric, it is even
Metachromia more preferably, while also have excellent lifting force index.
Embodiment
The present invention is described in further detail below by specific embodiment, required raw material is commercially available, or used
Known method is synthesized, but the scope of the present invention is not limited to that.
Embodiment 1
The dyestuff A that there is formula (I-a) by 15.0 grams, 10.0 grams there is formula (II-a) dyestuff B and 4.4 grams have it is logical
Formula (III-a) and 3.6 grams have formula (III-b) structure (being designated as III-ab), and totally 8.0 grams of dyestuff C and 1.7 grams have composition
Formula (IV-a) and 1.7 grams of dyestuff D with formula (IV-b) and 3.6 grams of dyestuff E with formula (V-a), with 100.0 grams of water
And 10.0 grams of sodium lignin sulfonates are ground 3 hours together in sand mill, be then spray-dried (130 DEG C of inlet temperature,
60 DEG C of outlet temperature), that is, obtain admixture of disperse dyes 1.
Embodiment 2
14.0 grams of dyestuff A and 2.0 grams of dispersing agent MFs and 40.0g water containing formula (I-c), 12.0 grams are contained into formula respectively
(II-a) dyestuff B and 2.0 grams of dispersing agent MFs and 34.0g water, containing 6 grams of formula (III-a) and containing 4 grams of formula (III-b) altogether
10.0 grams of dyestuff C and 0.5 gram of dispersing agent MF and 10.0g water, 2.3 grams of dyestuff D and 0.3 gram of dispersing agent MF containing formula (IV-b)
Mixed with 0.2 gram of dispersing agent MF and 8.0g water with 8.0g water, 1.7 grams of dyestuff E containing formula (V-b), then be ground spray
It is dry, finally five kinds of dyestuffs are mixed again and produce admixture of disperse dyes 2.
Embodiment 3
By 16.5 grams of dyestuff A with formula (I-b), 13.0 grams have the dyestuff B of formula (II-d), 7.0 grams have it is logical
The dyestuff C of formula (III-cd), 1.5 grams have formula (IV-e) dyestuff D, 2.0 grams have formula (V-j) dyestuff E, 4.0 grams
Dispersing agent MF and 100.0g water are ground 3 hours together in sand mill, are then spray-dried (130 DEG C of inlet temperature, outlet
Temperature 60 C), produce admixture of disperse dyes 3.
Embodiment 4
By the commercial dye A containing 13.0 grams of formulas (I-d), the commercial dye B containing 10.0 grams of formulas (II-e), contain
The commercial dye C of 10.0 grams of formulas (III-cd), the commercial dye D containing 3.5 grams of formulas (IV-d) and contain 3.5 grams of formulas
(V-g) commercial dye E is mixed, then directly obtains the admixture of disperse dyes 4.
Embodiment 5~16
According to embodiment 2, the preparation method of embodiment 3 or 4, continuous data as shown in table 1 is by the dyestuff containing logical formula (I)
A, the dyestuff B containing logical formula (II), the dyestuff C containing logical formula (III), the dyestuff D containing logical formula (IV) and the dyestuff E containing logical formula (V) with
Auxiliary agent is mixed, and admixture of disperse dyes 4~15 of the present invention is made.
Table 1:For embodiment 5-16
Test case
The admixture of disperse dyes of 1 gram of each embodiment is taken, is dispersed in 1000 milliliters of water.Above-mentioned solution is taken out 40 milliliters
Mixed with 160 milliliters of water, then HTHP dye model machine in 5.0 grams of hyperfine polyester fibers, under the conditions of pH value 4~4.5,
Dyed 60 minutes in 130 DEG C.
Using national standard GB/T3921-2008, GB/T3920-2008, GB/T8427-2008, GB/T/2397-2012, test
Its washing fastness, crock fastness, light fastness and lifting force.Test result is as shown in table 2.
Table 2:For the test result of embodiment.
Embodiment | Washing fastness | Crock fastness | Light fastness | Lifting force |
Embodiment 1 | 5 | 5 | 6-7 | It is excellent |
Embodiment 2 | 5 | 5 | 6 | It is excellent |
Embodiment 3 | 4-5 | 5 | 6 | It is excellent |
Embodiment 4 | 5 | 5 | 6 | It is excellent |
Embodiment 5 | 5 | 5 | 6 | It is excellent |
Embodiment 6 | 5 | 5 | 6-7 | It is excellent |
Embodiment 7 | 5 | 5 | 6 | It is excellent |
Embodiment 8 | 4-5 | 5 | 6 | It is excellent |
Embodiment 9 | 5 | 4-5 | 6 | It is excellent |
Embodiment 10 | 5 | 5 | 6-7 | It is excellent |
Embodiment 11 | 5 | 5 | 6 | It is excellent |
Embodiment 12 | 5 | 5 | 6-7 | It is excellent |
Embodiment 13 | 4-5 | 5 | 6-7 | It is excellent |
Embodiment 14 | 5 | 5 | 6 | It is excellent |
Embodiment 15 | 5 | 5 | 6-7 | It is excellent |
Embodiment 16 | 5 | 5 | 6-7 | It is excellent |
The data display of table 2:The mixture of the heretofore described high Exposure to Sunlight dispersed black dye for Car-use Fabric, no
Only there is superior washing fastness and crock fastness, and with remarkable light fastness, be respectively provided with good homogenized diet and
Excellent lifting force index, dye sample meets the index requests such as fastness.
Claims (9)
1. a kind of high Exposure to Sunlight dispersed black dye mixture, it is characterised in that described dispersed black dye mixture, with parts by weight
Meter, is mixed by A5-45 parts of dyestuff, 3-35 parts of dyestuff B, 3-30 parts of dyestuff C, 1-10 parts of dyestuff D, five kinds of components of dyestuff E1-10 parts
Conjunction is made.
2. a kind of high Exposure to Sunlight dispersed black dye mixture according to claim 1, it is characterised in that the knot of the dyestuff A
Structure formula is such as shown in (I):
In formula (I), X1, X2A kind of, R is respectively and independently selected from halogen, hydrogen ,-CN1One in alkyl or acrylic selected from H, C1-C4
Kind.
3. a kind of high Exposure to Sunlight dispersed black dye mixture according to claim 1, it is characterised in that the knot of the dyestuff B
Structure formula is such as shown in (II):
In formula (II):R2, R3, R4It is respectively and independently selected from-OH ,-NH2、-NO2Middle one kind, R5Alkyl selected from-H or C1-C4.
4. a kind of high Exposure to Sunlight dispersed black dye mixture according to claim 1, it is characterised in that the knot of the dyestuff C
Structure formula be as shown in (III), wherein, the mass ratio of 1 ' 5- dihydroxy structural material and 1 ' 8- dihydroxy structural materials in dyestuff C
For 30~85: 70~15:
In formula (III), R6, R7, R8, R9It is respectively and independently selected from-OH ,-NH2Middle one kind, X3For halogen.
5. a kind of high Exposure to Sunlight dispersed black dye mixture according to claim 1, it is characterised in that the knot of the dyestuff D
Structure formula is such as shown in (IV):
In formula (IV), R10, R11It is respectively and independently selected from-OH ,-NH2Middle one kind;R12Selected from-H ,-CH3、-OCH3、-OC2H5、-
OC6H5、-OC6H12OH、One kind in-NHCOC1-C4 amide groups, its
Middle R13, R14It is respectively and independently selected from C1-C4 alkyl a kind of.
6. a kind of high Exposure to Sunlight dispersed black dye mixture according to claim 1, it is characterised in that the knot of the dyestuff E
Structure formula is such as shown in (V):
In formula (V):X4, X5A kind of, R is respectively and independently selected from-H ,-Br ,-Cl ,-CN15, R16- it is respectively and independently selected from C1-C4 alkane
Base ,-CH2CH2CN、-CH2CH=CH2、-C2H4OC2H4OC2H5、-CH2C6H5Middle one kind, R17For-NHCO-C1-C4 alkyl amides.
7. a kind of high Exposure to Sunlight dispersed black dye mixture a kind of as defined in claim 1 answering on Car-use Fabric
With.
8. a kind of application of high Exposure to Sunlight dispersed black dye mixture according to claim 7, it is characterised in that automotive trim
Fabric is selected from hydrophobic fiber material.
9. the application of a kind of high Exposure to Sunlight dispersed black dye mixture according to claim 8, it is characterised in that hydrophobicity is fine
Tie up material and be selected from terylene, vinegar fibre, eyeball synthetic fibre, poly-vinegar or blending.
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Cited By (1)
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CN113214676A (en) * | 2021-04-28 | 2021-08-06 | 杭州吉华江东化工有限公司 | Reactive dye mixture and application thereof |
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CN113214676A (en) * | 2021-04-28 | 2021-08-06 | 杭州吉华江东化工有限公司 | Reactive dye mixture and application thereof |
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