CN107279179A - The agricultural chemicals and its compound method of a kind of high-efficiency low-toxicity preventing and treating shade tree insect pest - Google Patents

The agricultural chemicals and its compound method of a kind of high-efficiency low-toxicity preventing and treating shade tree insect pest Download PDF

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Publication number
CN107279179A
CN107279179A CN201710568808.3A CN201710568808A CN107279179A CN 107279179 A CN107279179 A CN 107279179A CN 201710568808 A CN201710568808 A CN 201710568808A CN 107279179 A CN107279179 A CN 107279179A
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CN
China
Prior art keywords
agricultural chemicals
toxicity
insect pest
efficiency low
shade tree
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710568808.3A
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Chinese (zh)
Inventor
张跃军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN SENTAI LANDSCAPING Co Ltd
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TIANJIN SENTAI LANDSCAPING Co Ltd
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Application filed by TIANJIN SENTAI LANDSCAPING Co Ltd filed Critical TIANJIN SENTAI LANDSCAPING Co Ltd
Priority to CN201710568808.3A priority Critical patent/CN107279179A/en
Publication of CN107279179A publication Critical patent/CN107279179A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/26Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
    • A01N57/28Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a kind of agricultural chemicals of high-efficiency low-toxicity preventing and treating shade tree insect pest and its compound method, active component includes chlorobenzene ether amide, orthene, butachlor and triadimefon, and the parts by weight of composition are:Chlorobenzene ether amide 5 20, orthene 5 10, butachlor 10 20, triadimefon 13, phenethyl phenol polyethenoxy ether 10 15, phosphate 13, organic solvent 5 10, antifreeze 15, thickener 0.1 2, water are surplus, and total amount is 100.The pesticidal chemical that the present invention is provided is capable of the generation of the pest and disease damage of effectively preventing shade tree, is worth promotion and application energetically.

Description

The agricultural chemicals and its compound method of a kind of high-efficiency low-toxicity preventing and treating shade tree insect pest
Technical field
The invention belongs to agrochemical formulation technology field, more particularly to a kind of preventing and treating shade tree insect pest of high-efficiency low-toxicity agricultural chemicals and Its compound method.
Background technology
Shade tree refers to plant takes up parting strip in road two, shades and constitute the seeds of streetscape to vehicle and pedestrian.Trade Tree play the role of it is a lot, can with supplemental oxygen, purification air, beautifying city, reduce noise etc..In the selection application of shade tree On, based on many broad leaved and deciduous broad leaved arbors graceful with green shade such as lid, form of downtown roads.There is plane tree using more avenue tree planting (oriental plane tree), lime tree, American elm, horse chestnut, maple, camplotheca acuminata, ginkgo, Liriodendron chinense, camphor tree, wide yulan, with a smile, glossy privet, blue or green paulownia, Willow, willow, Chinese scholartree, taxodium ascendens, banyan, metasequoia etc..
Shade tree plays vital effect for the greening and environmental protection in city, but the pest and disease damage that shade tree brings And its preventing and controlling are always a part important during urban afforestation maintenance management works, and are also a part for more headache.Only There is the generation for effectively preventing pest and disease damage, just do not interfere with the people around lived, just can be more favourable for environmental creation Condition.
Therefore, the generation of shade tree pest and disease damage how is prevented and treated, is those skilled in that art's technical problem urgently to be resolved hurrily.
The content of the invention
It is an object of the invention to provide a kind of high-efficiency low-toxicity preventing and treating shade tree insect pest agricultural chemicals and its compound method, effectively Solution shade tree pest and disease damage the problem of bring.
The present invention is achieved in that
A kind of high-efficiency low-toxicity prevents and treats the agricultural chemicals of shade tree insect pest, and active component includes chlorobenzene ether amide, orthene, fourth Careless amine and triadimefon.
It is preferred that, the parts by weight of the composition are:Chlorobenzene ether amide 5-20, orthene 5-10, butachlor 10-20, Triadimefon 1-3, phenethyl phenol polyethenoxy ether 10-15, phosphate 1-3, organic solvent 5-10, antifreeze 1-5, thickener 0.1- 2, water is surplus, and total amount is 100.
It is preferred that, the organic solvent is one in ethanol, acetone, ethyl acetate, dimethylformamide, benzene, dimethylbenzene Plant or two kinds.
It is preferred that, the antifreeze be ethylene glycol, propane diols, glycerine, polyethylene glycol, isopropanol, butanol, sodium chloride, One or two kinds of in calcium chloride.
It is preferred that, the thickener be carboxymethyl cellulose, yellow first glue, acrylic acid receive, one kind in polyacrylate or Two kinds of person.
It is preferred that, a kind of compound method of the agricultural chemicals of high-efficiency low-toxicity preventing and treating shade tree insect pest, step is as follows,
(1) active component is dissolved into appropriate organic solvent, and stirs 15-20mi n;
(2) a certain amount of phenethyl phenol polyethenoxy ether and phosphate are added, continues to stir, it is fully mixed;
(3) antifreeze is added, 5mi n are stirred;
(4) it is further continued for adding thickener, is sufficiently stirred for mixing, the oil phase formed in step (2) is converted into aqueous phase.
(5) suitable quantity of water is added, continues to stir and evenly mix.
It is preferred that, the agricultural chemicals can be processed into wettable powder, suspending agent or granule.
It is preferred that, when the pesticide processing is into wettable powder, adding ingredient and parts by weight are:Agricultural chemicals 15-20, N- acyl group Methyl amimoacetic acid 3-5, white carbon 4-8, sodium pyrophosphate 10-15, bentonite complement to 100.
It is preferred that, when the pesticide processing is into suspending agent, adding ingredient and parts by weight are:Agricultural chemicals 10-15, calgon 5-8, N- acyl group methyl amimoacetic acid 6-10, white carbon 4-8, ethylene glycol 2-3, tbp 1-3, water complement to 100.
It is preferred that, when the pesticide processing is into granule, adding ingredient and parts by weight are:Agricultural chemicals 3-5, binding agent 2-3, collapse Agent 8-10 is solved, filler complements to 100.
The beneficial effects of the present invention are:
1st, the agricultural chemicals that the present invention is prepared can produce certain collaboration summation action so that the effect produced jointly is more than each A variety of insect pests can be told on, it is possible to reduce times for spraying by the effect summation of individual composition, at the same save labour into This.
2nd, composition is easy to get, and processing is simple, low for equipment requirements.
3rd, it is low toxicity raw material that the activity that the present invention is used, which turns into, reduces the influence to environment and health of human body
4th, treatment effect is notable rapidly, and the continuation time is long.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Embodiment 1:Synergism determination is tested
Specific implementation method, different activities composition is combined, and then the Holcocerus insularis in fixed space is handled, Determine Holcocerus insularis inhibiting rate (death rate).
1 square meter space inhibiting rate and evaluation in the Room of table 1
It can be seen from Table 1 that, indoor 1 square meter space inhibiting rate testing experiment shows, active component chlorobenzene ether amide, second Acyl acephatemet, butachlor, triadimefon can show kind of the active component of synergy, especially four while when acting on.Need explanation , the dosage in this experiment is that the component ratio in experiment preset dose, with pharmacy procedure is irrelevant.
Embodiment 2:It is prepared by wettable powder
According to indoor development test, agricultural chemicals can be processed into wettable powder.
Wettable powder adding ingredient and parts by weight are:Agricultural chemicals 15, N- acyl groups methyl amimoacetic acid 5, white carbon 6, sodium pyrophosphate 12, Bentonite complements to 100.
Above-mentioned material is added in mixing and blending machine together, is mixed evenly, is then smashed through airslide disintegrating mill, powder Material after essence is mixed again, is finally screened with 600-800 the polished standard screens, obtains 15% wettable powder.
Embodiment 3:It is prepared by suspending agent
According to indoor development test, agricultural chemicals can be processed into suspending agent.
Suspending agent adding ingredient and parts by weight are:Agricultural chemicals 15, calgon 6, N- acyl groups methyl amimoacetic acid 8, white carbon 6, second Glycol 2, tbp 2, water complements to 100.
Above-mentioned material is scattered through high speed shear, is then sanded with sand mill, it is formed high dispersive, height in water-medium Stable suspension system, you can obtain 15% suspending agent.
Embodiment 4:It is prepared by granular preparation
According to indoor development test, agricultural chemicals can be processed into granular preparation.
Granule adding ingredient and parts by weight are:Agricultural chemicals 5, binding agent 3, disintegrant 8, filler complements to 100.
Above-mentioned material is added in mixing and blending machine together, is uniformly mixed, and is then smashed through airslide disintegrating mill, is smashed Material afterwards is mixed again, is finally screened with 300-400 the polished standard screens, that is, is obtained wettable powder, by this Wettable powder puts into granulating disc the granulation that adds water, and is dried, sieves in drying afterwards, subsequently carries out cold But, you can obtain 5% granular preparation.
Embodiment 5:The test of pesticide effectiveness one
Test period:312 provincial highways-seascape main road to Central Artery section
Test site:2016-07——2016-08
Test medicine:Chlorobenzene ether amide 15, orthene 10, butachlor 15, triadimefon 2, phenethyl phenol polyoxyethylene Ether 12, phosphate 3, ethanol 8, glycerine 3, carboxymethyl cellulose 0.8, water are surplus, and total amount is 100.
Pharmacy type:Wettable powder
Embodiment:Mechanical injection
Test drug effect:3d, 7d, 10d, 20d, 30d are checked after medication respectively, the red spider that 3d shade trees trigger after medication Spider, steinernema, Holcocerus insularis, leaf moth are significantly reduced, and red spider is loseed after loseing steinernema, Holcocerus insularis, leaf moth, 10d after 7d, 20d, 30d lose pest and disease damage.
The medicament of the present invention has good prevention effect to the pest and disease damage that shade tree triggers, is worth popularization energetically and answers With.
Embodiment 6:The test of pesticide effectiveness two
Test period:Central Artery-Jin Jin is at a high speed to Tianjin main road section
Test site:2017-05——2017-06
Test medicine:Chlorobenzene ether amide 15, orthene 8, butachlor 13, triadimefon 2, phenethyl phenol polyoxyethylene Ether 12, phosphate 3, dimethylformamide 10, polyethylene glycol 4, carboxymethyl cellulose 0.8, water are surplus, and total amount is 100.
Pharmacy type:Suspending agent
Embodiment:Mechanical injection
Test drug effect:3d, 7d, 10d, 20d, 30d are checked after medication respectively, the red spider that 3d shade trees trigger after medication Spider, steinernema, Holcocerus insularis, leaf moth significantly reduce, and lose red spider, steinernema, Holcocerus insularis, leaf moth after 7d, 10d, 20d, 30d loses pest and disease damage.
The medicament of the present invention has good prevention effect to the pest and disease damage that shade tree triggers, is worth popularization energetically and answers With.
Although the above-mentioned embodiment to the present invention is described, not to the limit of the scope of the present invention System, one of ordinary skill in the art should be understood that on the basis of technical scheme those skilled in the art need not pay Go out various modifications or deform still within protection scope of the present invention that performing creative labour can make.

Claims (10)

1. a kind of high-efficiency low-toxicity prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:Active component includes chlorobenzene ether amide, acetyl Acephatemet, butachlor and triadimefon.
2. a kind of high-efficiency low-toxicity as claimed in claim 1 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:The composition Parts by weight are:Chlorobenzene ether amide 5-20, orthene 5-10, butachlor 10-20, triadimefon 1-3, phenethyl phenol polyoxyethylene Ether 10-15, phosphate 1-3, organic solvent 5-10, antifreeze 1-5, thickener 0.1-2, water are surplus, and total amount is 100.
3. a kind of high-efficiency low-toxicity as claimed in claim 2 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:It is described organic molten Agent is the one or two kinds of in ethanol, acetone, ethyl acetate, dimethylformamide, benzene, dimethylbenzene.
4. a kind of high-efficiency low-toxicity as claimed in claim 2 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:The antifreeze For the one or two kinds of in ethylene glycol, propane diols, glycerine, polyethylene glycol, isopropanol, butanol, sodium chloride, calcium chloride.
5. a kind of high-efficiency low-toxicity as claimed in claim 2 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:The thickener Received for carboxymethyl cellulose, yellow first glue, acrylic acid, the one or two kinds of in polyacrylate.
6. a kind of compound method of the agricultural chemicals of high-efficiency low-toxicity preventing and treating shade tree insect pest as claimed in claim 2, it is characterised in that: Step is as follows,
(1) active component is dissolved into appropriate organic solvent, and stirs 15-20min;
(2) a certain amount of phenethyl phenol polyethenoxy ether and phosphate are added, continues to stir, it is fully mixed;
(3) antifreeze is added, 5min is stirred;
(4) it is further continued for adding thickener, is sufficiently stirred for mixing, the oil phase formed in step (2) is converted into aqueous phase.
(5) suitable quantity of water is added, continues to stir and evenly mix.
7. a kind of high-efficiency low-toxicity as claimed in claim 2 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:The agricultural chemicals can To be processed into wettable powder, suspending agent or granule.
8. a kind of high-efficiency low-toxicity as claimed in claim 7 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:The agricultural chemicals adds When work is into wettable powder, adding ingredient and parts by weight are:Agricultural chemicals 15-20, N- acyl group methyl amimoacetic acid 3-5, white carbon 4-8, burnt phosphorus Sour sodium 10-15, bentonite complements to 100.
9. a kind of high-efficiency low-toxicity as claimed in claim 7 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:The agricultural chemicals adds When work is into suspending agent, adding ingredient and parts by weight are:Agricultural chemicals 10-15, calgon 5-8, N- acyl group methyl amimoacetic acid 6-10, hard charcoal Black 4-8, ethylene glycol 2-3, tbp 1-3, water complement to 100.
10. a kind of high-efficiency low-toxicity as claimed in claim 7 prevents and treats the agricultural chemicals of shade tree insect pest, it is characterised in that:The agricultural chemicals When being processed into granule, adding ingredient and parts by weight are:Agricultural chemicals 3-5, binding agent 2-3, disintegrant 8-10, filler complement to 100.
CN201710568808.3A 2017-07-13 2017-07-13 The agricultural chemicals and its compound method of a kind of high-efficiency low-toxicity preventing and treating shade tree insect pest Pending CN107279179A (en)

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CN107279179A true CN107279179A (en) 2017-10-24

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101524086A (en) * 2009-04-27 2009-09-09 江苏辉丰农化股份有限公司 Insecticidal composition containing nitenpyram and acephate
CN102007939A (en) * 2010-11-01 2011-04-13 河南农业大学 Non-glutinous rice inferior grain fullness and chalkiness regulator and preparation method thereof
CN102428935A (en) * 2011-12-14 2012-05-02 安徽科立华化工有限公司 Oxadiargyl and butachlor aqueous emulsion and preparation method thereof
CN104322499A (en) * 2014-10-24 2015-02-04 北京燕化永乐生物科技股份有限公司 Compound bactericide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101524086A (en) * 2009-04-27 2009-09-09 江苏辉丰农化股份有限公司 Insecticidal composition containing nitenpyram and acephate
CN102007939A (en) * 2010-11-01 2011-04-13 河南农业大学 Non-glutinous rice inferior grain fullness and chalkiness regulator and preparation method thereof
CN102428935A (en) * 2011-12-14 2012-05-02 安徽科立华化工有限公司 Oxadiargyl and butachlor aqueous emulsion and preparation method thereof
CN104322499A (en) * 2014-10-24 2015-02-04 北京燕化永乐生物科技股份有限公司 Compound bactericide

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