CN102860307A - Compound pesticide containing validamycin and cyprosulfamide and application of compound pesticide - Google Patents
Compound pesticide containing validamycin and cyprosulfamide and application of compound pesticide Download PDFInfo
- Publication number
- CN102860307A CN102860307A CN2012103380484A CN201210338048A CN102860307A CN 102860307 A CN102860307 A CN 102860307A CN 2012103380484 A CN2012103380484 A CN 2012103380484A CN 201210338048 A CN201210338048 A CN 201210338048A CN 102860307 A CN102860307 A CN 102860307A
- Authority
- CN
- China
- Prior art keywords
- boscalid
- jinggangmeisu
- compound pesticide
- content
- cyprosulfamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000575 pesticide Substances 0.000 title claims abstract description 35
- 229930195482 Validamycin Natural products 0.000 title abstract description 5
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 title abstract description 5
- 150000001875 compounds Chemical class 0.000 title abstract 10
- OAWUUPVZMNKZRY-UHFFFAOYSA-N cyprosulfamide Chemical compound COC1=CC=CC=C1C(=O)NS(=O)(=O)C1=CC=C(C(=O)NC2CC2)C=C1 OAWUUPVZMNKZRY-UHFFFAOYSA-N 0.000 title abstract 5
- 241000209094 Oryza Species 0.000 claims abstract description 27
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 27
- 235000009566 rice Nutrition 0.000 claims abstract description 27
- 201000010099 disease Diseases 0.000 claims abstract description 16
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 16
- 239000005740 Boscalid Substances 0.000 claims description 56
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims description 56
- 229940118790 boscalid Drugs 0.000 claims description 56
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 230000002688 persistence Effects 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 11
- 230000003449 preventive effect Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000037149 energy metabolism Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a compound pesticide containing validamycin and cyprosulfamide and an application of compound pesticide, which belong to the technical field of compound pesticides. The compound pesticide contains 0.1-50% of cyprosulfamide and 0.1-50% of validamycin. By combining validamycin and cyprosulfamide, the compound pesticide has a good synergistic effect and a good control effect for rice sheath blight disease and rice false smut; according to field experiments, the prevention rate of the compound pesticide can reach more than 95%; the persistence of the compound pesticide is strong, and after 35 days, the prevention rate can still reach more than 85%; and the production cost of the compound pesticide is low and is reduced by more than 50% compared with the production cost of cyprosulfamide which is used separately.
Description
Technical field
The invention belongs to technical field of compounded pesticide, be specifically related to a kind of Recompounded pesticide and application thereof that contains jinggangmeisu and Boscalid.
Background technology
Rice sheath blight disease is a kind of common disease, the frequently-occurring disease of China paddy rice.Common control medicament has jinggangmeisu etc., and jinggangmeisu claims again valida, belongs to the low toxicity bactericide.Jinggangmeisu has stronger interior absorption, is easily absorbed by mycelia and rapidly conduction in its body, suppresses mycelial growth and grows.Be mainly used in rice sheath blight disease, also can be used for the control of the crop pests such as rice green smut and vegetables and cotton, shortcoming is that the lasting period is short, and generally at 7～15 days, along with the long-term use of jinggangmeisu, preventive effect descends to some extent.
Boscalid is the pyridines bactericide of being succeeded in developing by BASF AG, and it is by the breathing of the oxygen of inhibition succinic acid matrix, thereby the energy metabolism of obstruction pathogen is to present bactericidal activity.This medicament disinfecting spectrum is wider, and can be used for various crop and prevent and treat the multiple fungal diseases such as gray mold, and also effective to the resistance bacterium of other medicaments.Because this medicament has outstanding infiltration conduction, has given medicament suitable lasting effect, thereby can obviously reduce spraying times.Indoor isolated test proves, Boscalid to the rice sheath blight disease mycelia have stronger inhibitory action (Chen Hongzhou etc., the Agriculture in Jiangxi journal, 2011,23(5): 97～99).The shortcoming of Boscalid is that use cost is higher.Boscalid is used for preventing and treating rice sheath blight disease and the rice green smut field control effectiveness test yet there are no report.
Summary of the invention
For the problem that prior art exists, the object of the invention is to design provides a kind of Recompounded pesticide of jinggangmeisu and Boscalid and technical scheme of application thereof of containing.This Recompounded pesticide is good, quick-acting soon to the control efficiency of rice sheath blight disease and rice green smut, persistence is long, cost is low.
Described a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid is characterized in that containing Boscalid 0.1～50%, jinggangmeisu 0.1～50%.
Described a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid, the content that it is characterized in that Boscalid is 0.2～30%, the content of jinggangmeisu is 0.5～45%.
Described a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid, the content that it is characterized in that Boscalid is 0.5～25%, the content of jinggangmeisu is 1.5～40%.
Described a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid, the content that it is characterized in that Boscalid is 1.5～20%, the content of jinggangmeisu is 2～35%.
Described a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid, the content that it is characterized in that Boscalid is 2～15%, the content of jinggangmeisu is 5～30%.
Described a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid, the content that it is characterized in that Boscalid is 4～8%, the content of jinggangmeisu is 10～20%.
Described a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid, the content that it is characterized in that Boscalid is 5～7%, the content of jinggangmeisu is 12～16%.
The described a kind of application of Recompounded pesticide in preventing and treating rice sheath blight disease and rice green smut that contains jinggangmeisu and Boscalid.
Above-mentioned a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid can be made any formulation that allows on the Recompounded pesticides such as water dispersible granules, aqueous suspension agent, wetting powder.When making formulation, the reagent of employing is and well known to a person skilled in the art common agents, does not give unnecessary details at this.
Above-mentioned a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid is together composite with jinggangmeisu and Boscalid, has very strong synergistic effect, control efficiency to rice sheath blight disease and rice green smut is good, can reach more than 95% through its control rate of field trial; Continuation is strong, and after 35 days, its control rate also can reach more than 85%; Production cost is low, reduces more than 50% than independent use Boscalid.
The proportioning that relates among the present invention is the percentage by weight of the pure material of active ingredient.
Embodiment
Further specify the present invention below in conjunction with embodiment.Recompounded pesticide of the present invention can adopt following proportioning to produce.
Prescription one: Boscalid 5%, jinggangmeisu 5%.
Prescription two: Boscalid 2%, jinggangmeisu 10%.
Prescription three: Boscalid 3%, jinggangmeisu 45%.
Prescription four: Boscalid 1%, jinggangmeisu 30%.
Prescription five: Boscalid 0.1%, jinggangmeisu 6%.
Prescription six: Boscalid 0.4%, jinggangmeisu 32%.
Prescription seven: Boscalid 0.5%, jinggangmeisu 20%.
Prescription eight: Boscalid 25%, jinggangmeisu 5%.
Prescription nine: Boscalid 15%, jinggangmeisu 1%.
Prescription ten: Boscalid 18%, jinggangmeisu 0.6%.
Fill a prescription 11: Boscalid 12%, jinggangmeisu 0.2%.
Fill a prescription 12: Boscalid 20%, jinggangmeisu 0.25%.
Fill a prescription 13: Boscalid 10%, jinggangmeisu 0.1%.
Fill a prescription 14: Boscalid 45%, jinggangmeisu 50%.
That above-mentioned prescription can be made into water dispersible granules, aqueous suspension agent, wetting powder carrying out field trial.
Embodiment:
1. chemicals treatment
Table 1 reagent agent experimental scheme
2. test method:
Each residential quarter 20m
2, repeat 3 times.In Rise's boot period and each medication of cut phase once.Stage of yellow ripeness behind the medicine, the incidence of investigation rice sheath blight disease and rice green smut.Investigation drug effect method is: 5 samplings of each residential quarter diagonal, get 5 clumps at every, and record total strain number, diseased plant number and sick progression, calculate preventive effect.
3. results and analysis
Table 2 is respectively processed 10d preventive effect (%) behind the chemical control rice sheath blight disease medicine
Table 3 is respectively processed 10d preventive effect (%) behind the sick medicine of chemical control rice green smut
Table 4 is respectively processed 35d preventive effect (%) behind the chemical control rice sheath blight disease medicine
Table 5 is respectively processed 35d preventive effect (%) behind the chemical control rice green smut medicine
Field control effectiveness test is the result show, Boscalid and validamycin composition have good preventive effect to rice sheath blight disease and rice green smut, and control efficiency is compared with single dose has synergistic effect, can reduce the usage amount of agricultural chemicals, reduces cost.
Prescription three, four, six, eight, nine and 14 carries out above-mentioned field trial, all can reach more than 95% to rice sheath blight disease and rice green smut control rate; After 35 days, its control rate also can all reach more than 85%.
Claims (8)
1. a Recompounded pesticide that contains jinggangmeisu and Boscalid is characterized in that containing Boscalid 0.1～50%, jinggangmeisu 0.1～50%.
2. a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid as claimed in claim 1, the content that it is characterized in that Boscalid is 0.2～30%, the content of jinggangmeisu is 0.5～45%.
3. a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid as claimed in claim 1, the content that it is characterized in that Boscalid is 0.5～25%, the content of jinggangmeisu is 1.5～40%.
4. a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid as claimed in claim 1, the content that it is characterized in that Boscalid is 1.5～20%, the content of jinggangmeisu is 2～35%.
5. a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid as claimed in claim 1, the content that it is characterized in that Boscalid is 2～15%, the content of jinggangmeisu is 5～30%.
6. a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid as claimed in claim 1, the content that it is characterized in that Boscalid is 4～8%, the content of jinggangmeisu is 10～20%.
7. a kind of Recompounded pesticide that contains jinggangmeisu and Boscalid as claimed in claim 1, the content that it is characterized in that Boscalid is 5～7%, the content of jinggangmeisu is 12～16%.
8. a kind of application of Recompounded pesticide in preventing and treating rice sheath blight disease and rice green smut that contains jinggangmeisu and Boscalid as claimed in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210338048.4A CN102860307B (en) | 2012-09-13 | 2012-09-13 | Compound pesticide containing validamycin and cyprosulfamide and application of compound pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210338048.4A CN102860307B (en) | 2012-09-13 | 2012-09-13 | Compound pesticide containing validamycin and cyprosulfamide and application of compound pesticide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102860307A true CN102860307A (en) | 2013-01-09 |
| CN102860307B CN102860307B (en) | 2014-04-02 |
Family
ID=47439662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210338048.4A Active CN102860307B (en) | 2012-09-13 | 2012-09-13 | Compound pesticide containing validamycin and cyprosulfamide and application of compound pesticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102860307B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104115838A (en) * | 2014-06-27 | 2014-10-29 | 何芳 | Pesticide preparation for preventing and controlling rice sheath blight |
| CN104381293A (en) * | 2014-11-03 | 2015-03-04 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Fungicidal composition containing silthiopham and validamycin |
| CN104738036A (en) * | 2015-03-25 | 2015-07-01 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing zoxamide and validamycin |
| CN105340901A (en) * | 2015-11-16 | 2016-02-24 | 周红梅 | Sterilization composition containing shenqinmycin and boscalid |
| CN105941422B (en) * | 2016-07-13 | 2018-10-30 | 南京吉星生物技术开发有限公司 | A kind of bactericidal composition and its application containing Boscalid |
| CN108849916A (en) * | 2018-08-11 | 2018-11-23 | 何牧天 | A kind of bactericidal composition for sheath blight disease controlling |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1751026A (en) * | 2003-02-14 | 2006-03-22 | 巴斯夫股份有限公司 | Novel crystalline modification of the anhydrate of boscalid |
| CN101755797A (en) * | 2009-11-23 | 2010-06-30 | 陈章艳 | Bactericide composition containing boscalid |
| CN101808521A (en) * | 2007-09-26 | 2010-08-18 | 巴斯夫欧洲公司 | ternary fungicidal compositions comprising boscalid and chlorothalonil |
| WO2012031355A1 (en) * | 2010-09-09 | 2012-03-15 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
-
2012
- 2012-09-13 CN CN201210338048.4A patent/CN102860307B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1751026A (en) * | 2003-02-14 | 2006-03-22 | 巴斯夫股份有限公司 | Novel crystalline modification of the anhydrate of boscalid |
| CN101808521A (en) * | 2007-09-26 | 2010-08-18 | 巴斯夫欧洲公司 | ternary fungicidal compositions comprising boscalid and chlorothalonil |
| CN101755797A (en) * | 2009-11-23 | 2010-06-30 | 陈章艳 | Bactericide composition containing boscalid |
| WO2012031355A1 (en) * | 2010-09-09 | 2012-03-15 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
Non-Patent Citations (2)
| Title |
|---|
| TAIFO MAHMUD 等: "The Biosynthesis of Acarbose and Validamycin", 《THE CHEMICAL RECORD》 * |
| 亦冰: "新颖杀菌剂-啶酰菌胺", 《世界农药》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104115838A (en) * | 2014-06-27 | 2014-10-29 | 何芳 | Pesticide preparation for preventing and controlling rice sheath blight |
| CN104381293A (en) * | 2014-11-03 | 2015-03-04 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Fungicidal composition containing silthiopham and validamycin |
| CN104381293B (en) * | 2014-11-03 | 2016-05-25 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of bactericidal composition containing Silthiopham and jinggangmeisu |
| CN104738036A (en) * | 2015-03-25 | 2015-07-01 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Bactericidal composition containing zoxamide and validamycin |
| CN105340901A (en) * | 2015-11-16 | 2016-02-24 | 周红梅 | Sterilization composition containing shenqinmycin and boscalid |
| CN105941422B (en) * | 2016-07-13 | 2018-10-30 | 南京吉星生物技术开发有限公司 | A kind of bactericidal composition and its application containing Boscalid |
| CN108849916A (en) * | 2018-08-11 | 2018-11-23 | 何牧天 | A kind of bactericidal composition for sheath blight disease controlling |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102860307B (en) | 2014-04-02 |
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Owner name: ZHEJIANG TONGLU HUIFENG BIOSCIENCE CO., LTD. Free format text: FORMER OWNER: NI LIE Effective date: 20140707 Free format text: FORMER OWNER: WANG CHUNSHUI Effective date: 20140707 |
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Effective date of registration: 20140707 Address after: The streets of Tonglu County Tong Jun Yang Tang Lu in Hangzhou city of Zhejiang Province, No. 311 311500 Patentee after: ZHEJIANG TONGLU HUIFENG BIOSCIENCE CO., LTD. Address before: HSBC building, No. 121 Yingchun road Tonglu County of Hangzhou City, Zhejiang province 311500 28 floor Patentee before: Ni Lie Patentee before: Wang Chunshui |