CN107265500B - A kind of device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania - Google Patents
A kind of device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania Download PDFInfo
- Publication number
- CN107265500B CN107265500B CN201710277071.XA CN201710277071A CN107265500B CN 107265500 B CN107265500 B CN 107265500B CN 201710277071 A CN201710277071 A CN 201710277071A CN 107265500 B CN107265500 B CN 107265500B
- Authority
- CN
- China
- Prior art keywords
- connect
- pipe
- furnace body
- high pressure
- mixed expanded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000001257 hydrogen Substances 0.000 claims abstract description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
- 239000000446 fuel Substances 0.000 claims abstract description 13
- 229910003074 TiCl4 Inorganic materials 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011261 inert gas Substances 0.000 claims abstract description 7
- 239000000376 reactant Substances 0.000 claims abstract description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 5
- 239000011819 refractory material Substances 0.000 claims abstract description 4
- -1 furnace body Chemical compound 0.000 claims abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 22
- 239000007789 gas Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
- 239000012510 hollow fiber Substances 0.000 claims description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract description 9
- 239000000047 product Substances 0.000 description 8
- 238000005189 flocculation Methods 0.000 description 6
- 230000016615 flocculation Effects 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 235000012489 doughnuts Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000005348 self-cleaning glass Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
- C01G23/0536—Producing by wet processes, e.g. hydrolysing titanium salts by hydrolysing chloride-containing salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Abstract
A kind of device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania, including furnace body, TiCl4 input pipe, hydrogen-containing fuel pipe, water jacket is covered with outside the furnace body, refractory material layer is equipped in the furnace body, bottom of furnace body is equipped with reactant exit, the intracorporal top of furnace is equipped with burner noz(zle), burner noz(zle) is connect with mixed expanded bottom of the tube, mixed expanded pipe top is respectively equipped with oxygen gas connector, inert gas connector, high pressure outer cover is arranged with outside mixed expanded pipe, TiCl4 input pipe passes through to be connect in the middle part of high pressure outer cover and mixed expanded pipe, hydrogen-containing fuel pipe is connect with high pressure outer cover.
Description
Technical field
The invention belongs to titanium dioxide production apparatus fields more particularly to a kind of oxyhydrogen flame Hydrolyze method preparation high-purity to receive
The device of rice titanium dioxide.
Background technique
Titanium dioxide P25 is a kind of nanoscale white powder, and the hydroxyl group on surface makes it have hydrophily, and should
Product does not have any pigment feature.The average grain diameter of basic granules is about 21nm, and the size of particle and the density of 4g/cm3 make
Its special surface with 50m2/g.Titanium dioxide P25 belongs to mixed crystal type, and the weight ratio of anatase and rutile is about 71/
29, since two kinds of mixing up of structure increase the intracell defect concentration of TiO2, the concentration of carrier is increased, electronics, hole are made
Quantity increases, and makes it have the ability of solution components (water, oxygen, organic matter) of the stronger capture on the surface TiO2.Nanoscale
Titanium dioxide has the performances such as excellent ultraviolet radiation absorption, photo-catalyst, decomposing organic pollutant, can be used for nano paint, empty
Gas purifier, self-cleaning glass, ceramics etc..Nano-titanium dioxide antibacterial and mouldproof, exhaust gas purification, deodorization, water process, it is antifouling,
The fields such as weather-proof anti-aging, automobile finish have a wide range of applications, it is in environment, information, material, the energy, medical treatment and health etc.
Field has broad application prospects.
The titanium dioxide industry of China originates in mid-term the 1950s, but nanometer Ti02 powder product is recent five years
The high-end product of listing, production technology is mainly by the De Gaosa company of Germany, the Cabot Corporation in the U.S., moral mountain Cao of Ff sheet
It reaches, go out the monopolization of the large enterprises such as the emerging production of light, Osaka Ti industry company, the country still lacks this new and high technology.
Summary of the invention
The present invention provides a kind of device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania, existing to solve
Technical production is low, waste is big, the impurity of production is more, the uneconomical, technical problems such as not environmentally.
In order to solve the above technical problem, the technical solution used in the present invention is: prepared by a kind of oxyhydrogen flame Hydrolyze method
The device of high purity nanometer titania, including furnace body, TiCl4 input pipe, hydrogen-containing fuel pipe, it is characterized in that the furnace body outer cover
Equipped with water jacket, refractory material layer is equipped in the furnace body, bottom of furnace body is equipped with reactant exit, and the intracorporal top of furnace is equipped with burning
Nozzle, burner noz(zle) are connect with mixed expanded bottom of the tube, and mixed expanded pipe top is respectively equipped with oxygen gas connector, inert gas
Connector, mixed expanded pipe are arranged with high pressure outer cover outside, and TiCl4 input pipe passes through to be connect in the middle part of high pressure outer cover and mixed expanded pipe,
Hydrogen-containing fuel pipe is connect with high pressure outer cover, and hollow fiber film assembly is equipped between the mixed expanded pipe and high pressure outer cover.
Preferably, the burner noz(zle) exit is equipped with igniter.
Preferably, the hydrogen-containing fuel pipe is connect with ammonia decomposer, ammonia decomposer is connect with ammonia head tank.
Preferably, the reactant exit is connect with transfer pump, transfer pump is connect with level-one spiral flocculator, level-one spiral shell
Rotation flocculator is connect with spherical reaction kettle, and spherical reaction kettle is connect with deuterostrophies flocculator, the end of deuterostrophies flocculator
It connect through piping with cyclone separator, is connect at the top of spherical reaction kettle with pulse gas transmitter.
The present invention is easy to get with raw material, product very high purity, reunion is less, gained particle diameter distribution is narrow, it is energy saving, mention
High-purity increases the features such as efficiency.When the device works, hydrogen-containing fuel gas, oxygenated fuel gas and control flame combustion
The inert gas of situation imports in burner noz(zle) mixing chamber, after mixing in spray nozzle front end ignition.Simultaneously unstripped gas
Body is uniformly blended in burning gases, with combustion product vapor occur hydrolysis, and be aggregated into more than ten nanometer just
Grade particle, primary particle through flocculation, ageing, again flocculate grow up i.e. can be used cyclone separator be collected, obtain nano-powder.This
Invented technology can obtain that purity is 99.9%, flat diameter partial size is 25-35 nanometers, average specific surface in 50 m2/g, shape is ball
Shape, the nano TiO 2 that crystal form is rutile-type or anatase titanium dioxide.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention.
Specific embodiment
With reference to the accompanying drawings and detailed description, the technical solutions of the present invention will be further described.
As shown in connection with fig. 1, the oxyhydrogen flame Hydrolyze method prepare rutile type nano titanic oxide device include furnace body 9,
TiCl4 input pipe 15, hydrogen-containing fuel pipe 61, the furnace body 9 are covered with water jacket outside, are equipped with refractory material layer 9, furnace in the furnace body
Body bottom is equipped with reactant exit 93, and the intracorporal top of furnace is equipped with burner noz(zle) 5, and 5 exit of burner noz(zle) is equipped with igniting
Device 51.Burner noz(zle) 5 is connect with mixed expanded 21 bottom of pipe, and mixed expanded 21 top of pipe is respectively equipped with oxygen gas connector 2, lazy
Property gas connection 1, be arranged with high pressure outer cover 3 outside mixed expanded pipe, TiCl4 input pipe 15 pass through high pressure outer cover 3 with it is mixed expanded
It is connected in the middle part of pipe 21, hydrogen-containing fuel pipe 61 is connect with high pressure outer cover, and doughnut is equipped between mixed expanded pipe and high pressure outer cover
Membrane module 16.Hollow fiber film assembly has the doughnut of separation mixed gas function.Separation driving force is pressure difference, operation pressure
Power is 0.098-9.8MPa, realizes that mixed gas is separated using transmitance difference, is gas or steam through object.Preparation method is to adopt
Be made after more microporous homogeneous films with middle spinneret by thermoplastic resin melt-spun or by polymer solution dry-jet wet-spinning coat it is ultra-thin organic
Silicon seperation film can also be passed through certain solidification liquids in hollow portion to form anisotropic membrane structure.For hydrogen-nitrogen, oxygen-nitrogen, methane-
The mixed gas separations such as helium, alcohol-water and ethane, methane and ethylene.
Hydrogen-containing fuel pipe is connect with ammonia decomposer 7, and ammonia decomposer is connect with ammonia head tank 8.
Reactant exit 93 is connect with transfer pump 92, and transfer pump 92 is connect with level-one spiral flocculator 10, level-one spiral wadding
Condenser 10 connect with spherical reaction kettle 12, and spherical reaction kettle 12 is connect with deuterostrophies flocculator 100, spherical reaction kettle top and
Pulse gas generator 19 connects.The end of deuterostrophies flocculator 100 is connect through piping with cyclone separator.
Prepare liquefied ammonia, the TiCl4 that purity is 99%, pure, dry oxygen, inert gas.Oxygen is allowed to pass through oxygen gas
Connector 2 is introduced directly into the mixed expanded pipe 21 of flame hydrolysis furnace, and inert gas carrier is directly led by another way inert gas connector 1
Enter the mixed expanded pipe 21 of flame hydrolysis furnace, effect is to prevent burner noz(zle) mouth from scabbing using the impacting with high pressure effect of air-flow.Ammonia
The mixture of hydrogen and nitrogen obtained by decomposing is passed through hydrogen-containing fuel as hydrogen-containing fuel after the pressurization of air blower 6 by decomposer 7
Pipe 61 imports the high pressure outer cover 3 of mixed expanded pipe 21, using multiple hollow fiber film assemblies 16 by hydrogen penetrate into mixing it is swollen
In tube expansion 21.
TiCl4 input pipe 15 passes through high pressure outer cover 3 and TiCl4 is introduced directly into the mixed expanded pipe 21 of flame hydrolysis furnace, each road
Gas enters burning at burner noz(zle), hydrolysis after expansion tube 21 collects.Entire reaction occurs very fast, almost instantaneously into
Capable entire reaction process is also rapider than in water, and under this hot conditions, the most important product Ti02 of hydrolysis.It is big absolutely
Part is all existing for rutile-type.
The mixture that 9 bottom of furnace body comes out imports the flocculation of level-one flocculator by transfer pump.Aerosol is in flocculation pipe
Flocculation is usually unable to being grown up completely to several microns for primary row, therefore using spherical reaction kettle ageing reaction+second level flocculation
Mode solve, after the aerosol containing Ti02 particle stops 3-8 seconds again in flocculator flocculation, into spherical reaction kettle
Ageing reaction 1-2 minutes, spherical reaction kettle top are connect with pulse gas generator 19, and pulse gas generator 19 is anti-to spherical shape
It answers and is loaded into nucleation gas in kettle, nucleation gas carrier is nitrogen, potassium chloride, sodium aluminate mixed solution of the nucleating agent for 18%, wherein
Potassium chloride: sodium aluminate=1:1.To promote Ti02 particle growth.
Mixture by ageing reaction enters second level through flocculator, flocculates, is able to achieve again through flocculator by second level
99.5% or more collection rate.Then it is separated in cyclone separator, the product oxide obtained from cyclone separator 81 is de-
It collects to obtain product through product hopper after sour furnace depickling.The sweep gas mixture come out from cyclone separator carries out condensation process, cold
Solidifying temperature is -23 DEG C, will be recycled after gas filtration.
Referring in 5.1.1, GB/T2511.4-85, GB/T3185-92 in GB/T 5211.20-1999, GB1706-9
5.7, GB/T 1717-86, GB/T 1716-79(89), GB/T 1713-89 Ti02 produced by the invention is detected, obtain
Inspection result in following table.
Claims (4)
1. a kind of device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania, including furnace body, TiCl4Input pipe contains
Hydrogen fuel pipe is equipped with refractory material layer it is characterized in that being covered with water jacket outside the furnace body in the furnace body, bottom of furnace body is equipped with anti-
Object is answered to export, the intracorporal top of furnace is equipped with burner noz(zle), and burner noz(zle) is connect with mixed expanded bottom of the tube, mixed expanded pipe top
It is respectively equipped with oxygen gas connector, inert gas connector, high pressure outer cover, TiCl are arranged with outside mixed expanded pipe4Input pipe passes through
It is connect in the middle part of high pressure outer cover and mixed expanded pipe, hydrogen-containing fuel pipe is connect with high pressure outer cover, outside the mixed expanded pipe and high pressure
Hollow fiber film assembly is equipped between cover.
2. the device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania according to claim 1, it is characterized in that
The burner noz(zle) exit is equipped with igniter.
3. the device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania according to claim 1, it is characterized in that
The hydrogen-containing fuel pipe is connect with ammonia decomposer (7), and ammonia decomposer is connect with ammonia head tank.
4. the device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania according to claim 1, it is characterized in that
The reactant exit is connect with transfer pump, and transfer pump is connect with level-one spiral flocculator, and level-one spiral flocculator and spherical shape are anti-
Kettle is answered to connect, spherical reaction kettle is connect with deuterostrophies flocculator, and the end of deuterostrophies flocculator is through piping and whirlwind point
It connects from device, is connect at the top of spherical reaction kettle with pulse gas generator.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2016107796571 | 2016-08-31 | ||
| CN201610779657 | 2016-08-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107265500A CN107265500A (en) | 2017-10-20 |
| CN107265500B true CN107265500B (en) | 2019-06-07 |
Family
ID=60074288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710277071.XA Active CN107265500B (en) | 2016-08-31 | 2017-04-25 | A kind of device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107265500B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109319836A (en) * | 2018-10-16 | 2019-02-12 | 东北大学秦皇岛分校 | TiO under a kind of electric field controls2The pyrolytic synthesis method of nano particle |
| CN113198390A (en) * | 2021-05-28 | 2021-08-03 | 哈尔滨学院 | High-efficient processingequipment of nanometer titanium dioxide |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1391078A (en) * | 2001-06-11 | 2003-01-15 | 中国科学院化工冶金研究所 | Oxidizing furnace able to remove scar by spraying titanium oxide particles and chlorination process and its method for removing scar |
| CN1721328A (en) * | 2005-05-31 | 2006-01-18 | 昆明理工大学 | Method and apparatus for preparing fumed nano oxide |
| CN1736879A (en) * | 2005-07-21 | 2006-02-22 | 华东理工大学 | Preparation method of gas phase nano titanium dioxide with average grain size |
| WO2006135272A1 (en) * | 2005-06-14 | 2006-12-21 | Mikhail Alexeevich Gorovoi | Installation for synthesis of titanium dioxide and plasma chemical reactor |
-
2017
- 2017-04-25 CN CN201710277071.XA patent/CN107265500B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1391078A (en) * | 2001-06-11 | 2003-01-15 | 中国科学院化工冶金研究所 | Oxidizing furnace able to remove scar by spraying titanium oxide particles and chlorination process and its method for removing scar |
| CN1721328A (en) * | 2005-05-31 | 2006-01-18 | 昆明理工大学 | Method and apparatus for preparing fumed nano oxide |
| WO2006135272A1 (en) * | 2005-06-14 | 2006-12-21 | Mikhail Alexeevich Gorovoi | Installation for synthesis of titanium dioxide and plasma chemical reactor |
| CN1736879A (en) * | 2005-07-21 | 2006-02-22 | 华东理工大学 | Preparation method of gas phase nano titanium dioxide with average grain size |
Non-Patent Citations (1)
| Title |
|---|
| 氢氧火焰水解法制备纳米TiO2技术研究;冉青荣;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20051215(第8期);第47页最后一段-第49页倒数第二段，第54页倒数第二段，第55页第3段，第56页最后一段，第57页第2段，第59页最后一段，第60页表4-1，第66页最后一段，图4-2，图4-5，图4-6 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107265500A (en) | 2017-10-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100369803C (en) | Method and apparatus for preparing fumed nano oxide | |
| CN101791565B (en) | TiO2@ graphite phase carbon nitride heterojunction composite photocatalyst and preparation method thereof | |
| WO2016146070A1 (en) | Bismuth-titanium oxide nanowire material used for photocatalysis, and preparation method | |
| CN104646066B (en) | A kind of preparation method of polymer/titanium dioxide multiple elements design photocatalysis film | |
| CN107265500B (en) | A kind of device of oxyhydrogen flame Hydrolyze method preparation high purity nanometer titania | |
| CN1302998C (en) | Preparation method of gas phase nano titanium dioxide with average grain size | |
| CN102658105B (en) | Continuous preparation method of titanium dioxide with high visible light absorptivity | |
| CN108914250B (en) | Preparation method of polyacetylacetonato titanium precursor sol spinning solution, titanium oxide continuous fiber and nano fiber | |
| WO2015101361A1 (en) | Method of producing nanoscale white carbon black by using furnace flue gas directly to carbonize water glass | |
| CN100445209C (en) | Preparation method of new type nano-titanium dioxide powder | |
| CN106219605B (en) | A method of rutile type nano titanic oxide is prepared using oxyhydrogen flame stove | |
| CN106475125A (en) | Graphite phase carbon nitride and nano titanium oxide composite coating additive and preparation method | |
| CN105600790A (en) | Method for co-producing ultra-pure nano-silica and biological oil by using rice husk | |
| CN106492840A (en) | A kind of Titanium Dioxide sulfur indium copper composite nano-fiber material and preparation method thereof | |
| CN109279649B (en) | Preparation method of lithium titanate with nanotube hierarchical structure, application of lithium titanate and product | |
| CN103041866A (en) | Preparation method of titanium dioxide-mesoporous polymer nano porous composite visible light catalytic material | |
| CN1876289B (en) | Method for preparing antimony doped stannic oxide nanometer electricity-conductive powder | |
| CN103253704A (en) | Semiconductor porous bismuth oxide nanosphere and preparation method and application thereof | |
| CN206529301U (en) | A kind of oxyhydrogen flame stove for preparing rutile type nano titanic oxide | |
| CN108993558A (en) | A kind of preparation method of high-performance titanium dioxide optical catalyst | |
| CN110142038A (en) | The method for preparing the nano amorphous titanium dioxide of tin dope using chloridising intermediate | |
| CN108479746B (en) | Preparation method and application of bismuth titanate nanosheet | |
| CN102120611A (en) | Preparation method of rutile type nano titanium dioxide | |
| AU2021102854A4 (en) | A bismuth molybdate/carbon flexible membrane photocatalytic material, preparation method and application thereof | |
| CN105177765B (en) | A kind of method that use carboxylic acid prepares nickel oxide fiber as part |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190527 Address after: 433000 No. 21 Huanchang West Road, Shahu Original Seed Farm, Xiantao City, Hubei Province Applicant after: XIANTAO ZHONGXING ELECTRONIC MATERIAL CO.,LTD. Address before: 433000 Taoyuan Apartment, Taoyuan Avenue, Ganhe Office, Xiantao City, Hubei Province Applicant before: HUBEI ZHIQUAN PATENT TECHNOLOGY APPLICATION DEVELOPMENT Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20191217 Granted publication date: 20190607 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20221217 Granted publication date: 20190607 |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20221217 Granted publication date: 20190607 |