CN107254366A - A kind of glass cleaner and preparation method thereof - Google Patents

A kind of glass cleaner and preparation method thereof Download PDF

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Publication number
CN107254366A
CN107254366A CN201710396844.6A CN201710396844A CN107254366A CN 107254366 A CN107254366 A CN 107254366A CN 201710396844 A CN201710396844 A CN 201710396844A CN 107254366 A CN107254366 A CN 107254366A
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CN
China
Prior art keywords
parts
glass cleaner
mixture
mixing
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710396844.6A
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Chinese (zh)
Inventor
戴思捷
戴宇轩
沈天宇
潘逸汝
李雪琦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Fine Shield Energy Saving Technology Co Ltd
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Jiangsu Fine Shield Energy Saving Technology Co Ltd
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Application filed by Jiangsu Fine Shield Energy Saving Technology Co Ltd filed Critical Jiangsu Fine Shield Energy Saving Technology Co Ltd
Priority to CN201710396844.6A priority Critical patent/CN107254366A/en
Publication of CN107254366A publication Critical patent/CN107254366A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86Mixtures of anionic, cationic, and non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2017Monohydric alcohols branched
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/3409Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Surface Treatment Of Glass (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of glass cleaner and preparation method thereof, glass cleaner is made up of following components:Isopropanol, diethylene glycol monoethyl ether, chelating agent, calgon, triethanolamine, 2 methyl propane sulfonic acids, antistatic additive, antifoggant and APES.Preparation method is, first by isopropanol, diethylene glycol monoethyl ether, chelating agent, and calgon and triethanolamine stirring are mixed to get mixture one;Then by 2 methyl propane sulfonic acids, antistatic additive obtains mixture two after antifoggant and APES mixing;Finally mixture one and mixture two are heated under the conditions of susceptible gas shield after mixing, are cooled to room temperature, obtain glass cleaner.The glass cleaner that the present invention is provided can be applied well under cryogenic, and reaching prevents the effect of atomization.

Description

A kind of glass cleaner and preparation method thereof
Technical field
The invention belongs to cleaning agent preparing technical field, and in particular to a kind of glass cleaner and preparation method thereof.
Background technology
Glass is a kind of relatively transparent solid matter, and viscosity in contiguous network structure, cooling procedure is formed in melting Gradually increase and harden and non crystallized silicates nonmetallic materials.The composition Main Ingredients and Appearance of simple glass chemical oxide is Silica.It is widely used in building, for every wind printing opacity, belonging to mixture.It is easy to that dust, spot occurs on glass The problems such as, how the problem of cleaning is increasingly paid close attention to as people is carried out to glass.Can use at present ammonia solution or Gasoline or other glass cleaners are cleaned, by water and ammonia solution or gasoline or other glass during cleaning Cleaning glass window after cleaning agent mixing, is wiped with dry cloth again after glass is slightly dry, inconvenient for use, simultaneously because the species of glass It is varied, also have high requirements to use environment, such as at low ambient temperatures, when such as winter cleans vehicle glass, generally make Bath of glass is easy to produce atomization jelly film on vehicle glass after the cleaning, have impact on the normal of automobile and uses.
The content of the invention
It is an object of the invention to provide a kind of glass cleaner and its system to overcome above the deficiencies in the prior art Preparation Method, can at low ambient temperatures using and effectively prevent atomization.
Technical scheme is as follows:
A kind of glass cleaner, is made up of the component of following parts by weight meter:2-5 parts of isopropanol, diethylene glycol monoethyl ether 3-6 Part, 1-3 parts of chelating agent, 0.1-0.2 parts of calgon, 2-4 parts of triethanolamine, 1-3 parts of 2- methyl propane sulfonic acids, antistatic additive 0.5-1 parts, 2-6 parts of 1-2 parts of antifoggant and APES.
Described glass cleaner, chelating agent can be ethylenediamine tetra-acetic acid.
Described glass cleaner, antistatic additive can be ester based quaternary ammonium salt.
Described glass cleaner, antifoggant can be laurate.
The preparation method of described glass cleaner, comprises the following steps:
Step 1, by isopropanol, diethylene glycol monoethyl ether, chelating agent, calgon and triethanolamine stirring mix 10- 20 minutes, obtain mixture one;
Step 2, by 2- methyl propane sulfonic acids, antistatic additive is mixed after antifoggant and APES mixing Thing two;
Step 3, mixture one and mixture two are heated under the conditions of susceptible gas shield after mixing, are cooled to room temperature, Obtain glass cleaner.
Stirred in the preparation method of described glass cleaner, step 1 mixing mixing speed can for 130-150 turn/ Minute.
The heating-up temperature that mixing is heated in the preparation method of described glass cleaner, step 3 can be 30-40 DEG C.
The glass cleaner that the present invention is provided can be used in low temperature environment, and can effectively prevent glass atomization.
Embodiment:
Embodiment 1
A kind of glass cleaner, is made up of the component of following parts by weight meter:2 parts of isopropanol, 3 parts of diethylene glycol monoethyl ether, 1 part of chelating agent ethylenediamine tetra-acetic acid, 0.1 part of calgon, 2 parts of triethanolamine, 1 part of 2- methyl propane sulfonic acids, ester based quaternary ammonium salt 2 parts of 0.5 part of antistatic additive, 1 part of antifoggant laurate and APES.
The preparation method of described glass cleaner, comprises the following steps:
Step 1, by isopropanol, diethylene glycol monoethyl ether, chelating agent, calgon and triethanolamine stirring mix 10 points Clock, mixing speed is 130 revs/min, obtains mixture one;
Step 2, by 2- methyl propane sulfonic acids, antistatic additive is mixed after antifoggant and APES mixing Thing two;
Step 3, mixture one and mixture two are heated under the conditions of susceptible gas shield after mixing, are cooled to room temperature, Glass cleaner is obtained, heating-up temperature is 30 DEG C.
Embodiment 2
A kind of glass cleaner, is made up of the component of following parts by weight meter:3 parts of isopropanol, 4 parts of diethylene glycol monoethyl ether, 1 part of chelating agent ethylenediamine tetra-acetic acid, 0.1 part of calgon, 2 parts of triethanolamine, 2 parts of 2- methyl propane sulfonic acids, ester based quaternary ammonium salt 4 parts of 0.6 part of antistatic additive, 2 parts of antifoggant laurate and APES.
The preparation method of described glass cleaner, comprises the following steps:
Step 1, by isopropanol, diethylene glycol monoethyl ether, chelating agent, calgon and triethanolamine stirring mix 13 points Clock, mixing speed is 140 revs/min, obtains mixture one;
Step 2, by 2- methyl propane sulfonic acids, antistatic additive is mixed after antifoggant and APES mixing Thing two;
Step 3, mixture one and mixture two are heated under the conditions of susceptible gas shield after mixing, are cooled to room temperature, Glass cleaner is obtained, heating-up temperature is 35 DEG C.
Embodiment 3
A kind of glass cleaner, is made up of the component of following parts by weight meter:4 parts of isopropanol, 5 parts of diethylene glycol monoethyl ether, 2 parts of chelating agent ethylenediamine tetra-acetic acid, 0.2 part of calgon, 3 parts of triethanolamine, 2 parts of 2- methyl propane sulfonic acids, ester based quaternary ammonium salt 2-6 parts of 0.7 part of antistatic additive, 2 parts of antifoggant laurate and APES.
The preparation method of described glass cleaner, comprises the following steps:
Step 1, by isopropanol, diethylene glycol monoethyl ether, chelating agent, calgon and triethanolamine stirring mix 16 points Clock, mixing speed is 140 revs/min, obtains mixture one;
Step 2, by 2- methyl propane sulfonic acids, antistatic additive is mixed after antifoggant and APES mixing Thing two;
Step 3, mixture one and mixture two are heated under the conditions of susceptible gas shield after mixing, are cooled to room temperature, Glass cleaner is obtained, heating-up temperature is 35 DEG C.
Embodiment 4
A kind of glass cleaner, is made up of the component of following parts by weight meter:5 parts of isopropanol, 6 parts of diethylene glycol monoethyl ether, 3 parts of chelating agent ethylenediamine tetra-acetic acid, 0.2 part of calgon, 4 parts of triethanolamine, 3 parts of 2- methyl propane sulfonic acids, ester based quaternary ammonium salt 6 parts of 1 part of antistatic additive, 2 parts of antifoggant laurate and APES.
The preparation method of described glass cleaner, comprises the following steps:
Step 1, by isopropanol, diethylene glycol monoethyl ether, chelating agent, calgon and triethanolamine stirring mix 20 points Clock, mixing speed is 150 revs/min, obtains mixture one;
Step 2, by 2- methyl propane sulfonic acids, antistatic additive is mixed after antifoggant and APES mixing Thing two;
Step 3, mixture one and mixture two are heated under the conditions of susceptible gas shield after mixing, are cooled to room temperature, Glass cleaner is obtained, heating-up temperature is 40 DEG C.
The glass cleaner that is prepared to above example carries out performance test, mainly investigates it under cryogenic Cleaning situation, and preventing atomization performance, it by above cleaning agent according to the mass ratio with deionized water is 1 that specific method, which is,:5 are carried out Cleaning agent, then under the conditions of -10 DEG C, is sprayed on vehicle glass by configuration by the nozzle before automobile, opens wiper Clean windshield.Observed after cleaning up in 5h and jelly film is whether there is on vehicle glass occur, record case, and with conventional glass Glass water is contrasted, as a result as follows:
Having result above to can be seen that the glass cleaner that the present invention provides can use in low temperature environment, and energy It is enough effectively to prevent glass atomization.

Claims (7)

1. a kind of glass cleaner, it is characterised in that be made up of the component of following parts by weight meter:2-5 parts of isopropanol, diethylene glycol Single ether 3-6 parts, 1-3 parts of chelating agent, 0.1-0.2 parts of calgon, 2-4 parts of triethanolamine, 1-3 parts of 2- methyl propane sulfonic acids, 2-6 parts of 0.5-1 parts of antistatic additive, 1-2 parts of antifoggant and APES.
2. glass cleaner according to claim 1, it is characterised in that chelating agent is ethylenediamine tetra-acetic acid.
3. glass cleaner according to claim 1, it is characterised in that antistatic additive is ester based quaternary ammonium salt.
4. glass cleaner according to claim 1, it is characterised in that antifoggant is laurate.
5. the preparation method of the glass cleaner described in claim 1, it is characterised in that comprise the following steps:
Step 1, by isopropanol, diethylene glycol monoethyl ether, chelating agent, calgon and triethanolamine stirring mixing 10-20 divide Clock, obtains mixture one;
Step 2, by 2- methyl propane sulfonic acids, antistatic additive obtains mixture two after antifoggant and APES mixing;
Step 3, mixture one and mixture two are heated under the conditions of susceptible gas shield after mixing, is cooled to room temperature, obtains Glass cleaner.
6. the preparation method of glass cleaner according to claim 5, it is characterised in that stirring mixing stirs in step 1 Speed is mixed for 130-150 revs/min.
7. the preparation method of glass cleaner according to claim 5, it is characterised in that heating mixing adds in step 3 Hot temperature is 30-40 DEG C.
CN201710396844.6A 2017-05-31 2017-05-31 A kind of glass cleaner and preparation method thereof Pending CN107254366A (en)

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Application Number Priority Date Filing Date Title
CN201710396844.6A CN107254366A (en) 2017-05-31 2017-05-31 A kind of glass cleaner and preparation method thereof

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CN107254366A true CN107254366A (en) 2017-10-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108328945A (en) * 2018-01-19 2018-07-27 江苏理文化工有限公司 A kind of production technology of glass finishing agent
CN112266831A (en) * 2020-09-28 2021-01-26 南京慧智莲华科技有限公司 Polar region available biomass glass water and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434891A (en) * 2007-11-16 2009-05-20 比亚迪股份有限公司 Glass cleaning agent
CN102492582A (en) * 2011-11-29 2012-06-13 陕西中核大地实业有限公司 Long-acting environment-friendly automobile air window glass washing liquid
CN102766551A (en) * 2012-07-19 2012-11-07 山东商业职业技术学院 Multifunctional cleaning solution for automobile windshield
CN103614262A (en) * 2013-11-18 2014-03-05 河南农业大学 Automotive glass cleaning agent
CN103981043A (en) * 2014-06-11 2014-08-13 陈建宝 Stain-removal antifogging detergent for glass
CN104087440A (en) * 2014-07-12 2014-10-08 梁胜光 Powerfully-detergent glass cleaner

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434891A (en) * 2007-11-16 2009-05-20 比亚迪股份有限公司 Glass cleaning agent
CN102492582A (en) * 2011-11-29 2012-06-13 陕西中核大地实业有限公司 Long-acting environment-friendly automobile air window glass washing liquid
CN102766551A (en) * 2012-07-19 2012-11-07 山东商业职业技术学院 Multifunctional cleaning solution for automobile windshield
CN103614262A (en) * 2013-11-18 2014-03-05 河南农业大学 Automotive glass cleaning agent
CN103981043A (en) * 2014-06-11 2014-08-13 陈建宝 Stain-removal antifogging detergent for glass
CN104087440A (en) * 2014-07-12 2014-10-08 梁胜光 Powerfully-detergent glass cleaner

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108328945A (en) * 2018-01-19 2018-07-27 江苏理文化工有限公司 A kind of production technology of glass finishing agent
CN112266831A (en) * 2020-09-28 2021-01-26 南京慧智莲华科技有限公司 Polar region available biomass glass water and preparation method thereof

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Application publication date: 20171017