CN107201566A - A kind of waterproof oil resistant spinning of fabric for kitchen use - Google Patents
A kind of waterproof oil resistant spinning of fabric for kitchen use Download PDFInfo
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- CN107201566A CN107201566A CN201710351166.1A CN201710351166A CN107201566A CN 107201566 A CN107201566 A CN 107201566A CN 201710351166 A CN201710351166 A CN 201710351166A CN 107201566 A CN107201566 A CN 107201566A
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- well mixed
- oil resistant
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- fiber
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Abstract
The invention discloses a kind of waterproof oil resistant spinning of fabric for kitchen use, its raw material includes modified polylactic acid fiber, flax fiber, cotton fiber, lignocellulosic, polyester fiber, powdered whiting, barium sulfate, antimony oxide, triethanolamine oleate, amido silicon oil, glyceryl tristearate, N methyl pyrrolidones, polybutylene terephthalate (PBT), neopelex, trihydroxyethyl methyl quaternary ammonium Methylsulfate, sodium hydroxyethlcellulose, polyvinyl alcohol, silane coupler KH 560 and oil resistant modified additive.The fabric spinning for kitchen use of the present invention has excellent waterproof and oil resistance.
Description
Technical field
The present invention relates to the waterproof oil resistant spinning of the technical field of spinning, more particularly to a kind of fabric for kitchen use.
Background technology
Acid fiber by polylactic produces breast from rich amyloid crops such as corn, beet, potatos through lactobacillus-fermented
Acid, then pass through the processes such as polymerization, solution or the melt spinning of a series of complex and be made, its product has excellent bio-compatible
Property, degradability, flame retardancy, wrinkle resistance, UV resistant and the characteristic such as nontoxic, in fiber product exploitation, health care, agricultural ring
The fields such as guarantor obtain extensive use.Then the waterproof oil resistance of single acid fiber by polylactic preparation spinning can not meet and actually make
The demand of used time.
The content of the invention
To solve technical problem present in background technology, the present invention proposes that a kind of waterproof oil resistant of fabric for kitchen use is spun
Silk, with excellent waterproof and oil resistance.
A kind of waterproof oil resistant spinning of fabric for kitchen use proposed by the present invention, its raw material includes by weight：Modified poly- breast
Sour fiber 50-80 parts, 5-15 parts of flax fiber, 1-5 parts of cotton fiber, 3-8 parts of lignocellulosic, 3-5 parts of polyester fiber, heavy carbon
Sour calcium 1-4 parts, it is 3-6 parts of barium sulfate, 2-6 parts of antimony oxide, 2-6 parts of triethanolamine oleate, 4-8 parts of amido silicon oil, three stearic
1-4 parts of acid glyceride, 2-5 parts of 1-METHYLPYRROLIDONE, 2-8 parts of polybutylene terephthalate (PBT), neopelex
2-6 parts, 3-9 parts of trihydroxyethyl methyl quaternary ammonium Methylsulfate, 2-6 parts of sodium hydroxyethlcellulose, 5-15 parts of polyvinyl alcohol, silane it is even
Join 4-8 parts of agent KH-560,4-9 parts of oil resistant modified additive.
Preferably, the raw material of modified polylactic acid fiber includes by weight：5-15 parts of paraffin, 4-8 parts of nano silicon,
2-6 parts of toluene, 1-4 parts of Vitrified powder, 3-6 parts of hydrochloric acid solution, 2-6 parts of carbamate, 1-5 parts of isopropyl acrylate, PLA
10-20 parts of fiber.
Preferably, modified polylactic acid fiber is prepared by following technique：Paraffin is heated in water-bath melts it, so
Nano silicon is added afterwards and toluene is well mixed, stirring, is cooled to room temperature and is obtained material A；Vitrified powder is put into calcining furnace
Middle calcining, cooling is soaked in hydrochloric acid solution, and filtering is taken out, and cleans drying with clear water, crushing obtains material B, then by material
A, material B, carbamate and isopropyl acrylate are well mixed, heat up, and insulation then disperses, is cooled to room temperature, then adds
Enter acid fiber by polylactic to be well mixed, heat up, be incubated, stirring is cooled to room temperature and obtains modified polylactic acid fiber.
Preferably, modified polylactic acid fiber is prepared by following technique：Paraffin is heated in water-bath melts it, so
Nano silicon is added afterwards and toluene is well mixed, is stirred 20-40min in 350-450r/min rotating speeds, is cooled to room temperature and obtains
To material A；Vitrified powder is put into calcining furnace and calcines 2-5h at 820-920 DEG C, cools down, 1-3h is soaked in hydrochloric acid solution,
Filtering is taken out, and cleans drying with clear water, crushing obtains material B, then that material A, material B, carbamate and acrylic acid is different
Propyl ester is well mixed, and is warming up to 80-90 DEG C, is incubated 1-3h, is then disperseed 20-40min in 3500-4500r/min, is cooled to room
Temperature, is subsequently added into acid fiber by polylactic and is well mixed, be warming up to 120-140 DEG C, be incubated 20-40min, turn in 1500-2500r/min
Speed stirring 20-40min, is cooled to room temperature and obtains modified polylactic acid fiber.
Preferably, the raw material of oil resistant modified additive includes by weight：5-15 parts of CNT, 3-6 parts of the concentrated sulfuric acid, ethanol
1-5 parts, 2-6 parts of urea, 3-6 parts of polyvinylpyrrolidone, 2-5 parts of deionized water, 3-6 parts of sodium chloride, 2-6 parts of defoamer, nitre
Sour aluminium 1-4 parts, 3-8 parts of nano titanium oxide, 2-6 parts of zirconium sulfate, 2-6 parts of disodium hydrogen phosphate, 1-5 parts of zinc powder, silane coupler
3-6 parts of KH-570,4-8 parts of azodiisobutyronitrile, 2-6 parts of methyl methacrylate.
Preferably, oil resistant modified additive is prepared by following technique：CNT and the concentrated sulfuric acid are well mixed, stirred
Mix, filter, washing to neutrality, suction filtration is dried, and is ground, sieving, add ethanol and be well mixed, stirring in water bath is scattered to obtain material
a；Urea, polyvinylpyrrolidone, deionized water, sodium chloride and defoamer are well mixed, stir, then add aluminum nitrate,
Nano titanium oxide and zirconium sulfate are well mixed, heat up, insulation, are then cooled to addition disodium hydrogen phosphate mixing after room temperature equal
Even, ageing, filtration washing is dried, room temperature is cooled to after calcining and obtains material b；By material b, material c, zinc powder, silane coupler
KH-570, azodiisobutyronitrile and methyl methacrylate are well mixed, heat up, insulation, suction filtration, and washing is dried under vacuum to perseverance
Weight, grinds, and sieving produces oil resistant to modified additive.
Preferably, oil resistant modified additive is prepared by following technique：CNT and the concentrated sulfuric acid are well mixed, in
80-90 DEG C, 350-550 DEG C of stirring 2-4h, filtering, washing to neutrality, suction filtration are dried, and 150-250 mesh sieves are crossed in grinding, add second
Alcohol is well mixed, and disperseing 2-4h in 45-55 DEG C of stirring in water bath obtains material a；By urea, polyvinylpyrrolidone, deionized water,
Sodium chloride and defoamer are well mixed, and 10-30min is stirred in 350-650r/min rotating speeds, then add aluminum nitrate, nano-silica
Change titanium and zirconium sulfate is well mixed, be warming up to 70-90 DEG C, be incubated 10-20min, be then cooled to after room temperature and add phosphoric acid hydrogen two
Sodium is well mixed, ageing, and filtration washing is dried, room temperature is cooled to after calcining and obtains material b；By material b, material c, zinc powder, silicon
Alkane coupling agent kh-570, azodiisobutyronitrile and methyl methacrylate monomer, are warming up to 75-85 DEG C, are incubated 5-7h, suction filtration,
Washing, constant weight is dried under vacuum in 750-850 DEG C, is ground, and is crossed 150-250 mesh sieves, is produced oil resistant to modified additive.
The preparation method of the present invention, including：By modified polylactic acid fiber, flax fiber, cotton fiber, lignocellulosic, poly-
Ester fiber, powdered whiting, barium sulfate, antimony oxide, triethanolamine oleate, amido silicon oil, glyceryl tristearate, N- first
Base pyrrolidones, polybutylene terephthalate (PBT), neopelex, trihydroxyethyl methyl quaternary ammonium Methylsulfate, carboxylic
Ethyl cellulose sodium, polyvinyl alcohol, silane coupler KH-560 and oil resistant modified additive are well mixed, then in 500-800r/
Min rotating speeds stir 20-40min, are then placed in melt spinning machine, and in 140-160 DEG C, spinneret orifice is extruded, after cooling and solidifying
To the waterproof oil resistant spinning of fabric for kitchen use.
A kind of waterproof oil resistant spinning of fabric for kitchen use of the present invention, it is fine that its raw material includes modified polylactic acid fiber, flax
Dimension, cotton fiber, lignocellulosic, polyester fiber, powdered whiting, barium sulfate, antimony oxide, triethanolamine oleate, amino
Silicone oil, glyceryl tristearate, 1-METHYLPYRROLIDONE, polybutylene terephthalate (PBT), neopelex, three hydroxyls
Ethyl-methyl quaternary ammonium Methylsulfate, sodium hydroxyethlcellulose, polyvinyl alcohol, silane coupler KH-560 and oil resistant modified additive.
Using modified polylactic acid fiber, flax fiber, cotton fiber, lignocellulosic and polyester fiber as major ingredient, with powdered whiting, sulfuric acid
Barium and antimony oxide are filler, with triethanolamine oleate, amido silicon oil, glyceryl tristearate, 1-METHYLPYRROLIDONE, poly-
Mutual-phenenyl two acid bromide two alcohol ester, neopelex, trihydroxyethyl methyl quaternary ammonium Methylsulfate, sodium hydroxyethlcellulose,
Polyvinyl alcohol, silane coupler KH-560 and oil resistant modified additive are auxiliary agent, by the cooperation of major ingredient, filler and auxiliary agent, are obtained
Fabric spinning for kitchen use of the invention there is excellent waterproof oil resistance.Wherein, modified polylactic acid fiber by by paraffin in
Heating melts it in water-bath, then adds nano silicon and toluene is well mixed, stirring, be cooled to room temperature and obtain material
A；Vitrified powder is put into calcining furnace and calcined, cooling is soaked in hydrochloric acid solution, and filtering is taken out, and drying is cleaned with clear water, is crushed
Material B is obtained, then material A, material B, carbamate and isopropyl acrylate is well mixed, heated up, insulation then divides
Dissipate, be cooled to room temperature, be subsequently added into acid fiber by polylactic and be well mixed, heat up, be incubated, stirring is cooled to room temperature and obtains modified poly-
Acid fiber, in the kitchen fabric spinning for applying to the present invention, effectively increases the waterproof of fabric spinning in kitchen of the present invention
And oil resistance.Wherein, oil resistant modified additive is stirred by the way that CNT and the concentrated sulfuric acid are well mixed, and filtering is washed into
Property, suction filtration, drying, grinding, sieving, adding ethanol is well mixed, and stirring in water bath disperses to obtain material a；By urea, polyethylene pyrrole
Pyrrolidone, deionized water, sodium chloride and defoamer are well mixed, stirring, then add aluminum nitrate, nano titanium oxide and sulfuric acid
Zirconium is well mixed, and is heated up, insulation, is then cooled to addition disodium hydrogen phosphate after room temperature and is well mixed, ageing, filtration washing is done
It is dry, room temperature is cooled to after calcining and obtains material b；By material b, material c, zinc powder, Silane coupling reagent KH-570, azodiisobutyronitrile
It is well mixed with methyl methacrylate, heat up, insulation, suction filtration, washing is dried under vacuum to constant weight, grinds, sieving is produced resistance to
Oil arrives modified additive, and in the kitchen fabric spinning for applying to the present invention, the waterproof for effectively increasing kitchen fabric spinning is resistance to
Oiliness energy.The kitchen fabric spinning of the present invention has excellent waterproof and oil resistance.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of modified polylactic acid fiber can for 50 parts, 55 parts, 60 parts, 65 parts, 70 parts,
75 parts, 80 parts；The parts by weight of flax fiber can for 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts,
15 parts；The parts by weight of cotton fiber can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The parts by weight of lignocellulosic can for 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of polyester fiber can for 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts；The parts by weight of powdered whiting can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Sulphur
The parts by weight of sour barium can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of antimony oxide can be 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of triethanolamine oleate can for 2 parts, 3 parts,
4 parts, 5 parts, 6 parts；The parts by weight of amido silicon oil can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of glyceryl tristearate
It can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of 1-METHYLPYRROLIDONE can for 2 parts, 2.5
Part, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of polybutylene terephthalate (PBT) can for 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of neopelex can
Think 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of trihydroxyethyl methyl quaternary ammonium Methylsulfate can for 3 parts, 4 parts, 5 parts, 6
Part, 7 parts, 8 parts, 9 parts；The parts by weight of sodium hydroxyethlcellulose can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight of polyvinyl alcohol
Part can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；Silane coupler KH-560's
Parts by weight can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of oil resistant modified additive
It can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts.
Embodiment 1
A kind of waterproof oil resistant spinning of fabric for kitchen use proposed by the present invention, its raw material includes by weight：Modified poly- breast
Sour 65 parts of fiber, 10 parts of flax fiber, 3 parts of cotton fiber, 5.5 parts of lignocellulosic, 4 parts of polyester fiber, powdered whiting 2.5
Part, 4.5 parts of barium sulfate, 4 parts of antimony oxide, 4 parts of triethanolamine oleate, 6 parts of amido silicon oil, 2.5 parts of glyceryl tristearate,
3.5 parts of 1-METHYLPYRROLIDONE, 5 parts of polybutylene terephthalate (PBT), 4 parts of neopelex, trihydroxyethyl methyl
6 parts of quaternary ammonium Methylsulfate, 4 parts of sodium hydroxyethlcellulose, 10 parts of polyvinyl alcohol, 6 parts of silane coupler KH-560, oil resistant are modified
3.5 parts of auxiliary agent.
Modified polylactic acid fiber is prepared by following technique：10 parts of paraffin are heated in water-bath by weight melts it
Change, then add 6 parts of nano silicons and 4 parts of toluene are well mixed, stir 30min in 400r/min rotating speeds, be cooled to room
Temperature obtains material A；2.5 parts of Vitrified powders are put into calcining furnace and calcine 3.5h at 870 DEG C, are cooled down, in 4.5 parts of hydrochloric acid solutions
2h is soaked, filtering is taken out, clean drying with clear water, crushing obtains material B, then by material A, material B, 4 parts of carbamates
It is well mixed with 3 parts of isopropyl acrylates, 85 DEG C are warming up to, 2h is incubated, then disperses 30min in 4000r/min, is cooled to room
Temperature, is subsequently added into 15 parts of acid fiber by polylactic and is well mixed, be warming up to 130 DEG C, be incubated 30min, in the stirring of 2000r/min rotating speeds
30min, is cooled to room temperature and obtains modified polylactic acid fiber.
Oil resistant modified additive is prepared by following technique：10 parts of CNTs and 4.5 parts of concentrated sulfuric acids are mixed by weight
Close uniform, in 85 DEG C, 450 DEG C of stirring 3h, filtering, washing to neutrality, suction filtration is dried, and 200 mesh sieves are crossed in grinding, add 3 parts of second
Alcohol is well mixed, and disperseing 3h in 50 DEG C of stirring in water bath obtains material a；By 4 parts of urea, 4.5 parts of polyvinylpyrrolidones, 3.5 parts
Deionized water, 4.5 parts of sodium chloride and 4 parts of defoamers are well mixed, and are stirred 20min in 500r/min rotating speeds, are then added 2.5 parts
Aluminum nitrate, 5.5 parts of nano titanium oxides and 4 parts of zirconium sulfates are well mixed, and are warming up to 80 DEG C, are incubated 15min, are then cooled to room
Add 4 parts of disodium hydrogen phosphates after temperature to be well mixed, ageing, filtration washing is dried, room temperature is cooled to after calcining and obtains material b；Will
Material b, material c, 3 parts of zinc powders, 4.5 parts of Silane coupling reagent KH-570s, 6 parts of azodiisobutyronitriles and 4 parts of methyl methacrylates
Monomer, is warming up to 80 DEG C, is incubated 6h, and suction filtration, washing is dried under vacuum to constant weight in 800 DEG C, ground, crosses 200 mesh sieves, produce resistance to
Oil arrives modified additive.
Embodiment 2
A kind of waterproof oil resistant spinning of fabric for kitchen use proposed by the present invention, its raw material includes by weight：Modified poly- breast
Sour 50 parts of fiber, 15 parts of flax fiber, 1 part of cotton fiber, 8 parts of lignocellulosic, 3 parts of polyester fiber, 4 parts of powdered whiting, sulphur
Sour 3 parts of barium, 6 parts of antimony oxide, 2 parts of triethanolamine oleate, 8 parts of amido silicon oil, 1 part of glyceryl tristearate, N- methyl pyrroles
5 parts of pyrrolidone, 2 parts of polybutylene terephthalate (PBT), 6 parts of neopelex, trihydroxyethyl methyl quaternary ammonium sulfuric acid first
3 parts of ester, 6 parts of sodium hydroxyethlcellulose, 5 parts of polyvinyl alcohol, 8 parts of silane coupler KH-560,4 parts of oil resistant modified additive.
Modified polylactic acid fiber is prepared by following technique：5 parts of paraffin are heated in water-bath by weight melts it
Change, then add 8 parts of nano silicons and 2 parts of toluene are well mixed, stir 20min in 450r/min rotating speeds, be cooled to room
Temperature obtains material A；4 parts of Vitrified powders are put into calcining furnace and calcine 5h at 820 DEG C, are cooled down, are soaked in 3 parts of hydrochloric acid solutions
3h, filtering is taken out, and cleans drying with clear water, crushing obtains material B, then by material A, material B, 2 parts of carbamates and 5 parts
Isopropyl acrylate is well mixed, and is warming up to 80 DEG C, is incubated 3h, is then disperseed 40min in 3500r/min, is cooled to room temperature, connects
10 parts of acid fiber by polylactic of addition to be well mixed, be warming up to 140 DEG C, be incubated 20min, 20min is stirred in 2500r/min rotating speeds,
It is cooled to room temperature and obtains modified polylactic acid fiber.
Oil resistant modified additive is prepared by following technique：5 parts of CNTs and 6 parts of concentrated sulfuric acids are mixed equal by weight
Even, in 80 DEG C, 550 DEG C of stirring 2h, filtering, washing to neutrality, suction filtration is dried, and 250 mesh sieves are crossed in grinding, are added 1 part of ethanol and are mixed
Close uniform, disperseing 2h in 55 DEG C of stirring in water bath obtains material a；By 6 parts of urea, 3 parts of polyvinylpyrrolidones, 5 parts of deionized waters,
3 parts of sodium chloride and 6 parts of defoamers are well mixed, and 30min is stirred in 350r/min rotating speeds, then add 1 part of aluminum nitrate, 8 parts receive
Rice titanium dioxide and 2 parts of zirconium sulfates are well mixed, and are warming up to 90 DEG C, are incubated 10min, are then cooled to 6 parts of phosphorus of addition after room temperature
Sour disodium hydrogen is well mixed, ageing, and filtration washing is dried, room temperature is cooled to after calcining and obtains material b；By material b, material c, 1
Part zinc powder, 6 parts of Silane coupling reagent KH-570s, 4 parts of azodiisobutyronitriles and 6 parts of methyl methacrylate monomers, are warming up to 75 DEG C,
7h is incubated, suction filtration, washing is dried under vacuum to constant weight in 750 DEG C, ground, crosses 250 mesh sieves, produce oil resistant to modified additive.
Embodiment 3
A kind of waterproof oil resistant spinning of fabric for kitchen use proposed by the present invention, its raw material includes by weight：Modified poly- breast
Sour 80 parts of fiber, 5 parts of flax fiber, 5 parts of cotton fiber, 3 parts of lignocellulosic, 5 parts of polyester fiber, 1 part of powdered whiting, sulfuric acid
6 parts of barium, 2 parts of antimony oxide, 6 parts of triethanolamine oleate, 4 parts of amido silicon oil, 4 parts of glyceryl tristearate, N- methylpyrroles
2 parts of alkanone, 8 parts of polybutylene terephthalate (PBT), 2 parts of neopelex, trihydroxyethyl methyl quaternary ammonium Methylsulfate 9
Part, 2 parts of sodium hydroxyethlcellulose, 15 parts of polyvinyl alcohol, 4 parts of silane coupler KH-560,9 parts of oil resistant modified additive.
Modified polylactic acid fiber is prepared by following technique：15 parts of paraffin are heated in water-bath by weight melts it
Change, then add 4 parts of nano silicons and 6 parts of toluene are well mixed, stir 40min in 350r/min rotating speeds, be cooled to room
Temperature obtains material A；1 part of Vitrified powder is put into calcining furnace and calcines 2h at 920 DEG C, is cooled down, is soaked in 6 parts of hydrochloric acid solutions
1h, filtering is taken out, and cleans drying with clear water, crushing obtains material B, then by material A, material B, 6 parts of carbamates and 1 part
Isopropyl acrylate is well mixed, and is warming up to 90 DEG C, is incubated 1h, is then disperseed 20min in 4500r/min, is cooled to room temperature, connects
20 parts of acid fiber by polylactic of addition to be well mixed, be warming up to 120 DEG C, be incubated 40min, 40min is stirred in 1500r/min rotating speeds,
It is cooled to room temperature and obtains modified polylactic acid fiber.
Oil resistant modified additive is prepared by following technique：15 parts of CNTs and 3 parts of concentrated sulfuric acids are mixed by weight
Uniformly, in 90 DEG C, 350 DEG C of stirring 4h, filtering, washing to neutrality, suction filtration is dried, and 150 mesh sieves are crossed in grinding, add 5 parts of ethanol
It is well mixed, disperse 4h in 45 DEG C of stirring in water bath and obtain material a；By 2 parts of urea, 6 parts of polyvinylpyrrolidones, 2 parts of deionizations
Water, 6 parts of sodium chloride and 2 parts of defoamers are well mixed, and 10min is stirred in 650r/min rotating speeds, then add 4 parts of aluminum nitrates, 3 parts
Nano titanium oxide and 6 parts of zirconium sulfates are well mixed, and are warming up to 70 DEG C, are incubated 20min, are then cooled to after room temperature and add 2 parts
Disodium hydrogen phosphate is well mixed, ageing, and filtration washing is dried, room temperature is cooled to after calcining and obtains material b；By material b, material
C, 5 parts of zinc powders, 3 parts of Silane coupling reagent KH-570s, 8 parts of azodiisobutyronitriles and 2 parts of methyl methacrylate monomers, are warming up to 85
DEG C, 5h is incubated, suction filtration, washing is dried under vacuum to constant weight in 850 DEG C, ground, crosses 150 mesh sieves, produce oil resistant to modified additive.
Embodiment 4
A kind of waterproof oil resistant spinning of fabric for kitchen use proposed by the present invention, its raw material includes by weight：Modified poly- breast
Sour 55 parts of fiber, 12 parts of flax fiber, 2 parts of cotton fiber, 7 parts of lignocellulosic, 3.5 parts of polyester fiber, 3 parts of powdered whiting,
4 parts of barium sulfate, 5 parts of antimony oxide, 3 parts of triethanolamine oleate, 7 parts of amido silicon oil, 2 parts of glyceryl tristearate, N- methyl
4 parts of pyrrolidones, 3 parts of polybutylene terephthalate (PBT), 5 parts of neopelex, trihydroxyethyl methyl quaternary ammonium sulfuric acid
4 parts of methyl esters, 5 parts of sodium hydroxyethlcellulose, 8 parts of polyvinyl alcohol, 7 parts of silane coupler KH-560,5 parts of oil resistant modified additive.
Modified polylactic acid fiber is prepared by following technique：8 parts of paraffin are heated in water-bath by weight melts it
Change, then add 7 parts of nano silicons and 3 parts of toluene are well mixed, stir 25min in 420r/min rotating speeds, be cooled to room
Temperature obtains material A；3 parts of Vitrified powders are put into calcining furnace and calcine 4h at 830 DEG C, are cooled down, are soaked in 4 parts of hydrochloric acid solutions
2.5h, filtering is taken out, and cleans drying with clear water, crushing obtains material B, then by material A, material B, 3 parts of carbamates and 4
Part isopropyl acrylate is well mixed, and is warming up to 82 DEG C, is incubated 2.5h, is then disperseed 35min in 3800r/min, is cooled to room
Temperature, is subsequently added into 12 parts of acid fiber by polylactic and is well mixed, be warming up to 135 DEG C, be incubated 25min, in the stirring of 2200r/min rotating speeds
25min, is cooled to room temperature and obtains modified polylactic acid fiber.
Oil resistant modified additive is prepared by following technique：8 parts of CNTs and 5 parts of concentrated sulfuric acids are mixed equal by weight
Even, in 82 DEG C, 520 DEG C of stirring 2.5h, filtering, washing to neutrality, suction filtration is dried, and 220 mesh sieves are crossed in grinding, add 2 parts of ethanol
It is well mixed, disperse 2.5h in 52 DEG C of stirring in water bath and obtain material a；By 5 parts of urea, 4 parts of polyvinylpyrrolidones, 4 parts go from
Sub- water, 4 parts of sodium chloride and 5 parts of defoamers are well mixed, and are stirred 25min in 380r/min rotating speeds, are then added 2 parts of aluminum nitrates, 7
Part nano titanium oxide and 3 parts of zirconium sulfates are well mixed, and are warming up to 85 DEG C, are incubated 12min, are then cooled to after room temperature and add 5
Part disodium hydrogen phosphate is well mixed, ageing, and filtration washing is dried, room temperature is cooled to after calcining and obtains material b；By material b, thing
Expect c, 2 parts of zinc powders, 5 parts of Silane coupling reagent KH-570s, 5 parts of azodiisobutyronitriles and 5 parts of methyl methacrylate monomers, be warming up to
78 DEG C, 6.5h is incubated, suction filtration, washing is dried under vacuum to constant weight in 780 DEG C, ground, and crosses 220 mesh sieves, produces oil resistant and is helped to modification
Agent.
Embodiment 5
A kind of waterproof oil resistant spinning of fabric for kitchen use proposed by the present invention, its raw material includes by weight：Modified poly- breast
Sour 75 parts of fiber, 8 parts of flax fiber, 2 parts of cotton fiber, 7 parts of lignocellulosic, 3.5 parts of polyester fiber, 3 parts of powdered whiting, sulphur
Sour 4 parts of barium, 5 parts of antimony oxide, 3 parts of triethanolamine oleate, 7 parts of amido silicon oil, 2 parts of glyceryl tristearate, N- methyl pyrroles
4 parts of pyrrolidone, 3 parts of polybutylene terephthalate (PBT), 5 parts of neopelex, trihydroxyethyl methyl quaternary ammonium sulfuric acid first
4 parts of ester, 5 parts of sodium hydroxyethlcellulose, 8 parts of polyvinyl alcohol, 7 parts of silane coupler KH-560,5 parts of oil resistant modified additive.
Modified polylactic acid fiber is prepared by following technique：8 parts of paraffin are heated in water-bath by weight melts it
Change, then add 7 parts of nano silicons and 3 parts of toluene are well mixed, stir 25min in 420r/min rotating speeds, be cooled to room
Temperature obtains material A；3 parts of Vitrified powders are put into calcining furnace and calcine 4h at 830 DEG C, are cooled down, are soaked in 4 parts of hydrochloric acid solutions
2.5h, filtering is taken out, and cleans drying with clear water, crushing obtains material B, then by material A, material B, 3 parts of carbamates and 4
Part isopropyl acrylate is well mixed, and is warming up to 82 DEG C, is incubated 2.5h, is then disperseed 35min in 3800r/min, is cooled to room
Temperature, is subsequently added into 12 parts of acid fiber by polylactic and is well mixed, be warming up to 135 DEG C, be incubated 25min, in the stirring of 2200r/min rotating speeds
25min, is cooled to room temperature and obtains modified polylactic acid fiber.
Oil resistant modified additive is prepared by following technique：8 parts of CNTs and 5 parts of concentrated sulfuric acids are mixed equal by weight
Even, in 82 DEG C, 520 DEG C of stirring 2.5h, filtering, washing to neutrality, suction filtration is dried, and 220 mesh sieves are crossed in grinding, add 2 parts of ethanol
It is well mixed, disperse 2.5h in 52 DEG C of stirring in water bath and obtain material a；By 5 parts of urea, 4 parts of polyvinylpyrrolidones, 4 parts go from
Sub- water, 4 parts of sodium chloride and 5 parts of defoamers are well mixed, and are stirred 25min in 380r/min rotating speeds, are then added 2 parts of aluminum nitrates, 7
Part nano titanium oxide and 3 parts of zirconium sulfates are well mixed, and are warming up to 85 DEG C, are incubated 12min, are then cooled to after room temperature and add 5
Part disodium hydrogen phosphate is well mixed, ageing, and filtration washing is dried, room temperature is cooled to after calcining and obtains material b；By material b, thing
Expect c, 2 parts of zinc powders, 5 parts of Silane coupling reagent KH-570s, 5 parts of azodiisobutyronitriles and 5 parts of methyl methacrylate monomers, be warming up to
78 DEG C, 6.5h is incubated, suction filtration, washing is dried under vacuum to constant weight in 780 DEG C, ground, and crosses 220 mesh sieves, produces oil resistant and is helped to modification
Agent.
The raw material of the waterproof oil resistant spinning of fabric for kitchen use in embodiment 1- embodiments 5 is subjected to blending and is compiled into face
Material, and fabric progressive can be detected, obtained data are as shown in table 1.
Table 1：
By the analysis to data in table 1, obtain the waterproof oil resistant spinning of the fabric for kitchen use of the present invention have it is excellent
The performance of waterproof and oil resistant.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. the waterproof oil resistant spinning of a kind of fabric for kitchen use, it is characterised in that its raw material includes by weight：Polydactyl acid is fine
50-80 parts of dimension, 5-15 parts of flax fiber, 1-5 parts of cotton fiber, 3-8 parts of lignocellulosic, 3-5 parts of polyester fiber, powdered whiting
1-4 parts, 3-6 parts of barium sulfate, 2-6 parts of antimony oxide, 2-6 parts of triethanolamine oleate, 4-8 parts of amido silicon oil, three stearic acid it is sweet
1-4 parts of grease, 2-5 parts of 1-METHYLPYRROLIDONE, 2-8 parts of polybutylene terephthalate (PBT), neopelex 2-6
It is part, 3-9 parts of trihydroxyethyl methyl quaternary ammonium Methylsulfate, 2-6 parts of sodium hydroxyethlcellulose, 5-15 parts of polyvinyl alcohol, silane coupled
4-8 parts of agent KH-560,4-9 parts of oil resistant modified additive.
2. the waterproof oil resistant spinning of fabric for kitchen use according to claim 1, it is characterised in that modified polylactic acid fiber
Raw material includes by weight：5-15 parts of paraffin, 4-8 parts of nano silicon, 2-6 parts of toluene, 1-4 parts of Vitrified powder, hydrochloric acid solution
3-6 parts, 2-6 parts of carbamate, 1-5 parts of isopropyl acrylate, 10-20 parts of acid fiber by polylactic.
3. the waterproof oil resistant spinning of fabric for kitchen use according to claim 1 or 2, it is characterised in that polydactyl acid is fine
Dimension is prepared by following technique：Paraffin is heated in water-bath melts it, then adds nano silicon and toluene is mixed
Close uniform, stirring is cooled to room temperature and obtains material A；Vitrified powder is put into calcining furnace and calcined, cooling is soaked in hydrochloric acid solution
Bubble, filtering is taken out, and cleans drying with clear water, crushing obtains material B, then by material A, material B, carbamate and acrylic acid
Isopropyl ester is well mixed, and is heated up, and insulation then disperses, is cooled to room temperature, is subsequently added into acid fiber by polylactic and is well mixed, heating,
Insulation, stirring, is cooled to room temperature and obtains modified polylactic acid fiber.
4. the waterproof oil resistant spinning of the fabric for kitchen use according to claim any one of 1-3, it is characterised in that modified poly- breast
Sour fiber is prepared by following technique：Paraffin is heated in water-bath melts it, then adds nano silicon and first
Benzene is well mixed, and is stirred 20-40min in 350-450r/min rotating speeds, is cooled to room temperature and obtains material A；Vitrified powder is put into and forged
Burn in stove and 2-5h is calcined at 820-920 DEG C, cool down, 1-3h is soaked in hydrochloric acid solution, filtering is taken out, and is cleaned and dried with clear water
Dry, crushing obtains material B, is then well mixed material A, material B, carbamate and isopropyl acrylate, is warming up to 80-
90 DEG C, 1-3h is incubated, then disperses 20-40min in 3500-4500r/min, is cooled to room temperature, is subsequently added into acid fiber by polylactic
It is well mixed, 120-140 DEG C is warming up to, 20-40min is incubated, 20-40min is stirred in 1500-2500r/min rotating speeds, is cooled to
Room temperature obtains modified polylactic acid fiber.
5. the waterproof oil resistant spinning of the fabric for kitchen use according to claim any one of 1-4, it is characterised in that oil resistant is modified
The raw material of auxiliary agent includes by weight：5-15 parts of CNT, 3-6 parts of the concentrated sulfuric acid, 1-5 parts of ethanol, 2-6 parts of urea, polyethylene
3-6 parts of pyrrolidones, 2-5 parts of deionized water, 3-6 parts of sodium chloride, 2-6 parts of defoamer, 1-4 parts of aluminum nitrate, nano titanium oxide
3-8 parts, 2-6 parts of zirconium sulfate, 2-6 parts of disodium hydrogen phosphate, 1-5 parts of zinc powder, 3-6 parts of Silane coupling reagent KH-570, the isobutyl of azo two
4-8 parts of nitrile, 2-6 parts of methyl methacrylate.
6. the waterproof oil resistant spinning of the fabric for kitchen use according to claim any one of 1-5, it is characterised in that oil resistant is modified
Auxiliary agent is prepared by following technique：CNT and the concentrated sulfuric acid are well mixed, stirred, filtering, washing to neutrality, suction filtration,
Drying, grinds, sieving, adds ethanol and is well mixed, and stirring in water bath is scattered to obtain material a；By urea, polyvinylpyrrolidone,
Deionized water, sodium chloride and defoamer are well mixed, stirring, then add aluminum nitrate, nano titanium oxide and zirconium sulfate mixing
Uniformly, heat up, insulation is then cooled to addition disodium hydrogen phosphate after room temperature and is well mixed, ageing, filtration washing is dried, calcining
After be cooled to room temperature and obtain material b；By material b, material c, zinc powder, Silane coupling reagent KH-570, azodiisobutyronitrile and methyl
Methyl acrylate is well mixed, and is heated up, insulation, suction filtration, and washing is dried under vacuum to constant weight, grinds, and sieving produces oil resistant to changing
Property auxiliary agent.
7. the waterproof oil resistant spinning of the fabric for kitchen use according to claim any one of 1-6, it is characterised in that oil resistant is modified
Auxiliary agent is prepared by following technique：CNT and the concentrated sulfuric acid are well mixed, in 80-90 DEG C, 350-550 DEG C of stirring 2-
4h, filtering, washing to neutrality, suction filtration is dried, and 150-250 mesh sieves are crossed in grinding, is added ethanol and is well mixed, in 45-55 DEG C of water
Bath dispersed with stirring 2-4h obtains material a；Urea, polyvinylpyrrolidone, deionized water, sodium chloride and defoamer are mixed equal
It is even, 10-30min is stirred in 350-650r/min rotating speeds, aluminum nitrate, nano titanium oxide and zirconium sulfate mixing is then added equal
It is even, 70-90 DEG C is warming up to, 10-20min is incubated, addition disodium hydrogen phosphate after room temperature is then cooled to and is well mixed, ageing, mistake
Filter washing, dries, room temperature is cooled to after calcining and obtains material b；By material b, material c, zinc powder, Silane coupling reagent KH-570, idol
Nitrogen bis-isobutyronitrile and methyl methacrylate monomer, are warming up to 75-85 DEG C, are incubated 5-7h, and suction filtration, washing is true in 750-850 DEG C
Sky is dried to constant weight, grinding, is crossed 150-250 mesh sieves, is produced oil resistant to modified additive.
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Application publication date: 20170926 |