CN109468691A - A kind of antibiotic polyester fiber and preparation method thereof - Google Patents
A kind of antibiotic polyester fiber and preparation method thereof Download PDFInfo
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- CN109468691A CN109468691A CN201811210021.0A CN201811210021A CN109468691A CN 109468691 A CN109468691 A CN 109468691A CN 201811210021 A CN201811210021 A CN 201811210021A CN 109468691 A CN109468691 A CN 109468691A
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- nano silver
- polyester fiber
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of antibiotic polyester fibers and preparation method thereof, are related to textile technology field.The present invention is modified processing to nano silver using polyol, so that nanometer silver surface is surrounded by hydroxyl, to itself be not susceptible to assemble；Simultaneously as the presence of hydroxyl can be with, dissolution of the nano silver in polyester fiber, dispersibility can be improved, make it have preferable antibacterial effect；Active additive prepared by the present invention has adhesive property and more active group, pass through the hydroxyl of nanometer silver surface, so that nano silver and polyester fiber are connected by hydrogen bond, adhesion of the nano silver on polyester fiber is improved, and then improve the Durability of antimicrobial effect of fiber；The antibiotic polyester fiber fabric of the method for the present invention production is suitble to industrialized production to no skin irritation.
Description
Technical field:
The present invention relates to textile technology fields, and in particular to a kind of antibiotic polyester fiber and preparation method thereof.
Background technique:
The development of functional fibre is the symbol of modern fiber science progress.Functional fibre, fibre in differentiation and high-performance are fine
The development of dimension is the technological innovation of traditional textile industry, and the conversion to high-tech industry creates advantage, is human lives
Horizontal raising is made that contribution.In addition to functional fibre refers to the physical mechanical property possessed by the general fiber, also there is certain
The tencel of kind of specific function, such as: fiber has the function of health care (antibacterial, mite killing, physical therapy and eliminate the unusual smell)；It is anti-
Protective function (radiation protection, antistatic, uvioresistant etc.)；The wet comfortable function (heat absorption, heat release, moisture absorption, moisture releasing etc.) of heat；Medical treatment and ring
Protect function (biocompatibility and biological degradability) etc..As the improvement of people's living standards, the demand of functional fibre is increasingly
Surging, antibiotic property functional fibre is a great type.
Fiber can adhere to many microorganisms, if temperature and humidity is suitable for, these microorganisms will be bred rapidly, generate to human body
Various harm.With stepping up for human health consciousness, the antibiotic property of textile is also had been to be concerned by more and more people.Have
The fiber and textile of antibacterial action also become increasingly by focus concerned by people.Anti-bacterial fibre belongs to functional fibre, function
The now common production method of fiber is physical modification method, i.e., is blended in the different phase of fiberizing and antibacterial functions object is added
Matter, such as can be added when spinning material polymerize；It can also be blended and be added when spinning squeezes out；It can be with for wet spinning
Functional material is added in spinning solution.For physical modification because its is easy to operate, technical difficulty is low, and applicability is wide, at present
Main method as functional fibre manufacture.
Terylene is an important species in synthetic fibers, is the product name of China's polyester fiber, have it is durable,
Elasticity is good, be unlikely to deform, be corrosion-resistant, insulation, it is well-pressed, quick-drying washable the features such as.Terylene is world wide production maximum, most widely used
Synthetic fibers kind, terylene accounts for 60% or more of world's synthetic fibers yield.
Being embedded in Nano silver grain into fiber during melt spinning is better simply anti-bacterial fibre industrial process,
But the polarity of PET is low, easy to reunite without the poor compatibility of surface modified Nano silver grain and PET, affects it in polyester
The performance of antibiotic rate and Durability of antimicrobial effect in material.As to disclose a kind of nanometer multiple for the Chinese invention of Publication No. CN1789502A
It closes antibacterial dacron POY and high speed spinning processes is blended, which uses 20-60 nano silver-carrying, zinc, silicon-base oxide compound antibacterial powder
Dacron master grain is made, then master batch is added in spinning polyester resin with the additive amount of 3-7% and carries out melt spinning, antibacterial is made
Polyester fiber disperses irregular powder the disadvantages of the method are as follows antimicrobial powder is extremely difficult to good dispersion in polyester resin
Material will increase spinning pressure when spinning, block spinneret, influence the spinnability of fiber, and the uneven of antibacterial agent is divided
Dissipate the anti-microbial property that can also further influence fiber.For another example the Chinese invention of Publication No. CN101629334A discloses one kind
Uvioresistant, antibacterial lead wet type polyester fiber and its production method and application, and main method is that aluminium powder production is carried using basic zirconium phosphate
Antibacterial terylene master batch, it is evenly dispersed in polyester fiber that this method disadvantage is equally that antimicrobial powder is difficult to, and spinnability is easily caused to become
Difference and fibre antibacterial performance do not ensure.
Summary of the invention:
Technical problem to be solved by the present invention lies in overcome the deficiencies of the prior art and provide a kind of nano silver antimicrobials point
It dissipates uniform, durable antibacterial effect, antibiotic polyester fiber of fiber process and textile performance and preparation method thereof can be improved simultaneously.
The following technical solution is employed for the technical problems to be solved by the invention to realize:
A kind of antibiotic polyester fiber, is made of following raw material: PET polyester slice (fibre-grade) 80-100kg, modified Nano
Silver antibacterial agent 0.01-0.02kg, antioxidant 1-3kg, dispersing agent 1-5kg, lubricant 0.1-2kg, active additive 0.01-
0.015kg。
The modified Nano silver antibacterial agent the preparation method comprises the following steps: nano silver is washed in deionized water under ultrasonic wave effect
Wash, filtered, dry after remove its surface impurity；Pretreated nano silver and polyol are mixed and are placed in ball milling
Then ball-milling treatment 0.5-2h in machine is added natural plant grease and dehydrated alcohol, is then 5- with the pH of vinegar acid-conditioning solution
6, continue ball milling 0.5-2h, filtering is to get silver-colored to modified Nano.
The nano silver, polyol, natural plant grease, dehydrated alcohol mass ratio be 10-20:10-20:1-
5:15-30.
The polyol is selected from one of glycerine, Trimethylolhexane, trimethylolpropane.
The natural plant grease is selected from one of castor oil, rape seed oil, rice bran oil, and natural plant grease has higher
Reactivity, intramolecular also has many active functional groups, can promote polyol combined with nano silver.
Partial size is exactly accomplished nanoscale metallic silver simple substance by nano silver, and partial size is mostly in 25 rans.Nano silver is made
For antibacterial agent using when maximum problem be exactly it is easy to reunite and it is easy fall off from fiber, cannot be evenly dispersed in the base, directly
Connecing leads to increase difficulty in spinning and anti-microbial property is caused to decline or lose.By polyol to nano silver antimicrobials
Modification can make nano silver antimicrobials be uniformly dispersed in PET matrix, improve spinnability and fibre antibacterial performance.
The antioxidant is selected from one of antioxidant 1010 or 168.
The lubricant selects one of lubricant TAF or pentaerythritol stearate.
The dispersing agent is polyethylene glycol 400.
The active additive the preparation method comprises the following steps: hydroxymethyl cellulose is add to deionized water, be warming up to 50-60
DEG C stirring 10-30min, is then added salicylic acid and tetraethyl titanate, is heated to reflux state, insulated and stirred 0.5-3h, then
Epoxidized soybean oil and paraffin oil is added, continues to stir 10-30min, filter while hot, gained precipitating deionized water and dehydrated alcohol
Impurity is washed away, is sent into vacuum drying box, is dried to constant weight to get active additive is arrived.
The hydroxymethyl cellulose, salicylic acid, tetraethyl titanate, epoxidized soybean oil, paraffin oil mass ratio be 10-15:
10-15:0.1-0.2:1-3:1-2.
Antibiotic polyester fiber the preparation method comprises the following steps:
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) polyester slice, modified Nano silver antibacterial agent, antioxidant, dispersing agent, lubricant, active additive are mixed
Stir evenly, put into high-speed mixer in, then using melt spinning method carry out spinning, 280-295 DEG C of spinning temperature, side
28-30 DEG C of quenching wind-warm syndrome, cross air blasting wind speed 0.3-0.5m/s wind spinning speed 3000-3200m/min, drawing-off times
Rate 3.5-4.5, obtains antibiotic polyester fiber.
The beneficial effects of the present invention are:
(1) present invention is modified processing to nano silver using polyol, so that nanometer silver surface is by hydroxyl institute
It surrounds, to itself be not susceptible to assemble；Simultaneously as the presence of hydroxyl can be can be improved nano silver in polyester fiber
Dissolution, dispersibility, make it have preferable antibacterial effect；
(2) active additive prepared by the present invention has adhesive property and more active group, passes through nano silver table
The hydroxyl in face improves adhesion of the nano silver on polyester fiber, in turn so that nano silver and polyester fiber are connected by hydrogen bond
Improve the Durability of antimicrobial effect of fiber；
(3) the antibiotic polyester fiber fabric of the method for the present invention production is suitble to industrialized production to no skin irritation.
Specific embodiment:
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
The preparation of antibiotic polyester fiber:
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) by 90kg polyester slice, 0.015kg modified Nano silver antibacterial agent, 1kg antioxidant 1010,4kg polyethylene glycol
400,0.5kg lubricant TAF, 0.01kg active additive is mixed evenly, and puts into high-speed mixer, then using melting
Spin processes carry out spinning, and 280 DEG C of spinning temperature, 28 DEG C of cross air blasting cooling wind temperature, cross air blasting wind speed 0.3m/s, winding is spun
Silk speed 3000m/min, draft ratio 3.5 obtain antibiotic polyester fiber.
The preparation of modified Nano silver antibacterial agent: 15g nano silver is washed in deionized water under ultrasonic wave effect, is passed through
Its surface impurity is removed after filter, drying；Pretreated nano silver and 15g glycerine are mixed and are placed in ball mill at ball milling
2h is managed, 4g castor oil and 20g dehydrated alcohol is then added, is then 5-6 with the pH of vinegar acid-conditioning solution, continues ball milling 1h, mistake
It filters to get modified Nano silver antibacterial agent is arrived.
The preparation of active additive: 10g hydroxymethyl cellulose is add to deionized water, and is warming up to 50 DEG C of stirrings
Then 20min is added 10g salicylic acid and 0.1g tetraethyl titanate, is heated to reflux state, then 2g is added in insulated and stirred 2h
Epoxidized soybean oil and 1g paraffin oil continue to stir 20min, filter while hot, gained precipitating is washed away with deionized water and dehydrated alcohol
Impurity is sent into vacuum drying box, is dried to constant weight to get active additive is arrived.
Embodiment 2
The preparation of antibiotic polyester fiber:
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) by 95kg polyester slice, 0.02kg modified Nano silver antibacterial agent, 1kg antioxidant 1010,4kg polyethylene glycol
400,0.5kg lubricant TAF, 0.015kg active additive is mixed evenly, and puts into high-speed mixer, then using molten
Melt spin processes and carry out spinning, 290 DEG C of spinning temperature, 30 DEG C of cross air blasting cooling wind temperature, cross air blasting wind speed 0.5m/s, winds
Spinning speed 3100m/min, draft ratio 4.0, obtains antibiotic polyester fiber.
The preparation of modified Nano silver antibacterial agent: 20g nano silver is washed in deionized water under ultrasonic wave effect, is passed through
Its surface impurity is removed after filter, drying；Pretreated nano silver and 20g glycerine are mixed and are placed in ball mill at ball milling
2h is managed, 4g castor oil and 20g dehydrated alcohol is then added, is then 5-6 with the pH of vinegar acid-conditioning solution, continues ball milling 1h, mistake
It filters to get modified Nano silver antibacterial agent is arrived.
The preparation of active additive: 15g hydroxymethyl cellulose is add to deionized water, and is warming up to 50 DEG C of stirrings
Then 20min is added 15g salicylic acid and 0.1g tetraethyl titanate, is heated to reflux state, then 2g is added in insulated and stirred 2h
Epoxidized soybean oil and 1g paraffin oil continue to stir 20min, filter while hot, gained precipitating is washed away with deionized water and dehydrated alcohol
Impurity is sent into vacuum drying box, is dried to constant weight to get active additive is arrived.
Reference examples 1
The preparation of antibiotic polyester fiber:
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) by 90kg polyester slice, 0.015kg modified Nano silver antibacterial agent, 1kg antioxidant 1010,4kg polyethylene glycol
400,0.5kg lubricant TAF, 0.01kg active additive is mixed evenly, and puts into high-speed mixer, then using melting
Spin processes carry out spinning, and 280 DEG C of spinning temperature, 28 DEG C of cross air blasting cooling wind temperature, cross air blasting wind speed 0.3m/s, winding is spun
Silk speed 3000m/min, draft ratio 3.5 obtain antibiotic polyester fiber.
The preparation of modified Nano silver antibacterial agent: 15g nano silver is washed in deionized water under ultrasonic wave effect, is passed through
Its surface impurity is removed after filter, drying；Pretreated nano silver and 15g glycerine are mixed and are placed in ball mill at ball milling
2h is managed, 20g dehydrated alcohol is then added, is then 5-6 with the pH of vinegar acid-conditioning solution, continues ball milling 1h, filtering is to get to changing
Property nano silver antimicrobials.
The preparation of active additive: 10g hydroxymethyl cellulose is add to deionized water, and is warming up to 50 DEG C of stirrings
Then 20min is added 10g salicylic acid and 0.1g tetraethyl titanate, is heated to reflux state, then 2g is added in insulated and stirred 2h
Epoxidized soybean oil and 1g paraffin oil continue to stir 20min, filter while hot, gained precipitating is washed away with deionized water and dehydrated alcohol
Impurity is sent into vacuum drying box, is dried to constant weight to get active additive is arrived.
Reference examples 2
The preparation of antibiotic polyester fiber:
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) by 90kg polyester slice, 0.015kg nano silver antimicrobials, 1kg antioxidant 1010,4kg polyethylene glycol 400,
0.5kg lubricant TAF, 0.01kg active additive is mixed evenly, and puts into high-speed mixer, then uses melt spinning
Method carries out spinning, and 280 DEG C of spinning temperature, 28 DEG C of cross air blasting cooling wind temperature, cross air blasting wind speed 0.3m/s, winding spinning is fast
3000m/min is spent, draft ratio 3.5 obtains antibiotic polyester fiber.
The preparation of active additive: 10g hydroxymethyl cellulose is add to deionized water, and is warming up to 50 DEG C of stirrings
Then 20min is added 10g salicylic acid and 0.1g tetraethyl titanate, is heated to reflux state, then 2g is added in insulated and stirred 2h
Epoxidized soybean oil and 1g paraffin oil continue to stir 20min, filter while hot, gained precipitating is washed away with deionized water and dehydrated alcohol
Impurity is sent into vacuum drying box, is dried to constant weight to get active additive is arrived.
Reference examples 3
The preparation of antibiotic polyester fiber:
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) by 90kg polyester slice, 0.015kg modified Nano silver antibacterial agent, 1kg antioxidant 1010,4kg polyethylene glycol
400,0.5kg lubricant TAF, 0.01kg active additive is mixed evenly, and puts into high-speed mixer, then using melting
Spin processes carry out spinning, and 280 DEG C of spinning temperature, 28 DEG C of cross air blasting cooling wind temperature, cross air blasting wind speed 0.3m/s, winding is spun
Silk speed 3000m/min, draft ratio 3.5 obtain antibiotic polyester fiber.
The preparation of modified Nano silver antibacterial agent: 15g nano silver is washed in deionized water under ultrasonic wave effect, is passed through
Its surface impurity is removed after filter, drying；Pretreated nano silver and 15g glycerine are mixed and are placed in ball mill at ball milling
2h is managed, 4g castor oil and 20g dehydrated alcohol is then added, is then 5-6 with the pH of vinegar acid-conditioning solution, continues ball milling 1h, mistake
It filters to get modified Nano silver antibacterial agent is arrived.
The preparation of active additive: 10g hydroxymethyl cellulose is add to deionized water, and is warming up to 50 DEG C of stirrings
Then 20min is added 10g salicylic acid and 0.1g tetraethyl titanate, is heated to reflux state, insulated and stirred 2h continues to stir
20min is filtered while hot, and gained precipitating deionized water and dehydrated alcohol wash away impurity, are sent into vacuum drying box, dry to perseverance
It weighs to get active additive is arrived.
Reference examples 4
The preparation of antibiotic polyester fiber:
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) by 90kg polyester slice, 0.015kg modified Nano silver antibacterial agent, 1kg antioxidant 1010,4kg polyethylene glycol
400,0.5kg lubricant TAF is mixed evenly, and puts into high-speed mixer, then carries out spinning using melt spinning method, melts
Melt 280 DEG C of spinning temperature, 28 DEG C of cross air blasting cooling wind temperature, cross air blasting wind speed 0.3m/s, wind spinning speed 3000m/min,
Draft ratio 3.5, obtains antibiotic polyester fiber.
The preparation of modified Nano silver antibacterial agent: 15g nano silver is washed in deionized water under ultrasonic wave effect, is passed through
Its surface impurity is removed after filter, drying；Pretreated nano silver and 15g glycerine are mixed and are placed in ball mill at ball milling
2h is managed, 4g castor oil and 20g dehydrated alcohol is then added, is then 5-6 with the pH of vinegar acid-conditioning solution, continues ball milling 1h, mistake
It filters to get modified Nano silver antibacterial agent is arrived.
Embodiment 3
Based on embodiment 1, the reference examples 1 of castor oil, the reference examples not being modified to nano silver are not added in setting
2, the reference examples 3 of epoxidized soybean oil and paraffin oil are not added, do not add the reference examples 4 of active additive.
The preparation of antibiotic polyester fiber is carried out using embodiment 1-2, reference examples 1-4, and the anti-microbial property of fiber is carried out
Detection, the results are shown in Table 1.
The anti-microbial property of 1 polyester fiber of table
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (4)
1. a kind of antibiotic polyester fiber, it is characterised in that: be made of following raw material: PET polyester slice (fibre-grade) 80-100kg,
Modified Nano silver antibacterial agent 0.01-0.02kg, antioxidant 1-3kg, dispersing agent 1-5kg, lubricant 0.1-2kg, activity addition
Agent 0.01-0.015kg.
2. antibiotic polyester fiber according to claim 1, which is characterized in that the active additive the preparation method comprises the following steps:
Hydroxymethyl cellulose is add to deionized water, 50-60 DEG C of stirring 10-30min is warming up to, salicylic acid and metatitanic acid is then added
Tetra-ethyl ester is heated to reflux state, then epoxidized soybean oil and paraffin oil is added in insulated and stirred 0.5-3h, continues to stir 10-
30min is filtered while hot, and gained precipitating deionized water and dehydrated alcohol wash away impurity, are sent into vacuum drying box, dry to perseverance
It weighs to get active additive is arrived.
3. antibiotic polyester fiber according to claim 2, it is characterised in that: the hydroxymethyl cellulose, salicylic acid, metatitanic acid
Tetra-ethyl ester, epoxidized soybean oil, paraffin oil mass ratio be 10-15:10-15:0.1-0.2:1-3:1-2.
4. the preparation method of -3 antibiotic polyester fibers according to claim 1 characterized by comprising
(1) PET polyester slice is dried, drying temperature is 150 DEG C -170 DEG C, and drying time is 4-5 hours, until water content≤
60ppm, it is spare；
(2) polyester slice, modified Nano silver antibacterial agent, antioxidant, dispersing agent, lubricant, active additive are mixed
Uniformly, put into high-speed mixer in, then using melt spinning method carry out spinning, 280-295 DEG C of spinning temperature, cross air blasting
28-30 DEG C of cooling wind temperature, cross air blasting wind speed 0.3-0.5m/s, wind spinning speed 3000-3200m/min, draft ratio
3.5-4.5 obtaining antibiotic polyester fiber.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811210021.0A CN109468691A (en) | 2018-10-17 | 2018-10-17 | A kind of antibiotic polyester fiber and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811210021.0A CN109468691A (en) | 2018-10-17 | 2018-10-17 | A kind of antibiotic polyester fiber and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109468691A true CN109468691A (en) | 2019-03-15 |
Family
ID=65664572
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110952156A (en) * | 2019-12-12 | 2020-04-03 | 江阴市金茂特种纤维有限公司 | Preparation method of antibacterial and antifouling polyester composite fiber |
| CN113684556A (en) * | 2021-08-06 | 2021-11-23 | 宁波市富盾制式服装有限公司 | Modified polyester fiber, preparation method thereof and antibacterial polyester-cotton fabric |
| CN113832707A (en) * | 2021-09-10 | 2021-12-24 | 宿迁金楠织造有限公司 | Antibacterial light textile fabric and preparation method thereof |
| CN114311874A (en) * | 2021-11-22 | 2022-04-12 | 江苏中纺联针织有限公司 | Antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric and production method thereof |
| CN114672913A (en) * | 2022-03-15 | 2022-06-28 | 盐城市金达纺织有限公司 | Environment-friendly antibacterial textile fabric and processing technology thereof |
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| CN105040142A (en) * | 2015-08-17 | 2015-11-11 | 俞尧芳 | Antibacterial polyester fibers and preparation method thereof |
| CN107880500A (en) * | 2017-12-11 | 2018-04-06 | 晋大纳米科技（厦门）有限公司 | A kind of silver system antibacterial polyester masterbatches and preparation method thereof |
| CN108411399A (en) * | 2017-09-22 | 2018-08-17 | 浙江中迪纺织新材料科技有限公司 | A kind of bed necessaries prepared by the polyester antibacterial plastic concentrate based on 1-dimention nano Ag/C composite materials |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105040142A (en) * | 2015-08-17 | 2015-11-11 | 俞尧芳 | Antibacterial polyester fibers and preparation method thereof |
| CN108411399A (en) * | 2017-09-22 | 2018-08-17 | 浙江中迪纺织新材料科技有限公司 | A kind of bed necessaries prepared by the polyester antibacterial plastic concentrate based on 1-dimention nano Ag/C composite materials |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110952156A (en) * | 2019-12-12 | 2020-04-03 | 江阴市金茂特种纤维有限公司 | Preparation method of antibacterial and antifouling polyester composite fiber |
| CN113684556A (en) * | 2021-08-06 | 2021-11-23 | 宁波市富盾制式服装有限公司 | Modified polyester fiber, preparation method thereof and antibacterial polyester-cotton fabric |
| CN113832707A (en) * | 2021-09-10 | 2021-12-24 | 宿迁金楠织造有限公司 | Antibacterial light textile fabric and preparation method thereof |
| CN114311874A (en) * | 2021-11-22 | 2022-04-12 | 江苏中纺联针织有限公司 | Antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric and production method thereof |
| CN114311874B (en) * | 2021-11-22 | 2024-03-22 | 江苏中纺联针织有限公司 | Antibacterial warm-keeping moisture-absorbing quick-drying knitted sportswear fabric and production method thereof |
| CN114672913A (en) * | 2022-03-15 | 2022-06-28 | 盐城市金达纺织有限公司 | Environment-friendly antibacterial textile fabric and processing technology thereof |
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