CN107189558A - Environmental protection coating material prepared by a kind of modified starch and preparation method thereof - Google Patents
Environmental protection coating material prepared by a kind of modified starch and preparation method thereof Download PDFInfo
- Publication number
- CN107189558A CN107189558A CN201710530823.9A CN201710530823A CN107189558A CN 107189558 A CN107189558 A CN 107189558A CN 201710530823 A CN201710530823 A CN 201710530823A CN 107189558 A CN107189558 A CN 107189558A
- Authority
- CN
- China
- Prior art keywords
- parts
- modified starch
- environmental protection
- protection coating
- coating material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09D103/04—Starch derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses environmental protection coating material prepared by a kind of modified starch, the environmental protection coating material main component is made up of following weight fraction material：40 50 parts of modified starch, 30 40 parts of acrylic resin, 5 10 parts of seawood meal, 50 100 parts of modification infusorial earth, 38 parts of nano zine oxide, 35 parts of magnet powder, 5 15 parts of nano titanium oxide；The present invention is by adding modified starch and modification infusorial earth, dramatically increase the tackness of the present invention, so that the present invention is in aqueous solvent formation unit for uniform suspension, easily smearing easily to be filled and led up for rough surface makes surface smooth, the present invention is free of organic solvent, and modified starch has remarkable result with modification infusorial earth for adsorbing powder dust and formaldehyde gas absorption.
Description
Technical field
The present invention relates to freshener technical field.It is more particularly related to environmental protection prepared by a kind of modified starch
Coating and preparation method thereof.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in the body surface protected or decorated, and
The continuous film of firm attachment can be formed with coated article, is typically based on resin or oil or emulsion, to add or without face
Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or water.Chinese coating circle is more authoritative《Apply
Material technique》What one book was defined as：" coating is a kind of material, and this material can be coated in thing with different construction technologies
Part surface, forms and adheres to firmly, with some strength, continuous solid film.The film common name film so formed, also known as paint film
Or coating." traditional dope for inner wall of architecture is healthy to people to bring serious harm because containing formaldehyde, is gradually market institute
Eliminate, nontoxic environmental protection coating material then turns into the first choice of people.Environmental protection coating material is prepared into a kind of trend using starch, starch is can
Regenerated resources, are easily obtained, and cost is low, and the patent document of Application No. 201510288140.8 discloses a kind of glutinous rice environmental protection and applied
Material and preparation method thereof, is made up of according to mass percent following raw material：Glutinous rice flour 37%~39%, starch crops 15%~
20%, grey calcium 9.5%~11%, coarse whiting 14%~15%, diatom ooze 18%~19%, negative ion powder 1.5%~2%, this hair
Bright starch, glutinous rice flour do not pass through specially treated, easily cracking and mouldy, particularly winter after long-time after smearing
Just easily it is cracked, summer is easily mouldy.
The content of the invention
Present invention aim to address above mentioned problem there is provided environmental protection coating material prepared by a kind of modified starch, the present invention passes through
Modified starch and modification infusorial earth are added, the tackness of the present invention is dramatically increased so that the present invention forms uniform outstanding in aqueous solvent
Supernatant liquid, easily smearing easily to be filled and led up for rough surface makes surface smooth, and the present invention is free of organic solvent, and modified
Starch has remarkable result with modification infusorial earth for adsorbing powder dust and formaldehyde gas absorption.
The technical scheme that the present invention is provided is：
Environmental protection coating material prepared by a kind of modified starch, the environmental protection coating material main component is by following weight fraction material group
Into：It is 40-50 parts of modified starch, 30-40 parts of acrylic resin, 5-10 parts of seawood meal, 50-100 parts of modification infusorial earth, nano oxidized
3-8 parts of zinc, 3-5 parts of magnet powder, 5-15 parts of nano titanium oxide；The modified starch is made up of following methods：By tapioca
By mechanical crushing to less than 10 microns, after addition glycerine, deionized water, surfactant are well mixed, using citric acid
PH is adjusted to 2.5-4, is positioned in reactor, mixing speed be set to pressure in more than 2500rmp, reactor for-
0.8Mpa, temperature is 50-60 DEG C, and after reacting 1-5 hours, PH is adjusted to 7-8, enters more than horizontal high voltage 200Mpa spray drying, does
Dry temperature is 80-100 DEG C, and mechanical crushing crosses 2000 mesh sieve and produces the modified starch again after cooling, by this method
Modified starch, suspension is good in aqueous into small molecule for starch conversion, is easily smeared when making an addition to the present invention, and small point
Sub- starch easily forms one layer of fine and close cross linking membrane with modification infusorial earth, has protective effect to wall, be not easily cracked after dry and hard,
Skinning.
Preferably, the environmental protection coating material main component is made up of following weight fraction material：45 parts of modified starch, propylene
35 parts of acid resin, 8 parts of seawood meal, 65 parts of modification infusorial earth, 5 parts of nano zine oxide, 4 parts of magnet powder, 12 parts of nano titanium oxide；
The modified starch is made up of following methods：By tapioca by mechanical crushing to less than 10 microns, addition glycerine, go from
After sub- water, surfactant are well mixed, PH is adjusted to 2.5-4 using citric acid, is positioned in reactor, mixing speed is set
For more than 2500rmp, the pressure in reactor is -0.8Mpa, and temperature is 50-60 DEG C, and after reaction 1-5 hours, PH is adjusted to 7-
8, enter more than horizontal high voltage 200Mpa spray drying, dry temperature is 80-100 DEG C, and mechanical crushing crosses 2000 mesh sieves again after cooling
Son produces the modified starch.
Preferably, the tapioca, glycerine, deionized water, the weight of surfactant ratio are 100: 100: 50:
1-5。
Preferably, the modification infusorial earth is made up of following methods：Diatomite is added into alkaline soak 3-5 hours, entered
After row ball milling 1-3 hours, cross 500 mesh sieve and obtain suspension, dry after being less than 20% to water content, be positioned in sintering furnace
Sintering temperature is sintered for 400-450 DEG C, sintering after 2 hours more than, cooling mechanical crushing crosses 2000 mesh sieves and obtains described change
Property diatomite, wherein alkali lye is mass fraction 10-20% sodium bicarbonate aqueous solution, and modified specific surface area of diatomite increases
Greatly, porosity uniformly easily with one layer of fine and close diaphragm of small molecule Starch formation.
The present invention also provides a kind of preparation method of environmental protection coating material prepared by described modified starch, the preparation method bag
Include：Modified starch, acrylic resin, seawood meal, modification infusorial earth, nano zine oxide, magnet powder, nano titanium oxide are mixed
Glycerine, ethylene glycol, deionized water, surfactant are added, the addition of the glycerine is modified starch, acrylic acid tree
Fat, seawood meal, modification infusorial earth, nano zine oxide, the 50% of the gross weight of magnet powder and nano titanium oxide, wherein glycerine,
Ethylene glycol, deionized water, the weight ratio of the addition of surfactant are 10: 5: 10: 0.5-2, after above-mentioned material is mixed, are carried out
After ball milling 3-6 hours, it is spray-dried, then 1500 mesh sieve is crossed after mechanical crushing and produces the environmental protection coating material.
The application method of the present invention, is mixed into suspension with water by the present invention, is irradiated using preceding use uviol lamp
To temperature be 30-40 DEG C when spraying use, effect is more so that adherence of the present invention is greatly increased, and easily coating, ductility
Good, non-scale is cracked after drying, and not bulge, coating surface is smooth.
The present invention at least includes following beneficial effect：
The present invention dramatically increases the tackness of the present invention by adding modified starch and modification infusorial earth so that the present invention
In aqueous solvent formation unit for uniform suspension, easily smearing easily to be filled and led up for rough surface makes surface smooth, the present invention
Without organic solvent, and modified starch has remarkable result with modification infusorial earth for adsorbing powder dust and formaldehyde gas absorption；
The present invention also added magnet powder so that after the present invention is smeared, and make one in space is smeared, with sedative action.
Further advantage, target and the feature of the present invention embodies part by following explanation, and part will also be by this
The research and practice of invention and be understood by the person skilled in the art.
Embodiment
With reference to example below, the present invention is described in further detail, to make those skilled in the art with reference to specification
Word can be implemented according to this.
Embodiment 1
Environmental protection coating material main component prepared by a kind of modified starch is made up of following weight fraction material：Modified starch 40
Part, 30 parts of acrylic resin, 5 parts of seawood meal, 50 parts of modification infusorial earth, 3 parts of nano zine oxide, 3 parts of magnet powder, nanometer titanium dioxide
5 parts of titanium；The modified starch is made up of following methods：By tapioca by mechanical crushing to less than 10 microns, addition the third three
After alcohol, deionized water, surfactant are well mixed, PH is adjusted to 2.5 using citric acid, is positioned in reactor, stirring speed
The pressure that degree is set in 2600rmp, reactor is -0.8Mpa, and temperature is 50 DEG C, after reacting 1 hour, and PH is adjusted to 7, is carried out
High pressure 220Mpa is spray-dried, and dry temperature is 80 DEG C, and mechanical crushing crosses 2000 mesh sieve and produces the modification again after cooling
Starch, the tapioca, glycerine, deionized water, the weight of surfactant ratio are 100: 100: 50: 1.
The preparation method of environmental protection coating material prepared by described modified starch includes：By modified starch, acrylic resin, marine alga
Powder, modification infusorial earth, nano zine oxide, magnet powder, nano titanium oxide mixing add glycerine, ethylene glycol, deionized water, table
Face activating agent, the addition of the glycerine is modified starch, acrylic resin, seawood meal, modification infusorial earth, nano oxidized
The 50% of the gross weight of zinc, magnet powder and nano titanium oxide, wherein glycerine, ethylene glycol, deionized water, surfactant add
Plus weight ratio be 10: 5: 10: 0.5, after above-mentioned material is mixed, carry out ball milling after 3 hours, spray drying, then mechanical crushing
1500 mesh sieve are crossed afterwards produces the environmental protection coating material.
Embodiment 2
Environmental protection coating material main component prepared by a kind of modified starch is made up of following weight fraction material：Modified starch 50
Part, 40 parts of acrylic resin, 10 parts of seawood meal, 100 parts of modification infusorial earth, 8 parts of nano zine oxide, 5 parts of magnet powder, nano-silica
Change 15 parts of titanium；The modified starch is made up of following methods：By tapioca by mechanical crushing to less than 10 microns, third is added
After triol, deionized water, surfactant are well mixed, PH is adjusted to 4 using citric acid, is positioned in reactor, stirring speed
The pressure that degree is set in 3000rmp, reactor is -0.8Mpa, and temperature is 60 DEG C, after reacting 5 hours, and PH is adjusted to 8, is carried out
High pressure 250Mpa is spray-dried, and dry temperature is 100 DEG C, and mechanical crushing crosses 2000 mesh sieve and produces the modification again after cooling
Starch；The tapioca, glycerine, deionized water, the weight of surfactant ratio are 100: 100: 50: 5；The modified silicon
Diatomaceous earth is made up of following methods：Diatomite is added into alkaline soak 5 hours, ball milling is carried out after 3 hours, crosses 500 mesh sieve and obtain
Suspension, is dried after being less than 20% to water content, is positioned in sintering furnace and is sintered sintering temperature for 450 DEG C, sintering 2 is small
When after more than, cooling mechanical crushing crosses 2000 mesh sieves and obtains the modification infusorial earth, and wherein alkali lye is mass fraction 10-20%'s
Sodium bicarbonate aqueous solution.
The preparation method of environmental protection coating material prepared by described modified starch includes：By modified starch, acrylic resin, marine alga
Powder, modification infusorial earth, nano zine oxide, magnet powder, nano titanium oxide mixing add glycerine, ethylene glycol, deionized water, table
Face activating agent, the addition of the glycerine is modified starch, acrylic resin, seawood meal, modification infusorial earth, nano oxidized
The 50% of the gross weight of zinc, magnet powder and nano titanium oxide, wherein glycerine, ethylene glycol, deionized water, surfactant add
Plus weight ratio be 10: 5: 10: 2, after above-mentioned material is mixed, carry out ball milling after 6 hours, spray drying, then after mechanical crushing
Cross 1500 mesh sieve and produce the environmental protection coating material.
Embodiment 3
Environmental protection coating material main component prepared by a kind of modified starch is made up of following weight fraction material：Modified starch 45
Part, 35 parts of acrylic resin, 8 parts of seawood meal, 65 parts of modification infusorial earth, 5 parts of nano zine oxide, 4 parts of magnet powder, nanometer titanium dioxide
12 parts of titanium；The modified starch is made up of following methods：By tapioca by mechanical crushing to less than 10 microns, addition the third three
After alcohol, deionized water, surfactant are well mixed, PH is adjusted to 3 using citric acid, is positioned in reactor, mixing speed
The pressure being set in 2800rmp, reactor is -0.8Mpa, and temperature is 55 DEG C, after reacting 4 hours, and PH is adjusted to 7, is carried out high
More than 200Mpa spray drying is pressed, dry temperature is 90 DEG C, mechanical crushing crosses 2000 mesh sieve and produces described change again after cooling
Property starch；The tapioca, glycerine, deionized water, the weight of surfactant ratio are 100: 100: 50: 4；The modification
Diatomite is made up of following methods：Diatomite is added into alkaline soak 3-5 hours, ball milling is carried out after 2 hours, crosses 500 mesh sieve
Suspension is obtained, is dried after being less than 20% to water content, is positioned in sintering furnace and is sintered sintering temperature for 420 DEG C, burn
Knot after 2 hours more than, cooling mechanical crushing crosses 2000 mesh sieves and obtains the modification infusorial earth, and wherein alkali lye is mass fraction 15%
Sodium bicarbonate aqueous solution.
The preparation method of environmental protection coating material prepared by described modified starch includes：By modified starch, acrylic resin, marine alga
Powder, modification infusorial earth, nano zine oxide, magnet powder, nano titanium oxide mixing add glycerine, ethylene glycol, deionized water, table
Face activating agent, the addition of the glycerine is modified starch, acrylic resin, seawood meal, modification infusorial earth, nano oxidized
The 50% of the gross weight of zinc, magnet powder and nano titanium oxide, wherein glycerine, ethylene glycol, deionized water, surfactant add
Plus weight ratio be 10: 5: 10: 1.5, after above-mentioned material is mixed, carry out ball milling after 5 hours, spray drying, then mechanical crushing
1500 mesh sieve are crossed afterwards produces the environmental protection coating material.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention is not limited
In specific details and shown here as the embodiment with description.
Claims (5)
1. environmental protection coating material prepared by a kind of modified starch, it is characterised in that the environmental protection coating material main component is by following weight point
Number material composition：40-50 parts of modified starch, 30-40 parts of acrylic resin, 5-10 parts of seawood meal, 50-100 parts of modification infusorial earth,
3-8 parts of nano zine oxide, 3-5 parts of magnet powder, 5-15 parts of nano titanium oxide；The modified starch is made up of following methods：Will
Tapioca, to less than 10 microns, after addition glycerine, deionized water, surfactant are well mixed, is adopted by mechanical crushing
PH is adjusted to 2.5-4 with citric acid, is positioned in reactor, mixing speed is set to the pressure in more than 2500rmp, reactor
For -0.8Mpa, temperature is 50-60 DEG C, and after reacting 1-5 hours, PH is adjusted to 7-8, enters more than horizontal high voltage 200Mpa spray drying,
Dry temperature is 80-100 DEG C, and mechanical crushing crosses 2000 mesh sieve and produces the modified starch again after cooling.
2. environmental protection coating material prepared by modified starch according to claim 1, it is characterised in that the environmental protection coating material it is main into
Divide and be made up of following weight fraction material：45 parts of modified starch, 35 parts of acrylic resin, 8 parts of seawood meal, modification infusorial earth 65
Part, 5 parts of nano zine oxide, 4 parts of magnet powder, 12 parts of nano titanium oxide；The modified starch is made up of following methods：By cassava
Starch passes through mechanical crushing to less than 10 microns, after addition glycerine, deionized water, surfactant are well mixed, using lemon
PH is to 2.5-4 for lemon acid regulation, is positioned in reactor, mixing speed be set to pressure in more than 2500rmp, reactor for-
0.8Mpa, temperature is 50-60 DEG C, and after reacting 1-5 hours, PH is adjusted to 7-8, enters more than horizontal high voltage 200Mpa spray drying, does
Dry temperature is 80-100 DEG C, and mechanical crushing crosses 2000 mesh sieve and produces the modified starch again after cooling.
3. environmental protection coating material prepared by modified starch according to claim 2, it is characterised in that the tapioca, the third three
Alcohol, deionized water, the weight of surfactant ratio are 100: 100: 50: 1-5.
4. environmental protection coating material prepared by modified starch according to claim 3, it is characterised in that the modification infusorial earth by with
Lower section method is made：Diatomite is added into alkaline soak 3-5 hours, ball milling is carried out after 1-3 hours, crosses 500 mesh sieve and suspended
Liquid, is dried after being less than 20% to water content, is positioned in sintering furnace and is sintered sintering temperature for 400-450 DEG C, sintering 2 is small
When after more than, cooling mechanical crushing crosses 2000 mesh sieves and obtains the modification infusorial earth, and wherein alkali lye is mass fraction 10-20%'s
Sodium bicarbonate aqueous solution.
5. the preparation method of environmental protection coating material prepared by any described modified starch, its feature in a kind of 1-4 according to claim
It is, the preparation method includes：By modified starch, acrylic resin, seawood meal, modification infusorial earth, nano zine oxide, magnetite
Powder, nano titanium oxide mixing add glycerine, ethylene glycol, deionized water, surfactant, and the addition of the glycerine is
Modified starch, acrylic resin, seawood meal, modification infusorial earth, nano zine oxide, the gross weight of magnet powder and nano titanium oxide
50%, wherein glycerine, ethylene glycol, deionized water, the weight ratio of the addition of surfactant are 10: 5: 10: 0.5-2, will be upper
State after material mixing, carry out ball milling after 3-6 hours, be spray-dried, then 1500 mesh sieve are crossed after mechanical crushing and produce the environmental protection
Coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710530823.9A CN107189558A (en) | 2017-06-30 | 2017-06-30 | Environmental protection coating material prepared by a kind of modified starch and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710530823.9A CN107189558A (en) | 2017-06-30 | 2017-06-30 | Environmental protection coating material prepared by a kind of modified starch and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189558A true CN107189558A (en) | 2017-09-22 |
Family
ID=59881810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710530823.9A Pending CN107189558A (en) | 2017-06-30 | 2017-06-30 | Environmental protection coating material prepared by a kind of modified starch and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107189558A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502007A (en) * | 2017-09-26 | 2017-12-22 | 重庆华亚家私有限公司 | A kind of modification infusorial earth aqueous, environmental protective paint and preparation method thereof |
| CN108084869A (en) * | 2018-01-24 | 2018-05-29 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
| CN108191303A (en) * | 2018-02-10 | 2018-06-22 | 吴刚 | It is a kind of except the preparation method of the fungi-proofing diatom ooze of formaldehyde type |
| CN108215558A (en) * | 2017-12-19 | 2018-06-29 | 浙江锦旺新材料科技有限公司 | A kind of coiling-resistant heat-transferring printing paper |
| CN108456464A (en) * | 2018-02-07 | 2018-08-28 | 合肥达户电线电缆科技有限公司 | A kind of preparation method of new type environment friendly coating |
| CN108822625A (en) * | 2018-07-26 | 2018-11-16 | 合肥市大卓电力有限责任公司 | A kind of novel environment friendly coatings and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827518A (en) * | 2012-06-01 | 2012-12-19 | 安徽省金盾涂料有限责任公司 | Water paint composition |
| CN105131774A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Multifunctional inner wall paint |
| CN105885593A (en) * | 2016-06-27 | 2016-08-24 | 安徽省思维新型建材有限公司 | Coating used for external walls |
| CN106700760A (en) * | 2016-12-14 | 2017-05-24 | 四川熹玥广告传媒有限公司 | Water-based paint and preparation method thereof |
-
2017
- 2017-06-30 CN CN201710530823.9A patent/CN107189558A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827518A (en) * | 2012-06-01 | 2012-12-19 | 安徽省金盾涂料有限责任公司 | Water paint composition |
| CN105131774A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Multifunctional inner wall paint |
| CN105885593A (en) * | 2016-06-27 | 2016-08-24 | 安徽省思维新型建材有限公司 | Coating used for external walls |
| CN106700760A (en) * | 2016-12-14 | 2017-05-24 | 四川熹玥广告传媒有限公司 | Water-based paint and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502007A (en) * | 2017-09-26 | 2017-12-22 | 重庆华亚家私有限公司 | A kind of modification infusorial earth aqueous, environmental protective paint and preparation method thereof |
| CN107502007B (en) * | 2017-09-26 | 2020-04-07 | 重庆华亚家私有限公司 | Modified diatomite water-based environment-friendly paint and preparation method thereof |
| CN108215558A (en) * | 2017-12-19 | 2018-06-29 | 浙江锦旺新材料科技有限公司 | A kind of coiling-resistant heat-transferring printing paper |
| CN108215558B (en) * | 2017-12-19 | 2019-09-10 | 浙江锦旺新材料科技有限公司 | A kind of coiling-resistant heat-transferring printing paper |
| CN108084869A (en) * | 2018-01-24 | 2018-05-29 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
| CN108456464A (en) * | 2018-02-07 | 2018-08-28 | 合肥达户电线电缆科技有限公司 | A kind of preparation method of new type environment friendly coating |
| CN108191303A (en) * | 2018-02-10 | 2018-06-22 | 吴刚 | It is a kind of except the preparation method of the fungi-proofing diatom ooze of formaldehyde type |
| CN108822625A (en) * | 2018-07-26 | 2018-11-16 | 合肥市大卓电力有限责任公司 | A kind of novel environment friendly coatings and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107189558A (en) | Environmental protection coating material prepared by a kind of modified starch and preparation method thereof | |
| CN105949863A (en) | Functional diatomite putty powder and preparation method thereof | |
| CN104673033B (en) | A kind of inorganic aqueous metallic paint and preparation method thereof | |
| CN107384068B (en) | A kind of preparation method of high-quality mosquito repellent interior wall coating | |
| CN104629566A (en) | Antibacterial anion paint | |
| CN106366927A (en) | Coating | |
| CN105968916A (en) | Environment-friendly coating with shell powder | |
| CN108342130A (en) | A kind of diatom Fender formaldehyde indoor coating preparation process | |
| CN109161255A (en) | A kind of aqueous diatom coating with air purification function | |
| CN107163689A (en) | Environmental protection coating material prepared by a kind of modified fibre slurry and preparation method thereof | |
| CN105602375A (en) | External wall heat-insulation low-carbon energy-saving paint | |
| CN109385131A (en) | A kind of high strong water resistant ordor removing powder of lacquer putty for use on and its preparation process | |
| CN104073066B (en) | A kind of water type multi-color coating | |
| CN105754397B (en) | Environmentally friendly antibacterial powder of lacquer putty for use on of mosquito repellent and preparation method thereof | |
| CN106242363B (en) | A kind of sepiolite with coordination function/diatomite basic ring protects indoor wall material | |
| CN105754395B (en) | Environmentally friendly net taste powder of lacquer putty for use on and preparation method thereof | |
| CN104119748A (en) | High-temperature resistant water-based multicolor paint | |
| KR100879750B1 (en) | The natural water-soluble painting composite and method of manufacturing the same | |
| CN104151961A (en) | Nano modified polyvinyl acetate-acrylic acid building exterior wall emulsion paint | |
| CN104861788A (en) | Interior decoration facing powder coating | |
| CN103756378A (en) | Stable diatom liquid coating | |
| CN106675243A (en) | Environment-friendly and healthy white bamboo charcoal functional coating for interior walls | |
| CN104559671A (en) | Waterborne flame-retardant antirust noise reduction coating for multiple equipment shells and preparation method of coating | |
| CN105859211A (en) | Anion-adsorption/decomposition composite diatom ooze and preparation method thereof | |
| CN107417175A (en) | A kind of diatom ooze composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170922 |
|
| WD01 | Invention patent application deemed withdrawn after publication |