CN107384068B - A kind of preparation method of high-quality mosquito repellent interior wall coating - Google Patents
A kind of preparation method of high-quality mosquito repellent interior wall coating Download PDFInfo
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- CN107384068B CN107384068B CN201710493284.6A CN201710493284A CN107384068B CN 107384068 B CN107384068 B CN 107384068B CN 201710493284 A CN201710493284 A CN 201710493284A CN 107384068 B CN107384068 B CN 107384068B
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
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- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
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- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
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- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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Abstract
The invention discloses a kind of preparation methods of high-quality mosquito repellent interior wall coating, include the following steps：（1）Mixed essential oil preparation,（2）Compounded mix preparation,（3）Finished product coating preparation.The present invention has carried out special improvement to the preparation process of coating and has handled, and final interior wall coating repelling effect obtained is good, and mosquito repellent timeliness is long, and the performance of coating itself is preferable, and popularizing value is higher.
Description
Technical field
The invention belongs to coating processing technique fields, and in particular to a kind of preparation method of high-quality mosquito repellent interior wall coating.
Background technology
Coating is to cover with paint, lacquer, colour wash, etc. the material that can bond and be formed complete and tough and tensile protective film very well with basis material in body surface.
Coating and paint are identical concepts, and paint is people's custom title used for a long time, after introducing China, just utilize always and are building
Industry.The effect of coating may be summarized to be three aspects：Protective effect, decoration function, specific function effect.General group of coating
Become：Including film forming matter, color stuffing, solvent, auxiliary agent.
Building coating has the function of that decoration functions, defencive function and livability are improved.Proportion shared by various functions is because making
It is not quite similar with the difference of purpose.It includes two big portion of interior wall coating and exterior coating again that building coating is classified by building wall
Point.Interior wall coating focus on decoration and environmental protection, exterior coating focus on protection and it is durable.With the development of society, people are for coating
Performance require it is higher and higher, such as have again for interior wall coating health care, prevention pest and disease damage demand.
Mosquito is one of four pests, and is the portable object of virus.With the development of society, human living standard's constantly carries
Height, people are also being continuously increased the consciousness of health and self-protection, and various mosquito repellent products come into being in succession.Existing majority
Mosquito repellent product is to use indoors, and the purpose is to expel indoor mosquito in outdoor, but daily routines inevitably make
Mosquito is again introduced into interior, and has aggravated the mosquito repellent work of people.It is found in actually investigating, mosquito sting in building is attached to more
On the wall of passageway, interior etc., if the interior wall coating of wall inherently has repelling effect, the presence of mosquito can be greatly reduced
Probability repeatedly, to ensure that the safety of health.Based on above-mentioned theory, occur some currently on the market with mosquito repellent work(
The interior wall coating of effect, preparation method are mostly essential oil, chemical agent etc. of the addition with repelling effect directly in coating, but its
Mosquito repellent persistence is poor, improves this problem by adding the filler of the slow release effect with mosquito repellent to this someone, but mostly there is
The problems such as influencing coating performance itself.
Invention content
The purpose of the present invention is for existing problem, provide a kind of preparation method of high-quality mosquito repellent interior wall coating.
The present invention is achieved by the following technical solutions：
A kind of preparation method of high-quality mosquito repellent interior wall coating, includes the following steps：
（1）It is prepared by mixed essential oil：
By Lavender, Peppermint essential oil, thyme essential oil according to weight ratio 2 ~ 4：5~7：4 ~ 6 are mixed, and are put into and are stirred
It is spare to mix obtained mixed essential oil after being stirred evenly in tank；
（2）It is prepared by compounded mix：
A., attapulgite is first put into 10 ~ 15min of immersion treatment in the salpeter solution that mass fraction is 6 ~ 10%, after the completion
It filters out and is rinsed well with deionized water rear spare；
B. a will be operated treated in the calcining furnace that attapulgite is put into temperature is 770 ~ 810 DEG C and carry out calcination processing,
Attapulgite taken out after 1.5 ~ 2h spare；
C. to operation b treated attapulgite crushes processing, guarantee particle diameter is big after a portion crushes
Small is 150 ~ 200 mesh, and obtained powder A is spare, and another part ensures that particle diameter size is 1000 ~ 1500 mesh after crushing, be made
Powder material B is spare；
D. powder A made from operation c is immersed in step（1）In the mixed essential oil of preparation, filtered out after 2 ~ 3h of immersion treatment
Drying for standby；
E. powder material B made from c will be operated to be immersed in the silane coupler solution that mass fraction is 10 ~ 12%, heating is kept
The temperature of silane coupler solution is 55 ~ 60 DEG C, is filtered out after 45 ~ 50min of stir process spare；
F. will operation d treated powder A and operation e treated powder material Bs according to mass ratio 1：1 ~ 1.2, which carries out mixing, puts
Enter in treatment fluid C, be stirred continuously after 1 ~ 1.5h of processing filter out it is dry to after constant weight compounded mix is spare；The treatment fluid C
Middle each component and its corresponding weight percent are：Polyethylene glycol 3 ~ 5%, neopelex 1 ~ 2%, mixed essential oil 8 ~ 12%,
Surplus is water；
（3）Finished product coating preparation：
A. following substance is weighed by corresponding parts by weight：150 ~ 200 parts of filming emulsion, 3 ~ 6 parts of sodium pyrophosphate, alcohol ester 12 ~
7 parts, 25 ~ 35 parts of color stuffing, 1 ~ 1.5 part of antifoaming agent, 0.5 ~ 1 part of mould inhibitor, 45 ~ 55 parts of talcum powder, step（2）Gained it is compound
20 ~ 25 parts of filler；
B. all substances that a is weighed will be operated to be put into reaction kettle jointly, high-speed stirred is uniformly taken out and got product afterwards
Coating.
Further, step（2）Immersion treatment described in operation d is that the temperature of heating holding mixed essential oil is 40 ~ 45
℃。
Further, step（2）Rotating speed when operating the stir process described in f is 300 ~ 500 revs/min.
Further, step（2）The drying temperature control operated described in f is 70 ~ 80 DEG C.
Further, step（3）It is acrylic resin, vinylacetate, styrene-to operate the filming emulsion described in a
Any one in acrylic copolymer.
Further, step（3）Rotating speed when operating the high-speed stirred processing described in b is 800 ~ 1000 revs/min.
Mosquito component is directly added in coating, and there is effects to decline fast, the problem that the duration is not grown, to this someone
Mosquito repellent adding ingredient is first adsorbed using sorptive filler, prepared by the filling for being used further to coating, but the filler surface after absorption is special
Property change, the compatibility between the ingredients such as lotion reduces, and to influence the use characteristic of coating entirety, can make instead
The problem of at losing more than gain.Special processing carried out in the preparation to this present invention, first with Lavender, Peppermint essential oil,
Thyme, which progresses greatly to go to compound, has been modulated into mixed essential oil, has to mosquito and disperses performance well, and has carried out compound fill out
The making of material, compounded mix are made of two kinds of particles attapulgite of different sizes, wherein utilizing the larger concave convex rod of particle
Native powder A stores mixed essential oil as absorption fixative, serves as mixed essential oil source of release, and in order to reduce powder A for applying
The performance of material influences, and is added to the smaller attapulgite powder B of particle and carries out compound, and powder material B surface is modified with coating
Compatibility is preferable, and the outer surface for being adsorbed in powder A enhances the fusion characteristics of compounded mix, while powder material B can be controlled further again
The release of mixed essential oil processed, while the channel largely discharged is formd in coating again, it ensure that releasing for coating inside essential oil source
Go out, improves the timeliness of mosquito repellent.
The present invention has the following advantages compared with prior art：
The present invention has carried out special improvement to the preparation process of coating and has handled, final interior wall coating repelling effect obtained
Good, mosquito repellent timeliness is long, and the performance of coating itself is preferable, and popularizing value is higher.
Specific implementation mode
Embodiment 1
A kind of preparation method of high-quality mosquito repellent interior wall coating, includes the following steps：
（1）It is prepared by mixed essential oil：
By Lavender, Peppermint essential oil, thyme essential oil according to weight ratio 2：5：4 are mixed, and are put into agitator tank
It is spare that mixed essential oil is made after stirring evenly；
（2）It is prepared by compounded mix：
A., attapulgite is first put into immersion treatment 10min in the salpeter solution that mass fraction is 6%, is filtered out after the completion simultaneously
It is rinsed well with deionized water rear spare；
B. a will be operated treated and carry out calcination processing in the calcining furnace that attapulgite is put into temperature is 770 DEG C, after 1.5h
Attapulgite is taken out spare；
C. to operation b treated attapulgite crushes processing, guarantee particle diameter is big after a portion crushes
Small is 150 ~ 200 mesh, and obtained powder A is spare, and another part ensures that particle diameter size is 1000 ~ 1500 mesh after crushing, be made
Powder material B is spare；
D. powder A made from operation c is immersed in step（1）In the mixed essential oil of preparation, filtered out after immersion treatment 2h dry
It is dry spare；
E. powder material B made from c will be operated to be immersed in the silane coupler solution that mass fraction is 10%, heating keeps silicon
The temperature of alkane coupling agent solution is 55 DEG C, is filtered out after stir process 45min spare；
F. will operation d treated powder A and operation e treated powder material Bs according to mass ratio 1：1, which carries out mixing, is put into place
Manage in liquid C, be stirred continuously after processing 1h filter out it is dry to after constant weight compounded mix is spare；Each component in the treatment fluid C
And its corresponding weight percent is：Polyethylene glycol 3%, neopelex 1%, mixed essential oil 8%, surplus are water；
（3）Finished product coating preparation：
A. following substance is weighed by corresponding parts by weight：150 parts of filming emulsion, 3 parts of sodium pyrophosphate, 12 parts of alcohol ester, face are filled out
25 parts of material, 1 part of antifoaming agent, 0.5 part of mould inhibitor, 45 parts of talcum powder, step（2）20 parts of the compounded mix of gained；
B. all substances that a is weighed will be operated to be put into reaction kettle jointly, high-speed stirred is uniformly taken out and got product afterwards
Coating.
Further, step（2）Immersion treatment described in operation d is that the temperature of heating holding mixed essential oil is 40 DEG C.
Further, step（2）Rotating speed when operating the stir process described in f is 300 revs/min.
Further, step（2）The drying temperature control operated described in f is 70 DEG C.
Further, step（3）It is acrylic resin to operate the filming emulsion described in a.
Further, step（3）Rotating speed when operating the high-speed stirred processing described in b is 800 revs/min.
Embodiment 2
A kind of preparation method of high-quality mosquito repellent interior wall coating, includes the following steps：
（1）It is prepared by mixed essential oil：
By Lavender, Peppermint essential oil, thyme essential oil according to weight ratio 3：6：5 are mixed, and are put into agitator tank
It is spare that mixed essential oil is made after stirring evenly；
（2）It is prepared by compounded mix：
A., attapulgite is first put into immersion treatment 12min in the salpeter solution that mass fraction is 8%, is filtered out after the completion simultaneously
It is rinsed well with deionized water rear spare；
B. a will be operated treated and carry out calcination processing in the calcining furnace that attapulgite is put into temperature is 790 DEG C, after 1.8h
Attapulgite is taken out spare；
C. to operation b treated attapulgite crushes processing, guarantee particle diameter is big after a portion crushes
Small is 150 ~ 200 mesh, and obtained powder A is spare, and another part ensures that particle diameter size is 1000 ~ 1500 mesh after crushing, be made
Powder material B is spare；
D. powder A made from operation c is immersed in step（1）In the mixed essential oil of preparation, filtered out after immersion treatment 2.5h
Drying for standby；
E. powder material B made from c will be operated to be immersed in the silane coupler solution that mass fraction is 11%, heating keeps silicon
The temperature of alkane coupling agent solution is 57 DEG C, is filtered out after stir process 48min spare；
F. will operation d treated powder A and operation e treated powder material Bs according to mass ratio 1：1.1, which carry out mixing, is put into
In treatment fluid C, be stirred continuously after processing 1.2h filter out it is dry to after constant weight compounded mix is spare；It is each in the treatment fluid C
Component and its corresponding weight percent are：Polyethylene glycol 4%, neopelex 1.5%, mixed essential oil 10%, surplus are
Water；
（3）Finished product coating preparation：
A. following substance is weighed by corresponding parts by weight：180 parts of filming emulsion, 5 parts of sodium pyrophosphate, 12 parts of alcohol ester, face are filled out
30 parts of material, 1.2 parts of antifoaming agent, 0.8 part of mould inhibitor, 50 parts of talcum powder, step（2）22 parts of the compounded mix of gained；
B. all substances that a is weighed will be operated to be put into reaction kettle jointly, high-speed stirred is uniformly taken out and got product afterwards
Coating.
Further, step（2）Immersion treatment described in operation d is that the temperature of heating holding mixed essential oil is 43 DEG C.
Further, step（2）Rotating speed when operating the stir process described in f is 400 revs/min.
Further, step（2）The drying temperature control operated described in f is 75 DEG C.
Further, step（3）It is vinylacetate to operate the filming emulsion described in a.
Further, step（3）Rotating speed when operating the high-speed stirred processing described in b is 900 revs/min.
Embodiment 3
A kind of preparation method of high-quality mosquito repellent interior wall coating, includes the following steps：
（1）It is prepared by mixed essential oil：
By Lavender, Peppermint essential oil, thyme essential oil according to weight ratio 4：7：6 are mixed, and are put into agitator tank
It is spare that mixed essential oil is made after stirring evenly；
（2）It is prepared by compounded mix：
A., attapulgite is first put into immersion treatment 15min in the salpeter solution that mass fraction is 10%, is filtered out after the completion simultaneously
It is rinsed well with deionized water rear spare；
B. a will be operated treated and carry out calcination processing in the calcining furnace that attapulgite is put into temperature is 810 DEG C, after 2h
Attapulgite is taken out spare；
C. to operation b treated attapulgite crushes processing, guarantee particle diameter is big after a portion crushes
Small is 150 ~ 200 mesh, and obtained powder A is spare, and another part ensures that particle diameter size is 1000 ~ 1500 mesh after crushing, be made
Powder material B is spare；
D. powder A made from operation c is immersed in step（1）In the mixed essential oil of preparation, filtered out after immersion treatment 3h dry
It is dry spare；
E. powder material B made from c will be operated to be immersed in the silane coupler solution that mass fraction is 12%, heating keeps silicon
The temperature of alkane coupling agent solution is 60 DEG C, is filtered out after stir process 50min spare；
F. will operation d treated powder A and operation e treated powder material Bs according to mass ratio 1：1.2, which carry out mixing, is put into
In treatment fluid C, be stirred continuously after processing 1.5h filter out it is dry to after constant weight compounded mix is spare；It is each in the treatment fluid C
Component and its corresponding weight percent are：Polyethylene glycol 5%, neopelex 2%, mixed essential oil 12%, surplus are water；
（3）Finished product coating preparation：
A. following substance is weighed by corresponding parts by weight：200 parts of filming emulsion, 6 parts of sodium pyrophosphate, 12 parts of alcohol ester, face are filled out
35 parts of material, 1.5 parts of antifoaming agent, 1 part of mould inhibitor, 55 parts of talcum powder, step（2）25 parts of the compounded mix of gained；
B. all substances that a is weighed will be operated to be put into reaction kettle jointly, high-speed stirred is uniformly taken out and got product afterwards
Coating.
Further, step（2）Immersion treatment described in operation d is that the temperature of heating holding mixed essential oil is 45 DEG C.
Further, step（2）Rotating speed when operating the stir process described in f is 500 revs/min.
Further, step（2）The drying temperature control operated described in f is 80 DEG C.
Further, step（3）It is Styrene-acrylic copolymer to operate the filming emulsion described in a.
Further, step（3）Rotating speed when operating the high-speed stirred processing described in b is 1000 revs/min.
Comparative example 1
This comparative example 1 compared with Example 2, in step（2）In prepared by compounded mix, the system of operation c powder material Bs is saved
It is standby, while the respective operations namely compounded mix saved subsequently in relation to powder material B are made of powder A completely, adsorb mixed essential oil
After be directly used in step（3）In finished product coating preparation, method and step all same in addition to this.
Comparative example 2
This comparative example 2 compared with Example 2, in the entire manufacturing process of coating, saves the preparation of compounded mix
With use step, the mixed essential oil for being adsorbed corresponding parts by weight is added directly into step（3）In finished product coating preparation, in addition to this
Method and step all same.
In order to compare effect of the present invention, the mosquito repellent experiment of special designing is carried out, specific method is：Choose it is four long × wide ×
The mosquito cage of a height of 30cm × 30cm × 60cm is correspondingly placed into the aedes albopictus that 300 4 ~ 5 ages in days are not sucked blood in each mosquito cage
Then female mosquito places a plank of the surface through special coating processing in each mosquito cage, wherein three corresponding coatings respectively
Above-described embodiment 2, comparative example 1, the coating obtained by comparative example 2（The amount of coating is identical）, another work
For control group coating etc. quality vinyl acetate emulsion, finally in order to keep experimental phenomena apparent, on the coating of each plank
Also one layer of watery blood of atomized spray（Pig blood watery blood）, it is primary every 2h observations, observe 2min every time, and record stung on plank it is attached
Mosquito populations, on the basis of control group, the mosquito repellent for calculating remaining each group is efficient（%）, wherein mosquito repellent is efficient（%）=（Control
Group mosquito stings attached quantity-experimental group mosquito and stings attached quantity）/ control group mosquito stings attached quantity；The specific correction data of experiment is as follows
Shown in table 1：
Table 1
Although without directly adding essential oil when the coating it can be seen from upper table 1 obtained by the present invention uses in the early stage
2 effect of comparative example is good, but using effect is still preferable, with the increase of usage time, the mosquito repellent of 2 coating of the embodiment of the present invention
Effective percentage remains to reach 95% or more superior level, shows that its mosquito repellent duration is long, repelling effect is good.
In order to further compare effect of the present invention, obtained by above-described embodiment 2, comparative example 1, comparative example 2
Coating be tested for the property, specific correction data is as shown in table 2 below：
Table 2
| Impact resistance（kg·cm） | Adhesive force | |
| Embodiment 2 | 53.4 | 1 grade |
| Comparative example 1 | 48.4 | 1 grade |
| Comparative example 2 | 41.2 | 2 grades |
Note：Impact resistance described in upper table 1 is tested with reference to GB/T 1732-93；The adhesive force is with reference to GB/T
9286-1998 is tested.
It can be seen from upper table 2 the corresponding obtained coating of the present invention itself is preferable using characteristic, use value is higher.
Claims (6)
1. a kind of preparation method of high-quality mosquito repellent interior wall coating, which is characterized in that include the following steps：
（1）It is prepared by mixed essential oil：
By Lavender, Peppermint essential oil, thyme essential oil according to weight ratio 2 ~ 4：5~7：4 ~ 6 are mixed, and agitator tank is put into
It is spare that mixed essential oil is made after inside stirring evenly；
（2）It is prepared by compounded mix：
A., attapulgite is first put into 10 ~ 15min of immersion treatment in the salpeter solution that mass fraction is 6 ~ 10%, is filtered out after the completion
It is used in combination deionized water to rinse well rear spare；
B. a will be operated treated in the calcining furnace that attapulgite is put into temperature is 770 ~ 810 DEG C and carry out calcination processing, 1.5 ~ 2h
Attapulgite is taken out afterwards spare；
C. to operation b treated attapulgite crushes processing, guarantee particle diameter size is after a portion crushes
150 ~ 200 mesh, obtained powder A is spare, and another part ensures that particle diameter size is 1000 ~ 1500 mesh after crushing, powder material B is made
It is spare；
D. powder A made from operation c is immersed in step（1）In the mixed essential oil of preparation, drying is filtered out after 2 ~ 3h of immersion treatment
It is spare；
E. powder material B made from c will be operated to be immersed in the silane coupler solution that mass fraction is 10 ~ 12%, heating keeps silane
The temperature of coupling agent solution is 55 ~ 60 DEG C, is filtered out after 45 ~ 50min of stir process spare；
F. will operation d treated powder A and operation e treated powder material Bs according to mass ratio 1：1 ~ 1.2, which carries out mixing, is put into place
Manage in liquid C, be stirred continuously after 1 ~ 1.5h of processing filter out it is dry to after constant weight compounded mix is spare；It is each in the treatment fluid C
Component and its corresponding weight percent are：Polyethylene glycol 3 ~ 5%, neopelex 1 ~ 2%, mixed essential oil 8 ~ 12%, surplus
For water；
（3）Finished product coating preparation：
A. following substance is weighed by corresponding parts by weight：150 ~ 200 parts of filming emulsion, 3 ~ 6 parts of sodium pyrophosphate, 12 ~ 7 parts of alcohol ester,
25 ~ 35 parts of color stuffing, 1 ~ 1.5 part of antifoaming agent, 0.5 ~ 1 part of mould inhibitor, 45 ~ 55 parts of talcum powder, step（2）The compounded mix of gained
20 ~ 25 parts；
B. all substances that a is weighed will be operated to be put into reaction kettle jointly, high-speed stirred is uniformly taken out and gets product coating afterwards.
2. a kind of preparation method of high-quality mosquito repellent interior wall coating according to claim 1, which is characterized in that step（2）
Immersion treatment described in operation d is that the temperature of heating holding mixed essential oil is 40 ~ 45 DEG C.
3. a kind of preparation method of high-quality mosquito repellent interior wall coating according to claim 1, which is characterized in that step（2）
Rotating speed when operating the stir process described in f is 300 ~ 500 revs/min.
4. a kind of preparation method of high-quality mosquito repellent interior wall coating according to claim 1, which is characterized in that step（2）
The drying temperature control operated described in f is 70 ~ 80 DEG C.
5. a kind of preparation method of high-quality mosquito repellent interior wall coating according to claim 1, which is characterized in that step（3）
It is any one in acrylic resin, vinylacetate, Styrene-acrylic copolymer to operate the filming emulsion described in a.
6. a kind of preparation method of high-quality mosquito repellent interior wall coating according to claim 1, which is characterized in that step（3）
Rotating speed when operating the high-speed stirred processing described in b is 800 ~ 1000 revs/min.
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| CN108384381B (en) * | 2018-01-31 | 2020-06-02 | 连云港托普科技有限公司 | Preparation method of temperature-resistant sound-deadening architectural decorative coating |
| CN108997793A (en) * | 2018-04-24 | 2018-12-14 | 曹俊峰 | A kind of processing method of the inorganic filler for pervious asphalt production |
| CN108676443A (en) * | 2018-06-13 | 2018-10-19 | 合肥浦尔菲电线科技有限公司 | Mosquito repellent rate environment-friendly coating and preparation method thereof can be improved for cover surface in one kind |
| CN108997670A (en) * | 2018-06-22 | 2018-12-14 | 安徽索亚装饰材料有限公司 | A kind of high-strength PVC foaming wallpaper |
| CN108976960A (en) * | 2018-06-22 | 2018-12-11 | 安徽索亚装饰材料有限公司 | A kind of NEW TYPE OF COMPOSITE mosquito repellent environment-friendly interior wall coating and preparation method thereof |
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|---|---|---|---|---|
| CN1730583A (en) * | 2005-08-17 | 2006-02-08 | 马金山 | Lavender flavor type environment protective latex paint and its preparation method |
| CN101851451A (en) * | 2010-06-02 | 2010-10-06 | 中华制漆（深圳）有限公司 | Mosquito repellent water-based environment-friendly interior wall coating and preparation method thereof |
| CN102516871A (en) * | 2011-11-30 | 2012-06-27 | 福建中睿环保科技有限公司 | Mosquito-expelling water soluble paint |
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Patent Citations (3)
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|---|---|---|---|---|
| CN1730583A (en) * | 2005-08-17 | 2006-02-08 | 马金山 | Lavender flavor type environment protective latex paint and its preparation method |
| CN101851451A (en) * | 2010-06-02 | 2010-10-06 | 中华制漆（深圳）有限公司 | Mosquito repellent water-based environment-friendly interior wall coating and preparation method thereof |
| CN102516871A (en) * | 2011-11-30 | 2012-06-27 | 福建中睿环保科技有限公司 | Mosquito-expelling water soluble paint |
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