CN107164951A - A kind of preparation method of silver-plated conductive aramid fiber - Google Patents
A kind of preparation method of silver-plated conductive aramid fiber Download PDFInfo
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- CN107164951A CN107164951A CN201710532867.5A CN201710532867A CN107164951A CN 107164951 A CN107164951 A CN 107164951A CN 201710532867 A CN201710532867 A CN 201710532867A CN 107164951 A CN107164951 A CN 107164951A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/20—Halides of elements of Groups 4 or 14 of the Periodic System, e.g. zirconyl chloride
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic System
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
The invention discloses a kind of preparation method of silver-plated conductive aramid fiber, including removing photoresist and oil removing, roughening, sensitization, activation, reduction, chemical silvering, aramid fiber after chemical silvering is handled is rinsed with water to neutrality, and vacuum drying obtains silver-plated conductive aramid fiber.Compared with prior art, it is of the invention to have the beneficial effect that：The chemical silvering solution of the present invention is more stablized；The silver-plated rate of body weight gain of the present invention is 2 times of traditional handicraft；The electric conductivity of silver-plated conductive aramid fiber produced by the present invention is excellent, and sheet resistance is：0.23 Ω/cm, fracture strength is up to 45N, is the good high-performance conductive fiber of a kind of high intensity, high temperature resistant, fire resistance.
Description
Technical field
The present invention relates to high performance conductive fiber and its processing method field, particularly a kind of silver-plated conductive aramid fiber
Preparation method.
Background technology
Aramid fiber is a kind of high performance high molecular synthetic material, with the high fire-retardant of mould high temperature resistants of high-strength chemically
It can stablize and wait the performance of friendship and be widely applied to military project protection field.The conductive aramid fiber being made have fire-retardant it is heat-resisting and
Anti- electromagnet shield effect, can be applied to the fields such as Aero-Space military projects communications.Relevant fiber surface metallization both at home and abroad at present
The method of processing has sputtering method, electrodeposition process and electroless plating method.Wherein electroless plating method due to its required equipment it is simple, it is obtained
Coating and basal body binding force it is preferable, it is adaptable to the advantages of mass producing and the gold for being widely used in non-metal material surface
Categoryization processing.Because aramid fiber surface is smooth and one layer of organic layer is formed during preparation, it is covered before metal needs
Advance surface treatment, to increase roughness and surface area, improves quality of coating.But, the chemical silvering of prior art due to
It is not in place to aramid fiber surface processing, it is difficult to ensure that forming metal catalytic particulate on its surface to ensure smoothly entering for plating
OK, it is impossible to thicken coating, so as to influence the performance of obtained silver-plated conductive aramid fiber.
The content of the invention
The invention aims to the deficiency for solving prior art problem, there is provided a kind of preparation of silver-plated conductive aramid fiber
Method.
To reach above-mentioned purpose, the present invention is implemented according to following technical scheme：
A kind of preparation method of silver-plated conductive aramid fiber, comprises the following steps：
S1, remove photoresist and oil removing：Aramid fiber is inserted in the acetone that percent concentration is 25%, carried out using ultrasonic wave clear
25-35min is washed, aramid fiber is taken out and is dried under the conditions of 90 DEG C；
S2, roughening：Aramid fiber after S1 is handled is inserted to the sodium naphthalene tetrahydrochysene of percent concentration 10% at room temperature
In tetrahydrofuran solution, it is roughened, and is stirred continuously；
S3, sensitization：Aramid fiber Jing Guo S2 roughening treatments is inserted to sensitized treatment 8min in 50 DEG C of sensitizing solution, not
Disconnected stirring, then takes out aramid fiber and is rinsed with water to neutrality；
S4, activation：Aramid fiber after S3 sensitized treatments is inserted to activation process 5min in 50 DEG C of activating solution, and
Being stirred continuously makes it fully activate, and then takes out aramid fiber and is rinsed with water to neutrality；
S5, reduction：Aramid fiber after S4 activation process is inserted to 30g/L NaH at room temperature2PO2In solution also
2min is managed in original place, then takes out aramid fiber and is rinsed with water to neutrality；
S6, chemical silvering：Aramid fiber after S5 reduction treatments is inserted in the chemical silvering solution prepared, its
Described in chemical silvering solution the content of each component be：Silver nitrate：6-14g/L, glucose：4-12g/L, ammoniacal liquor：30-
80ml/L, sodium potassium tartrate tetrahydrate：1-4g/L, ethylenediamine：20ml/L, ethanol：40ml/L, potassium hydroxide：3-10g/L, polyethylene glycol：
75ml/L, the chemical silvering 10-30min under the conditions of the chemical silvering solution temperature is 25-30 DEG C；
S7, the aramid fiber after the processing of S6 chemical silverings rinsed with water to neutrality, and be dried in vacuo and obtain silver-plated
Conductive aramid fiber.
Further, the sensitizing solution in the step S3 by 15g/L SnCl2Solution and 20ml/L HCl solution composition.
Further, the activating solution in the step S4 by 0.5g/L PdCl2Solution and 10ml/L HCl solution composition.
Preferably, deionized water is used during the rinsing aramid fiber.
The present invention by aramid fiber surface is removed photoresist and oil removing, roughening, sensitization, activation, reduction treatment after, can be
Aramid fiber surface forms metal catalytic particulate to ensure being smoothed out for chemical silvering, and aramid fiber table during chemical silvering
When face is once deposited plating layer, the coating being deposited can continue to keep this catalytic performance, so that deposition process is continuous
Carry out, coating gradually thickeies.
Compared with prior art, it is of the invention to have the beneficial effect that：
1. the chemical silvering solution of the present invention is more stablized；
2. the silver-plated rate of body weight gain of the present invention is 2 times of traditional handicraft；
3. the electric conductivity of silver-plated conductive aramid fiber produced by the present invention is excellent, sheet resistance is：0.23 Ω/cm, breaks
Resistance to spalling is up to 45N, is the good high-performance conductive fiber of a kind of high intensity, high temperature resistant, fire resistance.
Embodiment
With reference to specific embodiment, the invention will be further described, the illustrative examples and explanation invented herein
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment one
S1, remove photoresist and oil removing：Aramid fiber is inserted in the acetone that percent concentration is 25%, carried out using ultrasonic wave clear
25min is washed, aramid fiber is taken out and is dried under the conditions of 90 DEG C；
S2, roughening：Aramid fiber after S1 is handled is inserted to the sodium naphthalene tetrahydrochysene of percent concentration 10% at room temperature
In tetrahydrofuran solution, it is roughened, and is stirred continuously；
S3, sensitization：Aramid fiber Jing Guo S2 roughening treatments is inserted to sensitized treatment 8min in 50 DEG C of sensitizing solution, its
In, sensitizing solution by 15g/L SnCl2Solution and 20ml/L HCl solution composition, and constantly stir, then take out aramid fiber fine
Wesy's deionized water is rinsed to neutrality；
S4, activation：Aramid fiber after S3 sensitized treatments is inserted to activation process 5min in 50 DEG C of activating solution, its
In, activating solution by 0.5g/L PdCl2Solution and 10ml/L HCl solution composition, and being stirred continuously makes it fully activate, then
Aramid fiber is taken out to be rinsed with deionized water to neutrality；
S5, reduction：Aramid fiber after S4 activation process is inserted to 30g/L NaH at room temperature2PO2In solution also
2min is managed in original place, then takes out aramid fiber and is rinsed with deionized water to neutrality；
S6, chemical silvering：Aramid fiber after S5 reduction treatments is inserted in the chemical silvering solution prepared, its
Described in chemical silvering solution the content of each component be：Silver nitrate：6g/L, glucose：4g/L, ammoniacal liquor：30ml/L, tartaric acid
Potassium sodium：1g/L, ethylenediamine：20ml/L, ethanol：40ml/L, potassium hydroxide：3g/L, polyethylene glycol：75ml/L, in the chemical plating
Silver-colored solution temperature is chemical silvering 10min under the conditions of 25 DEG C；
S7, the aramid fiber after the processing of S6 chemical silverings rinsed to neutrality with deionized water, and be dried in vacuo
To silver-plated conductive aramid fiber.
In the present embodiment, by being removed photoresist to aramid fiber surface and oil removing, roughening, sensitization, activation, reduction treatment
Afterwards, form metal catalytic particulate to ensure being smoothed out for chemical silvering, and aramid fiber during chemical silvering in aramid fiber surface
When fiber surface is once deposited plating layer, the coating being deposited can continue to keep this catalytic performance, so that depositing
Journey is carried out continuously, and coating gradually thickeies.
Embodiment two
S1, remove photoresist and oil removing：Aramid fiber is inserted in the acetone that percent concentration is 25%, carried out using ultrasonic wave clear
35min is washed, aramid fiber is taken out and is dried under the conditions of 90 DEG C；
S2, roughening：Aramid fiber after S1 is handled is inserted to the sodium naphthalene tetrahydrochysene of percent concentration 10% at room temperature
In tetrahydrofuran solution, it is roughened, and is stirred continuously；
S3, sensitization：Aramid fiber Jing Guo S2 roughening treatments is inserted to sensitized treatment 8min in 50 DEG C of sensitizing solution, its
In, sensitizing solution by 15g/L SnCl2Solution and 20ml/L HCl solution composition, and constantly stir, then take out aramid fiber fine
Wesy's deionized water is rinsed to neutrality；
S4, activation：Aramid fiber after S3 sensitized treatments is inserted to activation process 5min in 50 DEG C of activating solution, its
In, activating solution by 0.5g/L PdCl2Solution and 10ml/L HCl solution composition, and being stirred continuously makes it fully activate, then
Aramid fiber is taken out to be rinsed with deionized water to neutrality；
S5, reduction：Aramid fiber after S4 activation process is inserted to 30g/L NaH at room temperature2PO2In solution also
2min is managed in original place, then takes out aramid fiber and is rinsed with deionized water to neutrality；
S6, chemical silvering：Aramid fiber after S5 reduction treatments is inserted in the chemical silvering solution prepared, its
Described in chemical silvering solution the content of each component be：Silver nitrate：14g/L, glucose：12g/L, ammoniacal liquor：80ml/L, winestone
Sour potassium sodium：4g/L, ethylenediamine：20ml/L, ethanol：40ml/L, potassium hydroxide：10g/L, polyethylene glycol：75ml/L, in the chemistry
Silver plating solution temperature is chemical silvering 30min under the conditions of 30 DEG C；
S7, the aramid fiber after the processing of S6 chemical silverings rinsed to neutrality with deionized water, and be dried in vacuo
To silver-plated conductive aramid fiber.
In the present embodiment, by being removed photoresist to aramid fiber surface and oil removing, roughening, sensitization, activation, reduction treatment
Afterwards, form metal catalytic particulate to ensure being smoothed out for chemical silvering, and aramid fiber during chemical silvering in aramid fiber surface
When fiber surface is once deposited plating layer, the coating being deposited can continue to keep this catalytic performance, so that depositing
Journey is carried out continuously, and coating gradually thickeies.
Embodiment three
S1, remove photoresist and oil removing：Aramid fiber is inserted in the acetone that percent concentration is 25%, carried out using ultrasonic wave clear
30min is washed, aramid fiber is taken out and is dried under the conditions of 90 DEG C；
S2, roughening：Aramid fiber after S1 is handled is inserted to the sodium naphthalene tetrahydrochysene of percent concentration 10% at room temperature
In tetrahydrofuran solution, it is roughened, and is stirred continuously；
S3, sensitization：Aramid fiber Jing Guo S2 roughening treatments is inserted to sensitized treatment 8min in 50 DEG C of sensitizing solution, its
In, sensitizing solution by 15g/L SnCl2Solution and 20ml/L HCl solution composition, and constantly stir, then take out aramid fiber fine
Wesy's deionized water is rinsed to neutrality；
S4, activation：Aramid fiber after S3 sensitized treatments is inserted to activation process 5min in 50 DEG C of activating solution, its
In, activating solution by 0.5g/L PdCl2Solution and 10ml/L HCl solution composition, and being stirred continuously makes it fully activate, then
Aramid fiber is taken out to be rinsed with deionized water to neutrality；
S5, reduction：Aramid fiber after S4 activation process is inserted to 30g/L NaH at room temperature2PO2In solution also
2min is managed in original place, then takes out aramid fiber and is rinsed with deionized water to neutrality；
S6, chemical silvering：Aramid fiber after S5 reduction treatments is inserted in the chemical silvering solution prepared, its
Described in chemical silvering solution the content of each component be：Silver nitrate：10g/L, glucose：10g/L, ammoniacal liquor：50ml/L, winestone
Sour potassium sodium：3g/L, ethylenediamine：20ml/L, ethanol：40ml/L, potassium hydroxide：6g/L, polyethylene glycol：75ml/L, in the chemistry
Silver plating solution temperature is chemical silvering 20min under the conditions of 27 DEG C；
S7, the aramid fiber after the processing of S6 chemical silverings rinsed to neutrality with deionized water, and be dried in vacuo
To silver-plated conductive aramid fiber.
In the present embodiment, by being removed photoresist to aramid fiber surface and oil removing, roughening, sensitization, activation, reduction treatment
Afterwards, form metal catalytic particulate to ensure being smoothed out for chemical silvering, and aramid fiber during chemical silvering in aramid fiber surface
When fiber surface is once deposited plating layer, the coating being deposited can continue to keep this catalytic performance, so that depositing
Journey is carried out continuously, and coating gradually thickeies.
The silver-plated conductive aramid fiber prepared by above-described embodiment one, embodiment two and embodiment three is taken to carry out electric conductivity
With fracture strength test, the average value for measuring the sheet resistance of silver-plated conductive aramid fiber is：0.23 Ω/cm, fracture strength
Average value is up to 45N, therefore silver-plated conductive aramid fiber produced by the present invention is that a kind of high intensity, high temperature resistant, fire resistance are good
Good high-performance conductive fiber.
Technical scheme is not limited to the limitation of above-mentioned specific embodiment, and every technique according to the invention scheme is done
The technology deformation gone out, each falls within protection scope of the present invention.
Claims (4)
1. a kind of preparation method of silver-plated conductive aramid fiber, it is characterised in that comprise the following steps：
S1, remove photoresist and oil removing：Aramid fiber is inserted in the acetone that percent concentration is 25%, cleaned using ultrasonic wave
25-35min, takes out aramid fiber and is dried under the conditions of 90 DEG C；
S2, roughening：Aramid fiber after S1 is handled is inserted to the sodium naphthalene tetrahydrofuran of percent concentration 10% at room temperature
In solution, it is roughened, and is stirred continuously；
S3, sensitization：Aramid fiber Jing Guo S2 roughening treatments is inserted to sensitized treatment 8min in 50 DEG C of sensitizing solution, and constantly
Stirring, then takes out aramid fiber and is rinsed with water to neutrality；
S4, activation：Aramid fiber after S3 sensitized treatments is inserted to activation process 5min in 50 DEG C of activating solution, and constantly
Stirring makes it fully activate, and then takes out aramid fiber and is rinsed with water to neutrality；
S5, reduction：Aramid fiber after S4 activation process is inserted to 30g/L NaH at room temperature2PO2Original place is gone back in solution
2min is managed, aramid fiber is then taken out and is rinsed with water to neutrality；
S6, chemical silvering：Aramid fiber after S5 reduction treatments is inserted in the chemical silvering solution prepared, wherein institute
The content for stating each component in chemical silvering solution is：Silver nitrate：6-14g/L, glucose：4-12g/L, ammoniacal liquor：30-80ml/L,
Sodium potassium tartrate tetrahydrate：1-4g/L, ethylenediamine：20ml/L, ethanol：40ml/L, potassium hydroxide：3-10g/L, polyethylene glycol：75ml/L,
The chemical silvering 10-30min under the conditions of the chemical silvering solution temperature is 25-30 DEG C；
S7, the aramid fiber after the processing of S6 chemical silverings rinsed with water to neutrality, and be dried in vacuo and obtain silver-plated conduction
Aramid fiber.
2. the preparation method of silver-plated conductive aramid fiber according to claim 1, it is characterised in that：In the step S3
Sensitizing solution by 15g/L SnCl2Solution and 20ml/L HCl solution composition.
3. the preparation method of silver-plated conductive aramid fiber according to claim 1, it is characterised in that：In the step S4
Activating solution by 0.5g/L PdCl2Solution and 10ml/L HCl solution composition.
4. the preparation method of silver-plated conductive aramid fiber according to claim 1, it is characterised in that：The rinsing aramid fiber is fine
Deionized water is used during dimension.
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| CN201710532867.5A CN107164951A (en) | 2017-07-03 | 2017-07-03 | A kind of preparation method of silver-plated conductive aramid fiber |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109881189A (en) * | 2019-04-09 | 2019-06-14 | 苏州耐科泰斯纺织新材料有限公司 | The preparation method for the aromatic polyamide staple fiber that metallizes and stand-by provision processed |
| CN109989263A (en) * | 2019-04-10 | 2019-07-09 | 赣州西维尔金属材料科技有限公司 | A kind of preparation method of high-performance Conductive Silver-Coated PET Fibers |
| CN113447430A (en) * | 2020-03-25 | 2021-09-28 | 赣州西维尔金属材料科技有限公司 | Fiber surface coating bonding force testing device and testing method |
| CN115232384A (en) * | 2022-08-25 | 2022-10-25 | 青岛优派普环保科技股份有限公司 | Antistatic PE gas pipe and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705614A (en) * | 2009-11-03 | 2010-05-12 | 上海大学 | Preparation method of nickel-plated and silver-plated aromatic polyamide conductive fibers |
| CN102899890A (en) * | 2012-10-31 | 2013-01-30 | 昆明理工大学 | Aramid fiber surface metallization treatment method |
| CN103668944A (en) * | 2013-12-16 | 2014-03-26 | 天诺光电材料股份有限公司 | Silvered aramid conductive fiber and preparation method thereof |
| CN104532553A (en) * | 2014-12-19 | 2015-04-22 | 东华大学 | Method for chemical silver-plating of aramid conductive fibers |
| CN104695212A (en) * | 2015-03-20 | 2015-06-10 | 苏州陈恒织造有限公司 | Preparation method of electromagnetic shielding fabric |
-
2017
- 2017-07-03 CN CN201710532867.5A patent/CN107164951A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705614A (en) * | 2009-11-03 | 2010-05-12 | 上海大学 | Preparation method of nickel-plated and silver-plated aromatic polyamide conductive fibers |
| CN102899890A (en) * | 2012-10-31 | 2013-01-30 | 昆明理工大学 | Aramid fiber surface metallization treatment method |
| CN103668944A (en) * | 2013-12-16 | 2014-03-26 | 天诺光电材料股份有限公司 | Silvered aramid conductive fiber and preparation method thereof |
| CN104532553A (en) * | 2014-12-19 | 2015-04-22 | 东华大学 | Method for chemical silver-plating of aramid conductive fibers |
| CN104695212A (en) * | 2015-03-20 | 2015-06-10 | 苏州陈恒织造有限公司 | Preparation method of electromagnetic shielding fabric |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109881189A (en) * | 2019-04-09 | 2019-06-14 | 苏州耐科泰斯纺织新材料有限公司 | The preparation method for the aromatic polyamide staple fiber that metallizes and stand-by provision processed |
| CN109881189B (en) * | 2019-04-09 | 2023-12-08 | 苏州耐科泰斯纺织新材料有限公司 | Preparation method and preparation device of metallized aromatic polyamide short fibers |
| CN109989263A (en) * | 2019-04-10 | 2019-07-09 | 赣州西维尔金属材料科技有限公司 | A kind of preparation method of high-performance Conductive Silver-Coated PET Fibers |
| CN113447430A (en) * | 2020-03-25 | 2021-09-28 | 赣州西维尔金属材料科技有限公司 | Fiber surface coating bonding force testing device and testing method |
| CN113447430B (en) * | 2020-03-25 | 2023-07-18 | 赣州西维尔金属材料科技有限公司 | Device and method for testing binding force of fiber surface coating |
| CN115232384A (en) * | 2022-08-25 | 2022-10-25 | 青岛优派普环保科技股份有限公司 | Antistatic PE gas pipe and preparation method thereof |
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Application publication date: 20170915 |