CN107163491A - A kind of modified ABS material and preparation method and application - Google Patents
A kind of modified ABS material and preparation method and application Download PDFInfo
- Publication number
- CN107163491A CN107163491A CN201710453285.8A CN201710453285A CN107163491A CN 107163491 A CN107163491 A CN 107163491A CN 201710453285 A CN201710453285 A CN 201710453285A CN 107163491 A CN107163491 A CN 107163491A
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- modified abs
- abs material
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- 239000000463 material Substances 0.000 title claims abstract description 79
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004579 marble Substances 0.000 claims abstract description 42
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 36
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 24
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 24
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 22
- 230000000694 effects Effects 0.000 claims abstract description 22
- 239000010437 gem Substances 0.000 claims abstract description 21
- 239000012745 toughening agent Substances 0.000 claims abstract description 19
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 4
- WZHCOOQXZCIUNC-UHFFFAOYSA-N cyclandelate Chemical group C1C(C)(C)CC(C)CC1OC(=O)C(O)C1=CC=CC=C1 WZHCOOQXZCIUNC-UHFFFAOYSA-N 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000004595 color masterbatch Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000005034 decoration Methods 0.000 abstract description 12
- 239000002245 particle Substances 0.000 abstract description 9
- 239000012467 final product Substances 0.000 abstract description 4
- 239000003086 colorant Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 239000004575 stone Substances 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- BYACHAOCSIPLCM-UHFFFAOYSA-N 2-[2-[bis(2-hydroxyethyl)amino]ethyl-(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)CCN(CCO)CCO BYACHAOCSIPLCM-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- VCAFTIGPOYBOIC-UHFFFAOYSA-N phenyl dihydrogen phosphite Chemical class OP(O)OC1=CC=CC=C1 VCAFTIGPOYBOIC-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of modified ABS material and preparation method and application.The modified ABS material includes the synthesis main base materials of ABS and marble bar Masterbatch；By weight, the main base materials of the synthesis ABS include following component：Synthesize 80 85 parts of ABS resin；10 12 parts of toughener；13 parts of antioxidant；13 parts of compatilizer；By weight, the marble bar Masterbatch includes following component：1 1.4 parts of titanium dioxide；0.01 0.03 parts of toner；24 parts of synthetic gems bar；0.05 0.1 parts of compatilizer.The present invention substitutes traditional natural marble particle using synthetic gems bar, reduces the manufacturing cost of the decoration of traditional parian stripe effect decoration.Toner is formulated by red, yellow, blue toner, by adjusting toner mixed proportion, the adjustable marble appearance for allotting a variety of colors.Titanium dioxide of the present invention can allow final product to highlight marble stripe effect.
Description
Technical field
The present invention relates to parian Material Field, more particularly to a kind of modified ABS material and preparation method and application.
Background technology
Parian streak decoration material is widely used in the fields such as building, automobile, household electrical appliance, but traditional imitative big
The decoration of reason stone stripe effect decoration, mostly realized using modes such as overlay film, transfers in mould at present, and direct injection molding is imitated
Marble stripe effect decoration decoration also mostly using plus spot pigment or plus natural marble particle by the way of made
It is standby.Above marble stripe effect decoration forming process complex process, cost is higher.
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of modified ABS material and preparation method
With application, it is intended to solve existing marble stripe effect ornament materials complex forming technology, the problem of cost is higher.
Technical scheme is as follows：
A kind of modified ABS material, wherein, the modified ABS material includes the synthesis main base materials of ABS and marble bar Masterbatch；
By weight, the main base materials of the synthesis ABS include following component：
Synthesize 80-85 parts of ABS resin；
10-12 parts of toughener；
1-3 parts of antioxidant；
1-3 parts of compatilizer；
By weight, the marble bar Masterbatch includes following component：
1-1.4 parts of titanium dioxide；
0.01-0.03 parts of toner；
2-4 parts of synthetic gems bar；
0.05-0.1 parts of compatilizer.
Described modified ABS material, wherein,
By weight, the main base materials of the synthesis ABS include following component：
Synthesize 83 parts of ABS resin；
10 parts of toughener；
1 part of antioxidant；
2 parts of compatilizer；
By weight, the marble bar Masterbatch includes following component：
1.2 parts of titanium dioxide；
0.01 part of toner；
2.71 parts of synthetic gems bar；
0.08 part of compatilizer.
Described modified ABS material, wherein, the synthesis ABS resin is injection grade resins, and toughener is MBS resins, is resisted
Oxygen agent is 168, and compatilizer is mandelic resin.
Described modified ABS material, wherein, the toner is formulated by red toner, yellow toner, blue toner.
Described modified ABS material, wherein, on the basis of synthetic gems bar, by weight percentage, the synthetic gems
Bar includes following component：
PC 38-40%；
PA6 28-30%；
ABS 25-30%；
Toughener 1-2%；
Compatilizer 1-2%.
As above a kind of preparation method of any described modified ABS material, wherein, including：
Step A, according to above-mentioned parts by weight each component raw material is weighed, and be well mixed；
Step B, by the raw material mixed add double screw extruder in, by melting, granulation, pelletizing obtain modified ABS material.
The preparation method of described modified ABS material, wherein, in the step A, each component raw material weighed is added at a high speed
Mixed 5 ~ 8 minutes in batch mixer.
The preparation method of described modified ABS material, wherein, in the step B, the parameter in the double screw extruder
Control is as follows：
Each area's temperature is respectively set to：One 180 ° -190 ° of area, two 245 ° -255 ° of areas, three 250 ° -260 ° of areas, four 250 ° of areas -
260 °, five 250 ° -260 ° of areas, six 250 ° -260 ° of areas, seven 250 ° -260 ° of areas, eight 250 ° -260 ° of areas, nine 250 ° -260 ° of areas, ten
250 ° -260 ° of area；245 ° -255 ° of die head temperature.
The preparation method of described modified ABS material, wherein, in the step B, it is cut into particle diameter changing for 0.1-0.2mm
Property ABS material.
As above a kind of application of any described modified ABS material, wherein, the modified ABS material is used as parian
The ornament materials of stripe effect.
Beneficial effect：The present invention substitutes traditional natural marble particle using synthetic gems bar, effectively reduces tradition imitative
The manufacturing cost of the plastic decorating part of marble stripe effect decoration.In addition, the titanium dioxide in component can make final product
Highlight marble stripe effect.
Embodiment
The invention provides a kind of modified ABS material and preparation method and application, to make the purpose of the present invention, technical scheme
And effect is clearer, clear and definite, the present invention is described in more detail below.It should be appreciated that specific implementation described herein
Example is not intended to limit the present invention only to explain the present invention.
The invention provides a kind of modified ABS material, wherein, the modified ABS material includes the synthesis main base materials of ABS and cloud
Stone bar Masterbatch；
By weight, the main base materials of the synthesis ABS include following component：
Synthesize 80-85 parts of ABS resin；
10-12 parts of toughener；
1-3 parts of antioxidant；
1-3 parts of compatilizer；
By weight, the marble bar Masterbatch includes following component：
1-1.4 parts of titanium dioxide；
0.01-0.03 parts of toner；
2-4 parts of synthetic gems bar；
0.05-0.1 parts of compatilizer.
The invention provides a kind of modified ABS material with marble stripe effect outward appearance, the modified ABS material bag
Component one and component two are included, wherein component one is the synthesis main base materials of ABS, and component two is marble bar Masterbatch, corresponding by modulation
The main base materials of synthesis ABS and marble bar Masterbatch of ratio, the direct injection molding under 230 DEG C of -240 DEG C of temperature conditionss, you can obtain
There must be the parts of marble stripe effect.
The main base materials of synthesis ABS of the present invention are made up of synthesis ABS resin, toughener, antioxidant and compatilizer.The cloud
Stone bar Masterbatch is made up of titanium dioxide, toner, synthetic gems bar and compatilizer.Wherein, the synthetic gems bar is used to modulate big
Reason stone appearance color, the titanium dioxide is used for the color for modulating marble stripe effect.
Compared with prior art, the present invention is mainly theed improvement is that：In marble bar Masterbatch, replaced using synthetic gems bar
Generation traditional natural marble particle, effectively reduces being manufactured into for the plastic decorating part that traditional parian stripe effect is decorated
This.It is another to the improvement is that：Toner in marble bar Masterbatch of the present invention is matched somebody with somebody by red toner, yellow toner, blue toner
System is formed, and specifically a variety of colors can be easily mixed, so that it is different to obtain color by adjusting the mixed proportion of toner
Marble appearance, meets users ' individualized requirement.It is another to the improvement is that：Titanium dioxide in marble bar Masterbatch of the present invention
Final product can be allowed to highlight marble stripe effect.
Specifically, on the basis of synthetic gems bar, by weight percentage, the synthetic gems bar includes following component：
PC 38-40%；
PA6 28-30%；
ABS 25-30%；
Toughener 1-2%；
Compatilizer 1-2%.
Synthetic gems bar of the present invention is formed by the modulation of PC, PA6, ABS, toughener, compatilizer and toner.Specifically,
It is to be formed by the modulation of the PC of above-mentioned percentage by weight, PA6, ABS, toughener and compatilizer.According to outward appearance demand, change toner
Consumption, adjusts the color of marble bar Masterbatch.Traditional natural marble particle is substituted using the synthetic gems bar of above-mentioned formula, can
Effectively reduce the manufacturing cost of the plastic decorating part of traditional parian stripe effect decoration.
The main base materials of synthesis ABS of the present invention are made up of synthesis ABS resin, toughener, antioxidant and compatilizer.
Specifically, the synthesis ABS resin can be conventional injection grade resins.
Specifically, the toughener can be MBS resins（The copolymer of MBS）.
The present invention adds the toughener in the synthesis main base materials of ABS, can significantly improve the impact strength of material, effectively improve material
Toughness, so as to improve the mechanical property of material.
Specifically, the antioxidant can be 168（Three (2,4- di-t-butyls) phenyl-phosphites）.The present invention is in synthesis
The antioxidant is added in the main base materials of ABS, can delay or suppress the progress of polymer oxidizing process, so as to prevent the old of polymer
Change, and extend its service life.
Specifically, the compatilizer can be mandelic resin（The copolymer of phenylethylene-maleic anhydride）.The present invention exists
The compatilizer is added in the synthesis main base materials of ABS, incompatible component can be promoted to be combined together, so that the blending stablized
Thing.
Modified ABS material of the present invention, with the difference of toner ratio in the marble bar Masterbatch of addition, and is presented different
Color effects, corresponding modified ABS material can be specifically customized according to demand, then directly carry out Plastic Forming processing.
Present invention also offers the preparation method of a kind of as above any described modified ABS material, including：
Step A, according to above-mentioned parts by weight each component raw material is weighed, and be well mixed.
In the step A, by the synthesis ABS resin, toughener, antioxidant, compatilizer, titanium dioxide, toner and the conjunction that weigh
High speed mixer high speed is added into jade bar to mix 5 ~ 8 minutes.
Step B, by the raw material mixed add double screw extruder in, by melting, granulation, pelletizing obtain modified ABS
Material.
In the step B, the raw material mixed is added in double screw extruder, after high temperature plastifying fusion, through granulation
Grinding tool extrudes fine strip shape raw material, then is quickly cut into graininess by automatic pelletizing blade, and it is 0.1-0.2mm's to be specifically cut into particle diameter
Graininess, obtains modified ABS material.
Specifically, the state modulator in the double screw extruder is as follows：, each area's temperature is respectively set to：One area 180-
190 DEG C, two 245-255 DEG C of areas, three 250-260 DEG C of areas, four 250-260 DEG C of areas, five 250-260 DEG C of areas, six 250-260 DEG C of areas,
Seven 250-260 DEG C of areas, eight 250-260 DEG C of areas, nine 250-260 DEG C of areas, ten 250-260 DEG C of areas；245-255 DEG C of die head temperature.
The above-mentioned preparation technology of the present invention is simple, and cost is low, can be widely applied to each field.
Present invention also offers the application of a kind of as above any described modified ABS material, the modified ABS material is used as
The ornament materials of parian stripe effect.Modified ABS material of the present invention, when in use, can be by injection machine at 230-240 DEG C
Direct injection molding under temperature conditionss, prepares the product with marble stripe effect outward appearance, and with gloss.Product is extensive
Applied to the decoration in engineering decorative Material Field, it is especially applicable to many in the fields such as building, automobile and household electrical appliance
The plastic decorating part of higher gears.
Below by embodiment, the present invention is described in detail.
Embodiment
The first step：The each component in synthetic gems bar is weighed according to table 1 below, and is shaped through plastic working, strip is made.
The synthetic gems bar component of table 1.（Unit:Percentage by weight）
Second step：Marble bar Masterbatch each component is weighed according to table 2 below, and graininess is made through plastic working shaping.
The marble bar Masterbatch component of table 2.（Unit:Parts by weight）
3rd step：Modified ABS material each component is weighed according to table 3 below, and is well mixed.
The modified ABS material component of table 3.（Unit:Parts by weight）
Specifically, ABS resin, toughener, antioxidant, compatilizer and marble bar Masterbatch are added to high speed mixer high speed
Mixing 7 minutes；Then the raw material mixed is added in double screw extruder, after high temperature plastifying fusion, passes through granulation die
Fine strip shape is extruded into, 0.15mm particle is quickly cut into finally by automatic blade, product is obtained.Wherein, double screw extruder
Each area's temperature is respectively set to：One 185 DEG C of area, two 250 DEG C of areas, three 255 DEG C of areas, four 255 DEG C of areas, five 255 DEG C of areas, six areas 255
DEG C, seven 255 DEG C of areas, eight 255 DEG C of areas, nine 255 DEG C of areas, ten 255 DEG C of areas；250 DEG C of die head temperature.
Finally, the modified ABS material of acquisition is prepared with Dali by injection machine injection molding under the conditions of 235 DEG C
The product of stone stripe effect outward appearance.It is of course also possible to which the formula in table 1, table 2 and table 3, direct by all raw materials weighed
Put into high speed mixer and mix, final products are then made by twin-screw extrusion shaping and injection molding process.
In summary, the invention provides a kind of modified ABS material and preparation method and application, the present invention is beautiful using synthesis
Stone bar substitutes traditional natural marble particle, effectively reduces the system of the plastic decorating part of traditional parian stripe effect decoration
Cause this.In addition, the toner in marble bar Masterbatch of the present invention is formulated by red toner, yellow toner, blue toner, have
Body can easily mix a variety of colors, so as to obtain outside the different marble of color by adjusting the mixed proportion of toner
See, meet users ' individualized requirement.In addition, the titanium dioxide in marble bar Masterbatch of the present invention can allow final product to highlight
Go out marble stripe effect.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (10)
1. a kind of modified ABS material, it is characterised in that the modified ABS material includes the synthesis main base materials of ABS and marble bar color masterbatch
Grain；
By weight, the main base materials of the synthesis ABS include following component：
Synthesize 80-85 parts of ABS resin；
10-12 parts of toughener；
1-3 parts of antioxidant；
1-3 parts of compatilizer；
By weight, the marble bar Masterbatch includes following component：
1-1.4 parts of titanium dioxide；
0.01-0.03 parts of toner；
2-4 parts of synthetic gems bar；
0.05-0.1 parts of compatilizer.
2. modified ABS material according to claim 1, it is characterised in that
By weight, the main base materials of the synthesis ABS include following component：
Synthesize 83 parts of ABS resin；
10 parts of toughener；
1 part of antioxidant；
2 parts of compatilizer；
By weight, the marble bar Masterbatch includes following component：
1.2 parts of titanium dioxide；
0.01 part of toner；
2.71 parts of synthetic gems bar；
0.08 part of compatilizer.
3. modified ABS material according to claim 1 or 2, it is characterised in that the synthesis ABS resin is injection grade tree
Fat, toughener is MBS resins, and antioxidant is 168, and compatilizer is mandelic resin.
4. modified ABS material according to claim 1 or 2, it is characterised in that the toner is by red toner, yellow color
Powder, blue toner are formulated.
5. modified ABS material according to claim 1 or 2, it is characterised in that on the basis of synthetic gems bar, by weight
Percentages, the synthetic gems bar includes following component：
PC 38-40%；
PA6 28-30%；
ABS 25-30%；
Toughener 1-2%；
Compatilizer 1-2%.
6. a kind of preparation method of modified ABS material as described in claim 1-5 is any, it is characterised in that including：
Step A, according to above-mentioned parts by weight each component raw material is weighed, and be well mixed；
Step B, by the raw material mixed add double screw extruder in, by melting, granulation, pelletizing obtain modified ABS material.
7. the preparation method of modified ABS material according to claim 6, it is characterised in that in the step A, weigh
Each component raw material is added in high speed mixer and mixed 5 ~ 8 minutes.
8. the preparation method of modified ABS material according to claim 6, it is characterised in that in the step B, described double
State modulator in screw extruder is as follows：
Each area's temperature is respectively set to：One 180 ° -190 ° of area, two 245 ° -255 ° of areas, three 250 ° -260 ° of areas, four 250 ° of areas -
260 °, five 250 ° -260 ° of areas, six 250 ° -260 ° of areas, seven 250 ° -260 ° of areas, eight 250 ° -260 ° of areas, nine 250 ° -260 ° of areas, ten
250 ° -260 ° of area；245 ° -255 ° of die head temperature.
9. the preparation method of modified ABS material according to claim 6, it is characterised in that in the step B, be cut into grain
Footpath is 0.1-0.2mm modified ABS material.
10. a kind of application of modified ABS material as described in claim 1-5 is any, it is characterised in that the modified ABS material
Ornament materials of the material as parian stripe effect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710453285.8A CN107163491B (en) | 2017-06-15 | 2017-06-15 | Modified ABS material, preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710453285.8A CN107163491B (en) | 2017-06-15 | 2017-06-15 | Modified ABS material, preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107163491A true CN107163491A (en) | 2017-09-15 |
| CN107163491B CN107163491B (en) | 2020-01-14 |
Family
ID=59819702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710453285.8A Active CN107163491B (en) | 2017-06-15 | 2017-06-15 | Modified ABS material, preparation method and application |
Country Status (1)
| Country | Link |
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| CN (1) | CN107163491B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11140259A (en) * | 1997-11-10 | 1999-05-25 | Toagosei Co Ltd | Vinyl chloride-based resin composition and production of molded product comprising the same |
| JP2002194223A (en) * | 2000-12-27 | 2002-07-10 | Setsunan Kasei Kk | Process for producing resin molding having woodgrain pattern |
| CN101085839A (en) * | 2007-06-18 | 2007-12-12 | 俞善锋 | Artificial cobble and manufacturing method thereof |
| CN105255093A (en) * | 2015-11-03 | 2016-01-20 | 四川长虹电器股份有限公司 | Marble-imitated ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
| CN105482351A (en) * | 2015-11-30 | 2016-04-13 | 四川长虹电器股份有限公司 | ABS material with marble imitation decorative effect and preparation method thereof |
-
2017
- 2017-06-15 CN CN201710453285.8A patent/CN107163491B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11140259A (en) * | 1997-11-10 | 1999-05-25 | Toagosei Co Ltd | Vinyl chloride-based resin composition and production of molded product comprising the same |
| JP2002194223A (en) * | 2000-12-27 | 2002-07-10 | Setsunan Kasei Kk | Process for producing resin molding having woodgrain pattern |
| CN101085839A (en) * | 2007-06-18 | 2007-12-12 | 俞善锋 | Artificial cobble and manufacturing method thereof |
| CN105255093A (en) * | 2015-11-03 | 2016-01-20 | 四川长虹电器股份有限公司 | Marble-imitated ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
| CN105482351A (en) * | 2015-11-30 | 2016-04-13 | 四川长虹电器股份有限公司 | ABS material with marble imitation decorative effect and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN107163491B (en) | 2020-01-14 |
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