CN107142792A - A kind of wallpaper with antibacterial functions and preparation method thereof - Google Patents

A kind of wallpaper with antibacterial functions and preparation method thereof Download PDF

Info

Publication number
CN107142792A
CN107142792A CN201710467733.XA CN201710467733A CN107142792A CN 107142792 A CN107142792 A CN 107142792A CN 201710467733 A CN201710467733 A CN 201710467733A CN 107142792 A CN107142792 A CN 107142792A
Authority
CN
China
Prior art keywords
parts
wallpaper
protective layer
antibacterial functions
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710467733.XA
Other languages
Chinese (zh)
Inventor
俞克波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Still Decoration Engineering Co Ltd
Original Assignee
Hefei Still Decoration Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Still Decoration Engineering Co Ltd filed Critical Hefei Still Decoration Engineering Co Ltd
Priority to CN201710467733.XA priority Critical patent/CN107142792A/en
Publication of CN107142792A publication Critical patent/CN107142792A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/30—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/02—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with cellulose derivatives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001—Modification of pulp properties
    • D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
    • D21C9/004—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001—Modification of pulp properties
    • D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
    • D21C9/005—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001—Modification of pulp properties
    • D21C9/007—Modification of pulp properties by mechanical or physical means
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/52—Cellulose; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/54—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • D21H21/24—Surfactants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38—Corrosion-inhibiting agents or anti-oxidants
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/10—Particulate form, e.g. powder, granule
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/02—Properties of the materials having acoustical properties
    • D06N2209/025—Insulating, sound absorber
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/143—Inert, i.e. inert to chemical degradation, corrosion resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/165—Odour absorbing, deodorizing ability
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1692—Weather resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/06—Building materials
    • D06N2211/066—Floor coverings
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E04F2290/041—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against noise

Abstract

The invention discloses a kind of wallpaper with antibacterial functions and preparation method thereof, it is related in technical field of wallpaper, including basic unit, basic unit and coats layer protective layer, protective layer is provided with absorbed layer.The present invention has preferable antibacterial bacteriostatic and goes peculiar smell effect, and preparation method is simple, and Environmental Safety is easy to process, in addition, useful life longevity is strong, colour-fast, efflorescence, peeling etc., scrubbing resistance, be easy to arrange, decorative applications effect is good.

Description

A kind of wallpaper with antibacterial functions and preparation method thereof
Technical field
The present invention relates to technical field of wallpaper, and in particular to a kind of wallpaper with antibacterial functions and preparation method thereof.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of quite extensive house decorative material of application.Because wallpaper has color many A variety of other house decorative materials such as sample, pattern are abundant, luxurious style, safety and environmental protection, easy construction, affordable can not compare The characteristics of plan.
Current wallpaper is generally common coating paper, and wallpaper is largely used to the interior decorations such as house, office, hotel now, with Obtain certain decorative effect.But wallpaper is the same with other ornament materials, continued to develop with the development of World Economics culture Change.The use of different times wallpaper is local economic development level, new material, the body of popular consumer psychology composite factor It is existing.Continuous improvement with people's living standard and to quality of life requirement, environment-friendly type, health type, the wallpaper of Mobyneb Increasingly paid close attention to by people.People also want to wallpaper while obtaining certain aesthetic feeling when using wallpaper can be with anti- The functions such as fire, antistatic, purification air, sterilization, humidity regulation.At present, special antibacterial and deodouring wallpaper lacks very much on the market, The performance comparision of wallpaper this respect is poor.
The content of the invention
It is an object of the invention to provide a kind of wallpaper with antibacterial functions and preparation method thereof, with the suppression of preferable antibacterial Bacterium and peculiar smell effect is gone, preparation method is simple, Environmental Safety.
The invention provides following technical scheme：In a kind of wallpaper with antibacterial functions, including basic unit, the basic unit Layer protective layer is coated, protective layer is provided with absorbed layer；
The protective layer includes the raw material that following part is counted：Modified 45 ~ 47 parts of bamboo pulp fiber, 35 ~ 40 parts of diatomite, green tea powder 25 ~ 27 parts, it is 23 ~ 24 parts of ethanol, 18 ~ 19 parts of glycerine, 15 ~ 16 parts of sepiolite, 13 ~ 15 parts of nitrocellulose, 11 ~ 12 parts of starch, inorganic 8 ~ 9 parts of filler, 6 ~ 8 parts of thickener, 5 ~ 6 parts of water-loss reducer, 3 ~ 5 parts of plasticizer, 2 ~ 3 parts of antioxidant, 2 ~ 3 parts of mould inhibitor, fire retardant 1 ~ 2 parts and 100 ~ 125 parts of water；
The absorbed layer includes the raw material that following part is counted：28 ~ 32 parts of nano-particle, 25 ~ 26 parts of oleic acid, 23 ~ 24 parts of polyvinyl alcohol, 5 ~ 8 parts of 10 ~ 12 parts of surfactant and corrosion inhibitor.
Preferably, the basic unit is in hanging raw stock, pure paper, non-woven paper, non-woven fabrics, pure cotton cloth, chemical fabric and blended cloth It is any.
Preferably, the modified bamboo pulp fiber includes the raw material that following part is counted：20 ~ 25 parts of bamboo pulp fiber, chitosan 15 ~ 17 55 ~ 65 parts of part, 12 ~ 13 parts of sericin, 45 ~ 55 parts of hydrogenperoxide steam generator and sodium periodate solution.
Preferably, the preparation method of the modified bamboo pulp fiber is：Bamboo pulp fiber is weighed to add in sodium periodate solution, with 200~300r/min rotating speed stirs 10~20min, then adds acid solution and adjusts to neutrality, sequentially adds chitosan, silk gum Albumen and hydrogenperoxide steam generator, ultrasonically treated 1 ~ 2h, are filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo is obtained after drying Pulp fibres.
Preferably, it is described it is ultrasonically treated be in sonic oscillation instrument 1~2h of sonic oscillation, supersonic frequency be 25~35KHz, Ultrasonic power is 100~150W.
Preferably, the inorganic filler includes the raw material that following part is counted：25 ~ 27 parts of talcum powder, 23 ~ 24 parts of zeolite, wheat meal 5 ~ 8 parts of 15 ~ 17 parts of stone, 10 ~ 13 parts of mica powder and tourmaline powder.
Preferably, the thickener is the one or more in algin, Arabic gum and guar gum, and the water-loss reducer is One or more in carboxymethyl cellulose, hydroxyethyl cellulose and hydroxypropyl methyl cellulose, the plasticizer is adjacent benzene two Formic acid dibutyl ester, dioctyl phthalate, diisobutyl phthalate, dioctyl adipate, di-n-octyl sebacate and neighbour One or more in phthalic acid dinonyl, the antioxidant is 2,4-DTBP, phosphorus trioxide, pentaerythrite The mixture of ester and ethylenediamine, the mould inhibitor is ZPT, and the fire retardant is magnesium hydroxide.
Preferably, the nano-particle is nano titanium oxide, nano silicon, nano aluminium oxide and nano zine oxide In one or more, the particle diameter of the nano-particle is 45 ~ 50nm, and the corrosion inhibitor is phosphate, and the surface is lived Property agent be monoglyceride.
A kind of preparation method of the wallpaper with antibacterial functions is provided in the present invention, comprised the following steps：
（1）, according to proportioning weigh the raw material of protective layer, be put into reactor, added while stirring with 300 ~ 400r/min rotating speed Heat, heating-up temperature is 60 ~ 80 DEG C, and the heat time is 2 ~ 3h, obtains protective layer mixed solution；
（2）, according to proportioning weigh the raw material of absorbed layer, be put into another reactor, stirred with 500 ~ 600r/min rotating speed side Side is heated, and heating-up temperature is 80 ~ 90 DEG C, and the heat time is 1 ~ 2h, and be absorbed a layer mixed solution；
（3）, basic unit's machine-shaping be put into liquid nitrogen carry out quick-frozen, then will be infiltrated by quick-frozen basic unit in protective layer solution Taken out after 10 ~ 20s, carry out drying and processing, protective layer is evenly coated at base layer exterior surface；
（4）, through step（3）Even application absorbed layer solution above the protective layer of wallpaper after processing, in 80 ~ 90 DEG C of temperature 20 ~ 30min of lower drying, obtains finished product.
Beneficial effects of the present invention：With preferable antibacterial bacteriostatic and peculiar smell effect is gone, preparation method is simple, environmental protection peace Entirely, it is specific as follows：
（1）, add modified bamboo pulp fiber in the present invention, it is molten using chitosan, sericin, hydrogenperoxide steam generator and sodium metaperiodate Liquid is modified to bamboo pulp fiber so that substrate surface is produced without thalline, antibacterial bacteriostatic, plays the work of further protection basic unit With, in addition, also improve acoustical absorption heat preserving and waterproof and dampproof effect, the service life of extension wallpaper；
（2）, addition talcum powder, zeolite, medical stone and mica powder are used as inorganic filler in the present invention so that wallpaper tool of the invention There is function of heat insulation, indoor temperature can be kept, so as to reach the effect of environmental protection and energy saving；Furthermore it is also possible to play physics suction Attached effect, the tourmaline powder of addition can produce anion, the effect with purification air and removing peculiar smell；
（3）, the present invention add nano-particle in the raw material of absorbed layer, nano-particle has very strong photoredox function, It is oxidable to decompose various organic compounds and part inorganic matter, the cell membrane of bacterium and the protein of solidification virus can be destroyed, can Bacterium and decomposing organic pollutant are killed, organic pollution is resolved into free of contamination water and carbon dioxide, it is therefore, of the invention Wallpaper can effectively degrade in air and toxic and harmful gas and can effectively kill various bacteria；
（4）, the present invention protective layer raw material in diatomite content it is high, diatomite surface distributed has a pore, adsorbable, decompose air In peculiar smell, with damping, deodorization, it is heat-insulated, prevent bacterial growth and other effects；Environment will not only be polluted, can be with Improve the improvement of living environment, particularly humidity environment, greatly reduce the use of humidifier and dehumidifier, reduce the same of energy consumption When reduce living cost；
（5）, the present invention it is easy to process, useful life longevity is strong, colour-fast, efflorescence, peelings etc., scrubbing resistance, be easy to arrange, decoration is answered It is good with effect.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without In limitation the scope of the present invention.
Embodiment 1
Layer protective layer is coated in a kind of wallpaper with antibacterial functions, including basic unit, the basic unit, protective layer is provided with absorption Layer；
The protective layer includes the raw material that following part is counted：Modified 45 parts of bamboo pulp fiber, 35 parts of diatomite, 25 parts of green tea powder, ethanol 23 parts, 18 parts of glycerine, 15 parts of sepiolite, 13 parts of nitrocellulose, 11 parts of starch, 8 parts of inorganic filler, 6 parts of thickener, water-loss reducer 100 parts of 5 parts, 3 parts of plasticizer, 2 parts of antioxidant, 2 parts of mould inhibitor, 1 part of fire retardant and water；
The absorbed layer includes the raw material that following part is counted：28 parts of nano-particle, 25 parts of oleic acid, 23 parts of polyvinyl alcohol, surface-active 5 parts of 10 parts of agent and corrosion inhibitor.
Wherein, the basic unit is hanging raw stock.
Wherein, the modified bamboo pulp fiber includes the raw material that following part is counted：20 parts of bamboo pulp fiber, 15 parts of chitosan, silk gum 55 parts of protein 12 part, 45 parts of hydrogenperoxide steam generator and sodium periodate solution.
Wherein, the preparation method of the modified bamboo pulp fiber is：Bamboo pulp fiber is weighed to add in sodium periodate solution, with 200r/min rotating speed stirring 10min, then adds acid solution and adjusts to neutrality, sequentially add chitosan, sericin and mistake Hydrogen peroxide solution, ultrasonically treated 1h, is filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo pulp fiber is obtained after drying.
Wherein, it is described it is ultrasonically treated be in sonic oscillation instrument sonic oscillation 1h, supersonic frequency is 25KHz, ultrasonic power For 100W.
Wherein, the inorganic filler includes the raw material that following part is counted：25 parts of talcum powder, 23 parts of zeolite, 15 parts of medical stone, cloud 5 parts of 10 parts of female powder and tourmaline powder.
Wherein, the thickener is algin, and the water-loss reducer is carboxymethyl cellulose, and the plasticizer is O-phthalic Dibutyl phthalate, the antioxidant is the mixture of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine, institute Mould inhibitor is stated for ZPT, the fire retardant is magnesium hydroxide.
Wherein, the nano-particle is nano titanium oxide, and the particle diameter of the nano-particle is 45nm, the anti-corrosion inhibition Agent is phosphate, and the surfactant is monoglyceride.
A kind of preparation method of the wallpaper with antibacterial functions is provided in the present embodiment, comprised the following steps：
（1）, according to proportioning weigh the raw material of protective layer, be put into reactor, heated while stirring with 300r/min rotating speed, plus Hot temperature is 60 DEG C, and the heat time is 2h, obtains protective layer mixed solution；
（2）, according to proportioning weigh the raw material of absorbed layer, be put into another reactor, added while stirring with 500r/min rotating speed Heat, heating-up temperature is 80 DEG C, and the heat time is 1h, and be absorbed a layer mixed solution；
（3）, basic unit's machine-shaping be put into liquid nitrogen carry out quick-frozen, then will be infiltrated by quick-frozen basic unit in protective layer solution Taken out after 10s, carry out drying and processing, protective layer is evenly coated at base layer exterior surface；
（4）, through step（3）Even application absorbed layer solution above the protective layer of wallpaper after processing, at a temperature of 80 DEG C 20min is dried, finished product is obtained.
Embodiment 2
Layer protective layer is coated in a kind of wallpaper with antibacterial functions, including basic unit, the basic unit, protective layer is provided with absorption Layer；
The protective layer includes the raw material that following part is counted：Modified 47 parts of bamboo pulp fiber, 40 parts of diatomite, 27 parts of green tea powder, ethanol 24 parts, 19 parts of glycerine, 16 parts of sepiolite, 15 parts of nitrocellulose, 12 parts of starch, 9 parts of inorganic filler, 8 parts of thickener, water-loss reducer 125 parts of 6 parts, 5 parts of plasticizer, 3 parts of antioxidant, 3 parts of mould inhibitor, 2 parts of fire retardant and water；
The absorbed layer includes the raw material that following part is counted：32 parts of nano-particle, 26 parts of oleic acid, 24 parts of polyvinyl alcohol, surface-active 8 parts of 12 parts of agent and corrosion inhibitor.
Wherein, the basic unit is non-woven paper.
Wherein, the modified bamboo pulp fiber includes the raw material that following part is counted：25 parts of bamboo pulp fiber, 17 parts of chitosan, silk gum 65 parts of 13 parts of albumen, 55 parts of hydrogenperoxide steam generator and sodium periodate solution.
Wherein, the preparation method of the modified bamboo pulp fiber is：Bamboo pulp fiber is weighed to add in sodium periodate solution, with 300r/min rotating speed stirring 20min, then adds acid solution and adjusts to neutrality, sequentially add chitosan, sericin and mistake Hydrogen peroxide solution, ultrasonically treated 2h, is filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo pulp fiber is obtained after drying.
Wherein, it is described it is ultrasonically treated be in sonic oscillation instrument sonic oscillation 2h, supersonic frequency is 35KHz, ultrasonic power For 150W.
Wherein, the inorganic filler includes the raw material that following part is counted：27 parts of talcum powder, 24 parts of zeolite, 17 parts of medical stone, cloud 8 parts of 13 parts of female powder and tourmaline powder.
Wherein, the thickener is Arabic gum, and the water-loss reducer is hydroxyethyl cellulose, and the plasticizer is adjacent benzene two Diisobutyl formate, the antioxidant is the mixing of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine Thing, the mould inhibitor is ZPT, and the fire retardant is magnesium hydroxide.
Wherein, the nano-particle is nano silicon, and the particle diameter of the nano-particle is 50nm, the anti-corrosion inhibition Agent is phosphate, and the surfactant is monoglyceride.
A kind of preparation method of the wallpaper with antibacterial functions is provided in the present embodiment, comprised the following steps：
（1）, according to proportioning weigh the raw material of protective layer, be put into reactor, heated while stirring with 400r/min rotating speed, plus Hot temperature is 80 DEG C, and the heat time is 3h, obtains protective layer mixed solution；
（2）, according to proportioning weigh the raw material of absorbed layer, be put into another reactor, added while stirring with 600r/min rotating speed Heat, heating-up temperature is 90 DEG C, and the heat time is 2h, and be absorbed a layer mixed solution；
（3）, basic unit's machine-shaping be put into liquid nitrogen carry out quick-frozen, then will be infiltrated by quick-frozen basic unit in protective layer solution Taken out after 20s, carry out drying and processing, protective layer is evenly coated at base layer exterior surface；
（4）, through step（3）Even application absorbed layer solution above the protective layer of wallpaper after processing, at a temperature of 90 DEG C 30min is dried, finished product is obtained.
Embodiment 3
Layer protective layer is coated in a kind of wallpaper with antibacterial functions, including basic unit, the basic unit, protective layer is provided with absorption Layer；
The protective layer includes the raw material that following part is counted：Modified 46 parts of bamboo pulp fiber, 37 parts of diatomite, 26 parts of green tea powder, ethanol 23.5 parts, 18.5 parts of glycerine, 15.5 parts of sepiolite, 14 parts of nitrocellulose, 11.5 parts of starch, 8.5 parts of inorganic filler, thickener 11. parts of 7 parts, 5.5 parts of water-loss reducer, 4 parts of plasticizer, 2.5 parts of antioxidant, 2.5 parts of mould inhibitor, 1.5 parts of fire retardant and water；
The absorbed layer includes the raw material that following part is counted：30 parts of nano-particle, 25.5 parts of oleic acid, 23.5 parts of polyvinyl alcohol, surface 6.5 parts of 11 parts of activating agent and corrosion inhibitor.
Wherein, the basic unit is non-woven fabrics.
Wherein, the modified bamboo pulp fiber includes the raw material that following part is counted：22.5 parts of bamboo pulp fiber, chitosan 16 part, thread 60 parts of 12.5 parts of glue protein, 50 parts of hydrogenperoxide steam generator and sodium periodate solution.
Wherein, the preparation method of the modified bamboo pulp fiber is：Bamboo pulp fiber is weighed to add in sodium periodate solution, with 250r/min rotating speed stirring 15min, then adds acid solution and adjusts to neutrality, sequentially add chitosan, sericin and mistake Hydrogen peroxide solution, ultrasonically treated 1.5h, is filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo pulp fiber is obtained after drying.
Wherein, it is described it is ultrasonically treated be in sonic oscillation instrument sonic oscillation 1.5h, supersonic frequency is 30KHz, ultrasonic work( Rate is 125W.
Wherein, the inorganic filler includes the raw material that following part is counted：26 parts of talcum powder, 23.5 parts of zeolite, 16 parts of medical stone, 6.5 parts of 11.5 parts of mica powder and tourmaline powder.
Wherein, the thickener be guar gum, the water-loss reducer be hydroxypropyl methyl cellulose, the plasticizer for oneself two Dioctyl phthalate, the antioxidant is the mixture of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine, institute Mould inhibitor is stated for ZPT, the fire retardant is magnesium hydroxide.
Wherein, the nano-particle is nano aluminium oxide, and the particle diameter of the nano-particle is 47nm, the corrosion inhibitor For phosphate, the surfactant is monoglyceride.
A kind of preparation method of the wallpaper with antibacterial functions is provided in the present embodiment, comprised the following steps：
（1）, according to proportioning weigh the raw material of protective layer, be put into reactor, heated while stirring with 350r/min rotating speed, plus Hot temperature is 70 DEG C, and the heat time is 2.5h, obtains protective layer mixed solution；
（2）, according to proportioning weigh the raw material of absorbed layer, be put into another reactor, added while stirring with 550r/min rotating speed Heat, heating-up temperature is 85 DEG C, and the heat time is 1.5h, and be absorbed a layer mixed solution；
（3）, basic unit's machine-shaping be put into liquid nitrogen carry out quick-frozen, then will be infiltrated by quick-frozen basic unit in protective layer solution Taken out after 15s, carry out drying and processing, protective layer is evenly coated at base layer exterior surface；
（4）, through step（3）Even application absorbed layer solution above the protective layer of wallpaper after processing, at a temperature of 85 DEG C 25min is dried, finished product is obtained.
The present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, its according to The technical scheme described in foregoing embodiments can so be modified, or which part technical characteristic is equally replaced Change.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention Protection domain within.

Claims (9)

1. a kind of wallpaper with antibacterial functions, including basic unit, it is characterised in that layer protective layer is coated in the basic unit, are protected Sheath is provided with absorbed layer；
The protective layer includes the raw material that following part is counted：Modified 45 ~ 47 parts of bamboo pulp fiber, 35 ~ 40 parts of diatomite, green tea powder 25 ~ 27 parts, it is 23 ~ 24 parts of ethanol, 18 ~ 19 parts of glycerine, 15 ~ 16 parts of sepiolite, 13 ~ 15 parts of nitrocellulose, 11 ~ 12 parts of starch, inorganic 8 ~ 9 parts of filler, 6 ~ 8 parts of thickener, 5 ~ 6 parts of water-loss reducer, 3 ~ 5 parts of plasticizer, 2 ~ 3 parts of antioxidant, 2 ~ 3 parts of mould inhibitor, fire retardant 1 ~ 2 parts and 100 ~ 125 parts of water；
The absorbed layer includes the raw material that following part is counted：28 ~ 32 parts of nano-particle, 25 ~ 26 parts of oleic acid, 23 ~ 24 parts of polyvinyl alcohol, 5 ~ 8 parts of 10 ~ 12 parts of surfactant and corrosion inhibitor.
2. the wallpaper according to claim 1 with antibacterial functions, it is characterised in that the basic unit is hanging raw stock, pure Any of paper, non-woven paper, non-woven fabrics, pure cotton cloth, chemical fabric and blended cloth.
3. the wallpaper according to claim 1 with antibacterial functions, it is characterised in that the modified bamboo pulp fiber include with The raw material of lower part meter：20 ~ 25 parts of bamboo pulp fiber, 15 ~ 17 parts of chitosan, 12 ~ 13 parts of sericin, hydrogenperoxide steam generator 45 ~ 55 55 ~ 65 parts of part and sodium periodate solution.
4. the wallpaper according to claim 3 with antibacterial functions, it is characterised in that the preparation of the modified bamboo pulp fiber Method is：Weigh bamboo pulp fiber to add in sodium periodate solution, 10~20min is stirred with 200~300r/min rotating speed, then Add acid solution to adjust to neutrality, sequentially add chitosan, sericin and hydrogenperoxide steam generator, ultrasonically treated 1 ~ 2h, filtering Filter residue is obtained, filter residue is put into baking oven, the bamboo pulp fiber is obtained after drying.
5. the wallpaper according to claim 4 with antibacterial functions, it is characterised in that described ultrasonically treated to be shaken in ultrasound 1~2h of sonic oscillation in instrument is swung, supersonic frequency is 25~35KHz, and ultrasonic power is 100~150W.
6. the wallpaper according to claim 1 with antibacterial functions, it is characterised in that the inorganic filler includes following part The raw material of meter：25 ~ 27 parts of talcum powder, 23 ~ 24 parts of zeolite, 15 ~ 17 parts of medical stone, 10 ~ 13 parts of mica powder and tourmaline powder 5 ~ 8 Part.
7. the wallpaper according to claim 1 with antibacterial functions, it is characterised in that the thickener be algin, Ah The one or more in primary glue and guar gum are drawn, the water-loss reducer is carboxymethyl cellulose, hydroxyethyl cellulose and hydroxypropyl first One or more in base cellulose, the plasticizer is dibutyl phthalate, dioctyl phthalate, O-phthalic One or more in sour diisobutyl ester, dioctyl adipate, di-n-octyl sebacate and diisononyl phthalate, it is described anti- Oxygen agent is the mixture of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine, and the mould inhibitor is pyridine sulphur Ketone zinc, the fire retardant is magnesium hydroxide.
8. the wallpaper according to claim 1 with antibacterial functions, it is characterised in that the nano-particle is nano-silica Change the one or more in titanium, nano silicon, nano aluminium oxide and nano zine oxide, the particle diameter of the nano-particle is 45 ~ 50nm, the corrosion inhibitor is phosphate, and the surfactant is monoglyceride.
9. a kind of preparation method of wallpaper with antibacterial functions according to any one of claim 1 ~ 8, it is characterised in that Comprise the following steps：
（1）, according to proportioning weigh the raw material of protective layer, be put into reactor, added while stirring with 300 ~ 400r/min rotating speed Heat, heating-up temperature is 60 ~ 80 DEG C, and the heat time is 2 ~ 3h, obtains protective layer mixed solution；
（2）, according to proportioning weigh the raw material of absorbed layer, be put into another reactor, stirred with 500 ~ 600r/min rotating speed side Side is heated, and heating-up temperature is 80 ~ 90 DEG C, and the heat time is 1 ~ 2h, and be absorbed a layer mixed solution；
（3）, basic unit's machine-shaping be put into liquid nitrogen carry out quick-frozen, then will be infiltrated by quick-frozen basic unit in protective layer solution Taken out after 10 ~ 20s, carry out drying and processing, protective layer is evenly coated at base layer exterior surface；
（4）, through step（3）Even application absorbed layer solution above the protective layer of wallpaper after processing, in 80 ~ 90 DEG C of temperature 20 ~ 30min of lower drying, obtains finished product.
CN201710467733.XA 2017-06-20 2017-06-20 A kind of wallpaper with antibacterial functions and preparation method thereof Withdrawn CN107142792A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710467733.XA CN107142792A (en) 2017-06-20 2017-06-20 A kind of wallpaper with antibacterial functions and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710467733.XA CN107142792A (en) 2017-06-20 2017-06-20 A kind of wallpaper with antibacterial functions and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107142792A true CN107142792A (en) 2017-09-08

Family

ID=59782207

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710467733.XA Withdrawn CN107142792A (en) 2017-06-20 2017-06-20 A kind of wallpaper with antibacterial functions and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107142792A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107476137A (en) * 2017-09-13 2017-12-15 武汉菡美洛建筑材料有限公司 A kind of antibacterial environment protection wallpaper
CN107761467A (en) * 2017-11-17 2018-03-06 安徽银兔装饰材料有限公司 Wallpaper antiseptic and preparation method thereof
CN107905040A (en) * 2017-11-17 2018-04-13 安徽银兔装饰材料有限公司 Antibacterial wallpaper and preparation method thereof
CN108118555A (en) * 2017-12-21 2018-06-05 安徽银兔装饰材料有限公司 Possesses environmental protection wall paper of high anti-microbial property and preparation method thereof
CN108130820A (en) * 2017-12-21 2018-06-08 安徽银兔装饰材料有限公司 Has environmental protection wall paper of high anti-microbial property and preparation method thereof
CN108130793A (en) * 2017-12-21 2018-06-08 安徽银兔装饰材料有限公司 Environmental protection wall paper based on plant fiber and preparation method thereof
CN108130792A (en) * 2017-12-21 2018-06-08 安徽银兔装饰材料有限公司 Environmental protection wall paper based on plant fiber and preparation method thereof
CN108659266A (en) * 2018-05-18 2018-10-16 中国人民大学 A kind of zinc oxide/Cellulose nanocrystal composite material and preparation method and application
CN109024093A (en) * 2018-09-29 2018-12-18 佛山科学技术学院 A kind of environment-friendly antibacterial wallpaper
CN109132194A (en) * 2018-08-31 2019-01-04 平湖市景兴包装材料有限公司 A kind of package paper and preparation method thereof with sterilizing fresh-keeping function
CN109551855A (en) * 2018-11-30 2019-04-02 河南永威安防股份有限公司 A kind of photocatalysis high-pressure decorating plate and preparation method thereof
CN110438843A (en) * 2019-07-11 2019-11-12 陕西科技大学 The antibacterial varnished wall paper and preparation method of reuse paper diaper leftover pieces fiber preparation
CN111676736A (en) * 2020-05-15 2020-09-18 国投盛世承德科技股份有限公司 Multifunctional zeolite environment-friendly wallpaper and manufacturing method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109714A (en) * 1998-08-07 2000-04-18 Sanyo Chem Ind Ltd Water absorbent and its production
CN104712119A (en) * 2015-03-18 2015-06-17 江苏北台壁纸实业有限公司 Environment-friendly wallpaper
CN105544310A (en) * 2015-12-03 2016-05-04 高大元 Modified bamboo pulp fiber wallpaper preparation method
CN206220387U (en) * 2016-11-14 2017-06-06 山东中冠新材料科技有限公司 A kind of anion wall paper

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109714A (en) * 1998-08-07 2000-04-18 Sanyo Chem Ind Ltd Water absorbent and its production
CN104712119A (en) * 2015-03-18 2015-06-17 江苏北台壁纸实业有限公司 Environment-friendly wallpaper
CN105544310A (en) * 2015-12-03 2016-05-04 高大元 Modified bamboo pulp fiber wallpaper preparation method
CN206220387U (en) * 2016-11-14 2017-06-06 山东中冠新材料科技有限公司 A kind of anion wall paper

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107476137A (en) * 2017-09-13 2017-12-15 武汉菡美洛建筑材料有限公司 A kind of antibacterial environment protection wallpaper
CN107761467A (en) * 2017-11-17 2018-03-06 安徽银兔装饰材料有限公司 Wallpaper antiseptic and preparation method thereof
CN107905040A (en) * 2017-11-17 2018-04-13 安徽银兔装饰材料有限公司 Antibacterial wallpaper and preparation method thereof
CN108130792A (en) * 2017-12-21 2018-06-08 安徽银兔装饰材料有限公司 Environmental protection wall paper based on plant fiber and preparation method thereof
CN108130820A (en) * 2017-12-21 2018-06-08 安徽银兔装饰材料有限公司 Has environmental protection wall paper of high anti-microbial property and preparation method thereof
CN108130793A (en) * 2017-12-21 2018-06-08 安徽银兔装饰材料有限公司 Environmental protection wall paper based on plant fiber and preparation method thereof
CN108118555A (en) * 2017-12-21 2018-06-05 安徽银兔装饰材料有限公司 Possesses environmental protection wall paper of high anti-microbial property and preparation method thereof
CN108659266A (en) * 2018-05-18 2018-10-16 中国人民大学 A kind of zinc oxide/Cellulose nanocrystal composite material and preparation method and application
CN109132194A (en) * 2018-08-31 2019-01-04 平湖市景兴包装材料有限公司 A kind of package paper and preparation method thereof with sterilizing fresh-keeping function
CN109132194B (en) * 2018-08-31 2020-02-14 平湖市景兴包装材料有限公司 Packaging paper with antibacterial and fresh-keeping functions and preparation method thereof
CN109024093A (en) * 2018-09-29 2018-12-18 佛山科学技术学院 A kind of environment-friendly antibacterial wallpaper
CN109551855A (en) * 2018-11-30 2019-04-02 河南永威安防股份有限公司 A kind of photocatalysis high-pressure decorating plate and preparation method thereof
CN110438843A (en) * 2019-07-11 2019-11-12 陕西科技大学 The antibacterial varnished wall paper and preparation method of reuse paper diaper leftover pieces fiber preparation
CN111676736A (en) * 2020-05-15 2020-09-18 国投盛世承德科技股份有限公司 Multifunctional zeolite environment-friendly wallpaper and manufacturing method thereof

Similar Documents

Publication Publication Date Title
CN107142792A (en) A kind of wallpaper with antibacterial functions and preparation method thereof
CN105544310B (en) Modified bamboo pulp fiber wallpaper preparation method
CN102888155B (en) A kind of preparation method of clean taste environmental protection moisture adjustable antibiotic paint
CN105819752B (en) A kind of nanometer oyster shell whiting ecological functions are flat to apply coating
CN105623326B (en) A kind of nanometer oyster shell whiting ecological functions bullet applies coating
CN105176216A (en) Diatom ooze coating and preparation method thereof
CN107083124A (en) A kind of environmentally friendly diatom ooze emulsion paint and preparation method thereof
CN107288281A (en) A kind of mould-proof bacteria-removing wallpaper and preparation method
CN103755226A (en) Dry powder type ecological shell powder environment-friendly composite coating with comprehensive functions
CN104073072A (en) Nano functional ecological environmental-friendly coating
CN107236375A (en) It is a kind of effectively to purify emulsion paint of air and preparation method thereof
CN105754396A (en) Putty powder and preparing method thereof
CN108316020A (en) A kind of Environment-friendlywallpaper wallpaper and preparation method thereof of purification air
CN103589249A (en) Preparation of sound-insulation environment-friendly internal wall coating
CN106587813A (en) Multifunctional wall covering material and preparation method thereof
CN103146267B (en) The multifunctional coating of deposed polystyrene preparation energy release of trace elements negative ion
CN104893461A (en) Mildew-proof fiber coating
CN107268340A (en) A kind of environment-friendly antibacterial wallpaper and preparation method thereof
CN106752474A (en) A kind of environment-friendly materials and its manufacture method and application with expelling parasite purification function
CN105949805B (en) A kind of interior wall coating coil and preparation method thereof with air cleaning humidity conditioning function
CN108727916B (en) Antibacterial emulsion paint
CN105331232A (en) Mildew-proof fiber coating
CN108788938A (en) A kind of woodwork fungus-proof antisepsis treatment process
CN108193565A (en) A kind of preparation method of novel and multifunctional wallpaper
CN107173396A (en) A kind of nontoxic mildew resistant spraying agent and its preparation technology

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20170908