CN107129649A - A kind of 4 third fluorubber material centralizers and its production technology - Google Patents
A kind of 4 third fluorubber material centralizers and its production technology Download PDFInfo
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- CN107129649A CN107129649A CN201710295509.7A CN201710295509A CN107129649A CN 107129649 A CN107129649 A CN 107129649A CN 201710295509 A CN201710295509 A CN 201710295509A CN 107129649 A CN107129649 A CN 107129649A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
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Abstract
The present invention relates to centralizer production technology, more particularly to a kind of 4 third fluorubber material centralizers and its production technology.The centralizer raw material includes following parts by weight component：4 third 100~120 parts of fluorubber, middle 40~55 parts of particle thermal black, 3~5 parts of Triallyl isocyanurate, 1~2 part of activating agent calcium stearate, 1~2 part of ternary aliphatic acid, 1~2.5 part of vulcanizing agent two (t-butylperoxyisopropyl) benzene.The present invention is designed by the formula to elastomeric material, pass through unique process, obtaining production can be with meeting the stable rubber centralizer used of long-time, effective storage life is three times of existing centralizer, use specific binding agent and high-temperature process technique for sticking, ensure rubber situation Nian Jie with skeleton, solve moulding process bonding problem, rubber is departed from failure conditions with metallic framework and be reduced to original 10%, the centralizer can meet 175 DEG C of heatproof simultaneously, resistance to vapor, the work condition environment of resistance to oil-based media, make up this area rubber centralizer blank.
Description
Technical field
The present invention relates to centralizer production technology, more particularly to a kind of 4 third fluorubber centralizers and its production technology.
Background technology
The centralizer of underground probe type measuring instrument is used to be sleeved on the external diameter that probe type measuring instrument protects cylinder, helps
Positive device must assure that probe type measuring instrument is out-of-date in the mud stream of high temperature, high speed, high pressure, and probe type measuring instrument will not be produced
Vibrations and deformation.Existing centralizer is used as main material, resistance to height usually using nitrile rubber, hydrogenated nitrile-butadiene rubber, fluorubber
Warm corrosion-resistant, will damage, service life is short, especially for more than 6000 meters within the shorter time of going into the well by erosion
Deep mining, downhole temperature is up to 175 DEG C or so, and with high-temperature vapour and oil-based media environment, on this condition, general
Elastomeric material is more difficult to meet needs.Below common 130 DEG C of nitrile rubber temperature in use, hydrogenated nitrile-butadiene rubber temperature in use 150
Below DEG C, although fluorubber temperature in use can reach less than 200 DEG C, its poor water resistance, especially water-fast vapor permeability difference, also without
Method meets the requirement of application.Therefore, this area need one kind badly can be while meet high temperature resistant, resistance to vapor, resistance to oil machine ambient condition,
And reach the stable centralizer elastomeric material used.
The content of the invention
To make up the deficiencies in the prior art, the present invention provides a kind of 4 third fluorubber centralizers and its production technology, and this is helped
Positive device can meet 175 DEG C of heatproof, resistance to vapor, the underground work condition for the medium of resistance to oil machine simultaneously.
The present invention is adopted the following technical scheme that：A kind of 4 third fluorubber centralizers, including following parts by weight component：
4 third 100~120 parts of fluorubber, middle 40~55 parts of particle thermal black, Triallyl isocyanurate 3~5
Part, 1~2 part of activating agent calcium stearate, 1~2 part of ternary aliphatic acid, vulcanizing agent two-(t-butylperoxyisopropyl) benzene 1~
2.5 part.
It is preferred that, the rubber centralizer includes the component of following parts by weight：4 third 100~120 parts of fluorubber, middle grain
Sub- 45~50 parts of thermal black, 3~5 parts of Triallyl isocyanurate, 1~2 part of activating agent calcium stearate, ternary aliphatic acid
1~2 part, vulcanizing agent two -1~2.5 part of (t-butylperoxyisopropyl) benzene.
It is furthermore preferred that the rubber centralizer includes the component of following parts by weight：4 third 100 parts of fluorubber, middle particle
50 parts of thermal black, 5 parts of Triallyl isocyanurate, 1 part of activating agent calcium stearate, 1 part of ternary aliphatic acid, vulcanizing agent
Two-(t-butylperoxyisopropyl) 1 part of benzene.
The vulcanizing agent be anti-incipient scorch vulcanizing agent, two-(t-butylperoxyisopropyl) benzene, the anti-incipient scorch vulcanizing agent is one
Peroxide-based curing dose is planted, coordinates Triallyl isocyanurate and ternary aliphatic acid, optimal incipient scorch state can be reached.
The bonding agent that the present invention is used is phenolic resin binder, and the binding agent only reaches 250 DEG C of decomposition temperature ability
Activation point is produced, bridging action is played, makes 4 third fluorubber and metallic framework that there is firm caking property.
It is preferred that, described metallic framework material is without one kind in magnetic cast steel, titanium alloy, brass or red copper.
The cleaning agent that metallic framework cleaning of the present invention is used needs 96 DEG C of 15min bakings for trichloro ethylene after cleaning
Brushwork adhesive phenol-formaldehyde A P-5 after dry.
The production technology of above-mentioned centralizer is also claimed in the present invention, specifically includes following steps：
(1) sizing material is prepared, thickness carriage return is standby as requested；
(2) metallic framework trichloro ethylene cleaning by degreasing, sandblasting 10 minutes；
(3) metallic framework after sandblasting in step (2) is used into trichloro ethylene cleaning by degreasing once again；
(4) by the metallic framework after ungrease treatment in baking box 96 DEG C drying 15 minutes after take out；
(5) metallic framework of drying is taken out into brush binding agent AP-5, parks drying in 15 minutes after brushing at room temperature；
(6) metallic framework of binder-treatment is handled 30 minutes for 250 DEG C in baking box；
(7) metallic framework and sizing material are subjected to one step cure processing, 170~185 DEG C of vulcanizations of curing temperature in vulcanizer
20-40 minutes 10 MPas of pressure；
(8) post vulcanization is carried out, 200 DEG C of vulcanizations are raised again to after the vulcanization 1 hour of 190 DEG C of curing temperature and are taken out within 3 hours, are produced
Product.
It is preferred that, the one step cure temperature of the rubber centralizer is 170 DEG C, and cure time is 30 minutes.
The present invention, as matrix resin, because its compression set is small, is adapted to pressing from 4 third fluorubber；Four
The saturated hydrocarbyl structure of third fluorubber itself so that centralizer can be with resistance to 250 DEG C high temperature, while making the catalysis of high-temperature steam old
Change influence and be reduced to minimum, oil-based media is not invaded in centralizer, it is caused to be swelled destruction.Simultaneously based on 4 third fluorine
The rock-steady structure of rubber, makes it difficult to bond together with metallic framework, causes product easily to occur rubber and skeleton break-off.
The present invention passes through special high temperature bonding technique so that the use time of product is extended twice, and expulsion rate is reduced to original
10%.
The resistance to vapor permeability of product can be improved from calcium stearate, while adding ternary aliphatic acid improves rubber mobility.
Because the present invention uses metaideophone technique, require strict, it is necessary to adjust the composition and content of optimum cure agent for curing system, pass through
Repetition test matches 5 parts of Triallyl isocyanurate, two-(t-butylperoxyisopropyl) benzene 1 using optimum cure system
Part can reach optimal time of scorch.According to optimum cure system, it is decomposition that the present invention, which adjusts out optimum vulcanization process condition,
175 DEG C of temperature, thickness adjustment cure time is 20-40min according to needed for centralizer product.
Compared with prior art, the beneficial effects of the present invention are it is following some：
The present invention is designed by the formula to elastomeric material, by unique process, obtains production available full
The stable rubber centralizer used of sufficient long-time, effective storage life is three times of existing centralizer, using specific
Binding agent and high-temperature process technique for sticking, it is ensured that rubber situation Nian Jie with skeleton, solve moulding process bonding problem, make rubber
Depart from failure conditions with metallic framework and be reduced to original 10%, the centralizer can meet 175 DEG C of heatproof simultaneously, resistance to vapor,
The work condition environment of resistance to oil-based media, makes up this area rubber centralizer blank.
Embodiment
The present invention is described in further detail below by embodiment.
Embodiment 1
A kind of 4 third fluorubber centralizers include：4 third 100 parts of fluorubber, middle 55 parts of particle thermal black, three allyls
5 parts of base isocyanuric acid ester, 1 part of activating agent calcium stearate, 1 part of ternary aliphatic acid, vulcanizing agent two-(t-butylperoxyisopropyl)
1 part of benzene.
The preparation method of the centralizer is：
(1) sizing material is prepared according to above-mentioned raw materials composition, thickness carriage return is standby as requested；
(2) metallic framework trichloro ethylene cleaning by degreasing, sandblasting 10 minutes；
(3) metallic framework after sandblasting in step (2) is used into trichloro ethylene cleaning by degreasing once again；
(4) by the metallic framework after ungrease treatment in baking box 96 DEG C drying 15 minutes after take out；
(5) metallic framework of drying is taken out into brush binding agent AP-5, parks drying in 15 minutes after brushing at room temperature；
(6) metallic framework of binder-treatment is handled 30 minutes for 250 DEG C in baking box；
(7) metallic framework and sizing material are subjected to vulcanizing treatment, curing temperature 185 DEG C of vulcanizations, 30 minutes pressure in vulcanizer
10 MPas；
(8) post vulcanization is carried out, 200 DEG C of vulcanizations are raised again to after the vulcanization 1 hour of 190 DEG C of curing temperature and are taken out within 3 hours, are produced
Product.
Embodiment 2
A kind of 4 third fluorubber centralizers include：4 third 120 parts of fluorubber, middle 40 parts of particle thermal black, three allyls
3 parts of base isocyanuric acid ester, 2 parts of activating agent calcium stearate, 1 part of ternary aliphatic acid, vulcanizing agent two-(t-butylperoxyisopropyl)
2.5 parts of benzene.
The preparation method of the centralizer is：
(1) sizing material is prepared according to above-mentioned raw materials composition, thickness carriage return is standby as requested；
(2) metallic framework trichloro ethylene cleaning by degreasing, sandblasting 10 minutes；
(3) metallic framework after sandblasting in step (2) is used into trichloro ethylene cleaning by degreasing once again；
(4) by the metallic framework after ungrease treatment in baking box 96 DEG C drying 15 minutes after take out；
(5) metallic framework of drying is taken out into brush binding agent AP-5, parks drying in 15 minutes after brushing at room temperature；
(6) metallic framework of binder-treatment is handled 30 minutes for 250 DEG C in baking box；
(7) metallic framework and sizing material are subjected to vulcanizing treatment, curing temperature 170 DEG C of vulcanizations, 30 minutes pressure in vulcanizer
10 MPas；
(8) post vulcanization is carried out, 200 DEG C of vulcanizations are raised again to after the vulcanization 1 hour of 190 DEG C of curing temperature and are taken out within 3 hours, are produced
Product.
Embodiment 3
A kind of 4 third fluorubber centralizers include：4 third 110 parts of fluorubber, middle 45 parts of particle thermal black, three allyls
4 parts of base isocyanuric acid ester, 1 part of activating agent calcium stearate, 1 part of ternary aliphatic acid, vulcanizing agent two-(t-butylperoxyisopropyl)
2 parts of benzene.
The preparation method of the centralizer is：
(1) sizing material is prepared according to above-mentioned raw materials composition, thickness carriage return is standby as requested；
(2) metallic framework trichloro ethylene cleaning by degreasing, sandblasting 10 minutes；
(3) metallic framework after sandblasting in step (2) is used into trichloro ethylene cleaning by degreasing once again；
(4) by the metallic framework after ungrease treatment in baking box 96 DEG C drying 15 minutes after take out；
(5) metallic framework of drying is taken out into brush binding agent AP-5, parks drying in 15 minutes after brushing at room temperature；
(6) metallic framework of binder-treatment is handled 30 minutes for 250 DEG C in baking box；
(7) metallic framework and sizing material are subjected to vulcanizing treatment, curing temperature 180 DEG C of vulcanizations, 40 minutes pressure in vulcanizer
10 MPas；
(8) post vulcanization is carried out, 200 DEG C of vulcanizations are raised again to after the vulcanization 1 hour of 190 DEG C of curing temperature and are taken out within 3 hours, are produced
Product.
Embodiment 4
A kind of 4 third fluorubber centralizers include：4 third 100 parts of fluorubber, middle 50 parts of particle thermal black, three allyls
5 parts of base isocyanuric acid ester, 1 part of activating agent calcium stearate, 1 part of ternary aliphatic acid, vulcanizing agent two-(t-butylperoxyisopropyl)
1 part of benzene.
The preparation method of the centralizer is：
(1) sizing material is prepared according to above-mentioned raw materials composition, thickness carriage return is standby as requested；
(2) metallic framework trichloro ethylene cleaning by degreasing, sandblasting 10 minutes；
(3) metallic framework after sandblasting in step (2) is used into trichloro ethylene cleaning by degreasing once again；
(4) by the metallic framework after ungrease treatment in baking box 96 DEG C drying 15 minutes after take out；
(5) metallic framework of drying is taken out into brush binding agent AP-5, parks drying in 15 minutes after brushing at room temperature；
(6) metallic framework of binder-treatment is handled 30 minutes for 250 DEG C in baking box；
(7) metallic framework and sizing material are subjected to vulcanizing treatment, curing temperature 170 DEG C of vulcanizations, 30 minutes pressure in vulcanizer
10 MPas；
(8) post vulcanization is carried out, 200 DEG C of vulcanizations are raised again to after the vulcanization 1 hour of 190 DEG C of curing temperature and are taken out within 3 hours, are produced
Product.
Comparative example
Nitrile rubber 30g, antioxidant 1010 1g, anti-aging agent RD 15g are kneaded 8 minutes, add phenolic resin and mixing is made
Glue, is conventionally made rubber
The performance test results of the centralizer elastomeric material prepared in the 1-4 of the embodiment of the present invention of table 1 and comparative example
Claims (6)
1. a kind of 4 third fluorubber centralizers, it is characterised in that including following parts by weight component：
4 third 100~120 parts of fluorubber, middle 40~55 parts of particle thermal black, 3~5 parts of Triallyl isocyanurate is living
1~2 part of property agent calcium stearate, 1~2 part of ternary aliphatic acid, vulcanizing agent two -1~2.5 part of (t-butylperoxyisopropyl) benzene.
2. rubber centralizer according to claim 1, it is characterised in that include the component of following parts by weight：4 third fluorine
100~120 parts of rubber, middle 45~50 parts of particle thermal black, 3~5 parts of Triallyl isocyanurate, activating agent stearic acid
1~2 part of calcium, 1~2 part of ternary aliphatic acid, vulcanizing agent two -1~2.5 part of (t-butylperoxyisopropyl) benzene.
3. rubber centralizer according to claim 1, it is characterised in that include the component of following parts by weight：4 third fluorine
100 parts of rubber, middle 50 parts of particle thermal black, 5 parts of Triallyl isocyanurate, 1 part of activating agent calcium stearate, ternary fat
1 part of fat acid, vulcanizing agent two -1 part of (t-butylperoxyisopropyl) benzene.
4. a kind of production technology of rubber centralizer as claimed in claim 1, it is characterised in that comprise the following steps：
(1) sizing material is prepared, thickness carriage return is standby as requested；
(2) metallic framework trichloro ethylene cleaning by degreasing, sandblasting 10 minutes；
(3) metallic framework after sandblasting in step (2) is used into trichloro ethylene cleaning by degreasing once again；
(4) by the metallic framework after ungrease treatment in baking box 96 DEG C drying 15 minutes after take out；
(5) metallic framework of drying is taken out into brush binding agent AP-5, parks drying in 15 minutes after brushing at room temperature；
(6) metallic framework of binder-treatment is handled 30 minutes for 250 DEG C in baking box；
(7) metallic framework and sizing material are subjected to one step cure processing, 170~185 DEG C of vulcanization 20-40 of curing temperature in vulcanizer
10 MPas of pressure of minute；
(8) post vulcanization is carried out, 200 DEG C of vulcanizations are raised again to after the vulcanization 1 hour of 190 DEG C of curing temperature and are taken out within 3 hours, production is produced
Product.
5. production technology according to claim 4, it is characterised in that the one step cure temperature is 170~185 DEG C, sulphur
The change time is 20-40min.
6. production technology according to claim 4, it is characterised in that described metallic framework material is closed without magnetic cast steel, titanium
One kind in gold, brass or red copper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710295509.7A CN107129649A (en) | 2017-04-28 | 2017-04-28 | A kind of 4 third fluorubber material centralizers and its production technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710295509.7A CN107129649A (en) | 2017-04-28 | 2017-04-28 | A kind of 4 third fluorubber material centralizers and its production technology |
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| Publication Number | Publication Date |
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| CN107129649A true CN107129649A (en) | 2017-09-05 |
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|---|---|---|---|
| CN201710295509.7A Pending CN107129649A (en) | 2017-04-28 | 2017-04-28 | A kind of 4 third fluorubber material centralizers and its production technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113861595A (en) * | 2021-09-26 | 2021-12-31 | 昆山力普电子橡胶有限公司 | Fluorine rubber material for transfer molding, preparation method thereof and transfer molding method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN205743753U (en) * | 2016-06-06 | 2016-11-30 | 斯伦贝谢油田技术（山东）有限公司 | A kind of rubber centralizer |
-
2017
- 2017-04-28 CN CN201710295509.7A patent/CN107129649A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN205743753U (en) * | 2016-06-06 | 2016-11-30 | 斯伦贝谢油田技术（山东）有限公司 | A kind of rubber centralizer |
Non-Patent Citations (3)
| Title |
|---|
| D HULL: ""四丙氟橡胶在油田中的应用"", 《橡胶译丛》 * |
| 李振环: ""四丙氟橡胶的性能及应用"", 《机械工程材料》 * |
| 闫麦奎等: "新型随钻测井仪扶正器可靠性设计与研究", 《石油仪器》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113861595A (en) * | 2021-09-26 | 2021-12-31 | 昆山力普电子橡胶有限公司 | Fluorine rubber material for transfer molding, preparation method thereof and transfer molding method |
| CN113861595B (en) * | 2021-09-26 | 2023-02-10 | 昆山力普电子橡胶有限公司 | Fluorine rubber material for transfer molding, preparation method thereof and transfer molding method |
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Application publication date: 20170905 |