CN107119303A - Device for removing micro-arc oxidation tank liquid sediment in real time - Google Patents

Device for removing micro-arc oxidation tank liquid sediment in real time Download PDF

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Publication number
CN107119303A
CN107119303A CN201710339192.2A CN201710339192A CN107119303A CN 107119303 A CN107119303 A CN 107119303A CN 201710339192 A CN201710339192 A CN 201710339192A CN 107119303 A CN107119303 A CN 107119303A
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China
Prior art keywords
tank liquor
collection box
arc oxidation
real time
oxidation tank
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CN201710339192.2A
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Chinese (zh)
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CN107119303B (en
Inventor
王剑
何明洋
黄帅
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Xihua University
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Xihua University
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/026Anodisation with spark discharge
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/005Apparatus specially adapted for electrolytic conversion coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/06Filtering particles other than ions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention relates to a device for removing sediment, in particular to a device for removing micro-arc oxidation tank liquor sediment in real time. The utility model provides a device of real-time removal micro arc oxidation tank liquor deposit, includes: an oxidation tank, an ultrasonic generator and a cleaning circulating system; the oxidation tank is used for containing tank liquor and is used as a place for micro-arc oxidation; the ultrasonic generator is arranged at the outer bottom of the oxidation tank and used for generating ultrasonic waves to enable tank liquor sediment to float on the liquid level; the cleaning circulation system is used for removing the tank liquor sediment, and comprises: liquid inlet pipe, filter tube, filtering box, corrugated pipe, ring pipe, cooling barrel, circulating pump, and reflux pipe. The device designed by the invention can remove micro-arc oxidation bath solution sediment in real time, improve the stability of the bath solution, prolong the service life of the bath solution and ensure the uniform performance of the film layer. The apparatus according to the present invention is also suitable for anodic oxidation, chemical film formation, and electrochemical film formation.

Description

The device of differential arc oxidation tank liquor precipitation is removed in real time
Technical field
The present invention relates to the device for removing precipitation, more particularly to a kind of real-time device for removing differential arc oxidation tank liquor precipitation.
Background technology
Differential arc oxidation, also known as micro-plasma oxidation, be by changing power parameter and bath solution constituents, magnesium, aluminium, titanium and its Alloy surface arc discharge, produces TRANSIENT HIGH TEMPERATURE, its surface is formed the sufacing of layer of metal oxide ceramic layer.This film Layer has hardness height, film layer thick and corrosion resistant characteristic;Meanwhile, micro-arc oxidation process is simple, clean environment firendly, therefore in aviation boat My god, weapons manufacture and electronic industry in terms of be used widely.
However, during differential arc oxidation, that anion in tank liquor, with tank liquor can be dissolved in the form of ion is anti-for metallic element in matrix Colloidal precipitation should be formed, with the progress of oxidation, colloidal precipitation increases and occurs to sink to gather in tank liquor, makes tank liquor muddiness failure, greatly Width reduces bath life.Precipitate in the majority with amorphous state in tank liquor, it increases tank liquor viscosity;When tank liquor viscosity reaches certain journey Degree, the diffusion coefficient reduction of reactant and byproduct of reaction in tank liquor, mass transfer velocity reduction, tank liquor electrical conductivity reduction causes Stability of Bath Solution is poor, and film performance is uneven.
In view of the above-mentioned problems, solution main at present has two kinds:One is to remove precipitation by filtering, and plays certain Effect, but complicated, process-intensive, and experiment condition is simply possible to use in, it is difficult the popularization and application in large-scale production;Two be groove Stabilizer is added in liquid(Such as:Ethylenediamine tetra-acetic acid, neopelex), it is stable that the introducing of stabilizer improves tank liquor Property, but the tank liquor that is added to of stabilizer brings new ion, destroys the ion activity of former tank liquor, causes film performance not .Therefore, the problem of how timely and effective removal differential arc oxidation tank liquor precipitation is in the urgent need to address in current differential arc oxidization technique.
The content of the invention
It is an object of the invention to provide a kind of real-time device for removing differential arc oxidation tank liquor precipitation, this device can be timely The precipitation that tank liquor is produced in micro-arc oxidation process is effectively removed, the stability of tank liquor is lifted, extends the life-span of tank liquor, it is ensured that film layer Performance it is homogeneous.
The present invention solves above-mentioned technical problem by the following technical programs.
A kind of real-time device for removing differential arc oxidation tank liquor precipitation, including:
Oxidation trough, the oxidation trough is used to hold tank liquor, and the place occurred as differential arc oxidation;
Supersonic generator, the supersonic generator is placed in the outer bottom of the oxidation trough, for producing ultrasonic wave, makes tank liquor Precipitation floats on liquid level;
Cleaning circulation system, the cleaning circulation system is used to remove tank liquor precipitation.
The cleaning circulation system includes:Feed tube, screen pipe, filter collection box, bellows, ring pipe, cooling bucket, circulation Pump, return duct.
The feed tube material is acid and alkali-resistance high polymer material, and the lower end of the feed tube sets horn mouth, the loudspeaker Mouth is placed in ullage.
The screen pipe material is acid and alkali-resistance high polymer material, and the middle part of the screen pipe sets vertical isometrical phase to pass through pipe Road, the inner-walls of duct sets internal thread, for connecting the filter collection box;It is flange between the screen pipe and the feed tube Connection.
The filter collection box includes:First-level filtering collection box, two grades of filter collection boxes;The first-level filtering collection box collects on boxes with described two grades filters Portion is cylinder, and the cylindrical outer wall sets external screw thread, to connect the screen pipe;The first-level filtering collection box bottom was set Filter screen, two grades of filters collection box bottom sets pellicle;The first-level filtering collection box is respectively provided with collection with described two grades filter collection cassette bottom portions Slag plate, the collection slag plate is used to collect the precipitation after filtering;The first-level filtering collection box and the described two grades overall materials of filter collection box are equal For acid and alkali-resistance high polymer material;It is that screw thread connects between the first-level filtering collection box and two grades of filters collection box and the screen pipe Connect.
The bellows material is acid and alkali-resistance high polymer material, is connected between the bellows and the screen pipe for flange Connect, the bellows can be such that the horn mouth of the feed tube is moved in whole tank liquor liquid level.
The ring pipe material is acid and alkali-resistance high polymer material, and the ring pipe is placed in inside the cooling bucket, described cold But the gap of bucket and the ring pipe is equipped with coolant;Connected between the ring pipe and the bellows for flange.
The circulating pump is acid and alkali-resistance circulating pump, is connected between the circulating pump and the ring pipe for flange.
The return duct material is acid and alkali-resistance high polymer material, is connected between the return duct and the circulating pump for flange Connect, be welding between the side bottom of the return duct and the oxidation trough.
Brief description of the drawings
Fig. 1 is the apparatus structure schematic diagram of the real-time removal differential arc oxidation tank liquor precipitation described in embodiment.
Fig. 2 is first-level filtering collection box dimensional structure diagram.
Fig. 3 is two grades of filter collection box dimensional structure diagrams.
Fig. 4 is flange connection schematic diagram.
Wherein, 1. oxidation trough;2. supersonic generator;3. return duct;4. circulating pump;5. cool down bucket;51. annular Pipe;6. bellows;7. screen pipe;71. first-level filtering collection box;711. screen pack;72. two grades of filter collection boxes;721. pellicle; 8. flange;81. screw rod;82. nut;83. spring shim;84. flat shim;85. ring flange;86. ring washer;9. Feed tube;91. horn mouth.
Embodiment
As shown in figure 1, a kind of real-time device for removing differential arc oxidation tank liquor precipitation, including:Oxidation trough 1, ultrasonic wave occur Device 2 and cleaning circulation system.Oxidation trough 1 is used to hold tank liquor, and the place occurred as differential arc oxidation.Supersonic generator 2 The outer bottom of oxidation trough 1 is fixed on, for producing ultrasonic wave, tank liquor precipitation is floated on liquid level;Cleaning circulation system is used to remove Tank liquor is precipitated.
Cleaning circulation system includes:Feed tube 9, screen pipe 7, filter collection box, bellows 6, ring pipe 51, cooling bucket 5, circulation Pump 4, return duct 3.Under the dynamic action of circulating pump 4, tank liquor and precipitation enter feed tube 9 by horn mouth 91 in oxidation trough 1, Screen pipe 7 is flowed into, the middle part of screen pipe 7 sets vertical isometrical phase to pass through pipeline, and inner-walls of duct sets internal thread, for connecting filter collection Box, is connected between screen pipe 7 and feed tube 9 for flange 8.Filter collection box includes first-level filtering collection box 71 and two grades of filter collection boxes 72;One-level Filter collection box 71 and two grades of filter collection box 72 tops are cylinder, cylindrical outer wall setting external screw thread, to connect screen pipe 7;First-level filtering Collect box 71 bottom and screen pack 711 be set, two grades of filter collection box 72 bottoms set pellicles 721, when tank liquor flows through filter screen, carry out the Once filter, when flowing through pellicle, carry out second and filter;First-level filtering collection box 71 and two grades of filter collection box 72 bottoms are respectively provided with collection slag Plate, for collecting the precipitation after filtering;It is to be threadedly coupled between first-level filtering collection box 71 and two grades of filter collection boxes 72 and screen pipe 7, Filter collection box is taken out by rotating, so as to remove the precipitation adhered on screen pack 711, pellicle 721 and collection slag plate.Bellows 6 with Connected between screen pipe 7 for flange 8.Bellows 6 can be such that the lower end horn mouth 91 of feed tube 9 is moved in whole tank liquor liquid level.Annular Pipe 51 is placed in inside cooling bucket 5, and the gap of cooling bucket 5 and ring pipe 51 is equipped with coolant, is easy to the tank liquor cooling down flowed through; Connected between ring pipe 51 and bellows 6 for flange 8.Circulating pump 4 is acid and alkali-resistance circulating pump, is moved for needed for being provided tank liquor circulation Power, is connected between circulating pump 4 and ring pipe 51 for flange 8.Connected between return duct 3 and circulating pump 4 for flange 8, return duct 4 with It is welding between the side bottom of oxidation trough 1, tank liquor is returned in oxidation trough 1 by return duct 3, completes the filtering twice of tank liquor and follow Ring.
As shown in figure 4, the connection of flange 8 includes:Screw rod 81, nut 82, spring shim 83, flat shim 84, ring flange 85, ring Shape packing ring 86.
Preferred embodiment of the invention described in detail above.It should be appreciated that the ordinary skill of this area is without wound The property made work just can make many modifications and variations according to the design of the present invention.Therefore, all technical staff in the art Pass through the available technology of logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea Scheme, all should be determined by claims in protection domain.

Claims (9)

1. a kind of real-time device for removing differential arc oxidation tank liquor precipitation, it is characterised in that including:
Oxidation trough, the oxidation trough is used to hold tank liquor, and the place occurred as differential arc oxidation;
Supersonic generator, the supersonic generator is placed in the outer bottom of the oxidation trough, for producing ultrasonic wave, makes tank liquor Precipitation floats on liquid level;
Cleaning circulation system, the cleaning circulation system is used to remove tank liquor precipitation.
2. the device as claimed in claim 1 for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the cleaning circulation System includes:Feed tube, screen pipe, filter collection box, bellows, ring pipe, cooling bucket, circulating pump, return duct.
3. the device as claimed in claim 2 for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the feed liquor tubing Matter is acid and alkali-resistance high polymer material, and the lower end of the feed tube sets horn mouth, and the horn mouth is placed in ullage.
4. the device as claimed in claim 2 for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the filtering tubing Matter is acid and alkali-resistance high polymer material, and the middle part of the screen pipe sets vertical isometrical phase to pass through pipeline, and the inner-walls of duct sets interior Screw thread, for connecting the filter collection box;Connected between the screen pipe and the feed tube for flange.
5. the device as claimed in claim 2 for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the filter Ji Hebao Include:First-level filtering collection box, two grades of filter collection boxes;The first-level filtering collection box is cylinder with described two grades filter collection box tops, the cylinder Outer wall sets external screw thread, to connect the screen pipe;The first-level filtering collection box bottom sets screen pack, two grades of filters collection box Bottom sets pellicle;The first-level filtering collection box is respectively provided with collection slag plate with described two grades filter collection cassette bottom portions;The first-level filtering collection box It is acid and alkali-resistance high polymer material with the described two grades overall materials of filter collection box;The first-level filtering collection box and it is described two grades filter collection box with It is threaded connection between the screen pipe.
6. the device as claimed in claim 2 for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the corrugated pipe Matter is acid and alkali-resistance high polymer material, is connected between the bellows and the screen pipe for flange, and the bellows can make described The horn mouth of feed tube is moved in whole tank liquor liquid level.
7. the device as claimed in claim 2 for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the annular tubing Matter is acid and alkali-resistance high polymer material, and the ring pipe is placed in inside the cooling bucket, between the cooling bucket and the ring pipe Gap is equipped with coolant;Connected between the ring pipe and the bellows for flange.
8. the as claimed in claim 2 device for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the circulating pump is Acid and alkali-resistance circulating pump, is connected between the circulating pump and the ring pipe for flange.
9. the device as claimed in claim 2 for removing differential arc oxidation tank liquor precipitation in real time, it is characterised in that the backflow tubing Matter is acid and alkali-resistance high polymer material, is connected between the return duct and the circulating pump for flange, the return duct and the oxygen It is welding between the side bottom of change groove.
CN201710339192.2A 2017-05-15 2017-05-15 Device for removing micro-arc oxidation tank liquid sediment in real time Active CN107119303B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443486A1 (en) * 1984-11-29 1986-05-28 Dico Gesellschaft für Galvanotechnik mbH & Co KG, 4020 Mettmann Method and apparatus for speeding up the sedimentation of solids particles from a suspension
JPH05171500A (en) * 1991-12-26 1993-07-09 Fujitsu Ltd Method and device for plating
KR100753977B1 (en) * 2006-06-21 2007-08-31 동양기전 주식회사 Apparatus for recycling plating solution
CN101362208A (en) * 2008-09-24 2009-02-11 上海大学 Method for greatly reducing melting temperature of tin-base lead-free solder
CN104862769A (en) * 2015-05-16 2015-08-26 中北大学 Electroplate liquid circulating filtration system
CN204803432U (en) * 2015-05-29 2015-11-25 无锡金信表面处理有限公司 Take circulating filter apparatus's plating bath
CN205152311U (en) * 2015-12-02 2016-04-13 浙江三通金属制品有限公司 Novel plating zinc process's plating bath circulative cooling production line device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5171500B2 (en) * 2008-09-17 2013-03-27 富士重工業株式会社 Vehicle starting device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443486A1 (en) * 1984-11-29 1986-05-28 Dico Gesellschaft für Galvanotechnik mbH & Co KG, 4020 Mettmann Method and apparatus for speeding up the sedimentation of solids particles from a suspension
JPH05171500A (en) * 1991-12-26 1993-07-09 Fujitsu Ltd Method and device for plating
KR100753977B1 (en) * 2006-06-21 2007-08-31 동양기전 주식회사 Apparatus for recycling plating solution
CN101362208A (en) * 2008-09-24 2009-02-11 上海大学 Method for greatly reducing melting temperature of tin-base lead-free solder
CN104862769A (en) * 2015-05-16 2015-08-26 中北大学 Electroplate liquid circulating filtration system
CN204803432U (en) * 2015-05-29 2015-11-25 无锡金信表面处理有限公司 Take circulating filter apparatus's plating bath
CN205152311U (en) * 2015-12-02 2016-04-13 浙江三通金属制品有限公司 Novel plating zinc process's plating bath circulative cooling production line device

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
袁亚 等: "试验次数对AZ91D镁合金微弧氧化的影响", 《新技术新工艺》 *

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