CN107118632A - It is a kind of to discharge the environmental protection coating material preparation method of anion - Google Patents

It is a kind of to discharge the environmental protection coating material preparation method of anion Download PDF

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Publication number
CN107118632A
CN107118632A CN201710484307.7A CN201710484307A CN107118632A CN 107118632 A CN107118632 A CN 107118632A CN 201710484307 A CN201710484307 A CN 201710484307A CN 107118632 A CN107118632 A CN 107118632A
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parts
coating material
anion
environmental protection
protection coating
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陈赞
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Preparation (AREA)
  • Lubricants (AREA)

Abstract

The environmental protection coating material preparation method of anion can be discharged the invention discloses a kind of, is comprised the following steps:By kaolin, coarse whiting, diatomite, rutile, far-infrared powder and negative ion powder grinding and sieving, admixed finepowder A is obtained;Admixed finepowder A and water are added in ultrasonator jointly, high-temperature oscillation is well mixed, and obtains mixed liquid B;By suspending agent, preservative, dispersant, defoamer and lubricant and ethylene glycol and ethoxy co-ground it is uniform after, obtain mixed emulsion C;Mixed liquid B and mixed emulsion C and VAE are stirred under high temperature and high speed, it is well mixed to produce required environmental protection coating material.The present invention discharges anion by adding a certain amount of negative ion powder etc. in coating, room air pollution after degraded construction, lift indoor air freshness, make indoor anion concentration up to 1000~1500/cm3, it can be promoted in national room air standard limitation using rear room air, it is applied widely, it is worthy to be popularized.

Description

It is a kind of to discharge the environmental protection coating material preparation method of anion
Technical field
The present invention relates to technical field of environmental protection paint, more particularly to a kind of it can discharge the environmental protection coating material preparation side of anion Method.
Background technology
Negative aeroion is also negative oxygen ion, refers to obtain excess electron and negatively charged oxygen ion.Anion has There is splendid purifying and dedusting, reduction second-hand-cigarette is endangered, improvement prevents breathing problem, improvement is slept, anti-oxidant, anti-aging, clear Except interior free yl, the effect of blood viscosity is reduced, with calmness, analgesia, antibechic, antipruritic, diuresis, increasing appetite, hypotensive Effect.Laudatory titles such as " tie up his oxygen " " air vitamin " " long-lived element " " air vitamins " is enjoyed in medical field anion.Than thunderous After rain, the anion of air increases, and people feel happy.And in air-conditioned room, because anion is by one in air Row air conditioning purge processing and very long ventilation shaft after almost all disappear, people wherein extended stationary periods can feel it is uncomfortable in chest, dizzy, Weak, operating efficiency and health status decline, and are referred to as " air conditioner comprehensive disease ".Small particle anion, then have good biology Activity, it is easy to pass through human body blood-brain barrier, its biological effect is played into human body.
With the continuous improvement of people's living standards, people are to the demand of everyday environments also more and more higher.Family's conduct Comfortableness and health after the most important recreating facility of people, its finishing receive people and widely paid close attention to.Generally indoor dress After repairing, room air can become unusual muddiness.Because house decoration is improper have impact on health report it is innumerable.By The ornament materials of various continuous release harmful chemicals is excessively employed when to indoor fit up in people, interior is added Ventilation condition is not good, and people lives in this environment for a long time, and body will engender various abnormal symptoms, and severe patient is even Threat to life.Based on above statement, the present invention, which is proposed, a kind of can discharge the environmental protection coating material preparation method of anion.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of of proposition can discharge anion Environmental protection coating material preparation method.
It is a kind of to discharge the environmental protection coating material preparation method of anion, comprise the following steps:
S1, preparation coating material production raw material:0.2~0.5 part of ethylene glycol, 0.2~0.5 part of ethoxy, 3~8 parts of kaolin, 10~15 parts of coarse whiting, 5~10 parts of diatomite, 8~18 parts of rutile, 1~4 part of far-infrared powder, 2~12 parts of negative ion powder, VAE10~18 part, 0.1~0.5 part of suspending agent, 0.3~0.8 part of preservative, 0.5~1 part of dispersant, defoamer 0.1~0.3 Part, 0.1~0.3 part of lubricant, 35~45 parts of water;
S2, the kaolin of the proportion, coarse whiting, diatomite, rutile, far-infrared powder and negative ion powder sequentially added Into micronizer, 275~325 mesh sieves are crossed after fully crushing, admixed finepowder A is obtained;
S3, the water of admixed finepowder A and the proportion of gained in step S2 is added in ultrasonator jointly, 85 At a high temperature of~105 DEG C, vibration is well mixed, obtains mixed liquid B;
S4, the ethylene glycol by the suspending agent of the proportion, preservative, dispersant, defoamer and lubricant and the proportion It is added to jointly in grinder with ethoxy, grinds 20~40min, is repeated after grinding 1~3 time, obtain mixed emulsion C;
S5, mixed emulsion C and the proportion VAE of gained in the mixed liquid B and step S4 of gained in step S3 is total to With in the high-speed mixer added, at a high temperature of 115~145 DEG C, with 800~1200r/min rotating speed, it is uniformly mixed Produce required environmental protection coating material.
It is preferred that, the coating material production in the step S1 is included with raw material:0.3~0.4 part of ethylene glycol, ethoxy 0.3~ 0.4 part, 4~7 parts of kaolin, 11~14 parts of coarse whiting, 6~9 parts of diatomite, 10~16 parts of rutile, 2~3 parts of far-infrared powder, 4~10 parts of negative ion powder, VAE12~16 part, 0.2~0.4 part of suspending agent, 0.4~0.7 part of preservative, dispersant 0.6~0.9 Part, 0.15~0.25 part of defoamer, 0.15~0.25 part of lubricant, 38~42 parts of water.
It is preferred that, the coating material production in the step S1 is included with raw material:0.3 part of ethylene glycol, 0.3 part of ethoxy, kaolinite 5 parts of soil, 12 parts of coarse whiting, 8 parts of diatomite, 14 parts of rutile, 2.5 parts of far-infrared powder, 8 parts of negative ion powder, VAE14 parts, suspension 0.3 part of agent, 0.5 part of preservative, 0.8 part of dispersant, 0.2 part of defoamer, 0.2 part of lubricant, 40 parts of water.
It is preferred that, the mass ratio of ethylene glycol and ethoxy is 1 in the step S1:1.
It is preferred that, the anion concentration of the environmental protection coating material is up to 1000~1500/cm3
It is proposed by the present invention it is a kind of can discharge the environmental protection coating material preparation method of anion, by adding a certain amount of in coating The release anion such as negative ion powder, the room air pollution after degraded construction lifts indoor air freshness, makes indoor negative Ion concentration is up to 1000~1500/cm3, and anion value reaches national Indoor Air Quality standards GB/T18883-2002 limitations, Prepared by the present invention can discharge the environmental protection coating material of anion, environment-friendly, and national Interior Space can be promoted to using rear room air In gas standard limitation, its preparation method is simple, and preparation cost is low, with good Negative ion disengagement and dicoration, is applicable Scope is wide, is worthy to be popularized.
Embodiment
The present invention is made with reference to specific embodiment further to explain.
Embodiment one
It is proposed by the present invention it is a kind of can discharge the environmental protection coating material preparation method of anion, comprise the following steps:
S1, preparation coating material production raw material:0.3 part of ethylene glycol, 0.3 part of ethoxy, 5 parts of kaolin, 13 parts of coarse whiting, diatom Soil 5 parts, 10 parts of rutile, 2 parts of far-infrared powder, 10 parts of negative ion powder, VAE13 parts, suspending agent 0.3, preservative 0.4 part, point 0.7 part of powder, 0.15 part of defoamer, 0.2 part of lubricant, 39 parts of water;
S2, the kaolin of the proportion, coarse whiting, diatomite, rutile, far-infrared powder and negative ion powder sequentially added Into micronizer, 325 mesh sieves are crossed after fully crushing, admixed finepowder A is obtained;
S3, the water of admixed finepowder A and the proportion of gained in step S2 is added in ultrasonator jointly, At a high temperature of 105 DEG C, vibration is well mixed, obtains mixed liquid B;
S4, the ethylene glycol by the suspending agent of the proportion, preservative, dispersant, defoamer and lubricant and the proportion It is added to jointly in grinder with ethoxy, grinds 40min, obtain mixed emulsion C;
S5, mixed emulsion C and the proportion VAE of gained in the mixed liquid B and step S4 of gained in step S3 is total to With in the high-speed mixer added, at a high temperature of 145 DEG C, with 1200r/min rotating speed, it is uniformly mixed and produces required ring Friendly coating.
Embodiment two
It is proposed by the present invention it is a kind of can discharge the environmental protection coating material preparation method of anion, comprise the following steps:
S1, preparation coating material production raw material:0.5 part of ethylene glycol, 0.5 part of ethoxy, 8 parts of kaolin, 15 parts of coarse whiting, diatom Soil 10 parts, 18 parts of rutile, 4 parts of far-infrared powder, 12 parts of negative ion powder, VAE18 parts, 0.5 part of suspending agent, 0.8 part of preservative, 1 part of dispersant, 0.3 part of defoamer, 0.3 part of lubricant, 45 parts of water;
S2, the kaolin of the proportion, coarse whiting, diatomite, rutile, far-infrared powder and negative ion powder sequentially added Into micronizer, 300 mesh sieves are crossed after fully crushing, admixed finepowder A is obtained;
S3, the water of admixed finepowder A and the proportion of gained in step S2 is added in ultrasonator jointly, At a high temperature of 100 DEG C, vibration is well mixed, obtains mixed liquid B;
S4, the ethylene glycol by the suspending agent of the proportion, preservative, dispersant, defoamer and lubricant and the proportion It is added to jointly in grinder with ethoxy, grinds 30min, is repeated after grinding 2 times, obtain mixed emulsion C;
S5, mixed emulsion C and the proportion VAE of gained in the mixed liquid B and step S4 of gained in step S3 is total to With in the high-speed mixer added, at a high temperature of 130 DEG C, with 1000r/min rotating speed, it is uniformly mixed and produces required ring Friendly coating.
Embodiment three
It is proposed by the present invention it is a kind of can discharge the environmental protection coating material preparation method of anion, comprise the following steps:
S1, preparation coating material production raw material:0.3 part of ethylene glycol, 0.3 part of ethoxy, 5 parts of kaolin, 10 parts of coarse whiting, diatom Soil 10 parts, 15 parts of rutile, 2 parts of far-infrared powder, 3 parts of negative ion powder, VAE13 parts, 0.3 part of suspending agent, 0.4 part of preservative, 0.7 part of dispersant, 0.15 part of defoamer, 0.2 part of lubricant, 39 parts of water;
S2, the kaolin of the proportion, coarse whiting, diatomite, rutile, far-infrared powder and negative ion powder sequentially added Into micronizer, 290 mesh sieves are crossed after fully crushing, admixed finepowder A is obtained;
S3, the water of admixed finepowder A and the proportion of gained in step S2 is added in ultrasonator jointly, 90 At a high temperature of DEG C, vibration is well mixed, obtains mixed liquid B;
S4, the ethylene glycol by the suspending agent of the proportion, preservative, dispersant, defoamer and lubricant and the proportion It is added to jointly in grinder with ethoxy, grinds 40min, obtain mixed emulsion C;
S5, mixed emulsion C and the proportion VAE of gained in the mixed liquid B and step S4 of gained in step S3 is total to With in the high-speed mixer added, at a high temperature of 130 DEG C, with 1000r/min rotating speed, it is uniformly mixed and produces required ring Friendly coating.
Example IV
It is proposed by the present invention it is a kind of can discharge the environmental protection coating material preparation method of anion, comprise the following steps:
S1, preparation coating material production raw material:0.2 part of ethylene glycol, 0.2 part of ethoxy, 3 parts of kaolin, 10 parts of coarse whiting, diatom Soil 5 parts, 8 parts of rutile, 1 part of far-infrared powder, 2 parts of negative ion powder, VAE10 parts, 0.1 part of suspending agent, preservative 0.3 part, point 0.5 part of powder, 0.1 part of defoamer, 0.1 part of lubricant, 35 parts of water;
S2, the kaolin of the proportion, coarse whiting, diatomite, rutile, far-infrared powder and negative ion powder sequentially added Into micronizer, 275 mesh sieves are crossed after fully crushing, admixed finepowder A is obtained;
S3, the water of admixed finepowder A and the proportion of gained in step S2 is added in ultrasonator jointly, 85 At a high temperature of DEG C, vibration is well mixed, obtains mixed liquid B;
S4, the ethylene glycol by the suspending agent of the proportion, preservative, dispersant, defoamer and lubricant and the proportion It is added to jointly in grinder with ethoxy, grinds 20min, is repeated after grinding 3 times, obtain mixed emulsion C;
S5, mixed emulsion C and the proportion VAE of gained in the mixed liquid B and step S4 of gained in step S3 is total to With in the high-speed mixer added, at a high temperature of 115 DEG C, with 800r/min rotating speed, it is uniformly mixed and produces required ring Friendly coating.
The anion concentration of the environmental protection coating material that can discharge anion prepared respectively in the test embodiment of the present invention one~tetra-, And test the anion concentration of the negative ion paint of certain commercially available brand and compare, draw following parameter:
Anion concentration (individual/cm3)
Embodiment one 1350
Embodiment two 1500
Embodiment three 1200
Example IV 1050
Control group 725
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (5)

1. a kind of can discharge the environmental protection coating material preparation method of anion, it is characterised in that comprise the following steps:
S1, preparation coating material production raw material:0.2~0.5 part of ethylene glycol, 0.2~0.5 part of ethoxy, 3~8 parts of kaolin, coarse whiting 10~15 parts, 5~10 parts of diatomite, 8~18 parts of rutile, 1~4 part of far-infrared powder, 2~12 parts of negative ion powder, VAE10~ 18 parts, 0.1~0.5 part of suspending agent, 0.3~0.8 part of preservative, 0.5~1 part of dispersant, 0.1~0.3 part of defoamer, lubricant 0.1~0.3 part, 35~45 parts of water;
S2, the kaolin of the proportion, coarse whiting, diatomite, rutile, far-infrared powder and negative ion powder be added sequentially to surpass In atomizer, 275~325 mesh sieves are crossed after fully crushing, admixed finepowder A is obtained;
S3, the water of admixed finepowder A and the proportion of gained in step S2 is added in ultrasonator jointly, 85~ At a high temperature of 105 DEG C, vibration is well mixed, obtains mixed liquid B;
S4, ethylene glycol and hydroxyl by the suspending agent of the proportion, preservative, dispersant, defoamer and lubricant and the proportion Ethyl is added in grinder jointly, grinds 20~40min, is repeated after grinding 1~3 time, is obtained mixed emulsion C;
S5, mixed emulsion C and the proportion VAE of gained in the mixed liquid B and step S4 of gained in step S3 added jointly In the high-speed mixer entered, at a high temperature of 115~145 DEG C, with 800~1200r/min rotating speed, it is uniformly mixed and produces Required environmental protection coating material.
2. a kind of the environmental protection coating material preparation method of anion can be discharged according to claim 1, it is characterised in that the step Coating material production in rapid S1 is included with raw material:0.3~0.4 part of ethylene glycol, 0.3~0.4 part of ethoxy, 4~7 parts of kaolin, again 11~14 parts of calcium, 6~9 parts of diatomite, 10~16 parts of rutile, 2~3 parts of far-infrared powder, 4~10 parts of negative ion powder, VAE12 ~16 parts, 0.2~0.4 part of suspending agent, 0.4~0.7 part of preservative, 0.6~0.9 part of dispersant, 0.15~0.25 part of defoamer, 0.15~0.25 part of lubricant, 38~42 parts of water.
3. a kind of the environmental protection coating material preparation method of anion can be discharged according to claim 1, it is characterised in that the step Coating material production in rapid S1 is included with raw material:0.3 part of ethylene glycol, 0.3 part of ethoxy, 5 parts of kaolin, 12 parts of coarse whiting, diatomite 8 Part, 14 parts of rutile, 2.5 parts of far-infrared powder, 8 parts of negative ion powder, VAE14 parts, 0.3 part of suspending agent, preservative 0.5 part, point 0.8 part of powder, 0.2 part of defoamer, 0.2 part of lubricant, 40 parts of water.
4. a kind of the environmental protection coating material preparation method of anion can be discharged according to claim 1, it is characterised in that the step The mass ratio of ethylene glycol and ethoxy is 1 in rapid S1:1.
5. a kind of the environmental protection coating material preparation method of anion can be discharged according to claim 1, it is characterised in that the ring The anion concentration of friendly coating is up to 1000~1500/cm3
CN201710484307.7A 2017-06-23 2017-06-23 It is a kind of to discharge the environmental protection coating material preparation method of anion Pending CN107118632A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110343416A (en) * 2018-04-03 2019-10-18 哈尔滨森易环保科技有限公司 A kind of environmental protection negative ion paint and its preparation method and application
CN111154406A (en) * 2020-01-12 2020-05-15 石家庄市油漆厂 Water-based environment-friendly long-acting nano-anion multifunctional ecological building coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277043A (en) * 2011-06-22 2011-12-14 嘉宝莉化工集团股份有限公司 Algae-clay air purification coating and preparation method thereof
CN103965754A (en) * 2014-05-23 2014-08-06 桑达化工(南通)有限公司 Anionic environment-friendly paint
CN104774514A (en) * 2015-04-29 2015-07-15 富思特新材料科技发展股份有限公司 Low-volatility organic compound smell removing coating capable of adsorbing and decomposing formaldehyde in air and preparation method thereof
CN106433280A (en) * 2015-08-06 2017-02-22 上海利民环保节能科技有限公司 Nanometer negative ion environmental-protection coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277043A (en) * 2011-06-22 2011-12-14 嘉宝莉化工集团股份有限公司 Algae-clay air purification coating and preparation method thereof
CN103965754A (en) * 2014-05-23 2014-08-06 桑达化工(南通)有限公司 Anionic environment-friendly paint
CN104774514A (en) * 2015-04-29 2015-07-15 富思特新材料科技发展股份有限公司 Low-volatility organic compound smell removing coating capable of adsorbing and decomposing formaldehyde in air and preparation method thereof
CN106433280A (en) * 2015-08-06 2017-02-22 上海利民环保节能科技有限公司 Nanometer negative ion environmental-protection coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110343416A (en) * 2018-04-03 2019-10-18 哈尔滨森易环保科技有限公司 A kind of environmental protection negative ion paint and its preparation method and application
CN111154406A (en) * 2020-01-12 2020-05-15 石家庄市油漆厂 Water-based environment-friendly long-acting nano-anion multifunctional ecological building coating and preparation method thereof

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Application publication date: 20170901