CN107091763B - The continuous abjection collection device of dissolved gas - Google Patents

The continuous abjection collection device of dissolved gas Download PDF

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Publication number
CN107091763B
CN107091763B CN201710531383.9A CN201710531383A CN107091763B CN 107091763 B CN107091763 B CN 107091763B CN 201710531383 A CN201710531383 A CN 201710531383A CN 107091763 B CN107091763 B CN 107091763B
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CN
China
Prior art keywords
gas
sample chamber
cylinder
piston portion
abjection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201710531383.9A
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Chinese (zh)
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CN107091763A (en
Inventor
程思海
李燕
王金莲
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GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE
Guangzhou Marine Geological Survey
Original Assignee
GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE
Guangzhou Marine Geological Survey
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Application filed by GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE, Guangzhou Marine Geological Survey filed Critical GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE
Priority to CN201710531383.9A priority Critical patent/CN107091763B/en
Publication of CN107091763A publication Critical patent/CN107091763A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2294Sampling soil gases or the like

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Soil Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

Continuous abjection and collection device the invention discloses a kind of dissolved gas, including:Hollow cylinder;The sample chamber being set in cylinder;The piston portion that can be moved back and forth in cylinder along the axis of cylinder is set to, piston portion outer diameter is adapted with cylinder internal diameter;The gas production bag being set to outside cylinder, gas production bag are connected with flowline;Gas abjection check valve and the gas collection check valve being set on sample chamber side wall;Gas abjection check valve is used for when piston portion toward during the direction movement far from the sample chamber, gas in sample chamber is delivered in the space between piston portion and sample chamber, gas collection check valve is used to, when piston portion is toward close to the movement of the direction of the sample chamber, the gas in the space between piston portion and sample chamber is delivered to by flowline in gas production bag;The supersonic generator being set in sample chamber.The present invention, which can realize, to be flowed submarine surface half the automatic continuous abjection of dissolved gas in shape deposit or seabed muddy water and collects.

Description

The continuous abjection collection device of dissolved gas
Technical field
Abjection the present invention relates to gas is used for submarine surface half with collecting device manufacturing technology field more particularly to one kind Flow the automatic continuous abjection of dissolved gas and collection device in shape deposit or seabed muddy water.
Background technology
With the continuous development of China's economic strength and science and technology, actively development Deep Sea Minerals (are such as hydrated Object, oil and natural gas etc.) investigation and marine environment investigation etc..Semi-fluid is often presented in the sediment sample on marine bottom surface layer Dynamic shape.When seabed there are natural gas, hydrate and oil when mineral reserve when or water body environment be contaminated when, the hydration in seabed The exudation of the gases such as methane, hydrogen sulfide is had in object, oil and gas deposit and eutrophic deposit, the gas of exudation is in high pressure low temperature object Under the conditions of reason, submarine surface half can be dissolved in and flowed in the deposit of shape or seabed muddy water.The type of these dissolved gas, Component, content can be that ocean gas hydrate investigation, the investigation of ocean lake environment and Marine oil and gas resource are detected and provided Fast and efficiently GEOCHEMICAL EVIDENCE has a very important significance.So dissolved gas in deposit on marine-bottom surface Abjection and collection are the bases of follow-up oceanographic survey research, oceanographic survey are studied extremely important.But since submarine surface sinks Product composition granule is thinner, more sticky, and adsorptivity is stronger, and it is difficult abjection to be dissolved in dissolved gas therein, there is no at present The means of effect can realize the automatic of from sticky, the half flowing deposit on marine-bottom surface of shape or seabed muddy water dissolved gas Continuous abjection and collection.
Invention content
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide a kind of high degree of automations for will be molten The solution device that dissolved gas is continuously deviate from and collected in deposit on marine-bottom surface or seabed muddy water.
The purpose of the present invention is realized using following technical scheme:
The continuous abjection of dissolved gas and collection device, including:Hollow cylinder;The sample being set in the cylinder Cabin, the sample chamber are closed cavity;The piston portion being set in the cylinder, the piston portion can be along the axis of the cylinder It moves back and forth, the outer diameter of the piston portion and the internal diameter of the cylinder are adapted;The gas production bag being set to outside the cylinder, it is described Gas production bag is connected with a flowline;The gas abjection check valve and gas collection being set on the sample chamber side wall are unidirectional Valve;The gas deviates from check valve, for when piston portion toward during the direction movement far from the sample chamber, by the gas in sample chamber Body is delivered in the space between piston portion and sample chamber, the gas collection check valve, for working as piston portion toward close to described During the direction movement of sample chamber, the gas in the space between piston portion and sample chamber by flowline is delivered to and is adopted In airbag;
The supersonic generator being set in the sample chamber.
Optionally, the piston portion is using motor or cylinder or Driven by Hydraulic Cylinder.
Optionally, the supersonic generator is set to the bottom of the sample chamber.
Optionally, it is provided with gas flowmeter on the flowline.
Optionally, the sample chamber is located at the bottom of the cylinder, and the piston portion is set to the top of the sample chamber.
Optionally, the gas abjection check valve and gas collection check valve are set on the roof of the sample chamber.
Optionally, the sample chamber is the closing sky being separated out in cylinder by the demarcation strip being set in the cylinder Between.
Optionally, the cylinder at least one end is blind end.
Compared with prior art, the beneficial effects of the present invention are:The present invention is placed using the sample chamber of closing dissolved with gas The deposit of body forms negative pressure of vacuum environment using the reciprocating motion of piston portion, makes the deposit in sample chamber in vacuum and surpasses Under conditions of sound wave shock, dissolved gas from the deposit of half flow regime is detached, is collected into gas production bag, it is real The abjection and collection of solution gas in existing deposit on marine-bottom surface sample, and can further be received by the way that gas flowmeter is set to measure The volume of the gas of collection, so as to calculate the volume of dissolved gas in the sediment sample of unit volume.The present invention has knot The characteristics of structure is simple, easy to operate, high degree of automation.
Description of the drawings
Fig. 1 is the structure diagram of the embodiment of the present invention.
Specific embodiment
In the following, with reference to specific embodiment, the present invention is described further.
As shown in Figure 1, the continuous abjection of the dissolved gas of the present embodiment and collection device include hollow cylinder 1, sample Cabin 2, piston portion 3, gas abjection check valve 4, gas collection check valve 5, gas production bag 6, gas flowmeter 7 and supersonic generator 8.At least one end of cylinder 1 is closing.
Sample chamber 2 is set in cylinder 1, and sample chamber 2 is closed vacuum cavity.Piston portion 3 is set in cylinder 1, sample The top in product cabin 2, the outer diameter of piston portion 3 and the internal diameter of cylinder 1 are adapted.The outer diameter of piston portion of the present invention and cylinder Internal diameter refers respectively to the external dimensions of piston portion and the inside dimension of cylinder, and when cylinder 1 is cylinder, piston portion 3 also mutually should be Circle, the outer diameter of piston portion just refer to circular outer diameter, and the internal diameter of cylinder just refers to the internal diameter of cylinder, when cylinder for square tube or During other polygon cylinders, piston portion also mutually should be rectangular or other polygons, and the outer diameter of piston portion just refers to that rectangular or other are more The external dimensions of side shape, the internal diameter of cylinder just refer to the shape of inside dimension, i.e. piston portion 3 that square tube or other polygons lead to It is identical with the shapes and sizes inside cylinder 1 with size.Piston portion 3 can be moved back and forth up and down along the axis direction of cylinder 1, piston Motor or cylinder or Driven by Hydraulic Cylinder can be used in portion 3.
Gas deviates from check valve 4 and gas collection check valve 5 is set on the roof of sample chamber 2, wherein, gas abjection is single It is set in connection sample chamber 2 and cylinder 1 between 2 roof of sample chamber and piston portion 3 in the channel in space to valve 4, gas collection Check valve 5 is set in connection cylinder 1 between 2 roof of sample chamber and piston portion 3 in the channel of space and flowline 9, gas production Another termination gas production bag 6 of pipeline 9.Gas flowmeter 7 is set on flowline 9, can be adopted to flowing through the entrance of flowline 9 The flow of the gas of airbag 6 is counted.The practical demarcation strip to be set in cylinder 1 of roof of sample chamber 2, demarcation strip is in cylinder An enclosure space is separated out in body 1 as sample chamber, its complementary space in sample chamber and cylinder is isolated.
Supersonic generator 8 is provided in sample chamber 2, the supersonic generator 8 of the present embodiment is set to sample chamber 2 Bottom, that is, the bottom of cylinder 1.Gas abjection check valve 4 is used to control gas interior to sample chamber 2 and living from sample chamber 2 Space outflow between piston part 3, gas collection check valve 5 are used to control the sky that gas can only be between sample chamber 2 and piston portion 3 Between flowed out into flowline 9.
The operation principle of the gas abjection collection device of the present invention is illustrated below:
Half flowing shape deposit is full of sample chamber 2, piston portion 3 is made to be moved to the roof of sample chamber 2, the bottom of piston portion 3 Face is closely set in the gas abjection check valve 4 of 2 roof of sample chamber and gas collection check valve 5, while gas production bag 6 is taken out very It is empty;
During work, start supersonic generator 8 first, then piston portion 3 is driven to move upwards, in piston portion 3 from sample During 2 roof of cabin moves up, one can be formed in the space below 1 inner carrier portion 3 of cylinder between 2 roof of sample chamber The environment of a negative pressure opens gas abjection check valve 4 at this time, and gas collection check valve 5 is closed, in negative pressure and ultrasound Under the action of wave, the dissolved gas in half flowing shape deposit in sample chamber 2 will be deviate from, and deviate from check valve 4 through gas It diffuses in the space of 3 lower section of piston portion;
When piston portion 3 is moved to top, during piston portion 3 moves down, gas abjection check valve 4 is closed, is beaten Gas collection check valve 5 is opened, piston portion 3 can be by the gas deviate from out of sample chamber 2 through gas collection check valve 5 and flowline 9 are expressed in gas production bag 6, and the gas flowmeter 7 being set on flowline 9 can record the gas volume of abjection;
When piston portion 3 moves down on earth, piston portion 3, which starts again at, to move up, and repeats abovementioned steps, starts next A degassing and the process of collection;When the reading of gas flowmeter 7 is not further added by, you can think in sample chamber 2 in deposit Dissolved gas is all deviate from.
Previous embodiment is vertically set with cylinder, and piston region is in the top of sample chamber, above sample bin It moves back and forth up and down, but cylinder can also be horizontally disposed, when cylinder is horizontal positioned, piston portion can be located at sample chamber Left or right side, and left and right moves back and forth in the horizontal direction.
Apparatus of the present invention can realize the company of dissolved gas in deposit in sample chamber using the reciprocating motion of piston portion Continuous abjection and collection work, high degree of automation, the constituent analysis research for subsequent dissolution gas provide basis, can be applied to ocean Sample collection in the fields such as scientific investigation, ocean water body environmental survey, marine oil and gas investigation and exploitation, before there is wide application Scape.
For those skilled in the art, technical solution that can be as described above and design are made other each Kind is corresponding to be changed and deforms, and all these change and deform the protection model that should all belong to the claims in the present invention Within enclosing.

Claims (8)

1. the continuous abjection of dissolved gas and collection device, which is characterized in that including:
Hollow cylinder;
The sample chamber being set in the cylinder, the sample chamber are closed cavity;
The piston portion being set in the cylinder, the piston portion can be moved back and forth along the axis of the cylinder, the piston portion The internal diameter of outer diameter and the cylinder be adapted;
The gas production bag being set to outside the cylinder, the gas production bag are connected with a flowline;
Gas abjection check valve and the gas collection check valve being set on the sample chamber side wall;Wherein, gas abjection is unidirectional Valve is set in connection sample chamber and cylinder between sample chamber roof and piston portion in the channel in space, and gas collection check valve is set It is placed in connection cylinder between sample chamber roof and piston portion in the channel of space and flowline;The gas abjection is unidirectional Valve, for, toward during the direction movement far from the sample chamber, the gas in sample chamber being delivered to piston portion and sample when piston portion In space between product cabin, the gas collection check valve, for when piston portion toward close to the sample chamber direction movement when, Gas in space between piston portion and sample chamber is delivered to by flowline in gas production bag;
The supersonic generator being set in the sample chamber.
2. the continuous abjection of dissolved gas according to claim 1 and collection device, it is characterised in that:The piston portion Using motor or cylinder or Driven by Hydraulic Cylinder.
3. the continuous abjection of dissolved gas according to claim 1 or 2 and collection device, it is characterised in that:It is described super Sonic generator is set to the bottom of the sample chamber.
4. the continuous abjection of dissolved gas according to claim 1 or 2 and collection device, it is characterised in that:It is described to adopt Gas flowmeter is provided in feed channel.
5. the continuous abjection of dissolved gas according to claim 1 and collection device, it is characterised in that:The sample chamber Positioned at the bottom of the cylinder, the piston portion is set to the top of the sample chamber.
6. the continuous abjection of dissolved gas according to claim 5 and collection device, it is characterised in that:The gas takes off Go out check valve and gas collection check valve is set on the roof of the sample chamber.
7. continuous abjection and the collection device of the dissolved gas according to claim 1 or 5 or 6, it is characterised in that:It is described Sample chamber is the enclosure space being separated out in cylinder by the demarcation strip being set in the cylinder.
8. the continuous abjection of dissolved gas according to claim 1 and collection device, it is characterised in that:The cylinder is extremely Rare one end is blind end.
CN201710531383.9A 2017-07-03 2017-07-03 The continuous abjection collection device of dissolved gas Expired - Fee Related CN107091763B (en)

Priority Applications (1)

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CN201710531383.9A CN107091763B (en) 2017-07-03 2017-07-03 The continuous abjection collection device of dissolved gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710531383.9A CN107091763B (en) 2017-07-03 2017-07-03 The continuous abjection collection device of dissolved gas

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CN107091763B true CN107091763B (en) 2018-06-15

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108318655B (en) * 2018-01-25 2023-09-26 广州海洋地质调查局 Liquid nitrogen frozen hydrate sample decomposition gas quantitative sampling system
CN108318100B (en) * 2018-01-25 2023-10-10 广州海洋地质调查局 System and method for measuring volume of gas released by decomposing liquid nitrogen frozen hydrate sample

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JP4311714B2 (en) * 2003-03-31 2009-08-12 西松建設株式会社 Dissolved gas detection method, dissolved gas detection device, muddy water shield method using the dissolved gas detection device, and muddy water shield machine
US7634936B2 (en) * 2006-02-17 2009-12-22 Uti Limited Partnership Method and system for sampling dissolved gas
CN102478470B (en) * 2010-11-26 2014-07-02 中国石油化工股份有限公司 Piston type vacuum degasser and its degassing method
DE102011088959B4 (en) * 2011-12-19 2022-08-04 Endress+Hauser Conducta Gmbh+Co. Kg Device for degassing a liquid and use of this device in an analysis device
CN102749228B (en) * 2012-06-18 2014-04-09 河海大学 Shallow lake greenhouse gas in-situ collection device

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Granted publication date: 20180615